CN103479532A - Surfactant composition and uses thereof - Google Patents
Surfactant composition and uses thereof Download PDFInfo
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- CN103479532A CN103479532A CN201210192296.2A CN201210192296A CN103479532A CN 103479532 A CN103479532 A CN 103479532A CN 201210192296 A CN201210192296 A CN 201210192296A CN 103479532 A CN103479532 A CN 103479532A
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Abstract
The invention discloses a surfactant composition, the surfactant composition comprises essential components such as a component (a), a component (b), a component (c) and a component (d); wherein the component (a) is selected from one or more long-chain fatty acyl amino acid salt represented by the following general formula (1) or (2), the component (a) accounts for 1% to 50wt% of the total weight of the surfactant composition, and the general formula (1) and (2) are shown in the specification; the component (b) is selected from one or more linear chain or branched chain aliphatic hydrocarbon glyceryl ether represented by the following general formula (3), the component (b) accounts for 0.1% to 10wt% of the total weight of the surfactant composition, and the general formula (3) is shown in the specification; the component (c) is selected from one or more water-lost sorbitol fatty acid ester represented by the following general formula (4) and/or is selected from one or more alkyl saccharide represented by the following general formula (5), the component (c) accounts for 0.1% to 10wt% of the total weight of the surfactant composition, and the general formula (4) and (5) are shown in the specification; the component (d) is selected from a solvent comprising one or more from water, lower alcohol, polyol and polyol ether, and the component (d) accounts for 30% to 90wt% of the total weight of the surfactant composition.
Description
Technical field
The present invention relates to fine chemical product, relate in particular to a kind of surface activator composition that to take for the human body clean product be purpose.
Background technology
All the time, long-chain fat amic acid salt surfactant is widely used as main component in the cleaning product of human body.Such cleaning product has the safety of washability preferably and use, but foaminess is inadequate.
" " the proposition acyl sarcosinates is as a kind of foaming agent, and the use in crust (as concrete surface) is clean as Babassuamidopropylamine of specific glycerin ether for Cleasing compositions for publication CN101484563A.But do not consider safety, and the two uses foaminess good not.
Openly in Japanese Patent Laid-Open 2003055690 " cleansing composition ", A is proposed) N-acylamino-hydrochlorate, B) alkyl polyglucoside, its technical problem to be solved is improve the viscosity of compositions and make transparent appearance, but there is no gratifying foaming effect.
Therefore this area is in the urgent need to providing a kind of foam to enrich and the gentle surface activator composition for the human body clean product.
Summary of the invention
The present invention aims to provide a kind of surface activator composition for the human body clean product.
In a first aspect of the present invention, a kind of surface activator composition is provided, the necessary component in described compositions comprises component (a), component (b), component (c) and component (d), wherein,
Component (a) is selected from the long-chain fat acylamino-hydrochlorate of one or more following general formulas (1) or (2) expression, and in the gross weight of compositions, the percentage by weight of component (a) is 1% to 50%:
General formula (1)
General formula (2)
In general formula (1) and (2), R and R
3mean respectively hydrogen or methyl; R
1the straight chain that the expression carbon number is 7-17 or the aliphatic alkyl of branched chain; R
2and R
4mean respectively hydrogen atom, alkali metal, alkaline-earth metal, organic ammonium or alkanolamine; N means 0 or 1 integer; M means 1 or 2 integer;
Component (b) is selected from the straight chain of one or more following general formulas (3) expressions or the aliphatic alkyl glycerin ether of branched chain, and in the gross weight of compositions, the percentage by weight of component (b) is 0.1%-10%:
General formula (3)
In general formula (3), R
5the straight chain that the expression carbon number is 6-22 or the aliphatic alkyl of branched chain;
Component (c) is selected from the sorbitan fatty acid ester that one or more following general formulas (4) mean, and/or be selected from the alkyl saccharide that one or more following general formulas (5) mean, in the gross weight of compositions, the percentage by weight of component (c) is 0.1%-10%:
General formula (4)
General formula (5)
In general formula (4), R
6the straight chain that the expression carbon number is 9-19 or the aliphatic alkyl of branched chain;
In general formula (5), R
7the straight chain that the expression carbon number is 8-18 or the aliphatic alkyl of branched chain; X means the integer of 1-10;
Component (d) is selected from the solvent of one or more formations in water, lower alcohol, polyhydric alcohol, polyol ethers, and in the gross weight of compositions, the percentage by weight of component (d) is 30%-90%.
In another preference, component (a) is selected from one or more of following substances: the fatty acyl sarcosinate that the carbon number of fatty acyl group is 8-18, the fatty acyl glutamate, Glu that the carbon number of fatty acyl group is 8-18, the fatty acyl glycinate that the carbon number of fatty acyl group is 8-18, the fatty acyl alanine salt that the carbon number of fatty acyl group is 8-18, the fatty acyl that the carbon number of fatty acyl group is 8-18-Beta-alanine salt, the fatty acyl aspartate that the carbon number of fatty acyl group is 8-18; Described salt is potassium salt, sodium salt or triethanolamine salt;
Component (b) is selected from one or more of following substances: the aliphatic alkyl glycerin ether of the straight chain that the carbon number of alkyl is 6-22 or branched chain;
Component (c) is selected from one or more of following substances: the straight chain that the carbon number that becomes the fatty acid of ester is 10-20 or the sorbitan fatty acid ester of branched chain; And/or be selected from one or more of following substances: the alkyl polyglucoside that the carbon number of alkyl is 8-18.
In another preference, component (a) is selected from one or more of following substances: the fatty acyl sarcosinate that the carbon number of fatty acyl group is 8-14, the fatty acyl glutamate, Glu that the carbon number of fatty acyl group is 8-14, the fatty acyl glycinate that the carbon number of fatty acyl group is 8-14, the fatty acyl alanine salt that the carbon number of fatty acyl group is 8-14, the fatty acyl that the carbon number of fatty acyl group is 8-14-Beta-alanine salt, the fatty acyl aspartate that the carbon number of fatty acyl group is 8-14; Described salt is potassium salt, sodium salt or triethanolamine salt;
Component (b) is selected from one or more of following substances: the aliphatic alkyl glycerin ether of the straight chain that the carbon number of alkyl is 6-18 or branched chain;
Component (c) is selected from one or more of following substances: the straight chain that the carbon number that becomes the fatty acid of ester is 10-18 or the sorbitan fatty acid ester of branched chain; And/or be selected from one or more of following substances: the alkyl polyglucoside that the carbon number of alkyl is 8-14.
In another preference, the carbon number of described fatty acyl group is that 8-14 fatty acyl sarcosinate is selected from decoyl sarcosinate, caprinoyl sarcosinate, Hamposyl L salt, myristoyl-N-methylaminoacetic acid salt, fatty acid distribution of coconut oil acylsarcosine salt or palm-kernel oil fatty acid acyl sarcosinate;
The carbon number of described fatty acyl group is that 8-14 fatty acyl glycinate is selected from decoyl glycinate, caprinoyl glycinate, lauroyl glycinate, myristoyl glycinate, fatty acid distribution of coconut oil acyl glycinate or palm-kernel oil fatty acid acyl glycinate;
The carbon number of described fatty acyl group is that 8-14 fatty acyl glutamate, Glu is selected from decoyl glutamate, Glu, caprinoyl glutamate, Glu, lauroyl glutamate, myristoyl glutamate, Glu, fatty acid distribution of coconut oil acyl glutamate, Glu or palm-kernel oil fatty acid acyl glutamate, Glu;
The carbon number of described fatty acyl group is that 8-14 fatty acyl alanine salt is selected from decoyl alanine salt, caprinoyl alanine salt, lauroyl alanine salt, myristoyl alanine salt, fatty acid distribution of coconut oil acyl alanine salt or palm-kernel oil fatty acid acyl alanine salt;
The carbon number of described fatty acyl group is that 8-14 fatty acyl-Beta-alanine salt is selected from decoyl-Beta-alanine salt, caprinoyl-Beta-alanine salt, lauroyl-Beta-alanine salt, myristoyl-Beta-alanine salt, fatty acid distribution of coconut oil acyl-Beta-alanine salt or palm-kernel oil fatty acid acyl-Beta-alanine salt;
The carbon number of described fatty acyl group is that 8-14 fatty acyl aspartate is selected from decoyl aspartate, caprinoyl aspartate, lauroyl aspartate, myristoyl aspartate, fatty acid distribution of coconut oil acyl aspartate or palm-kernel oil fatty acid acyl aspartate;
The aliphatic alkyl glycerin ether of the straight chain that the carbon number of described alkyl is 6-18 or branched chain is selected from: hexyl glycerin ether, octyl group glycerin ether, decyl glycerin ether, lauryl glycerin ether, myristyl glycerin ether, stearyl glycerin ether, isohesyl glycerin ether, iso-octyl glycerin ether, Fancol ID base glycerol ether, isotridecyl glycerin ether, different pentadecyl glycerin ether or iso stearyl glycerin ether;
The straight chain that the carbon number of the fatty acid of described one-tenth ester is 10-18 or the sorbitan fatty acid ester of branched chain are selected from the anhydrous sorbitol decanoin, the anhydrous sorbitol laurate, the anhydrous sorbitol myristinate, the anhydrous sorbitol cetylate, Span60, anhydrous sorbitol isodecyl acid esters, the different laurate of anhydrous sorbitol, the different myristinate of anhydrous sorbitol, the different cetylate of anhydrous sorbitol, the anhydrous sorbitol isostearate, anhydrous sorbitol laurylene acid esters, anhydrous sorbitol tetradecene acid esters, anhydrous sorbitol hexadecylene acid esters or anhydrous sorbitol octadecylene acid esters,
The alkyl polyglucoside of the carbon number 8-14 of described alkyl is selected from octyl group polyglucoside, decyl polyglucoside, lauryl polyglucoside, myristyl polyglucoside or cocoyl polyglucoside.
In another preference, the percentage by weight of component (a) is 3%-40%, more preferably 5%-25%.
In another preference, the percentage by weight of component (b) is 0.1%-8%, more preferably 0.2%-5%; The percentage by weight of component (c) is 0.1%-8%, more preferably 0.2%-5%.
In another preference, the percentage by weight of component (c) is 45%-85%, more preferably 65%-85%.
In another preference, described necessary component consists of component (a), component (b), component (c) and component (d).
In another preference, described compositions also contains following for beauty treatment and clean adjuvant, is selected from: be different from component (a), (b) and auxiliary suds booster (c), rheology control agent, wetting agent, polymer, the agent of tax fat, saccharide, powder, siloxanes, pearling agent, pH adjusting agent, opacifier, cosmetics and efficacy cosmetic product special composition, antiseptic, chelating agen, antimicrobial, antioxidant, dyestuff or essence used.
In a second aspect of the present invention, provide the purposes of surface activator composition provided by the invention as above, for the preparation of the human body clean product;
Described human body clean product comprises human body skin cleaning product, human oral cavity cleaning product, human hair cleaning product and human body eye cleaning product.
Accordingly, the invention provides a kind of foam enriches and the gentle surface activator composition for the human body clean product.
The specific embodiment
The inventor is through extensive and deep research, find the surface activator composition of long-chain fat amic acid salt surfactant, alkyl glycerol ethers surfactant and anhydrous sorbitol fatty acid surfactant and/or alkyl polyglucoside class surfactant and solvent mix proportion, can produce abundant foam, the character gentleness, used safety simultaneously.Said composition can be used for the purposes of the cleaning product at each position of human body, such as clean for the face such as cleansing milk, facial cleaning cream and eye; The body skin such as bath oil, fancy soap is clean; The hair cleanings such as two-in-one shampoo; The oral cavity cleanings such as collutory.
As used herein, term " necessary component " is to instigate surfactant to possess the component that purpose that requirement of the present invention reaches must contain, and comprises component (a), component (b), component (c) and component (d).
As used herein, term " contain " or " comprising " comprised " comprising ", " basically by ... form " and " by ... form ".
Although claims of the present invention particularly point out and know the protection domain that has required " a kind of surface activator composition for the human body clean product " of the present invention, should believe that following explanation will understand the present invention better.
The invention provides a kind of surface activator composition for cleaning agent, containing being necessary component (a), (b), (c) and (d);
Component (a) is selected from the long-chain fat acylamino-hydrochlorate of at least one following general formula (1)-(2) expression or their mixture, accounts for composition weight percentage ratio 1% to 50%;
General formula (1)
General formula (2)
In general formula (1)-(2), R and R
3mean hydrogen or methyl; R
1the straight chain that the expression carbon number is 7-17 or the aliphatic alkyl of branched chain; R
2and R
4mean hydrogen atom, alkali metal, alkaline-earth metal, organic ammonium or alkanolamine; N means 0 or 1 integer; M means 1 or 2 integers.
The present composition; wherein; it is 8-18 fatty acyl aspartate or their mixture that component (a) at least is selected from the carbon number that carbon number that carbon number that the carbon number of fatty acyl glutamate, Glu that the carbon number of fatty acyl sarcosinate that a kind of carbon number of fatty acyl group is 8-18, fatty acyl group is 8-18, fatty acyl group is 8-18 fatty acyl glycinate, fatty acyl group is 8-18 fatty acyl alanine salt, fatty acyl group is 8-18 fatty acyl-Beta-alanine salt, fatty acyl group, and the salt become can be potassium salt, sodium salt or triethanolamine salt.
The present composition, wherein, the fatty acyl sarcosinate that in component (a), the carbon number of fatty acyl group is 8-18 specifically can be selected from least one: decoyl sarcosinate, caprinoyl sarcosinate, Hamposyl L salt, myristoyl-N-methylaminoacetic acid salt, palmitoyl sarcosine salt, Hamposyl S salt fatty acid distribution of coconut oil acylsarcosine salt, palm-kernel oil fatty acid acyl sarcosinate or their mixture; The fatty acyl glutamate, Glu that the carbon number of fatty acyl group is 8-18 specifically can be selected from least one: decoyl glutamate, Glu, caprinoyl glutamate, Glu, lauroyl glutamate, myristoyl glutamate, Glu, palmityl glutamate, Glu, stearoyl-glutamic acid salt, fatty acid distribution of coconut oil acyl glutamate, Glu, palm-kernel oil fatty acid acyl glutamate, Glu or their mixture; The fatty acyl glycinate that the carbon number of fatty acyl group is 8-18 specifically can be selected from least one: decoyl glycinate, caprinoyl glycinate, lauroyl glycinate, myristoyl glycinate, palmityl glycinate, stearoylglycine salt, fatty acid distribution of coconut oil acyl glycinate, palm-kernel oil fatty acid acyl glycinate or their mixture; The fatty acyl alanine salt that the carbon number of fatty acyl group is 8-18 specifically can be selected from least one: decoyl alanine salt, caprinoyl alanine salt, lauroyl alanine salt, myristoyl alanine salt, palmityl alanine salt, stearoyl alanine salt, fatty acid distribution of coconut oil acyl alanine salt, palm-kernel oil fatty acid acyl alanine salt or their mixture; The fatty acyl aspartate that the carbon number of fatty acyl group is 8-18 specifically can be selected from least one: decoyl aspartate, caprinoyl aspartate, lauroyl aspartate, myristoyl aspartate, palmityl aspartate, stearoyl aspartate, fatty acid distribution of coconut oil acyl aspartate, palm-kernel oil fatty acid acyl aspartate or their mixture; The fatty acyl that the carbon number of fatty acyl group is 8-18-Beta-alanine salt specifically can be selected from least one: decoyl-Beta-alanine salt, caprinoyl-Beta-alanine salt, lauroyl-Beta-alanine salt, myristoyl-Beta-alanine salt, palmityl-Beta-alanine salt, stearoyl-Beta-alanine salt, fatty acid distribution of coconut oil acyl-Beta-alanine salt, palm-kernel oil fatty acid acyl-Beta-alanine salt or their mixture; The salt that said components becomes is potassium salt, sodium salt or triethanolamine salt specifically.
Although their carbon chain lengths difference of the fatty acyl amino acid salts that the carbon number of above-mentioned fatty acyl group is 8-18 or the salt difference become, for a person skilled in the art, their character is close with the application effect.
The present composition; wherein; the carbon number that the carbon number that the carbon number that the carbon number of the fatty acyl sarcosinate that component (a) is at least preferably 8-14 from a kind of carbon number of fatty acyl group, fatty acyl glutamate, Glu that the carbon number of fatty acyl group is 8-14, fatty acyl group is 8-14 fatty acyl glycinate, fatty acyl group is 8-14 fatty acyl alanine salt, fatty acyl group is 8-14 fatty acyl-Beta-alanine salt, fatty acyl group is 8-14 fatty acyl aspartate or their mixture, and the salt become can be potassium salt, sodium salt or triethanolamine salt.
The present composition, wherein, the fatty acyl sarcosinate that the carbon number of fatty acyl group is 8-14 in component (a) specifically can be preferably from least one: decoyl sarcosinate, caprinoyl sarcosinate, Hamposyl L salt, myristoyl-N-methylaminoacetic acid salt, fatty acid distribution of coconut oil acylsarcosine salt, palm-kernel oil fatty acid acyl sarcosinate or their mixture; The fatty acyl glutamate, Glu that the carbon number of fatty acyl group is 8-14 specifically can be preferably from least one: decoyl glutamate, Glu, caprinoyl glutamate, Glu, lauroyl glutamate, myristoyl glutamate, Glu, fatty acid distribution of coconut oil acyl glutamate, Glu, palm-kernel oil fatty acid acyl glutamate, Glu or their mixture; The fatty acyl glycinate that the carbon number of fatty acyl group is 8-14 specifically can be preferably from least one: decoyl glycinate, caprinoyl glycinate, lauroyl glycinate, myristoyl glycinate, fatty acid distribution of coconut oil acyl glycinate, palm-kernel oil fatty acid acyl glycinate or their mixture; The fatty acyl alanine salt that the carbon number of fatty acyl group is 8-14 specifically can be preferably from least one: decoyl alanine salt, caprinoyl alanine salt, lauroyl alanine salt, myristoyl alanine salt, fatty acid distribution of coconut oil acyl alanine salt, palm-kernel oil fatty acid acyl alanine salt or their mixture; The fatty acyl aspartate that the carbon number of fatty acyl group is 8-14 specifically can be preferably from least one: decoyl aspartate, caprinoyl aspartate, lauroyl aspartate, myristoyl aspartate, fatty acid distribution of coconut oil acyl aspartate, palm-kernel oil fatty acid acyl aspartate or their mixture; The fatty acyl that the carbon number of fatty acyl group is 8-14-Beta-alanine salt specifically can be preferably from least one: decoyl-Beta-alanine salt, caprinoyl-Beta-alanine salt, lauroyl-Beta-alanine salt, myristoyl-Beta-alanine salt, fatty acid distribution of coconut oil acyl-Beta-alanine salt, palm-kernel oil fatty acid acyl-Beta-alanine salt or their mixture; The salt that said components becomes is potassium salt, sodium salt or triethanolamine salt specifically.
The present composition; wherein; the fatty acyl glutamate, Glu that the fatty acyl sarcosinate that component (a) is further preferably 8-14 from the carbon number of at least one fatty acyl group, the carbon number of fatty acyl group are 8-14, the carbon number of fatty acyl group are 8-14 fatty acyl glycinate or their mixture, and the salt become can be potassium salt, sodium salt or triethanolamine salt.
The present composition, wherein, the fatty acyl sarcosinate that the carbon number of fatty acyl group is 8-14 in component (a) specifically can be further preferably from least one: decoyl sarcosinate, caprinoyl sarcosinate, Hamposyl L salt, myristoyl-N-methylaminoacetic acid salt, fatty acid distribution of coconut oil acyl glycinate, palm-kernel oil fatty acid acyl glycinate or their mixture; The fatty acyl glutamate, Glu that the carbon number of fatty acyl group is 8-14 specifically can be further preferably from least one: decoyl glutamate, Glu, caprinoyl glutamate, Glu, lauroyl glutamate, myristoyl glutamate, Glu, fatty acid distribution of coconut oil acyl glutamate, Glu, palm-kernel oil fatty acid acyl glutamate, Glu or their mixture; The fatty acyl glycinate that the carbon number of fatty acyl group is 8-14 specifically can be further preferably from least one: decoyl glycinate, caprinoyl glycinate, lauroyl glycinate, myristoyl glycinate, fatty acid distribution of coconut oil acyl glycinate, palm-kernel oil fatty acid acyl glycinate or their mixture; The salt that said components becomes is potassium salt, sodium salt or triethanolamine salt specifically.
The present composition.Wherein, component (a) long-chain fat acylamino-hydrochlorate accounts for composition weight percentage ratio and is preferably 3%-40%, more preferably 5%-25%.
The present composition, wherein, component (b) is selected from straight chain that the carbon number of the represented alkyl of at least one following general formula (3) is 6-22 or the aliphatic alkyl glycerin ether of branched chain, and accounting for composition weight percentage ratio is 0.1%-10%;
General formula (3)
In formula, R
5the straight chain that the expression carbon number is 6-22 or the aliphatic alkyl of branched chain.
The present composition, wherein, component (b) specifically can be selected from least following a kind of: hexyl glycerin ether, octyl group glycerin ether, decyl glycerin ether, lauryl glycerin ether, myristyl glycerin ether, cetyl glycerin ether, stearyl glycerin ether, eicosyl glycerin ether, docosyl glycerin ether, isohesyl glycerin ether, iso-octyl glycerin ether, Fancol ID base glycerol ether, isotridecyl glycerin ether, different pentadecyl glycerin ether, isooctadecane base glycerol ether, Isoeicosane base glycerol ether, different docosyl glycerin ether or their mixture.
The present composition, wherein, straight chain or the aliphatic alkyl glycerin ether of branched chain or their mixture that component (b) is preferably 6-18 from the carbon number of at least one alkyl.
The present composition, wherein, component (b) specifically can be preferably certainly at least following a kind of: hexyl glycerin ether, octyl group glycerin ether, decyl glycerin ether, lauryl glycerin ether, myristyl glycerin ether, stearyl glycerin ether, isohesyl glycerin ether, iso-octyl glycerin ether, Fancol ID base glycerol ether, isotridecyl glycerin ether, different pentadecyl glycerin ether, iso stearyl glycerin ether or their mixture.
In the present invention, component (b) accounts for composition weight percentage ratio and is preferably: 0.1%-8%.More preferably: 0.2%-5%.
The present composition, wherein, component (c) is selected from the alkyl saccharide that the carbon number of the sorbitan fatty acid ester of the straight chain of carbon number 10-20 of fatty acid of the represented one-tenth ester of at least one following general formula (4) or branched chain and/or the represented alkyl of general formula (5) is 8-18, or their mixture, accounting for composition weight percentage ratio is 0.1%-10%;
General formula (4)
In formula, R
6the straight chain that the expression carbon number is 9-19 or the aliphatic alkyl of branched chain.
General formula (5)
In formula, R
7the straight chain that the expression carbon number is 8-18 or the aliphatic alkyl of branched chain; X means the integer of 1-10.
The present composition, wherein, component (c) at least is selected from alkyl polyglucoside that the carbon number of the sorbitan fatty acid ester of straight chain that a kind of carbon number that becomes the fatty acid of ester is 10-20 or branched chain and/or alkyl is 8-18 or their mixture.
The present composition, wherein, component (c) is selected from least one: the straight chain that the carbon number that becomes the fatty acid of ester is 10-20 or the sorbitan fatty acid ester of branched chain, specifically: the anhydrous sorbitol decanoin, the anhydrous sorbitol laurate, the anhydrous sorbitol myristinate, the anhydrous sorbitol cetylate, Span60, the anhydrous sorbitol Arachidate, anhydrous sorbitol isodecyl acid esters, the different laurate of anhydrous sorbitol, the different myristinate of anhydrous sorbitol, the different cetylate of anhydrous sorbitol, the anhydrous sorbitol isostearate, the different Arachidate of anhydrous sorbitol, anhydrous sorbitol laurylene acid esters, anhydrous sorbitol tetradecene acid esters, anhydrous sorbitol hexadecylene acid esters, anhydrous sorbitol octadecylene acid esters, anhydrous sorbitol icosa alkene acid esters or their mixture, the alkyl polyglucoside of the carbon number 8-18 of alkyl is specifically: octyl group polyglucoside, decyl polyglucoside, lauryl polyglucoside, myristyl polyglucoside, palmityl polyglucoside, stearoyl polyglucoside, cocoyl polyglucoside, or the mixture of above-claimed cpd.
The present composition, the alkyl polyglucoside that the carbon number of the straight chain that wherein, component (c) is at least preferably 10-18 from a kind of carbon number that becomes the fatty acid of ester or the sorbitan fatty acid ester of branched chain and/or alkyl is 8-14 or their mixture.
The present composition, wherein, component (c) is preferably from least one: the straight chain that the carbon number that becomes the fatty acid of ester is 10-18 or the aliphatic alkyl sorbitan ester of branched chain, specifically: the anhydrous sorbitol decanoin, the anhydrous sorbitol laurate, the anhydrous sorbitol myristinate, the anhydrous sorbitol cetylate, Span60, anhydrous sorbitol isodecyl acid esters, the different laurate of anhydrous sorbitol, the different myristinate of anhydrous sorbitol, the different cetylate of anhydrous sorbitol, the anhydrous sorbitol isostearate, anhydrous sorbitol laurylene acid esters, anhydrous sorbitol tetradecene acid esters, anhydrous sorbitol hexadecylene acid esters, anhydrous sorbitol octadecylene acid esters or their mixture, the alkyl polyglucoside of the carbon number 8-14 of alkyl is specifically: octyl group polyglucoside, decyl polyglucoside, lauryl polyglucoside, myristyl polyglucoside, cocoyl polyglucoside, or the mixture of above-claimed cpd.
In the present invention, component (c) accounts for composition weight percentage ratio and is preferably: 0.1%-8%.More preferably: 0.2%-5%.
In surface activator composition of the present invention, at least one is selected from the solvent of polyhydric alcohol, water component (d).Specifically can be selected from following one or more: water, lower alcohol, polyhydric alcohol, polyol ethers, be selected from more specifically following one or more: the polypropylene glycol of the Polyethylene Glycol of pure water, distilled water, deionized water, mineral water, ethanol, propanol, isopropyl alcohol, ethylene glycol, different molecular weight, diethylene glycol, propylene glycol, different molecular weight, dipropylene glycol, glycerol, polyglycereol, maltose alcohol, sorbitol etc. account for composition weight percentage ratio 30%-90%.
In the present invention, solvent accounts for the Cleasing compositions percentage by weight and is preferably 45%-85%; 65%-85% more preferably.
Surface activator composition of the present invention is the effect for the cleaning product of partes corporis humani position.When preparing cleaning product, can be according to final use, in the situation that do not affect stability and result of use adds various tradition beauty treatments or clean adjuvant.They can be, for example be different from component (a), (b), special composition, antiseptic, chelating agen, antimicrobial, antioxidant, dyestuff or the essence of other auxiliary suds booster, rheology control agent, wetting agent, polymer, the agent of tax fat, saccharide, powder, siloxanes, pearling agent, pH adjusting agent, opacifier, cosmetics and efficacy cosmetic product (c).
Various traditional beauty treatments or clean adjuvant are the auxiliary material of the present invention as the preparation cleaning agent, but are further to understand and explanation embodiment, and these additives are exemplified below:
Be different from component (a), (b), the auxiliary suds booster of (c) other is:
Anion surfactant: carboxylate, alkyl polyoxyethylene base ether carboxylate, alkyl sulfate, alkyl polyoxyethylene base ether sulfate, the alkylamide ether sulfate, alkyl aryl polyether sulfate, alkylsulfonate, alkyl polyoxyethylene base ether sulfonate, alkylamide sulfonate, alkylaryl sulfonates, alpha-alkene sulfonate, petroleum sulfonate, alkyl phosphate salt, alkyl polyoxyethylene base ether phosphate salt, acyl-hydroxyethyl sulfonate, fatty acyl taurine salt, sulfosuccinate ester salt, acyl-lactate or their mixture,
Zwitterionic surfactant: alkyl betaine, alkyl amido betaine, sulfobetaines, sulfinyl group and sulfatobetaine, phosphonous acid base and phosphonate group betanin, phosphorous acid base and phosphate betanin, imidazoline type amphoteric surfactant, both sexes acetate, both sexes propionate, amino acid type amphoteric surface active agent or their mixture;
Non-ionic surface active agent: fatty glyceride polyoxyethylene ether, alkylphenol-polyethenoxy base ether, polyoxyethylene carboxylate, alkanolamide, polyethenoxy alkanolamide, polyoxyethylene sorbitan fatty acid ester or their mixture;
Cationic surfactant: chain alkyl trimethyl-ammonium halide, long chain alkyl dimethyl benzyl ammonium halide, long-chain amide alkyl-dimethyl benzyl ammonium halide, two long-chain amide alkyl dibenzyl ammonium halides and imidazoline quaternary ammonium salt, Fixanol or their mixture.
Rheology control agent is: the association type polymer of hydrophobically modified, the nonionic polyhydric alcohol of hydrophobically modified, cellulose derivative etc.For example: PEG-120 methyl glucosamine dioleate, PEG-150 pentaerythritol tetrastearate, PEG-75 dioleate and PEG-150 distearate.
Wetting agent is: sodium chondroitin sulfate, hyaluronate sodium, adenylic acid sodium, sodium lactate, pyrrolidone carboxylic acid salt etc.;
Polymer is: polyvinylpyrrolidone etc.;
Composing the fat agent is: animal and plant fat derivant, fatty acid ester etc.;
Saccharide is: maltose, glucose, fructose etc.;
Powder is: the silicon dioxide of modification or non-modification, bentonite, kieselguhr, modified starch, lauroyl lysine etc.;
Siloxanes is: dimethyl siloxane etc.;
Pearling agent is: ethylene glycol monostearate, Ethylene Glycol Distearate etc.;
PH adjusting agent is: citric acid, fruit acid, potassium hydroxide, sodium hydroxide, triethanolamine etc.;
The special composition of cosmetics and efficacy cosmetic product is: vitamins, each Plant Extracts etc.;
Opacifier is: phenylethylene ethylene/propenoic acid ester copolymer etc.;
Antiseptic is: phenyl phenol, methyl parahydroxybenzoate etc.;
Chelating agen is: disodiumedetate etc.;
Antimicrobial is: Zinc Pyrithione, chloroxylenol etc.;
Antioxidant is: ditertbutylparacresol etc.
These tradition beauty treatments or clean adjuvant annotate " cosmetics, science and technology " (Cosmetics, the Science and Technology) that is found in Sagarin in detail.The various tradition beauty treatments or the numerous of clean adjuvant kind and quantity that can be used for Cleasing compositions can not exemplify one by one, only otherwise affect under the prerequisite of the stability of compositions of the present invention and result of use, can add.
Preparation method
Production technology of the present invention is the general methods of those skilled in the art, be summarized as follows: in the container of stirrer paddle is housed, (stirrer paddle is the anchor formula, frame, screw-pushing type) container with chuck or metal coil pipe heating and cooling system, first add solvent (water normally, the mixed solvents such as polyhydric alcohol), open heating, container slowly is heated to 60 ℃ of left and right, then add successively other various components (except volatile component, antiseptic and essence are outer), slowly be heated to 80 ℃ up and down in stirring simultaneously, open and stir and be incubated at 80 ℃ up and down, maintain three hours.After confirmation is fully stirred and is reached index of correlation, open cooling system and begin to cool down, be cooled to 40 ℃ of left and right and add again volatile component, antiseptic and essence, emit the material body after fully mixing.
Described surface activator composition of the present invention is for the preparation of partes corporis humani position cleaning product, and main manifestations is to have abundant foaming capacity.
The test of foaming capacity:
The model that the foaming capacity result is produced by German SITA company is that SITA Form Tester R-2000 foam tester records.
Test condition:
Specimen volume: 500ml;
Sample concentration: 2%;
Probe temperature: 40 ℃;
Rotor rotation speed: 500rpm.
Purposes
Surface activator composition provided by the invention, depending on purity and the quality of compound, can be for the preparation of the purposes of the cleaning product of partes corporis humani position.Such as clean for the face such as cleansing milk, facial cleaning cream and eye; The body skin such as bath oil, fancy soap is clean; The hair cleanings such as two-in-one shampoo; The oral cavity cleanings such as collutory.
The above-mentioned feature that the present invention mentions, or the feature that embodiment mentions can combination in any.All features that this case description discloses can with any composition forms use, each feature disclosed in description, can anyly provide the alternative characteristics of identical, impartial or similar purpose to replace.Therefore except special instruction is arranged, the feature disclosed is only the general example of equalization or similar features.
Major advantage of the present invention is:
Surface activator composition provided by the invention has excellent foam performance, and said composition character gentleness, used safety simultaneously.
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment are only for the present invention is described but not limit the scope of the invention.The experimental technique of unreceipted actual conditions in the following example, usually according to normal condition or the condition of advising according to manufacturer.
Except as otherwise noted, " INCI (cosmetic composition international nomenclature International Nomenclature of Cosmetic Ingredients) " title that each component all is familiar with chemical name or this area provides.
In embodiment and Comparative Examples, the numeral of corresponding component is this component percentage by weight in this example.
Unit in percent weight in volume in the present invention is well-known to those skilled in the art, for example refers to the weight of solute in the solution of 100 milliliters.
Unless otherwise defined, the same meaning that all specialties of using in literary composition and scientific words and one skilled in the art are familiar.In addition, any method similar or impartial to described content and material all can be applicable in the inventive method.The use that better implementation method described in literary composition and material only present a demonstration.
Embodiment 1-27:
Table one
In table one, according to embodiments of the invention 1-3, due to after having adopted component of the present invention (a), (b), (c) to reach (d), foamability will obviously be better than does not use component of the present invention (b) and Comparative Examples (c) 1.Embodiment of the present invention 1-3 can be used for producing the cleansing milk product, and for the human body face cleaning action, the character gentleness, used safety.
Table two
In table two, according to embodiments of the invention 4-6 due to adopted component of the present invention (a), (b), (c) and (d) after, foamability will obviously be better than the Comparative Examples 2 of not using component of the present invention=(c).
Table three
In table three, according to embodiments of the invention 7-9, due to after having adopted component of the present invention (a), (b), (c) to reach (d), foamability will obviously be better than does not use component of the present invention (b) and Comparative Examples (c) 3.Embodiment of the present invention 7-9 can be used for producing the bath gel product, for the human body skin clean, and the character gentleness, skinfeel is comfortable.
Table four
In table four, according to embodiments of the invention 10-12, due to after having adopted component of the present invention (a), (b), (c) to reach (d), foamability will obviously be better than does not use component of the present invention (b) and Comparative Examples (c) 4.Embodiment of the present invention 10-12 can be used for producing the facial cleaning cream product, clean for human body face and eye part skin, the character gentleness.
Table five
In table five, according to embodiments of the invention 13-15 due to adopted component of the present invention (a), (b), (c) and (d) after, foamability will obviously be better than the Comparative Examples 5 of not using component of the present invention=(c).Embodiment of the present invention 13-15 can be used for producing two-in-one shampoo, clean for human hair, the character gentleness.
Table six
In table six, according to embodiments of the invention 16-18, due to after having adopted component of the present invention (a), (b), (c) to reach (d), foamability will obviously be better than does not use component of the present invention (b) and Comparative Examples (c) 6.Embodiment of the present invention 16-18 can be used for producing the bath gel product, for the human body skin clean, and the character gentleness, skinfeel is comfortable.
Table seven
In table seven, according to embodiments of the invention 19-21, due to after having adopted component of the present invention (a), (b), (c) to reach (d), foamability will obviously be better than does not use component of the present invention (b) and Comparative Examples (c) 7.Embodiment of the present invention 19-21 can be used for producing the collutory product, clean for human oral cavity, the character gentleness.
Table eight
In table eight, according to embodiments of the invention 22-24, due to after having adopted component of the present invention (a), (b), (c) to reach (d), foamability will obviously be better than does not use component of the present invention (b) and Comparative Examples (c) 8.
Table nine
In table nine, according to embodiments of the invention 25-27, due to after having adopted component of the present invention (a), (b), (c) to reach (d), foamability will obviously be better than does not use component of the present invention (b) and Comparative Examples (c) 9.Embodiment of the present invention 25-27 can be used for producing the facial cleaning cream product, clean for human body face and eye part skin, the character gentleness.
The foregoing is only preferred embodiment of the present invention, not in order to limit essence technology contents scope of the present invention, essence technology contents of the present invention is broadly to be defined in the claim scope of application, any technology entity or method that other people complete, if defined identical with the claim scope of application, also or a kind of change of equivalence, all will be regarded as being covered by among this claim scope.
Claims (10)
1. a surface activator composition, is characterized in that, the necessary component in described compositions comprises component (a), component (b), component (c) and component (d), wherein,
Component (a) is selected from the long-chain fat acylamino-hydrochlorate of one or more following general formulas (1) or (2) expression, and in the gross weight of compositions, the percentage by weight of component (a) is 1% to 50%:
General formula (1)
General formula (2)
In general formula (1) and (2), R and R
3mean respectively hydrogen or methyl; R
1the straight chain that the expression carbon number is 7-17 or the aliphatic alkyl of branched chain; R
2and R
4mean respectively hydrogen atom, alkali metal, alkaline-earth metal, organic ammonium or alkanolamine; N means 0 or 1 integer; M means 1 or 2 integer;
Component (b) is selected from the straight chain of one or more following general formulas (3) expressions or the aliphatic alkyl glycerin ether of branched chain, and in the gross weight of compositions, the percentage by weight of component (b) is 0.1%-10%:
General formula (3)
In general formula (3), R
5the straight chain that the expression carbon number is 6-22 or the aliphatic alkyl of branched chain;
Component (c) is selected from the sorbitan fatty acid ester that one or more following general formulas (4) mean, and/or be selected from the alkyl saccharide that one or more following general formulas (5) mean, in the gross weight of compositions, the percentage by weight of component (c) is 0.1%-10%:
General formula (4)
General formula (5)
In general formula (4), R
6the straight chain that the expression carbon number is 9-19 or the aliphatic alkyl of branched chain;
In general formula (5), R
7the straight chain that the expression carbon number is 8-18 or the aliphatic alkyl of branched chain; X means the integer of 1-10;
Component (d) is selected from the solvent of one or more formations in water, lower alcohol, polyhydric alcohol, polyol ethers, and in the gross weight of compositions, the percentage by weight of component (d) is 30%-90%.
2. surface activator composition according to claim 1, it is characterized in that, component (a) is selected from one or more of following substances: the fatty acyl sarcosinate that the carbon number of fatty acyl group is 8-18, the fatty acyl glutamate, Glu that the carbon number of fatty acyl group is 8-18, the fatty acyl glycinate that the carbon number of fatty acyl group is 8-18, the fatty acyl alanine salt that the carbon number of fatty acyl group is 8-18, the fatty acyl that the carbon number of fatty acyl group is 8-18-Beta-alanine salt, the fatty acyl aspartate that the carbon number of fatty acyl group is 8-18; Described salt is potassium salt, sodium salt or triethanolamine salt;
Component (b) is selected from one or more of following substances: the aliphatic alkyl glycerin ether of the straight chain that the carbon number of alkyl is 6-22 or branched chain;
Component (c) is selected from one or more of following substances: the straight chain that the carbon number that becomes the fatty acid of ester is 10-20 or the sorbitan fatty acid ester of branched chain; And/or be selected from one or more of following substances: the alkyl polyglucoside that the carbon number of alkyl is 8-18.
3. surface activator composition according to claim 2, it is characterized in that, component (a) is selected from one or more of following substances: the fatty acyl sarcosinate that the carbon number of fatty acyl group is 8-14, the fatty acyl glutamate, Glu that the carbon number of fatty acyl group is 8-14, the fatty acyl glycinate that the carbon number of fatty acyl group is 8-14, the fatty acyl alanine salt that the carbon number of fatty acyl group is 8-14, the fatty acyl that the carbon number of fatty acyl group is 8-14-Beta-alanine salt, the fatty acyl aspartate that the carbon number of fatty acyl group is 8-14; Described salt is potassium salt, sodium salt or triethanolamine salt;
Component (b) is selected from one or more of following substances: the aliphatic alkyl glycerin ether of the straight chain that the carbon number of alkyl is 6-18 or branched chain;
Component (c) is selected from one or more of following substances: the straight chain that the carbon number that becomes the fatty acid of ester is 10-18 or the sorbitan fatty acid ester of branched chain; And/or be selected from one or more of following substances: the alkyl polyglucoside that the carbon number of alkyl is 8-14.
4. surface activator composition according to claim 3, it is characterized in that, the carbon number of described fatty acyl group is that 8-14 fatty acyl sarcosinate is selected from decoyl sarcosinate, caprinoyl sarcosinate, Hamposyl L salt, myristoyl-N-methylaminoacetic acid salt, fatty acid distribution of coconut oil acylsarcosine salt or palm-kernel oil fatty acid acyl sarcosinate;
The carbon number of described fatty acyl group is that 8-14 fatty acyl glycinate is selected from decoyl glycinate, caprinoyl glycinate, lauroyl glycinate, myristoyl glycinate, fatty acid distribution of coconut oil acyl glycinate or palm-kernel oil fatty acid acyl glycinate;
The carbon number of described fatty acyl group is that 8-14 fatty acyl glutamate, Glu is selected from decoyl glutamate, Glu, caprinoyl glutamate, Glu, lauroyl glutamate, myristoyl glutamate, Glu, fatty acid distribution of coconut oil acyl glutamate, Glu or palm-kernel oil fatty acid acyl glutamate, Glu;
The carbon number of described fatty acyl group is that 8-14 fatty acyl alanine salt is selected from decoyl alanine salt, caprinoyl alanine salt, lauroyl alanine salt, myristoyl alanine salt, fatty acid distribution of coconut oil acyl alanine salt or palm-kernel oil fatty acid acyl alanine salt;
The carbon number of described fatty acyl group is that 8-14 fatty acyl-Beta-alanine salt is selected from decoyl-Beta-alanine salt, caprinoyl-Beta-alanine salt, lauroyl-Beta-alanine salt, myristoyl-Beta-alanine salt, fatty acid distribution of coconut oil acyl-Beta-alanine salt or palm-kernel oil fatty acid acyl-Beta-alanine salt;
The carbon number of described fatty acyl group is that 8-14 fatty acyl aspartate is selected from decoyl aspartate, caprinoyl aspartate, lauroyl aspartate, myristoyl aspartate, fatty acid distribution of coconut oil acyl aspartate or palm-kernel oil fatty acid acyl aspartate;
The aliphatic alkyl glycerin ether of the straight chain that the carbon number of described alkyl is 6-18 or branched chain is selected from: hexyl glycerin ether, octyl group glycerin ether, decyl glycerin ether, lauryl glycerin ether, myristyl glycerin ether, stearyl glycerin ether, isohesyl glycerin ether, iso-octyl glycerin ether, Fancol ID base glycerol ether, isotridecyl glycerin ether, different pentadecyl glycerin ether or iso stearyl glycerin ether;
The straight chain that the carbon number of the fatty acid of described one-tenth ester is 10-18 or the sorbitan fatty acid ester of branched chain are selected from the anhydrous sorbitol decanoin, the anhydrous sorbitol laurate, the anhydrous sorbitol myristinate, the anhydrous sorbitol cetylate, Span60, anhydrous sorbitol isodecyl acid esters, the different laurate of anhydrous sorbitol, the different myristinate of anhydrous sorbitol, the different cetylate of anhydrous sorbitol, the anhydrous sorbitol isostearate, anhydrous sorbitol laurylene acid esters, anhydrous sorbitol tetradecene acid esters, anhydrous sorbitol hexadecylene acid esters or anhydrous sorbitol octadecylene acid esters,
The alkyl polyglucoside of the carbon number 8-14 of described alkyl is selected from octyl group polyglucoside, decyl polyglucoside, lauryl polyglucoside, myristyl polyglucoside or cocoyl polyglucoside.
5. surface activator composition according to claim 1, is characterized in that, the percentage by weight of component (a) is 3%-40%, is preferably 5%-25%.
6. surface activator composition according to claim 1, is characterized in that, the percentage by weight of component (b) is 0.1%-8%, is preferably 0.2%-5%; The percentage by weight of component (c) is 0.1%-8%, is preferably 0.2%-5%.
7. surface activator composition according to claim 1, is characterized in that, the percentage by weight of component (c) is 45%-85%, is preferably 65%-85%.
8. according to the described surface activator composition of claim 1-7 any one, it is characterized in that, described necessary component consists of component (a), component (b), component (c) and component (d).
9. surface activator composition according to claim 1, it is characterized in that, described compositions also contains following for beauty treatment and clean adjuvant, is selected from: be different from component (a), (b) and auxiliary suds booster (c), rheology control agent, wetting agent, polymer, the agent of tax fat, saccharide, powder, siloxanes, pearling agent, pH adjusting agent, opacifier, cosmetics and efficacy cosmetic product special composition, antiseptic, chelating agen, antimicrobial, antioxidant, dyestuff or essence used.
10. according to the purposes of the described surface activator composition of claim 1-9 any one, for the preparation of the human body clean product;
Described human body clean product comprises human body skin cleaning product, human oral cavity cleaning product, human hair cleaning product and human body eye cleaning product.
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| CN106999389B (en) * | 2014-11-18 | 2020-12-18 | 荷兰联合利华有限公司 | Compositions comprising acylglutamates as primary surfactant or primary anionic surfactant |
| CN106999389A (en) * | 2014-11-18 | 2017-08-01 | 荷兰联合利华有限公司 | Principal surfactant or the composition of Main Anions surfactant are used as comprising acyl glutamate |
| EP3220883B1 (en) | 2014-11-18 | 2018-07-04 | Unilever PLC | Composition comprising salt of acyl glutamate as primary surfactant or primary anionic surfactant |
| CN104800091B (en) * | 2015-04-22 | 2017-12-29 | 湖南艾丽科技实业有限公司 | Composition and method for thickening for transparent type pure amino acid surfactant system cleaning products from thickening |
| CN104800091A (en) * | 2015-04-22 | 2015-07-29 | 湖南艾丽科技实业有限公司 | Composition used for self thickening of transparent type pure amino acid surfactant system cleaning product, and thickening method |
| CN106588701A (en) * | 2016-12-02 | 2017-04-26 | 南京华狮新材料有限公司 | Amino acid derivative and preparation method and application thereof |
| CN110022845B (en) * | 2016-12-15 | 2022-10-04 | 莱雅公司 | Foamable compositions |
| CN110022845A (en) * | 2016-12-15 | 2019-07-16 | 莱雅公司 | Foamable composite |
| US11179307B2 (en) | 2016-12-15 | 2021-11-23 | L'oreal | Foamable composition |
| JP2020502200A (en) * | 2016-12-21 | 2020-01-23 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Liquid personal cleansing composition |
| EP3669861A1 (en) | 2016-12-21 | 2020-06-24 | Unilever PLC | Liquid personal cleansing composition |
| EP3669860A1 (en) | 2016-12-21 | 2020-06-24 | Unilever PLC | Liquid personal cleansing composition |
| US11065189B2 (en) | 2016-12-21 | 2021-07-20 | Conopco, Inc. | Liquid personal cleansing composition |
| CN110381916A (en) * | 2016-12-21 | 2019-10-25 | 荷兰联合利华有限公司 | Liquid personal cleansing composition |
| CN110381916B (en) * | 2016-12-21 | 2022-04-08 | 联合利华知识产权控股有限公司 | Liquid personal cleansing compositions |
| WO2018114536A1 (en) | 2016-12-21 | 2018-06-28 | Unilever Plc | Liquid personal cleansing composition |
| US11896699B2 (en) | 2016-12-21 | 2024-02-13 | Conopco, Inc. | Liquid personal cleansing composition comprising an acyl glycinate/acyl glutamate mixture |
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