CN103484075B - 一种常温无机纳米相变储能材料及其制备方法 - Google Patents
一种常温无机纳米相变储能材料及其制备方法 Download PDFInfo
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- CN103484075B CN103484075B CN201310387302.4A CN201310387302A CN103484075B CN 103484075 B CN103484075 B CN 103484075B CN 201310387302 A CN201310387302 A CN 201310387302A CN 103484075 B CN103484075 B CN 103484075B
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- energy storage
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- 238000004146 energy storage Methods 0.000 title claims abstract description 49
- 239000011232 storage material Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 20
- 239000011734 sodium Substances 0.000 claims abstract description 17
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 16
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000009413 insulation Methods 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 9
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000741 silica gel Substances 0.000 claims abstract description 7
- 229910002027 silica gel Inorganic materials 0.000 claims abstract description 7
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims abstract description 6
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims abstract description 6
- 230000009466 transformation Effects 0.000 claims abstract description 6
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 13
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 13
- 235000011152 sodium sulphate Nutrition 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 7
- 229920001971 elastomer Polymers 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 230000018044 dehydration Effects 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- 239000002775 capsule Substances 0.000 claims description 4
- 238000005191 phase separation Methods 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 238000003786 synthesis reaction Methods 0.000 claims description 3
- 239000004566 building material Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 238000004821 distillation Methods 0.000 claims description 2
- 229960004756 ethanol Drugs 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- HFCSXCKLARAMIQ-UHFFFAOYSA-L disodium;sulfate;hydrate Chemical compound O.[Na+].[Na+].[O-]S([O-])(=O)=O HFCSXCKLARAMIQ-UHFFFAOYSA-L 0.000 claims 1
- 230000008859 change Effects 0.000 abstract description 14
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 239000011162 core material Substances 0.000 abstract 2
- 239000012071 phase Substances 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 239000012074 organic phase Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
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Abstract
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CN103484075A CN103484075A (zh) | 2014-01-01 |
CN103484075B true CN103484075B (zh) | 2016-04-13 |
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Families Citing this family (4)
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CN104946210A (zh) * | 2015-07-14 | 2015-09-30 | 贵州华益能环保科技有限公司 | 一种提高十水合硫酸钠热焓值的方法 |
CN106244117A (zh) * | 2016-08-30 | 2016-12-21 | 中国矿业大学 | 一种无机水合盐相变储能微胶囊及其制备方法 |
CN109674085B (zh) * | 2017-10-18 | 2022-04-12 | 湖南中烟工业有限责任公司 | 一种用于降低卷烟主流烟气温度的储热胶囊及其制备和应用 |
CN114199058B (zh) * | 2021-11-29 | 2024-02-20 | 南方科技大学 | 一种热化学储能微胶囊及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6270836B1 (en) * | 1998-07-27 | 2001-08-07 | Frisby Technologies, Inc. | Gel-coated microcapsules |
CN1995264A (zh) * | 2006-12-06 | 2007-07-11 | 清华大学深圳研究生院 | 二氧化硅包覆相变储能材料微囊的制备方法 |
CN101029217A (zh) * | 2007-03-29 | 2007-09-05 | 上海大学 | 棕榈酸/二氧化硅纳米复合相变储能材料的制备方法 |
CN101503618A (zh) * | 2009-03-09 | 2009-08-12 | 中国科学技术大学 | 一种二氧化硅凝胶微胶囊化相变储能材料及其制备方法 |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6270836B1 (en) * | 1998-07-27 | 2001-08-07 | Frisby Technologies, Inc. | Gel-coated microcapsules |
EP1100342B1 (en) * | 1998-07-27 | 2005-02-02 | Frisby Technologies, Inc. | Gel-coated microcapsules |
CN1995264A (zh) * | 2006-12-06 | 2007-07-11 | 清华大学深圳研究生院 | 二氧化硅包覆相变储能材料微囊的制备方法 |
CN101029217A (zh) * | 2007-03-29 | 2007-09-05 | 上海大学 | 棕榈酸/二氧化硅纳米复合相变储能材料的制备方法 |
CN101503618A (zh) * | 2009-03-09 | 2009-08-12 | 中国科学技术大学 | 一种二氧化硅凝胶微胶囊化相变储能材料及其制备方法 |
Non-Patent Citations (2)
Title |
---|
10H2OSiO2 Solid Nanobowls toward Smart Heat Storage.《J. Phys. Chem. C》.2011,(第115期),第20061-20066页. * |
J. Zhang et al..In Situ Synthesis and Phase Change Properties of Na2SO4• * |
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