CN103482812B - Osmunda waste water treatment liquid as well as preparation method and application thereof - Google Patents
Osmunda waste water treatment liquid as well as preparation method and application thereof Download PDFInfo
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Abstract
The invention belongs the technical field of plant extraction and discloses an osmunda waste water treatment liquid as well as a preparation method and application thereof. The content of selenium ions in the osmunda waste water treatment liquid provided by the invention is 0.05 mg/L to 0.30 mg/L. The preparation method of the osmunda waste water treatment liquid comprises the following steps: mixing osmunda with water, heating, and collecting the liquid to obtain osmunda waste water; performing first filtering on the osmunda waste water, collecting a first filter liquor, heating the first filter liquor under the condition of 90 DEG C to 100 DEG C for 30 min to 60 min, adopting an ultrafiltration membrane with the molecular weight cutoff of 20 KDa for second filtering, collecting a second filter liquor, and concentrating to obtain the osmunda waste water treatment liquid. According to the osmunda waste water treatment liquid provided by the invention, osmunda waste water resources are fully utilized, and the preparation technology is simple; in addition, the preparation technology is rich in selenium ions and can be applied to preparation of drugs or drinks containing selenium ions.
Description
Technical field
The invention belongs to technical field of plant extraction, particularly common vetch dish wastewater treatment liquid, its preparation method and application.
Background technology
Common vetch dish, formal name used at school osmund, is Osmundaceae Osmunda per nnial herb.Common vetch dish is a kind of Specialty vegetable of integration of drinking and medicinal herbs, and tender leaf of its curling not exhibition is nutritious, containing protein, humatite matter and multivitamin, enjoys in the world the reputation of " pollution-free dish ", and delicious flavour, unique flavor, for edible top grade.In Chinese materia medica, common vetch dish is called again JapaneseFloweringFernRhizome or high pin rhizome of cyrtomium, have anti-inflammatory, antiviral, improve the effect such as immunity of organisms.So common vetch dish is one of pteridophyte that current economic worth is higher.But fresh common vetch dish is easy to aging and loses value, therefore, on market, common vetch dish is main mainly with drying processed goods, i.e. Dried Osmund.That Dried Osmund has is red, blue or green two kinds, i.e. " red dry " and " blue or green doing ".Dried Osmund is owing to being favored compared with high nutritive value, at present, the price of Dried Osmund prepared by the common vetch dish of artificial growth has reached 100 yuan of left and right of per kilogram, and the market value of Dried Osmund prepared by the wild common vetch dish 300 yuan of left and right of per kilogram of having risen, and also have the trend rising.Dried Osmund has become one of important vegetables that Chinese exports earns foreign exchange, tens thousand of kilograms of annual exported products, main exit Japan, Korea S and south east asia.
The preparation process complexity of Dried Osmund, annual May first arrival mid-June, has 4～5 days when common vetch dish germinates, and petiole is unearthed more than 18 centimetres, can gather and not stretch the tender dish of palm, if do not injured root, can continue to send out a sprouting after adopting, and can adopt every year 4～5 times.After blade volume hook, start agingly, stop plucking.The common vetch dish of gathering will be selected arrangement in time, and thickness differentiation, removes aging root, carries out the deep processing of common vetch dish, otherwise, easily form old stalk, black, rotten, rotten dish phenomenon, and cause heavy losses.At present to the deep processing of common vetch dish taking Dried Osmund as main, work flow is mainly divided into: boil boiling hot, ted, rub, toast, pick, finished product.
The first step, boils boiling hot: will be newly pluck the fresh and tender common vetch dish of returning, the boiled water pot of putting into boiling is scalded 3～4min, makes common vetch dish soft by embrittlement, is become yellowishly by viridescent, then pulls out and teds.Or employing water-boiling method, is placed in fresh and tender common vetch dish in boiled water pot and carries out poach, after cooking, heats rapidly with very hot oven, will often stir simultaneously, makes to be heated evenly, and boils common vetch dish and sends blue or green fragrance, and look bud green, picks up and drain.
Second step, teds: the common vetch dish boiling spread in time on bast mat, puts on the sunny side, ventilation airing, and when the common vetch dish tedding transfers red-purple to, the solarization another side that turns over, romaine lettuce or cross cooked food and become black, becomes waste product or substandard products.
The 3rd step, rubs: dry when tedding surface-moisture, epidermis presents wrinkle, and color becomes brown when brown, just can rub for the 1st time.While rubbing, do not overexert, note do not rub brokenly epidermis or rub disconnected, until rub water outlet.Then spread out and continue to shine, in the time that top is dry, carries out the 2nd time and rub, still to rub till water outlet divides.So rub on solarization limit, limit, makes dish shrinkage, is finally subject to uviolizing to form redness.
The 4th step, baking: the common vetch dish of airing is toasted, and will often stir, rub on baking limit, limit, carries out repeatedly, until common vetch dish is dried.
The 5th step, picks, finished product: the common vetch dish of drying is removed to thinner common vetch dish, volume head, the aging part of base portion, leave relatively thick middle portion, last finishing and packing.
Due to, common vetch dish is plucked each treatment step afterwards can affect the Quality and yield of Dried Osmund, so each step requirement is stricter.For example, scald in process boiling, require the ratio of water and dish to be preferably 3:1, dish can not surface, and every pot of water boils at most three times and just should change.So whole common vetch dish boils to scald in process and produces a large amount of waste water, is common vetch dish waste water, these waste water abandon mainly with the form of waste, and this has caused pollution to environment on the one hand, has also caused on the one hand the very large wasting of resources.
Summary of the invention
In view of this, the invention provides a kind of common vetch dish wastewater treatment liquid, its preparation method and application.This common vetch dish wastewater treatment liquid takes full advantage of common vetch dish waste water resource, and preparation technology is simple, and contains abundant plasma selenium in this common vetch dish wastewater treatment liquid, can be applied to medicine or the beverage of preparation containing plasma selenium.
In order to realize object of the present invention, the present invention adopts following technical scheme:
The invention provides a kind of common vetch dish wastewater treatment liquid, the content of its plasma selenium is 0.05mg/L～0.30mg/L.
Selenium is one of trace element of needed by human, is some antioxidases in animal and human's body, and for example the important component part of Selenoperoxidase, selenium-P albumen, plays a part balance oxidation reduction reaction in vivo.Selenium is respectfully called " kindling material of life " by domestic and international the world of medicine and nutrition educational circles, enjoys the good reputations such as " long-lived element ", " anticancer king ", " heart patron saint ", " natural toxinicide ".Clinical medicine proves, threatens 40 various diseases of human health and life all relevant with the scarce selenium of human body, as cancer, cardiovascular diseases, hepatopathy, cataract, pancreas disease, diabetes, reproductive system disease etc.At present, experimentation on animals and clinical practice have all proved that body should constantly obtain the plasma selenium of q.s from diet, as do not supplemented in time, will reduce immunity of organisms.According to statistics, 42Ge countries and regions in whole world lack selenium, in state-owned 72% area in lacking the ecotope of selenium or low selenium.It is micrograms every days 50～250 that the intake of adult's plasma selenium is recommended by Chinese Soclety of Nutrition, so common vetch dish wastewater treatment liquid provided by the invention, has fully recycled wherein abundant plasma selenium.
In some embodiments of the invention, this common vetch dish wastewater treatment liquid, also comprises:
The potassium ion of 10mg/L～50mg/L;
The calcium ion of 20mg/L～110mg/L;
The iron ion of 0.1mg/L～0.8mg/L;
The magnesium ion of 10mg/L～50mg/L;
The cupric ion of 0.2mg/L～1.5mg/L;
The vitamins C of 4mg/L～20mg/L;
And the carotene of 0.03mg/L～0.18mg/L.
Potassium belongs to human body major element, and potassium ion is one of main positively charged ion of intracellular fluid.Potassium ion, sodium ion, chlorion, these three kinds of substances maintain body fluid and approach neutrality.Meanwhile, potassium ion also contributes to neural system to convey a message.Potassium deficiency can cause myasthenia, irregular pulse etc.
Calcium is also important major element in human body, in the growth of bone and tooth, plays an important role.Meanwhile, calcium ion also participates in maintaining normal nerve conduction, and the synthetic and release of neurotransmitter and hormone.Calcium deficiency can cause osteoporosis, nervous etc.
Iron is one of trace element important in human body, and the function in human body is mainly to participate in the formation of oxyphorase and promote hematopoiesis.Iron deficiency can cause Anemia.
Magnesium is one of biological necessary nutritive element, belongs to important trace element in human body, is the active necessary metal ion of body plurality of enzymes, and utilization and the hundreds of groups of enzyme systems synthetic, fat and sugar class of protein are all played an important role.Meanwhile, magnesium ion has provide protection to nerve, can prevent and treat heart trouble.Magnesium deficiency can cause that serum calcium declines, hyperfunction, the elevation of blood pressure of neural muscle excitability, irregular pulse etc.
Copper is also one of trace element important in human body, and copper is that oxygenant is again antioxidant, and many copper-containing metal enzymes participate in vivo oxidation reduction process as oxydase.The major function of copper is the formation of participation hematopoiesis, pigment etc.Scarce copper can affect body normal development, tissue tension decline, malnutrition etc.
Vitamins C, claims again L-AA, is a kind of water-soluble vitamins, in body redox reaction, plays regulatory role.What meanwhile, vitamins C also participated in collagen protein synthesizes, promotes lymphoblastic generation etc.The C that is deficient in vitamin can cause vitamin C deficiency, hypoimmunity etc.
Carotene can be converted into Vogan-Neu and retinene in body, can prevent nyctalopia and visual deterioration.Meanwhile, carotene is also a kind of antioxidant, can in and body endoperoxides free radical, improve immunizing power.Lacking carotene can cause yctalopia, xeropthalmus, grow and be obstructed etc.
The present invention also provides a kind of preparation method of common vetch dish wastewater treatment liquid, comprises the following steps:
Common vetch dish is mixed with water, and heating, collects liquid, obtains common vetch dish waste water;
By this common vetch dish waste water, through the first filtration, collect the first filtrate, the first filtrate is heated to 30min～60min under 90 DEG C～100 DEG C conditions, adopt the ultra-filtration membrane second that molecular weight cut-off is 20KDa to filter, collect the second filtrate, concentrated, to obtain final product.
In gained common vetch dish wastewater treatment liquid, the content of plasma selenium is 0.05mg/L～0.30mg/L.
Common vetch dish, slightly poisonous, directly eat and likely can cause person poultry poisoning.After common vetch dish and water Hybrid Heating, the poisonous alkaloids of part common vetch dish is extracted, and makes to have contained poisonous alkaloids in common vetch dish waste water.The present invention adopts the first filtrate is heated to 30min～60min under 90 DEG C～100 DEG C conditions, to destroy wherein poisonous alkaloids, makes the common vetch dish wastewater treatment liquid of preparation method's gained provided by the invention can be applied to medicine or the beverage of preparation containing plasma selenium.
The present invention also provides the application of a kind of common vetch dish wastewater treatment liquid in medicine or the beverage of the anti-curing oncoma of preparation, and in this common vetch dish wastewater treatment liquid, the content of plasma selenium is 0.05mg/L～0.30mg/L, and its preparation method comprises the following steps:
Common vetch dish is mixed with water, and heating, collects liquid, obtains common vetch dish waste water;
By this common vetch dish waste water, through the first filtration, collect the first filtrate, the first filtrate is heated to 30min～60min under 90 DEG C～100 DEG C conditions, adopt the ultra-filtration membrane second that molecular weight cut-off is 20KDa to filter, collect the second filtrate, concentrated, to obtain final product.
The present invention also provides the application of a kind of common vetch dish wastewater treatment liquid in medicine or the beverage of the anti-curing cancers of preparation, and in this common vetch dish wastewater treatment liquid, the content of plasma selenium is 0.05mg/L～0.30mg/L, and its preparation method comprises the following steps:
Common vetch dish is mixed with water, and heating, collects liquid, obtains common vetch dish waste water;
By this common vetch dish waste water, through the first filtration, collect the first filtrate, the first filtrate is heated to 30min～60min under 90 DEG C～100 DEG C conditions, adopt the ultra-filtration membrane second that molecular weight cut-off is 20KDa to filter, collect the second filtrate, concentrated, to obtain final product.
In some embodiments of the invention, common vetch dish wastewater treatment liquid provided by the present invention preparation anti-curing cancers medicine or beverage in application in for cancer be mammary cancer, lung cancer, cancer of the stomach or liver cancer.
The present invention also provides a kind of beverage, and it comprises acceptable foodstuff additive in common vetch dish wastewater treatment liquid and beverage, and in this common vetch dish wastewater treatment liquid, the content of plasma selenium is 0.05mg/L～0.30mg/L, and its preparation method comprises the following steps:
Common vetch dish is mixed with water, and heating, collects liquid, obtains common vetch dish waste water;
By this common vetch dish waste water, through the first filtration, collect the first filtrate, the first filtrate is heated to 30min～60min under 90 DEG C～100 DEG C conditions, adopt the ultra-filtration membrane second that molecular weight cut-off is 20KDa to filter, collect the second filtrate, concentrated, to obtain final product.
Preferably, in this beverage, the content of plasma selenium is 0.05mg/L～0.25mg/L.
As preferably, this beverage also comprises:
The potassium ion of 5mg/L～50mg/L;
The calcium ion of 15mg/L～100mg/L;
The iron ion of 0.1mg/L～0.8mg/L;
The magnesium ion of 5mg/L～50mg/L;
The cupric ion of 0.1mg/L～1.5mg/L;
The vitamins C of 2mg/L～20mg/L;
And the carotene of 0.02mg/L～0.2mg/L.
In some embodiments of the invention, beverage provided by the invention comprises:
The plasma selenium of 0.05mg/L～0.25mg/L;
The potassium ion of 8.3mg/L～41.7mg/L;
The calcium ion of 18.2mg/L～91mg/L;
The iron ion of 0.1mg/L～0.67mg/L;
The magnesium ion of 8.3mg/L～40.9mg/L;
The cupric ion of 0.2mg/L～1.2mg/L;
The vitamins C of 3.3mg/L～16.5mg/L;
And the carotene of 0.03mg/L～0.15mg/L.
The invention provides a kind of common vetch dish wastewater treatment liquid, its preparation method and application.In this common vetch dish wastewater treatment liquid, the content of plasma selenium is 0.05mg/L～0.30mg/L.This common vetch dish wastewater treatment liquid takes full advantage of common vetch dish waste water resource, and its preparation technology is simple, and contains abundant plasma selenium, can be applied to medicine or the beverage of preparation containing plasma selenium.In beverage provided by the invention, the content of plasma selenium is 0.05mg/L～0.25mg/L.Experimental result shows, cancer patients is after oral this beverage, and serum selenium ion content is improved, and illustrates that the plasma selenium in this common vetch dish wastewater treatment liquid can be absorbed by the body, and is body supplement selenium ion, and then enhancing body immunizing power, anti-curing oncoma.
Embodiment
The invention discloses a kind of common vetch dish wastewater treatment liquid, its preparation method and application.Those skilled in the art can obtain this common vetch dish wastewater treatment liquid with reference to this paper content, realize its application, special needs to be pointed out is, all similar replacements and change apparent to those skilled in the artly, they are all deemed to be included in the present invention.Methods and applications of the present invention are described by preferred embodiment, related personnel obviously can change or suitably change and combination methods and applications herein not departing from content of the present invention, spirit and scope, realizes and apply the technology of the present invention.
In a kind of common vetch dish wastewater treatment liquid provided by the invention, its preparation method and application, reagent used and raw material all can be buied by market.
In order to make those skilled in the art can understand better technical scheme of the present invention, below in conjunction with embodiment, further set forth the present invention:
The preparation of embodiment 1 common vetch dish wastewater treatment liquid
Get the common vetch dish 20kg of new harvesting, put into 60L, the water of 90 DEG C heats 3min, collects liquid, obtains common vetch dish waste water 58L; By gained common vetch dish waste water, be the extremely clarification of filter paper filtration under diminished pressure of 2 μ m with aperture, collect filtrate in beaker; This filtrate is poured in reactor and is heated to 90 DEG C, after insulation 60min, be cooled to room temperature, filter with ultra-fine filter, selecting molecular weight cut-off is that the ultra-filtration membrane of 20KDa is to remove the impurity such as high molecular weight protein, collect filtrate, this filtrate is poured in vacuum concentration pot, concentrated 10 times, obtain 5.8L common vetch dish wastewater treatment liquid.
Use sampling Graphite Furnace Atomic Absorption spectrophotometer, utilize the characteristic wavelength light (resonance line) of the tested element being sent by light source, element to be measured is by characteristic wavelength light being produced and absorbed after atomize, calculates the content of each element in the common vetch dish waste water of gained and common vetch dish wastewater treatment liquid by measuring the size of this absorption; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 440nm, to detect the content of carotene wherein; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 254nm, to detect ascorbic content wherein.In the present embodiment, common vetch dish is placed in to water and heats the each material of common vetch dish waste water of gained and the content of the each material of common vetch dish wastewater treatment liquid in table 1.
The content of each material before and after the wastewater treatment of table 1 common vetch dish
The preparation of embodiment 2 common vetch dish wastewater treatment liquid
By the common vetch dish 20kg newly plucking, put into 60L, the water of 98 DEG C heats 3min, collects liquid, obtains common vetch dish waste water 58L; By gained common vetch dish waste water, be the extremely clarification of filter paper filtration under diminished pressure of 2 μ m with aperture, collect filtrate in beaker; This filtrate is poured in reactor and is heated to 100 DEG C, after insulation 30min, be cooled to room temperature, filter with ultra-fine filter, selecting molecular weight cut-off is that the ultra-filtration membrane of 20KDa is to remove the impurity such as high molecular weight protein, collect filtrate, this filtrate is poured in vacuum concentration pot, concentrated 5 times, obtain 11.6L common vetch dish wastewater treatment liquid.
Use sampling Graphite Furnace Atomic Absorption spectrophotometer, utilize the characteristic wavelength light (resonance line) of the tested element being sent by light source, element to be measured is by characteristic wavelength light being produced and absorbed after atomize, calculates the content of each element in the common vetch dish waste water of gained and common vetch dish wastewater treatment liquid by measuring the size of this absorption; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 440nm, to detect the content of carotene wherein; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 254nm, to detect ascorbic content wherein.In the present embodiment, common vetch dish is placed in to water and heats the each material of common vetch dish waste water of gained and the content of the each material of common vetch dish wastewater treatment liquid in table 2.
The content of each material before and after the wastewater treatment of table 2 common vetch dish
The preparation of embodiment 3 common vetch dish wastewater treatment liquid
Collect common vetch dish 20kg, put it in 60L, the water of 100 DEG C and heat 5min, collect liquid, obtain common vetch dish waste water 58L; By gained common vetch dish waste water, be the extremely clarification of filter paper filtration under diminished pressure of 2 μ m with aperture, collect filtrate in beaker; This filtrate is poured in reactor and is heated to 95 DEG C, after insulation 45min, naturally cool to room temperature, filter with ultra-fine filter, selecting molecular weight cut-off is that the ultra-filtration membrane of 20KDa is to remove the impurity such as high molecular weight protein, collect filtrate, this filtrate is poured in vacuum concentration pot, concentrated 20 times, obtain 2.9L common vetch dish wastewater treatment liquid.
Use sampling Graphite Furnace Atomic Absorption spectrophotometer, utilize the characteristic wavelength light (resonance line) of the tested element being sent by light source, element to be measured is by characteristic wavelength light being produced and absorbed after atomize, calculates the content of each element in the common vetch dish waste water of gained and common vetch dish wastewater treatment liquid by measuring the size of this absorption; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 440nm, to detect the content of carotene wherein; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 254nm, to detect ascorbic content wherein.In the present embodiment, common vetch dish is placed in to water and heats the each material of common vetch dish waste water of gained and the content of the each material of common vetch dish wastewater treatment liquid in table 3.
The content of each material of the treated front and back of table 3 common vetch dish waste water
The preparation of embodiment 4 beverages
The common vetch dish wastewater treatment liquid 4.167L that the preparation method that getting provides according to embodiment 1 is prepared into, adds the glycyrrhizin monosodium glutamate of 15g wherein, mixes, add water to 5L, adopt autoclave techniques to carry out sterilizing, gained solution is filling according to 500mL/ bottle, and packaging obtains containing selenium beverage.
Use sampling Graphite Furnace Atomic Absorption spectrophotometer, utilize the characteristic wavelength light (resonance line) of the tested element being sent by light source, element to be measured, by characteristic wavelength light being produced and absorbed after atomize, calculates the content of each element in the beverage that detects gained by measuring the size of this absorption; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 440nm, to detect the content of carotene wherein; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 254nm, to detect ascorbic content wherein.In the present embodiment gained beverage, the content of each material is in table 4.
The content of each material in table 4 gained beverage
| Material title | Potassium ion | Iron ion | Cupric ion | Magnesium ion | Plasma selenium | Calcium ion | Carotene | Vitamins C |
| Concentration | 19mg/L | 0.25mg/L | 0.5mg/L | 23mg/L | 0.1mg/L | 46.7mg/L | 0.08mg/L | 7.7mg/L |
The preparation of embodiment 5 beverages
The common vetch dish wastewater treatment liquid 5L that the preparation method that getting provides according to embodiment 2 is prepared into, the glycyrrhizin monosodium glutamate that adds wherein 20g, mixes, and adopts autoclave techniques to carry out sterilizing, gained solution is filling according to 100mL/ bottle, and packaging obtains containing selenium beverage.
Use sampling Graphite Furnace Atomic Absorption spectrophotometer, utilize the characteristic wavelength light (resonance line) of the tested element being sent by light source, element to be measured, by characteristic wavelength light being produced and absorbed after atomize, calculates the content of each element in the beverage that detects gained by measuring the size of this absorption; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 440nm, to detect the content of carotene wherein; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 254nm, to detect ascorbic content wherein.In the present embodiment gained beverage, the content of each material is in table 5.
The content of each material in table 5 gained beverage
| Material title | Potassium ion | Iron ion | Cupric ion | Magnesium ion | Plasma selenium | Calcium ion | Carotene | Vitamins C |
| Concentration | 10mg/L | 0.1mg/L | 0.2mg/L | 10mg/L | 0.05mg/L | 20mg/L | 0.03mg/L | 4mg/L |
The preparation of embodiment 6 beverages
The common vetch dish wastewater treatment liquid 4.167L that the preparation method that getting provides according to embodiment 3 is prepared into, adds the glycyrrhizin monosodium glutamate of 25g wherein, mixes, add water to 5L, adopt autoclave techniques to carry out sterilizing, gained solution is filling according to 500mL/ bottle, and packaging obtains containing selenium beverage.
Use sampling Graphite Furnace Atomic Absorption spectrophotometer, utilize the characteristic wavelength light (resonance line) of the tested element being sent by light source, element to be measured, by characteristic wavelength light being produced and absorbed after atomize, calculates the content of each element in the beverage that detects gained by measuring the size of this absorption; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 440nm, to detect the content of carotene wherein; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 254nm, to detect ascorbic content wherein.In the present embodiment gained beverage, the content of each material is in table 6.
The content of each material in table 6 gained beverage
| Material title | Potassium ion | Iron ion | Cupric ion | Magnesium ion | Plasma selenium | Calcium ion | Carotene | Vitamins C |
| Concentration | 41.7mg/L | 0.67mg/L | 1.2mg/L | 40.9mg/L | 0.25mg/L | 91mg/L | 0.15mg/L | 16.5mg/L |
The preparation of embodiment 7 beverages
The common vetch dish wastewater treatment liquid 1.667L that the preparation method that getting provides according to embodiment 3 is prepared into, adds the glycyrrhizin monosodium glutamate of 20g wherein, mixes, add water to 5L, adopt autoclave techniques to carry out sterilizing, gained solution is filling according to 100mL/ bottle, and packaging obtains containing selenium beverage.
Use sampling Graphite Furnace Atomic Absorption spectrophotometer, utilize the characteristic wavelength light (resonance line) of the tested element being sent by light source, element to be measured, by characteristic wavelength light being produced and absorbed after atomize, calculates the content of each element in the beverage that detects gained by measuring the size of this absorption; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 440nm, to detect the content of carotene wherein; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 254nm, to detect ascorbic content wherein.In the present embodiment gained beverage, the content of each material is in table 7.
The content of each material in table 7 gained beverage
| Material title | Potassium ion | Iron ion | Cupric ion | Magnesium ion | Plasma selenium | Calcium ion | Carotene | Vitamins C |
| Concentration | 16.7mg/L | 0.27mg/L | 0.5mg/L | 16.6mg/L | 0.1mg/L | 36.5mg/L | 0.05mg/L | 6.6mg/L |
The preparation of embodiment 8 beverages
The common vetch dish wastewater treatment liquid 0.833L that the preparation method that getting provides according to embodiment 3 is prepared into, adds the glycyrrhizin monosodium glutamate of 15g wherein, mixes, add water to 5L, adopt autoclave techniques to carry out sterilizing, gained solution is filling according to 200mL/ bottle, and packaging obtains containing selenium beverage.
Use sampling Graphite Furnace Atomic Absorption spectrophotometer, utilize the characteristic wavelength light (resonance line) of the tested element being sent by light source, element to be measured, by characteristic wavelength light being produced and absorbed after atomize, calculates the content of each element in the beverage that detects gained by measuring the size of this absorption; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 440nm, to detect the content of carotene wherein; Adopt high performance liquid chromatography, utilize anti-phase C18 post under wavelength 254nm, to detect ascorbic content wherein.In the present embodiment gained beverage, the content of each material is in table 8.
The content of each material in table 8 gained beverage
| Material title | Potassium ion | Iron ion | Cupric ion | Magnesium ion | Plasma selenium | Calcium ion | Carotene | Vitamins C |
| Concentration | 8.3mg/L | 0.13mg/L | 0.25mg/L | 8.3mg/L | 0.05mg/L | 18.2mg/L | 0.03mg/L | 3.3mg/L |
The clinical application of embodiment 9 beverages
In order to investigate the benefit selenium effect of beverage provided by the present invention, the beverage that the preparation method that getting provides according to embodiment 4 makes is tested.First, the content of plasma selenium in cancer patients's serum in the content, affiliated hospital of Medical University Of Anhui of plasma selenium in investigation normal human serum; Afterwards, the preparation method who investigates lung cancer in 50 attached hospitals of routine Medical University Of Anhui, mammary cancer, cancer of the stomach, the oral embodiment of the present invention 4 of liver cancer patient and provide be prepared into beverage after the content of serum selenium ion.The specification of tested beverage is 500mL/ bottle, and patient drinks 1～2 bottle every day, and life cycle is 2～3 months.Adopt atomic absorption spectrometry to detect the content of plasma selenium in patients serum.In the normal people of investigation and cancer patients's serum, the mean value of the content of plasma selenium is in table 9; Tested 50 routine cancer patients's beverages are mended the mean value of the content of serum selenium ion before and after selenium in table 10.
The content of plasma selenium in table 9 normal people and cancer patients's serum
| Group | Number of cases | Serum selenium (X-± SD μ g/mL) |
| Normal people | 34 | 0.1271±0.0532 |
| Lung cancer patient | 60 | 0.0703±0.0215* |
| Breast cancer patients | 54 | 0.0712±0.0290* |
| Patients with Gastric Cancer | 61 | 0.0723±0.0159* |
| Hepatocarcinoma patient | 49 | 0.0711±0.0155* |
* P<0.05 compared with normal people
The routine cancer patients of table 1050 mends the content of selenium front and back serum selenium ion
* two groups are P<0.05 relatively
From table 9, data can obtain, and compare the content of plasma selenium in normal human serum, and cancer patients's serum selenium ion content obviously reduces, and this result conforms to scientific research, illustrate between the scarce selenium of cancer and body and have certain relation.From table 10, data can obtain, in this experiment, lung cancer, mammary cancer, cancer of the stomach and liver cancer patient make in the preparation method who drinks the embodiment of the present invention 4 and provide containing selenium beverage after 2～3 months, in all patients serums, the content of plasma selenium is all significantly improved, and illustrates that the beverage that the preparation method that drinks the embodiment of the present invention 4 and provide makes can effectively improve human body selenium content.Because selenium has the effect of anti-curing cancers, and the beverage that the preparation method that the embodiment of the present invention 4 provides makes can effectively improve selenium content in cancer patients's body, so beverage provided by the invention has the effect of the cancer of preventing and treating, the common vetch dish wastewater treatment liquid that the preparation method that the embodiment of the present invention 1 provides makes can be applied to medicine or the beverage of the anti-curing cancers of preparation.Because Cancerous disease belongs to malignancy disease, and beverage provided by the invention has the effect of the cancer of preventing and treating, so beverage provided by the invention has the effect of the tumour of preventing and treating, the common vetch dish wastewater treatment liquid that the preparation method that the embodiment of the present invention 1 provides makes can be applied to medicine or the beverage of the anti-curing oncoma of preparation.
Adopt identical experimental technique, the benefit selenium effect of the beverage that the preparation method that investigating the embodiment of the present invention 5 to embodiment 8 provides obtains, obtained similar experimental result, the beverage that the preparation method that embodiment of the present invention 5 to embodiment 8 provides obtains also can effectively improve the content of plasma selenium in lung cancer, mammary cancer, cancer of the stomach and liver cancer patient body.Because selenium has the effect of anti-curing oncoma, and the beverage that the embodiment of the present invention 5 to embodiment 8 preparation methods that provide make can effectively improve selenium content in cancer patients's body, so beverage provided by the invention has the effect of the cancer of preventing and treating, the common vetch dish wastewater treatment liquid that the preparation method that the embodiment of the present invention 2 and embodiment 3 provide is prepared into also can be applied to medicine or the beverage of the anti-curing cancers of preparation.Because Cancerous disease belongs to malignancy disease, and beverage provided by the invention has the effect of the cancer of preventing and treating, so beverage provided by the invention has the effect of the tumour of preventing and treating, the common vetch dish wastewater treatment liquid that the preparation method that the embodiment of the present invention 2 and embodiment 3 provide makes also can be applied to medicine or the beverage of the anti-curing oncoma of preparation.
Below be only the preferred embodiment of the present invention, it should be pointed out that above-mentioned preferred implementation should not be considered as limitation of the present invention, protection scope of the present invention should be as the criterion with claim limited range.For those skilled in the art, without departing from the spirit and scope of the present invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (8)
1. a common vetch dish wastewater treatment liquid, is characterized in that, the content of its plasma selenium is 0.05mg/L～0.30mg/L;
It also comprises:
The potassium ion of 10mg/L～50mg/L;
The calcium ion of 20mg/L～110mg/L;
The iron ion of 0.1mg/L～0.8mg/L;
The magnesium ion of 10mg/L～50mg/L;
The cupric ion of 0.2mg/L～1.5mg/L;
The vitamins C of 4mg/L～20mg/L;
And the carotene of 0.03mg/L～0.18mg/L;
Described common vetch dish waste water is that whole common vetch dish boils and scalds the waste water producing in process.
2. common vetch dish wastewater treatment liquid according to claim 1, is characterized in that, its preparation method comprises the following steps:
Common vetch dish is mixed with water, and heating, collects liquid, obtains common vetch dish waste water;
By described common vetch dish waste water, through the first filtration, collect the first filtrate, described the first filtrate is heated to 30min～60min under 90 DEG C～100 DEG C conditions, adopt the ultra-filtration membrane second that molecular weight cut-off is 20KDa to filter, collect the second filtrate, concentrated, to obtain final product.
3. the application of common vetch dish wastewater treatment liquid as claimed in claim 1 or 2 in medicine or the beverage of the anti-curing oncoma of preparation.
4. the application of common vetch dish wastewater treatment liquid as claimed in claim 1 or 2 in medicine or the beverage of the anti-curing cancers of preparation.
5. application according to claim 4, is characterized in that, described cancer is mammary cancer, lung cancer, cancer of the stomach or liver cancer.
6. a beverage, is characterized in that, it comprises as claimed in claim 1 or 2 acceptable foodstuff additive in common vetch dish wastewater treatment liquid and beverage.
7. beverage according to claim 6, is characterized in that, the content of its plasma selenium is 0.05mg/L～0.25mg/L.
8. beverage according to claim 7, is characterized in that, it also comprises:
The potassium ion of 5mg/L～50mg/L;
The calcium ion of 15mg/L～100mg/L;
The iron ion of 0.1mg/L～0.8mg/L;
The magnesium ion of 5mg/L～50mg/L;
The cupric ion of 0.1mg/L～1.5mg/L;
The vitamins C of 2mg/L～20mg/L;
And the carotene of 0.02mg/L～0.2mg/L.
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