CN103468361B - 铌及铌合金板带材热轧润滑剂 - Google Patents
铌及铌合金板带材热轧润滑剂 Download PDFInfo
- Publication number
- CN103468361B CN103468361B CN201310415266.8A CN201310415266A CN103468361B CN 103468361 B CN103468361 B CN 103468361B CN 201310415266 A CN201310415266 A CN 201310415266A CN 103468361 B CN103468361 B CN 103468361B
- Authority
- CN
- China
- Prior art keywords
- agent
- niobium
- hot rolling
- compound
- rolling lubricating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 229910052758 niobium Inorganic materials 0.000 title claims abstract description 19
- 239000010955 niobium Substances 0.000 title claims abstract description 19
- 239000000314 lubricant Substances 0.000 title claims abstract description 11
- 229910001257 Nb alloy Inorganic materials 0.000 title abstract description 8
- 238000005098 hot rolling Methods 0.000 title abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 150000001336 alkenes Chemical class 0.000 claims abstract description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002199 base oil Substances 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 5
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 4
- 230000000996 additive effect Effects 0.000 claims abstract description 3
- 239000002131 composite material Substances 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 15
- -1 Triazole lipid Chemical class 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 5
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical group [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 claims description 5
- 150000001993 dienes Chemical group 0.000 claims description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 210000000582 semen Anatomy 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- 238000005987 sulfurization reaction Methods 0.000 claims description 5
- 150000003751 zinc Chemical class 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 230000002335 preservative effect Effects 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 238000011010 flushing procedure Methods 0.000 abstract description 4
- 231100000956 nontoxicity Toxicity 0.000 abstract description 4
- 239000003921 oil Substances 0.000 abstract description 4
- 238000000137 annealing Methods 0.000 abstract description 3
- 239000002480 mineral oil Substances 0.000 abstract description 3
- 235000010446 mineral oil Nutrition 0.000 abstract description 3
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- 239000002585 base Substances 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 3
- 230000000994 depressogenic effect Effects 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- NICDRCVJGXLKSF-UHFFFAOYSA-N nitric acid;trihydrochloride Chemical compound Cl.Cl.Cl.O[N+]([O-])=O NICDRCVJGXLKSF-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002887 superconductor Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
一种铌及铌合金板带材热轧润滑剂，采用聚内烯烃作为基础油，配合多种复合添加剂，包括抗磨剂、摩擦改进剂、抗氧防腐剂、抗乳化剂、抗泡剂、清净剂、分散剂。采用硫含量极低的精制矿物油调配成，具有良好的耐负荷性、压下性及安定性，不产生退火污斑；同时，可提高工艺润滑性能，增加变形区内油膜强度，降低摩擦系数，组成和性能稳定；不易发生轧件与轧辊热粘结现象；具有清洁和冲洗性能；对金属和设备无腐蚀，无毒性，无刺激性气味。
Description
技术领域
本发明属铌及铌合金板带材热轧润滑剂领域。
背景技术
铌是灰白色金属，熔点2468℃，沸点4742℃，密度8.578.57g/cm3。室温下铌在空气中稳定，在氧气中红热时也不被完全氧化，高温下与硫、氮、碳直接化合，能与钛、锆、铪、钨形成合金。不与无机酸或碱作用，也不溶于王水，但可溶于氢氟酸。铌能吸收气体，用作除气剂，也是一种良好的超导体。用铌制造的合金，临界温度高达绝对温度十八点五到二十一度，是目前最重要的超导材料。超导材料几乎不会损失电流。如果使用超导电缆输电，因为它没有电阻，电流通过时不会有能量损耗，所以输电效率将会大大提高。
在钢的各种微合金化元素中，铌是最有效的微合金化元素，铌的作用如此之大，以至于铁原子中含有丰富的铌原子，就能达到改善钢性能的目的。用铌条代替人体里折断了的骨头之后，经过一段时间，肌肉居然会在铌条上生长起来，就像在真正的骨头上生长一样；这一切都源于其超强的抗腐蚀能力。
实际上钢中加入0.001%～0.1%的铌，就足以改变钢的力学性能。铌还可以通过诱导析出和控制冷却速度，实现析出物弥散分布。在较宽的范围内调整钢的韧性水平。因此，加入铌不仅可以提高钢的强度，还可以提高钢的韧性、抗高温氧化性和耐蚀性，降低钢脆性转变温度，获得好的焊接性能和成型性能。
铌及铌合金板带材的热轧要求采用硫含量极低的精制矿物油调配成，具有耐负荷性、压下性及安定性良好，不产生退火污斑；同时，提高工艺润滑性能，增加变形区内油膜强度，降低摩擦系数，组成和性能稳定；不易发生轧件与轧辊热粘洁现象，具有清洁和冲洗性能；对金属和设备无腐蚀，无毒性，无刺激性气味的润滑剂。
发明内容
本发明要解决的技术问题是提供一种具有良好耐负荷性、压下性及安定性、能提高工艺润滑性能，增加变形区内油膜强度，降低摩擦系数，组成和性能稳定，不易发生轧件与轧辊热粘结，有清洁和冲洗性能、对金属和设备无腐蚀，无毒性，无刺激性气味的铌及铌合金板带材热轧润滑剂。
本发明以如下技术方案解决上述技术问题：采用聚内烯烃作为基础油，配合多种复合添加剂，其各组分及其质量百分数为：
| 组分 | 含量（质量百分比） |
| 基础油 | 75%～82% |
| 抗磨剂 | 4.0%～6.0% |
| 摩擦改进剂 | 4.0%～7.0% |
| 抗氧防腐剂 | 0.8%～1.2% |
| 抗乳化剂 | 0.01%～0.1% |
| 抗泡剂 | 0.001%～0.005% |
| 清净剂 | 3.0%～5.0% |
| 分散剂 | 4.0%～6.0% |
基础油是聚内烯烃。
抗磨剂是质量比60%～50%的硼酸盐与40%～50%的磷酸三甲酚酯复合。
摩擦改进剂是质量比70%～60%的硫化棉籽油与30%～40%的苯三唑脂肪酸胺盐复合。
抗氧防腐剂是硫磷仲基锌盐。
抗乳化剂是聚醚高分子化合物。
抗泡剂是二甲基硅油。
清净剂是超高碱值合成磺酸镁。
分散剂是双烯基丁二酰亚胺。
本发明的铌及铌合金板带材热轧润滑剂，采用硫含量极低精制矿物油调配成具有耐负荷性、压下性及安定性良好、不产生退火污斑的润滑剂；同时，提高工艺润滑性能，增加变形区内油膜强度，降低摩擦系数，组成和性能稳定；不易发生轧件与轧辊热粘结现象，具有清洁和冲洗性能；对金属和设备无腐蚀，无毒性，无刺激性气味。
具体实施方式
实施例1：
将下列组分按质量百分比调和而成：
| 组分 | 含量（质量百分比） |
| 聚内烯烃 | 75% |
| 质量比60%的硼酸盐与40%的磷酸三甲酚酯复合 | 6.0% |
| 质量比70%的硫化棉籽油与30%的苯三唑脂肪酸胺盐复合 | 7.0% |
| 硫磷仲基锌盐 | 0.9% |
| 聚醚高分子化合物 | 0.095% |
| 二甲基硅油 | 0.005% |
| 超高碱值合成磺酸镁 | 5.0% |
| 双烯基丁二酰亚胺 | 6.0% |
以上组分总和为100%。
实施例2：
将下列组分按质量百分比调和而成：
| 组分 | 含量（质量百分比） |
| 聚内烯烃 | 78% |
| 质量比55%的硼酸盐与45%的磷酸三甲酚酯复合 | 5.0% |
| 质量比65%的硫化棉籽油与35%的苯三唑脂肪酸胺盐复合 | 6.0% |
| 硫磷仲基锌盐 | 0.91% |
| 聚醚高分子化合物 | 0.087% |
| 二甲基硅油 | 0.003% |
| 超高碱值合成磺酸镁 | 4.5% |
| 双烯基丁二酰亚胺 | 5.5% |
以上组分总和为100%。
实施例3：
将下列组分按质量百分比调和而成：
| 组分 | 含量（质量百分比） |
| 聚内烯烃 | 80% |
| 质量比50%的硼酸盐与50%的磷酸三甲酚酯复合 | 4.5% |
| 质量比60%的硫化棉籽油与40%的苯三唑脂肪酸胺盐复合 | 5.5% |
| 硫磷仲基锌盐 | 0.82% |
| 聚醚高分子化合物 | 0.078% |
| 二甲基硅油 | 0.002% |
| 超高碱值合成磺酸镁 | 4.1% |
| 双烯基丁二酰亚胺 | 5.0% |
以上组分总和为100%。
以下为实施例1产品的主要理化指标：
| 项目 | 质量指标 |
| 水分，% | 痕迹 |
| 40℃运动粘度mm2/s | 70.2 |
| 闪点（开口）℃， | 234 |
| 机械杂质，% | 无 |
| 最大无卡咬负荷(Pb)，Kg | 95 |
| 倾点，℃， | -25 |
| 水溶性酸或碱 | 无 |
| 腐蚀试验(铜片、100℃、3h)，级 | 1 |
| 粘度指数， | 120 |
Claims (1)
1.一种铌及其合金板带材热轧润滑剂，其特征在于采用聚内烯烃作为基础油，配合多种复合添加剂，其各组分及其质量百分数为：
以上各组分含量百分数之和为100％；
其中：
基础油是聚内烯烃；
抗磨剂是质量比60％～50％的硼酸盐与40％～50％的磷酸三甲酚酯复合；
摩擦改进剂是质量比70％～60％的硫化棉籽油与30％～40％的苯三唑脂肪酸胺盐复合；
抗氧防腐剂是硫磷仲基锌盐；
抗乳化剂是聚醚高分子化合物；
抗泡剂是二甲基硅油；
清净剂是超高碱值合成磺酸镁；
分散剂是双烯基丁二酰亚胺。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310415266.8A CN103468361B (zh) | 2013-09-12 | 2013-09-12 | 铌及铌合金板带材热轧润滑剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310415266.8A CN103468361B (zh) | 2013-09-12 | 2013-09-12 | 铌及铌合金板带材热轧润滑剂 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103468361A CN103468361A (zh) | 2013-12-25 |
| CN103468361B true CN103468361B (zh) | 2014-08-27 |
Family
ID=49793406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310415266.8A Expired - Fee Related CN103468361B (zh) | 2013-09-12 | 2013-09-12 | 铌及铌合金板带材热轧润滑剂 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103468361B (zh) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796594B (zh) * | 2012-08-24 | 2014-08-06 | 东北大学 | 含改性纳米铜的冷轧薄板轧制乳化油及其制备方法 |
-
2013
- 2013-09-12 CN CN201310415266.8A patent/CN103468361B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN103468361A (zh) | 2013-12-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103468362B (zh) | 铅及其合金箔材冷轧润滑剂 | |
| CN103695091A (zh) | 铝及铝合金材料冷锻造的润滑剂 | |
| CN103436333B (zh) | 钒及其合金板带材冷轧润滑剂 | |
| CN103421591B (zh) | 铝及铝合金材热轧复合型乳化液组合物 | |
| CN103627483B (zh) | 钒及其合金板带材中间冷轧润滑剂 | |
| CN103468361B (zh) | 铌及铌合金板带材热轧润滑剂 | |
| CN103710079A (zh) | 铜及铜合金材料冷锻造的润滑剂 | |
| CN103409212B (zh) | 钼及钼合金板带材热轧润滑剂 | |
| CN103409205B (zh) | 钒及其合金板带材热轧润滑剂 | |
| CN103421586B (zh) | 锆及锆合金箔材冷轧润滑剂 | |
| CN103468365B (zh) | 铌及铌合金板带材中间冷轧润滑剂 | |
| CN103666703A (zh) | 冲压铅及铅合金材料的润滑剂 | |
| CN103450987B (zh) | 铝及铝合金材热轧非离子型乳化液组合物 | |
| CN103450992B (zh) | 铌及铌合金箔材冷轧润滑剂 | |
| CN103409215B (zh) | 钼及钼合金箔材冷轧润滑剂 | |
| CN103421590B (zh) | 锆及锆合金板带材热轧润滑剂 | |
| CN105063294A (zh) | 环境友好低温回火液的组合物 | |
| CN103450970B (zh) | 铌与铌合金板带材成品冷轧润滑剂 | |
| CN103614191B (zh) | 锰及其合金板带材热轧润滑剂 | |
| CN103571584A (zh) | 铼及其合金板带材冷轧润滑剂 | |
| CN103627482B (zh) | 钒及其合金箔材冷轧润滑剂 | |
| CN103450976B (zh) | 钨及其合金箔材冷轧润滑剂 | |
| CN103627479B (zh) | 铪及其合金箔材冷轧润滑剂 | |
| CN103571583B (zh) | 锰及其合金板带材冷轧润滑剂 | |
| CN103627480B (zh) | 镉及其合金箔材冷轧润滑剂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Huang Fuchuan Inventor after: Tian Zongyi Inventor after: Liao Dankui Inventor after: Liu Kun Inventor after: Mo Yufei Inventor after: Su man Rong Inventor after: Tang Xingzhong Inventor after: Lan Mingxin Inventor after: Xiao Youcheng Inventor after: Li Sheng Inventor after: Liang Hui Inventor after: Tang Caizhen Inventor before: Huang Fuchuan Inventor before: Tang Caizhen Inventor before: Tian Zongyi Inventor before: Liao Dankui Inventor before: Liu Kun Inventor before: Mao Hanling Inventor before: Mo Yufei Inventor before: Su man Rong Inventor before: Tang Xingzhong Inventor before: Lan Mingxin Inventor before: Xiao Youcheng Inventor before: Li Sheng Inventor before: Liang Hui |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: HUANG FUCHUAN MAO HANLING MO YUFEI SU MANRONG TANG XINGZHONG LAN MINGXIN XIAO YOUCHENG LI SHENG LIANG HUI TANG CAIZHEN TIAN ZONGYI LIAO DANKUI LIU KUN TO: HUANG FUCHUAN MO YUFEI SU MANRONG TANG XINGZHONG LAN MINGXIN XIAO YOUCHENG LI SHENG LIANG HUI TANG CAIZHEN TIAN ZONGYI LIAO DANKUI LIU KUN |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140827 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |