Summary of the invention
The invention reside in and provide a kind of waste material that utilizes to economize on resources, prevent the effective and durable stone-like coating of stone.
In order to realize the foregoing invention purpose, the invention provides a kind of stone-like coating, in described coating, each raw material and ratio of weight and number thereof are: water 100-150 part, thickening material 6-11 part, dispersion wetting agent 6-12 part, defoamer 5-9 part, sanitas 2-5 part, frostproofer 3-7 part, hydrophobizing agent 2-5 part, fluidizer 15-19 part, filler 145-175 part, third lactic acid 110-190 part, the husky 110-155 part of natural color stone, pigment 3-9 part and silane coupling agent 0.5-3 part.
In described coating, each raw material and ratio of weight and number thereof can also be preferably: water 105-135 part, thickening material 7-10 part, dispersion wetting agent 7-11 part, defoamer 6-8 part, sanitas 2-3 part, frostproofer 3-5 part, hydrophobizing agent 2-3 part, fluidizer 15-17 part, filler 151-162 part, third lactic acid 131-161 part, the husky 119-131 part of natural color stone, pigment 4-8 part and silane coupling agent 1-2 part.
In described coating, each raw material and ratio of weight and number thereof can be preferably again: 121 parts, water, 7 parts of thickening materials, disperse 1.5 parts of 8 parts of wetting agents, 7 parts of defoamers, 2.5 parts of sanitass, 4 parts of frostproofers, 2.5 parts of hydrophobizing agents, 16 parts of fluidizers, 156 parts of fillers, 145 parts of the third lactic acid, husky 125 parts of natural color stone, 4.5 parts of pigment and silane coupling agents.
Described filler is the waste material powder after the polishing of artificial quartz in lump goods, through screening, gets 800 orders-1000 purpose powder.
The composition of described filler is: unsaturated polyester resin 10-40 part, inorganic silicon material 35-98 part, toner 1-8 part, γ-mercaptopropyl trimethoxysilane 1-3 part, cobalt iso-octoate 0.5-1.2 part and methylethyl ketone peroxide 0.1-2.1 part.
Described unsaturated polyester resin is metaphenylene unsaturated polyester resin, adjacent benzene type unsaturated polyester resin, terephthalic unsaturated polyester resin, containing the adjacent benzene type unsaturated polyester resin of 10% plexiglass, containing the metaphenylene unsaturated polyester resin of 10% plexiglass, containing one or more in the terephthalic unsaturated polyester resin of 10% plexiglass.
Described thickening material is one or more in carboxylic carbonyl sodium cellulosate, sodium-chlor, wilkinite and attapulgite; Described dispersion wetting agent is phosphoric acid, silicate, how joins one or more in polyvalent alcohol-many ethyleneimines segmented copolymer, sodium oleate and sulfonate in; Described defoamer is one or more in HT-606, HT-610 and NXZ.
Described sanitas is one or both in sodium rice silver and zinc oxide; Described frostproofer is one or more in acid phosphate amine salt, alkylamine, fatty acid amide, organic acid acetic and alkyl succinimide.
Described hydrophobizing agent is the lotus leaf hydrophobizing agent; Described fluidizer is one or more in epoxy soybean oil, clorafin, adjacent benzene dicaprylate and adjacent benzene dibutyrate; Described pigment is one or both in toner or mill base.
Described silane coupling agent is one or more in methacryloxy Trimethoxy silane coupling agent, γ-isocyanic ester propyl-triethoxysilicane and γ-mercaptopropyl trimethoxysilane.
The beneficial effect that the technical scheme that the embodiment of the present invention provides is brought is: utilize the waste material powder after the polishing of synthetic quartz stoneware to make stone-like coating as filler, not only saved ample resources, and compare with traditional stone-like coating, its time of drying (surface drying), cohesive strength, water-absorbent and dynamic splitting resistance all are better than traditional product, product meets the coating property examination criteria fully, and simulated effect is good.
Embodiment
Embodiment 1
The embodiment of the present invention 1 provides a kind of stone-like coating, and in coating, each raw material and ratio of weight and number thereof are: 121 parts, water, 7 parts of thickening materials, disperse 1.5 parts of 8 parts of wetting agents, 7 parts of defoamers, 2.5 parts of sanitass, 4 parts of frostproofers, 2.5 parts of hydrophobizing agents, 16 parts of fluidizers, 156 parts of fillers, 145 parts of the third lactic acid, husky 125 parts of natural color stone, 4.5 parts of pigment and silane coupling agents.
Wherein, filler is the waste material powder after the polishing of artificial quartz in lump goods, through screening, gets 900 purpose powder; The composition of filler (being the waste material powder) is: 1.1 parts of 26 parts of unsaturated polyester resins, 69 parts of inorganic silicon materials, 4.5 parts of toners, 2 parts of γ-mercaptopropyl trimethoxysilanes, 0.8 part of cobalt iso-octoate and methylethyl ketone peroxides.
Unsaturated polyester resin is grouped into by the one-tenth of following weight percent: metaphenylene unsaturated polyester resin 31%, adjacent benzene type unsaturated polyester resin 18%, terephthalic unsaturated polyester resin 9%, containing the adjacent benzene type unsaturated polyester resin 11% of 10% plexiglass, containing the metaphenylene unsaturated polyester resin 21% of 10% plexiglass, containing the terephthalic unsaturated polyester resin 10% of 10% plexiglass.
Thickening material is grouped into by the one-tenth of following weight percent: carboxylic carbonyl sodium cellulosate 30%, sodium-chlor 27%, wilkinite 17% and attapulgite 26%; Disperse wetting agent to be grouped into by the one-tenth of following weight percent: phosphatase 11 0%, silicate 8%, how to join polyvalent alcohol-many ethyleneimines segmented copolymer 11%, sodium oleate 31% and sulfonate 40% in; Defoamer is grouped into by the one-tenth of following weight percent: 18%HT-606,23%HT-610 and 59%NXZ; Sanitas is grouped into by the one-tenth of following weight percent: 30% sodium rice silver and 70% zinc oxide; Frostproofer is grouped into by the one-tenth of following weight percent: 9% acid phosphate amine salt, 6% alkylamine, 27% fatty acid amide, 28% organic acid acetic and 30% alkyl succinimide; Hydrophobizing agent is the lotus leaf hydrophobizing agent; Fluidizer is grouped into by the one-tenth of following weight percent: epoxy soybean oil 13%, clorafin 11%, adjacent benzene dicaprylate 51% and adjacent benzene dibutyrate 25%; Pigment is grouped into by the one-tenth of following weight percent: toner 30% and mill base 70%; Silane coupling agent is grouped into by the one-tenth of following weight percent: methacryloxy Trimethoxy silane coupling agent 30%, γ-isocyanic ester propyl-triethoxysilicane 37% and γ-mercaptopropyl trimethoxysilane 33%.
Embodiment 2
The embodiment of the present invention 2 provides a kind of stone-like coating, and in coating, each raw material and ratio of weight and number thereof are: 105 parts, water, 10 parts of thickening materials, disperse 1 part of 7 parts of wetting agents, 8 parts of defoamers, 2 parts of sanitass, 5 parts of frostproofers, 2 parts of hydrophobizing agents, 15 parts of fluidizers, 151 parts of fillers, 161 parts of the third lactic acid, husky 119 parts of natural color stone, 8 parts of pigment and silane coupling agent.
Wherein, filler is the waste material powder after the polishing of artificial quartz in lump goods, through screening, gets 800 purpose powder; The composition of filler (being the waste material powder) is: 0.1 part of 10 parts of unsaturated polyester resins, 98 parts of inorganic silicon materials, 8 parts of toners, 1 part of γ-mercaptopropyl trimethoxysilane, 0.5 part of cobalt iso-octoate and methylethyl ketone peroxide; Unsaturated polyester resin is grouped into by the one-tenth of following weight percent: metaphenylene unsaturated polyester resin 12%, terephthalic unsaturated polyester resin 23%, containing the adjacent benzene type unsaturated polyester resin 37% of 10% plexiglass with containing the terephthalic unsaturated polyester resin 37% of 10% plexiglass.
Thickening material is grouped into by the one-tenth of following weight percent: sodium-chlor 12%, wilkinite 27% and attapulgite 61%; Disperse wetting agent to be grouped into by the one-tenth of following weight percent: silicate 23%, how to join polyvalent alcohol-many ethyleneimines segmented copolymer 19% and sulfonate 58% in; Defoamer is grouped into by the one-tenth of following weight percent: 71%HT-606 and 29%NXZ; Sanitas is sodium rice silver; Frostproofer is grouped into by the one-tenth of following weight percent: acid phosphate amine salt 29%, fatty acid amide 27% and alkyl succinimide 44%; Hydrophobizing agent is the lotus leaf hydrophobizing agent; Fluidizer is grouped into by the one-tenth of following weight percent: clorafin 39%, adjacent benzene dicaprylate 12% and adjacent benzene dibutyrate 49%; Pigment is toner; Silane coupling agent is grouped into by the one-tenth of following weight percent: methacryloxy Trimethoxy silane coupling agent 46% and γ-mercaptopropyl trimethoxysilane 54%.
Embodiment 3
The embodiment of the present invention 3 provides a kind of stone-like coating, and in coating, each raw material and ratio of weight and number thereof are: 135 parts, water, 7 parts of thickening materials, disperse 2 parts of 11 parts of wetting agents, 6 parts of defoamers, 3 parts of sanitass, 3 parts of frostproofers, 3 parts of hydrophobizing agents, 17 parts of fluidizers, 162 parts of fillers, 131 parts of the third lactic acid, husky 131 parts of natural color stone, 4 parts of pigment and silane coupling agents.
Wherein, filler is the waste material powder after the polishing of artificial quartz in lump goods, through screening, gets 1000 purpose powder; The composition of filler (being the waste material powder) is: 0.1 part of 40 parts of unsaturated polyester resins, 35 parts of inorganic silicon materials, 1 part of toner, 3 parts of γ-mercaptopropyl trimethoxysilanes, 1.2 parts of cobalt iso-octoates and methylethyl ketone peroxide; Unsaturated polyester resin is grouped into by the one-tenth of following weight percent: adjacent benzene type unsaturated polyester resin 34%, containing the metaphenylene unsaturated polyester resin 26% of 10% plexiglass with containing the terephthalic unsaturated polyester resin 40% of 10% plexiglass.
Thickening material is grouped into by the one-tenth of following weight percent: carboxylic carbonyl sodium cellulosate 50% and attapulgite 50%; Disperse wetting agent to be grouped into by the one-tenth of following weight percent: phosphoric acid 26% and sodium oleate 73%; Defoamer is grouped into by the one-tenth of following weight percent: 49%HT-610 and 51%NXZ; Sanitas is zinc oxide; Frostproofer is grouped into by the one-tenth of following weight percent: alkylamine 27%, organic acid acetic 38% and alkyl succinimide 35%; Hydrophobizing agent is the lotus leaf hydrophobizing agent; Fluidizer is grouped into by the one-tenth of following weight percent: epoxy soybean oil 33% and adjacent benzene dibutyrate 67%; Pigment is mill base; Silane coupling agent is grouped into by the one-tenth of following weight percent: γ-isocyanic ester propyl-triethoxysilicane 56% and γ-mercaptopropyl trimethoxysilane 44%.
Embodiment 4
The embodiment of the present invention 4 provides a kind of stone-like coating, and in coating, each raw material and ratio of weight and number thereof are: 145 parts, water, 9 parts of thickening materials, disperse 2.5 parts of 10 parts of wetting agents, 9 parts of defoamers, 4 parts of sanitass, 6 parts of frostproofers, 4 parts of hydrophobizing agents, 18 parts of fluidizers, 171 parts of fillers, 112 parts of the third lactic acid, husky 147 parts of natural color stone, 6 parts of pigment and silane coupling agents.
Wherein, filler is the waste material powder after the polishing of artificial quartz in lump goods, through screening, gets 950 purpose powder; The composition of filler (being the waste material powder) is: 2.1 parts of 17 parts of unsaturated polyester resins, 83 parts of inorganic silicon materials, 6 parts of toners, 2 parts of γ-mercaptopropyl trimethoxysilanes, 0.9 part of cobalt iso-octoate and methylethyl ketone peroxides.
Unsaturated polyester resin is grouped into by the one-tenth of following weight percent: containing the metaphenylene unsaturated polyester resin 46% of 10% plexiglass, containing the terephthalic unsaturated polyester resin 54% of 10% plexiglass; Thickening material is grouped into by the one-tenth of following weight percent: carboxylic carbonyl sodium cellulosate 25%, sodium-chlor 41% and attapulgite 34%; Disperse wetting agent to be grouped into by the one-tenth of following weight percent: how to join polyvalent alcohol-many ethyleneimines segmented copolymer 36%, sodium oleate 22% and sulfonate 42% in; Defoamer is HT-606; Sanitas is grouped into by the one-tenth of following weight percent: sodium rice silver 13% and zinc oxide 87%; Frostproofer is grouped into by the one-tenth of following weight percent: acid phosphate amine salt 23%, fatty acid amide 37% and alkyl succinimide 40%; Hydrophobizing agent is the lotus leaf hydrophobizing agent; Fluidizer is grouped into by the one-tenth of following weight percent: adjacent benzene dicaprylate 45% and adjacent benzene dibutyrate 55%; Pigment is toner; Silane coupling agent is grouped into by the one-tenth of following weight percent: methacryloxy Trimethoxy silane coupling agent 48% and γ-mercaptopropyl trimethoxysilane 52%.
Embodiment 5
The embodiment of the present invention 5 provides a kind of stone-like coating, and in coating, each raw material and ratio of weight and number thereof are: 100 parts, water, 11 parts of thickening materials, disperse 0.5 part of 12 parts of wetting agents, 9 parts of defoamers, 2 parts of sanitass, 3 parts of frostproofers, 2 parts of hydrophobizing agents, 15 parts of fluidizers, 145 parts of fillers, 190 parts of the third lactic acid, husky 110 parts of natural color stone, 3 parts of pigment and silane coupling agent.
Wherein, filler is the waste material powder after the polishing of artificial quartz in lump goods, through screening, gets 850 purpose powder; The composition of filler (being the waste material powder) is: 0.1 part of 40 parts of unsaturated polyester resins, 35 parts of inorganic silicon materials, 1 part of toner, 3 parts of γ-mercaptopropyl trimethoxysilanes, 0.5 part of cobalt iso-octoate and methylethyl ketone peroxide.
Unsaturated polyester resin is the terephthalic unsaturated polyester resin containing 10% plexiglass; Thickening material is carboxylic carbonyl sodium cellulosate; The dispersion wetting agent is sodium oleate; Defoamer is HT-606; Sanitas is sodium rice silver; Frostproofer is alkyl succinimide; Hydrophobizing agent is the lotus leaf hydrophobizing agent; Fluidizer is adjacent benzene dibutyrate 55%; Pigment is toner; Silane coupling agent is γ-mercaptopropyl trimethoxysilane.
Embodiment 6
The embodiment of the present invention 6 provides a kind of stone-like coating, and in coating, each raw material and ratio of weight and number thereof are: 150 parts, water, 6 parts of thickening materials, disperse 3 parts of 6 parts of wetting agents, 5 parts of defoamers, 5 parts of sanitass, 7 parts of frostproofers, 5 parts of hydrophobizing agents, 19 parts of fluidizers, 175 parts of fillers, 110 parts of the third lactic acid, husky 155 parts of natural color stone, 9 parts of pigment and silane coupling agents.
Wherein, filler is the waste material powder after the polishing of artificial quartz in lump goods, through screening, gets 1050 purpose powder; The composition of filler (being the waste material powder) is: 2.1 parts of 10 parts of unsaturated polyester resins, 98 parts of inorganic silicon materials, 8 parts of toners, 1 part of γ-mercaptopropyl trimethoxysilane, 1.2 parts of cobalt iso-octoates and methylethyl ketone peroxides.
Unsaturated polyester resin is the metaphenylene unsaturated polyester resin containing 10% plexiglass; Thickening material is sodium-chlor; Disperse wetting agent to join polyvalent alcohol-many ethyleneimines segmented copolymer for how in; Defoamer is HT-606; Sanitas is grouped into by the one-tenth of following weight percent: sodium rice silver 80% and zinc oxide 20%; Frostproofer is: acid phosphate amine salt; Hydrophobizing agent is the lotus leaf hydrophobizing agent; Fluidizer is adjacent benzene dicaprylate; Pigment is toner; Silane coupling agent is methacryloxy Trimethoxy silane coupling agent.
Simultaneous test
The stone-like coating of embodiment of the present invention 1-6 and traditional stone-like coating are carried out to Performance Detection, and detected result is as shown in table 1.
Table 1 Performance Detection synopsis
As can be seen from Table 1, the Performance Detection of embodiment of the present invention 1-6 stone-like coating product is all qualified, and its time of drying (surface drying), cohesive strength, water-absorbent and dynamic splitting resistance all are better than traditional product.
To sum up, with traditional stone-like coating, compare, stone-like coating of the present invention not only has advantages of environmental protection, economizes on resources, and its time of drying (surface drying), cohesive strength, water-absorbent and dynamic splitting resistance all are better than traditional product.
The foregoing is only preferred embodiment of the present invention, in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.