CN103469427B - High performance fabric and manufacturing method thereof - Google Patents

High performance fabric and manufacturing method thereof Download PDF

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Publication number
CN103469427B
CN103469427B CN201310410223.0A CN201310410223A CN103469427B CN 103469427 B CN103469427 B CN 103469427B CN 201310410223 A CN201310410223 A CN 201310410223A CN 103469427 B CN103469427 B CN 103469427B
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Prior art keywords
grey cloth
dispersant
change material
phase
phototropic
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CN103469427A (en
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欧卫国
薛鹏飞
徐建华
王月华
季平
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Nantong Jinshida Gaojing Industrial Co ltd
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NANTONG ISO SPECIAL FABRIC CO Ltd
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Abstract

The invention discloses a manufacturing method of high performance fabric. The method includes gray fabric weaving, photosensitive discoloring processing, one-way humidity-guiding processing, shaping and preshrinking to obtain a finished product. The fabric is convenient to manufacture, and products are comfortable to use.

Description

High-performance fabric and manufacture method thereof
Technical field
The present invention relates to a kind of high-performance fabric and manufacture method thereof.
Background technology
Under the trend of global warming, very hot weather constantly occurs, in 2013 summers of just passing by, high temperature record is constantly refreshed, and ultraviolet radiation intensity is the trend rising year by year simultaneously.Social progress, living standards of the people improve constantly, but the environment of depending on for existence is severe all the more.
Along with growth in the living standard, during the broiling summer, people have higher requirement to wearing the functional of clothing, develop a kind of one-way wet-guide quick-drying that has, can give again the refreshing body sense of ice simultaneously and can effectively reduce ultraviolet ray the fabric of the injury of human body is become to extremely urgent problem, also there are relevant report and the application of patent of invention: CN102851808A to disclose the blended yarn that a kind of cross section structure comprises outer coolmax and inner layer cotton fibre both at home and abroad, there is hydroscopic fast-drying effect.CN103122219A discloses a kind of by the fibrous hydroscopic fast-drying shell fabric of two-layer difference.CN102134777A discloses a kind of two-layer fabric, and internal layer yarn consists of a kind of nice and cool nylon fiber FLYCOOL, but raw material manufacturing cost is high comparatively speaking, and current raw material is by state monopolies such as Japan, the U.S..
Possess above function simultaneously, and from financial cost, consider to have the also less report of seeing of larger popularization.Therefore develop and a kind ofly there is can one-way wet-guide quick-drying reducing of the refreshing body sense of ice and ultraviolet the high-performance textile of the injury of human body is had to very important meaning to the social people's livelihood simultaneously.
Summary of the invention
The object of the present invention is to provide a kind of method easy, use comfortable high-performance fabric and manufacture method thereof.
Technical solution of the present invention is:
A manufacture method for high-performance fabric, is characterized in that: comprise the following steps:
1. grey cloth is weaved:
A. phase-change material capsule of nano particle and polyester master particle congruent melting spray thread, in silk, the mass content of phase-change material is 5-20%; Described phase-change material is for being one or more in ammonium nitrate, ammonium chloride, ammonium sulfate, lithium hydroxide, glacial acetic acid sodium, calcium chloride hexahydrate, sodium thiosulfate;
B. tow and regenerated celulose fibre carry out blending, and mass ratio is polyester fiber 10-40%, regenerated celulose fibre 60-90%, spandex 0-5%; Blending is woven into grey cloth together;
2. photosensitive colour-changing is processed:
Grey cloth is put into phototropic treatment fluid, and 1-3 ℃/min is warming up to 100 ℃, and 1-2 ℃/min is warming up to 130 ℃, and insulation 30-60min, is cooled to 70 ℃ naturally, 80-100 ℃ of oven dry after washing;
Described phototropic treatment fluid is comprised of the component of following percentage by weight:
Phototropic reagent 5-30%
Dispersant 1-5%
Modification beta-schardinger dextrin-or beta-schardinger dextrin-3-10%
Polyvinyl alcohol 1-3%
CMC 3-10%
Water surplus;
3. one-way wet-guide is processed: by the grey cloth of 2. processing through step, with coating finishing agent, carry out one side top finish, be coated with reverse side, then 80-90 ℃ dries latter 140 ℃ and bake 2-6min;
Described coating finishing agent is comprised of the component of following percentage by weight:
The cotton hydrophober 2-8% that uses
Modification PU emulsion 2-20%
Blowing agent 1-10%
Stabilizing agent 1-5%
Water surplus;
4. through sizing, preshrunk, obtain finished product.
Step 2. in color changing reagent be 2-(2,4) the poly-hexanitro pyrans of-dinitro benzene yl pyridines, β-tetrachloro naphthalenone, diimidazole hydrazine, 4-amino aniline, MeF 2, one or more in the made reagent of alkaline-earth silicate class; Dispersant is: a kind of in dispersant 5040, dispersant mf, dispersant 5027, dispersant PK-100.
Step 3. middle cotton with hydrophober is: one or more in HS-1100, SP-2366, WE-137D, GN-SF2811; Stabilizing agent is hydroxyl two base cellulose or n-dodecanols; The polyurethane that modification PU emulsion is terminal groups modification, end group and polyester are detested water base combination, make polyester become hydrophilic; Blowing agent is hexadecane benzene sulfonic acid sodium salt, alkylol polyoxyethylene ether, alkyl glycoside, methyl glucamine or natural tea saponin.
The present invention is easily manufactured, and product is used comfortable.
Fabric is when as summer clothes, and because heat people knows from experience a large amount of perspirations, now, through the one side (being internal layer) of foam coating arrangement, it is to refuse water that cellulose fibre forms, and polyester fiber is hydrophilic; And outer whole take hydrophilic as main, now can produce potential difference, sweat can spread (through polyester fiber) in diffusion process to skin automatically, phase-change material first absorption portion moisture content produces endothermic effect, cause body surface microenvironment to produce the refreshing body sense of ice, and then, when moisture content touches outerly when refusing the renewable cellulose fibre of water treatment, can accelerate to spread, this process has also been accelerated water evaporates, and comprehensive function has been played unidirectional then quick-drying and had the refreshing sensation of ice.
In addition, study and show that dark clothes are than the ultraviolet injury to human body of can reducing better of light color, it is to be all subject to after illumination to darken that photosensitive colour-changing is processed, and dark color can better protect human body to avoid ultraviolet injury in summer; And when to indoor or while there is no the environment of solar irradiation fabric can recover light color originally or white, the heat radiation of the absorption surrounding environment that light color or white can be still less, makes human body feel more comfortable.
Below in conjunction with embodiment, the invention will be further described.
The specific embodiment
Embodiment 1:
A manufacture method for high-performance fabric, comprises the following steps:
1. grey cloth is weaved:
A. phase-change material capsule of nano particle and polyester master particle congruent melting spray thread, in silk, the mass content of phase-change material is 18%; Described phase-change material is for being one or more in ammonium nitrate, ammonium chloride, ammonium sulfate, lithium hydroxide, glacial acetic acid sodium, calcium chloride hexahydrate, sodium thiosulfate;
B. tow and Modal fibre carry out blending, and mass ratio is polyester fiber 40%, model 55%, spandex 5%; Blending is woven into grey cloth together;
2. photosensitive colour-changing is processed:
Grey cloth is put into phototropic treatment fluid, and 2 ℃/min is warming up to 100 ℃, and 1.5 ℃/min is warming up to 130 ℃, and insulation 40min, is cooled to 70 ℃ naturally, 90 ℃ of oven dry after washing;
Described phototropic treatment fluid is comprised of the component of following percentage by weight:
Phototropic reagent 15%
Dispersant 2%
Modification beta-schardinger dextrin-or beta-schardinger dextrin-7%
Polyvinyl alcohol 2%
CMC 6%
Water surplus;
3. one-way wet-guide is processed: by the grey cloth of 2. processing through step, with coating finishing agent, carry out one side top finish, be coated with reverse side, coating head pressure is 1kg/cm 2, then 90 ℃ dry latter 140 ℃ and bake 3.5min;
Described coating finishing agent is comprised of the component of following percentage by weight:
Cotton with hydrophober 4%
Modification PU emulsion 15%
Blowing agent 5%
Stabilizing agent 3%
Water surplus;
4. through sizing, preshrunk, obtain finished product.
Step 2. in color changing reagent be 2-(2,4) the poly-hexanitro pyrans of-dinitro benzene yl pyridines, β-tetrachloro naphthalenone, diimidazole hydrazine, 4-amino aniline, MeF 2, one or more in the made reagent of alkaline-earth silicate class; Dispersant is: a kind of in dispersant 5040, dispersant mf, dispersant 5027, dispersant PK-100.
Step 3. middle cotton with hydrophober is: one or more in HS-1100, SP-2366, WE-137D, GN-SF2811; Stabilizing agent is hydroxyl two base cellulose or n-dodecanols; The polyurethane that modification PU emulsion is terminal groups modification, end group and polyester are detested water base combination, make polyester become hydrophilic; Blowing agent is hexadecane benzene sulfonic acid sodium salt, alkylol polyoxyethylene ether, alkyl glycoside, methyl glucamine or natural tea saponin.
Embodiment 2:
A manufacture method for high-performance fabric, comprises the following steps:
1. grey cloth is weaved:
A. phase-change material capsule of nano particle and polyester master particle congruent melting spray thread, in silk, the mass content of phase-change material is 18%; Described phase-change material is for being one or more in ammonium nitrate, ammonium chloride, ammonium sulfate, lithium hydroxide, glacial acetic acid sodium, calcium chloride hexahydrate, sodium thiosulfate;
B. tow carries out blending with a day silk, and mass ratio is polyester fiber 42%, regenerated celulose fibre 55%, spandex 3%; Blending is woven into grey cloth together;
2. photosensitive colour-changing is processed:
Grey cloth is put into phototropic treatment fluid, and 2 ℃/min is warming up to 100 ℃, and 1.5 ℃/min is warming up to 130 ℃, and insulation 45min, is cooled to 70 ℃ naturally, 90 ℃ of oven dry after washing;
Described phototropic treatment fluid is comprised of the component of following percentage by weight:
Phototropic reagent 18%
Dispersant 2%
Modification beta-schardinger dextrin-or beta-schardinger dextrin-8%
Polyvinyl alcohol 2.5%
CMC 7%
Water surplus;
3. one-way wet-guide is processed: by the grey cloth of 2. processing through step, with coating finishing agent, carry out one side top finish, be coated with reverse side, coating head pressure is 1kg/cm 2, then 90 ℃ dry latter 140 ℃ and bake 3.5min;
Described coating finishing agent is comprised of the component of following percentage by weight:
Cotton with hydrophober 6%
Modification PU emulsion 18%
Blowing agent 5%
Stabilizing agent 3%
Water surplus;
4. through sizing, preshrunk, obtain finished product.
Step 2. in color changing reagent be 2-(2,4) the poly-hexanitro pyrans of-dinitro benzene yl pyridines, β-tetrachloro naphthalenone, diimidazole hydrazine, 4-amino aniline, MeF 2, one or more in the made reagent of alkaline-earth silicate class; Dispersant is: a kind of in dispersant 5040, dispersant mf, dispersant 5027, dispersant PK-100.
Step 3. middle cotton with hydrophober is: one or more in HS-1100, SP-2366, WE-137D, GN-SF2811; Stabilizing agent is hydroxyl two base cellulose or n-dodecanols; The polyurethane that modification PU emulsion is terminal groups modification, end group and polyester are detested water base combination, make polyester become hydrophilic; Blowing agent is hexadecane benzene sulfonic acid sodium salt, alkylol polyoxyethylene ether, alkyl glycoside, methyl glucamine or natural tea saponin.

Claims (4)

1. a high-performance fabric, is characterized in that: by following production method, made:
1. grey cloth is weaved:
A. phase-change material capsule of nano particle and polyester master particle congruent melting spray thread, in silk, the mass content of phase-change material is 5-20%; Described phase-change material is one or more in ammonium nitrate, ammonium chloride, ammonium sulfate, lithium hydroxide, glacial acetic acid sodium, calcium chloride hexahydrate, sodium thiosulfate;
B. tow and regenerated celulose fibre carry out blending, and mass ratio is polyester fiber 10-40%, regenerated celulose fibre 60-90%, spandex 0-5%; Blending is woven into grey cloth together;
2. photosensitive colour-changing is processed:
Grey cloth is put into phototropic treatment fluid, and 1-3 ℃/min is warming up to 100 ℃, and 1-2 ℃/min is warming up to 130 ℃, and insulation 30-60min, is cooled to 70 ℃ naturally, 80-100 ℃ of oven dry after washing;
Described phototropic treatment fluid is comprised of the component of following percentage by weight:
3. one-way wet-guide is processed: by the grey cloth of 2. processing through step, with coating finishing agent, carry out one side top finish, be coated with reverse side, then 80-90 ℃ dries latter 140 ℃ and bake 2-6min;
Described coating finishing agent is comprised of the component of following percentage by weight:
4. through sizing, preshrunk, obtain finished product.
2. a manufacture method for high-performance fabric, is characterized in that: comprise the following steps:
1. grey cloth is weaved:
A. phase-change material capsule of nano particle and polyester master particle congruent melting spray thread, in silk, the mass content of phase-change material is 5-20%; Described phase-change material is for being one or more in ammonium nitrate, ammonium chloride, ammonium sulfate, lithium hydroxide, glacial acetic acid sodium, calcium chloride hexahydrate, sodium thiosulfate;
B. tow and regenerated celulose fibre carry out blending, and mass ratio is polyester fiber 10-40%, regenerated celulose fibre 60-90%, spandex 0-5%; Blending is woven into grey cloth together;
2. photosensitive colour-changing is processed:
Grey cloth is put into phototropic treatment fluid, and 1-3 ℃/min is warming up to 100 ℃, and 1-2 ℃/min is warming up to 130 ℃, and insulation 30-60min, is cooled to 70 ℃ naturally, 80-100 ℃ of oven dry after washing;
Described phototropic treatment fluid is comprised of the component of following percentage by weight:
3. one-way wet-guide is processed: by the grey cloth of 2. processing through step, with coating finishing agent, carry out one side top finish, be coated with reverse side, then 80-90 ℃ dries latter 140 ℃ and bake 2-6min;
Described coating finishing agent is comprised of the component of following percentage by weight:
4. through sizing, preshrunk, obtain finished product.
3. the manufacture method of high-performance fabric according to claim 2, it is characterized in that: step 2. middle phototropic reagent is one or more in 2-(2,4)-dinitro benzene yl pyridines, β-tetrachloro naphthalenone, diimidazole hydrazine, the poly-hexanitro pyrans of 4-amino aniline, MeF2, the made reagent of alkaline-earth silicate class; Dispersant is: a kind of in dispersant 5040, dispersant mf, dispersant 5027, dispersant PK-100.
4. according to the manufacture method of the high-performance fabric described in claim 2 or 3, it is characterized in that: step 3. middle cotton with hydrophober is: one or more in HS-1100, SP-2366, WE-137D, GN-SF2811; Stabilizing agent is hydroxyl two base cellulose or n-dodecanols; The polyurethane that modification PU emulsion is terminal groups modification, end group and polyester are detested water base combination, make polyester become hydrophilic; Blowing agent is hexadecane benzene sulfonic acid sodium salt, alkylol polyoxyethylene ether, alkyl glycoside, methyl glucamine or natural tea saponin.
CN201310410223.0A 2013-09-11 2013-09-11 High performance fabric and manufacturing method thereof Active CN103469427B (en)

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CN104404647B (en) * 2014-10-15 2016-08-17 浙江恒逸高新材料有限公司 Hydrophilic polyesters fiber that a kind of Cellulose nanocrystal is modified and preparation method thereof
CN104313765A (en) * 2014-11-04 2015-01-28 常熟市新达纬编厂 Anti-ultraviolet fabric
CN105040241B (en) * 2015-08-22 2016-06-22 苏州正业昌智能科技有限公司 A kind of preparation method of antibacterial blended yarn weaved fabric
US10584432B2 (en) * 2015-09-28 2020-03-10 Asahi Kasei Kabushiki Kaisha Multilayer-structure circular knit fabric
CN106048875A (en) * 2016-06-03 2016-10-26 浙江真爱毯业科技有限公司 Production method for Flycool fiber Raschel blanket
CN107471760A (en) * 2017-08-09 2017-12-15 浙江联翔家居装饰股份有限公司 One kind discoloration embroidery wall cloth production technology
CN108085835A (en) * 2017-12-26 2018-05-29 郑州莱雅实业有限公司 A kind of processing technology of chameleon fibre garment material
CN107904752A (en) * 2017-12-26 2018-04-13 郑州莱雅实业有限公司 A kind of processing technology of the environmental garment fabric of discoloration
CN108085834A (en) * 2017-12-26 2018-05-29 郑州莱雅实业有限公司 A kind of garment material and its processing technology
CN109736083A (en) * 2018-12-29 2019-05-10 中润科技股份有限公司 A kind of nano modification bidirectional inductive Far Infrared Polyester Fiber long filament and its preparation process
CN111041655A (en) * 2020-01-20 2020-04-21 安正时尚集团股份有限公司 Breathable moisture-absorbing warm-keeping fabric
CN111455658B (en) * 2020-03-26 2021-12-10 南通大学 Photochromic cotton fabric and preparation method thereof

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Address after: 226000 No. 8, Xinhe Road, economic and Technological Development Zone, Nantong City, Jiangsu Province

Patentee after: Nantong jinshida Gaojing Industrial Co.,Ltd.

Address before: 226000 No. 8, New River Road, Nantong Development Zone, Jiangsu

Patentee before: NANTONG SPECIAL FABRIC Co.,Ltd.

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