CN103468041A - Water-based paint with mosquito repelling effect and preparation method thereof - Google Patents
Water-based paint with mosquito repelling effect and preparation method thereof Download PDFInfo
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- CN103468041A CN103468041A CN2013103510162A CN201310351016A CN103468041A CN 103468041 A CN103468041 A CN 103468041A CN 2013103510162 A CN2013103510162 A CN 2013103510162A CN 201310351016 A CN201310351016 A CN 201310351016A CN 103468041 A CN103468041 A CN 103468041A
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Abstract
The invention relates to an environment-friendly coating, in particular to a water-based paint with a mosquito repelling effect and a preparation method thereof. The raw materials for preparation of the water-based paint with a mosquito repelling effect contains a citronellal solution, which is prepared from citronellal and a 97%-99% ethanol solution in a weight part ratio of 10-40:60-90. The raw materials for preparation of the paint also include water, a dispersant, a wetting agent, a defoaming agent, a thickening agent, titanium dioxide, a pH regulator, heavy calcium carbonate, kaolin, talc powder, an emulsion, a coalescing agent, an antifreezing agent, a mildewproof agent and a leveling agent. The water-based paint provided in the invention has a mosquito expelling effect, and is harmless to the human body, also can purify indoor air properly, and can meet the requirements of indoor decoration.
Description
Technical field
The present invention relates to a kind of environmental protection coating material, particularly a kind of (for the indoor wall surface decoration) has water-borne coatings of repelling effect and preparation method thereof.
Background technology
People generally believe, living environment is become better and better, and mosquito also should reduce thereupon; Yet true really not so, along with growth in the living standard, domestic refuse and green belt are also more and more, the discarded container of wide green belt and easy ponding can become multiplying of mosquito and habitat; In addition, in the water gathering system of city, a large amount of catch-basins, pump well etc. are also the natural hotbeds that mosquito breeds.
People's shelter is mainly in order to allow the people feel comfortable, relieved, to feel at ease, but due to the interference that is subject to mosquito, cause people's life doubly disturbed, life for the interference people that solve mosquito, often in the place of shelter, put the flowers and plants of some mosquito repellents, but do not have very large effect, only have the place of placement to reduce mosquito, but elsewhere still has the existence of mosquito.
Summary of the invention
The present invention be directed to mosquito and affect the problem that people live, a kind of water-borne coatings with repelling effect and preparation method thereof is provided, and it had both had the driving away mosquito effect, harmless again, simultaneously can suitable purifying the air of a room, and can also meet the requirement of upholstery.
Technical solution of the present invention is as follows:
One) scheme one: a kind of water-borne coatings with repelling effect is characterized in that: contain geranial solution in the raw material for the preparation of coating.
Described geranial solution is that the ethanolic soln that is 97%-99% by geranial and concentration is formulated according to the ratio of weight and number of 10-40:60-90.
The described raw material for the preparation of coating also comprises water, dispersion agent, wetting agent, defoamer, thickening material, titanium dioxide, PH conditioning agent, water-ground limestone, kaolin, talcum powder, emulsion, film coalescence aid, frostproofer, mould inhibitor and flow agent, and the weight proportion of each raw material is as follows:
Described dispersion agent is the polycarboxylate sodium; Described water-ground limestone adopts 800 purpose water-ground limestones; Described kaolin adopts calcined kaolin or water-washed kaoline.
Described polycarboxylate sodium can adopt SN-5040 or similar other type product of Nuo Puke; Described wetting agent can peaceful PE100 or similar other type product of employing section; Described defoamer can adopt CF-246 or similar other type product of Blackburn; Described mould inhibitor can adopt EPW or similar other type product of Sol; Described thickening material can adopt inferior to imperial 250HBR or similar other type product; Described titanium dioxide can adopt R706 or similar other type product of Dupont; Described PH conditioning agent can adopt AMP-95 or similar other type product of DOW Chemical; Described emulsion can adopt the rich RS998 of Ahmedabad or similar other type product; Described film coalescence aid can adopt Yi Shiman Texno1 or similar other type product.
Two) scheme two: a kind of for the preparation of the described preparation method with water-borne coatings of repelling effect of scheme one, it is characterized in that: it comprises following step of sequentially carrying out:
(1) be less than under the speed of 500r/min, by 90% of whole total amounts of 10-35 part water, 0.4-0.8 part dispersion agent, 0.1-0.2 part wetting agent, 50% of whole total amounts of 0.2-0.5 part defoamer, 0.3-0.6 part thickening material adds in container, mixing and stirring;
(2), under the speed of 500r/min-1000r/min, add successively 8-30 part titanium dioxide, 0.05-0.15 part PH conditioning agent, 5-30 part water-ground limestone, 5-15 part kaolin, 5-15 part talcum powder, mixing and stirring;
(3) be greater than under the speed of 1000r/min, dispersion or sand milling are to fineness<50 μ m;
(4) be less than under the speed of 500r/min, add successively 10-35 part emulsion, 0.5-2.5 part film coalescence aid, 0.5-2.5 part frostproofer, 0.1-0.4 part sanitas, 0.5-2.5 part geranial solution, 0.1-1.5 part flow agent, 0.2-0.5 part defoamer whole total amounts 50%, whole total amounts of 10-35 part water 10%, mixing and stirring, obtain product of the present invention.
The preparation method of described geranial solution is as follows: the ethanolic soln that is 97%-99% by 60-90 part concentration adds in another container, add while stirring 10-40 part geranial, heating is no more than under 70 ℃, and geranial is dissolved in ethanolic soln fully, forms clear solution.
Compared with prior art, the present invention has following advantage:
1) contain geranial in the coating that prepared by the present invention, the aromatic odour of its geranial not only has unique repelling effect, and harmless;
2) the present invention's nonirritant chemical odor not only, and the geranial fragrance with fragrance uniqueness, can play allowing the effect of people's spirit and QI cleaning;
3) the present invention has good material performance, the air in decontamination chamber that can be suitable, and can also meet the requirement of upholstery.
Embodiment
Below in conjunction with embodiment, embodiment, content of the present invention is elaborated:
(1) embodiment
The specific embodiment of the invention provides a kind of water-borne coatings with repelling effect, contains geranial solution in the raw material for the preparation of coating.
Described geranial solution is that the ethanolic soln that is 97%-99% by geranial and concentration is formulated according to the ratio of weight and number of 10-40:60-90.
The described raw material for the preparation of coating also comprises water, dispersion agent, wetting agent, defoamer, thickening material, titanium dioxide, PH conditioning agent, water-ground limestone, kaolin, talcum powder, emulsion, film coalescence aid, frostproofer, mould inhibitor and flow agent, and the weight proportion of each raw material is as follows:
The above-mentioned preparation method with water-borne coatings of repelling effect, it comprises following step of sequentially carrying out:
(1) be less than under the speed of 500r/min, by 90% of whole total amounts of 10-35 part water, 0.4-0.8 part dispersion agent, 0.1-0.2 part wetting agent, 50% of whole total amounts of 0.2-0.5 part defoamer, 0.3-0.6 part thickening material adds in container, mixing and stirring;
(2), under the speed of 500r/min-1000r/min, add successively 8-30 part titanium dioxide, 0.05-0.15 part PH conditioning agent, 5-30 part water-ground limestone, 5-15 part kaolin, 5-15 part talcum powder, mixing and stirring;
(3) be greater than under the speed of 1000r/min, dispersion or sand milling are to fineness<50 μ m;
(4) be less than under the speed of 500r/min, add successively 10-35 part emulsion, 0.5-2.5 part film coalescence aid, 0.5-2.5 part frostproofer, 0.1-0.4 part sanitas, 0.5-2.5 part geranial solution, 0.1-1.5 part flow agent, 0.2-0.5 part defoamer whole total amounts 50%, whole total amounts of 10-35 part water 10%, mixing and stirring, obtain product of the present invention.
The preparation method of above-mentioned geranial solution is as follows: the ethanolic soln that is 97%-99% by 60-90 part concentration adds in another container, add while stirring 10-40 part geranial, heating is no more than under 70 ℃, and geranial is dissolved in ethanolic soln fully, forms clear solution.
(2) embodiment
Embodiment 1 is most preferred embodiment
Water-borne coatings with repelling effect, it is made by the raw material of following weight proportioning:
The above-mentioned preparation method with water-borne coatings of repelling effect, it comprises following step of sequentially carrying out:
, be less than under the speed of 500r/min, by 90%, 0.7 part of dispersion agent of whole total amounts of 21.2 parts of water, 0.1 part of wetting agent, 50%, 0.4 part of thickening material of whole total amounts of 0.4 part of defoamer adds in container, mixing and stirring;
, under the speed of 1000r/min, add successively 21 parts of titanium dioxides, 0.1 part of PH conditioning agent, 5 parts of water-ground limestones, 5 parts of kaolin, 5 parts of talcum powder, mixing and stirring;
, be greater than under the speed of 1000r/min, disperse or sand milling to fineness<50 μ m;
(4), be less than under the speed of 500r/min, add successively 32 parts of emulsions, 2.5 part film coalescence aid, 2.5 part frostproofer, 0.8 portion of sanitas, 2 parts of geranial solution, 1.5 flow agent, 0.4 remain residue 10% mixing and stirring in the total amount of 50%, 21.2 part of water in the total amount of part defoamer, can obtain product of the present invention.
The preparation method of above-mentioned geranial solution is as follows: the ethanolic soln that is 98% by 70 parts of concentration adds in another container, adds while stirring 20 parts of geranials, and heating is no more than under 70 ℃, and geranial is dissolved in ethanolic soln fully, forms clear solution.
Embodiment 2
Water-borne coatings with repelling effect, it is made by the raw material of following weight proportioning:
The above-mentioned preparation method with water-borne coatings of repelling effect, it comprises following step of sequentially carrying out:
, be less than under the speed of 500r/min, by 90%, 0.5 part of dispersion agent of whole total amounts of 21.2 parts of water, 0.1 part of wetting agent, 50%, 0.4 part of thickening material of whole total amounts of 0.4 part of defoamer adds in container, mixing and stirring;
, under the speed of 500r/min, add successively 15 parts of titanium dioxides, 0.1 part of PH conditioning agent, 25 parts of water-ground limestones, 5 parts of kaolin, 10 parts of talcum powder, mixing and stirring;
, be greater than under the speed of 1000r/min, disperse or sand milling to fineness<50 μ m;
(4), be less than under the speed of 500r/min, add successively 15 parts of emulsions, 1 part of film coalescence aid, 2 parts of frostproofers, 0.8 portion of sanitas, 3 parts of geranial solution, 0.5 flow agent, 0.4 remain residue 10% mixing and stirring in the total amount of 50%, 21.2 part of water in the total amount of part defoamer, can obtain product of the present invention.
The preparation method of above-mentioned geranial solution is as follows: the ethanolic soln that is 99% by 60 parts of concentration adds in another container, adds while stirring 10 parts of geranials, and heating is no more than under 70 ℃, and geranial is dissolved in ethanolic soln fully, forms clear solution.
Embodiment 3
Water-borne coatings with repelling effect, it is made by the raw material of following weight proportioning:
The above-mentioned preparation method with water-borne coatings of repelling effect, it comprises following step of sequentially carrying out:
, be less than under the speed of 500r/min, by 90%, 0.7 part of dispersion agent of whole total amounts of 22.5 parts of water, 0.1 part of wetting agent, 50%, 0.4 part of thickening material of whole total amounts of 0.4 part of defoamer adds in container, mixing and stirring;
, under the speed of 800r/min, add successively 21 parts of titanium dioxides, 0.1 part of PH conditioning agent, 5 parts of water-ground limestones, 5 parts of kaolin, 5 parts of talcum powder, mixing and stirring;
, be greater than under the speed of 1000r/min, disperse or sand milling to fineness<50 μ m;
(4), be less than under the speed of 500r/min, add successively 32 parts of emulsions, 2.5 part film coalescence aid, 2.5 part frostproofer, 0.3 portion of sanitas, 2 parts of geranial solution, 1.5 flow agent, 0.4 remain residue 10% mixing and stirring in the total amount of 50%, 22.5 part of water in the total amount of part defoamer, can obtain product of the present invention.
The preparation method of above-mentioned geranial solution is as follows: the ethanolic soln that is 98% by 70 parts of concentration adds in another container, adds while stirring 20 parts of geranials, and heating is no more than under 70 ℃, and geranial is dissolved in ethanolic soln fully, forms clear solution.
Embodiment 4
Water-borne coatings with repelling effect, it is made by the raw material of following weight proportioning:
The above-mentioned preparation method with water-borne coatings of repelling effect, it comprises following step of sequentially carrying out:
, be less than under the speed of 500r/min, by 90%, 0.5 part of dispersion agent of whole total amounts of 35.3 parts of water, 0.1 part of wetting agent, 50%, 0.4 part of thickening material of whole total amounts of 0.4 part of defoamer adds in container, mixing and stirring;
, under the speed of 1000r/min, add successively 8 parts of titanium dioxides, 0.1 part of PH conditioning agent, 25 parts of water-ground limestones, 10 parts of kaolin, 6 parts of talcum powder, mixing and stirring;
, be greater than under the speed of 1000r/min, disperse or sand milling to fineness<50 μ m;
(4), be less than under the speed of 500r/min, add successively 10 parts of emulsions, 0.5 part film coalescence aid, 1.2 part frostproofer, 0.3 portion of sanitas, 2 parts of geranial solution, 0.2 flow agent, 0.4 remain residue 10% mixing and stirring in the total amount of 50%, 35.3 part of water in the total amount of part defoamer, can obtain product of the present invention.
The preparation method of above-mentioned geranial solution is as follows: the ethanolic soln that is 98% by 70 parts of concentration adds in another container, adds while stirring 20 parts of geranials, and heating is no more than under 70 ℃, and geranial is dissolved in ethanolic soln fully, forms clear solution.
Embodiment 5
Water-borne coatings with repelling effect, it is made by the raw material of following weight proportioning:
The above-mentioned preparation method with water-borne coatings of repelling effect, it comprises following step of sequentially carrying out:
, be less than under the speed of 500r/min, by 90%, 0.8 part of dispersion agent of whole total amounts of 40 parts of water, 0.2 part of wetting agent, 50%, 0.6 part of thickening material of whole total amounts of 0.5 part of defoamer adds in container, mixing and stirring;
, under the speed of 800r/min, add successively 8 parts of titanium dioxides, 0.15 part of PH conditioning agent, 17 parts of water-ground limestones, 10 parts of kaolin, 10 parts of talcum powder, mixing and stirring;
, be greater than under the speed of 1000r/min, disperse or sand milling to fineness<50 μ m;
(4), be less than under the speed of 500r/min, add successively 10 parts of emulsions, 0.5 part film coalescence aid, 2.5 part frostproofer, 0.4 portion of sanitas, 3 parts of geranial solution, 1.5 flow agent, 0.5 remain residue 10% mixing and stirring in the total amount of 50%, 35 part of water in the total amount of part defoamer, can obtain product of the present invention.
The preparation method of above-mentioned geranial solution is as follows: the ethanolic soln that is 99% by 60 parts of concentration adds in another container, adds while stirring 10 parts of geranials, and heating is no more than under 70 ℃, and geranial is dissolved in ethanolic soln fully, forms clear solution.
Embodiment 6
Water-borne coatings with repelling effect, it is made by the raw material of following weight proportioning:
The above-mentioned preparation method with water-borne coatings of repelling effect, it comprises following step of sequentially carrying out:
, be less than under the speed of 500r/min, by 90%, 0.4 part of dispersion agent of whole total amounts of 20 parts of water, 0.1 part of wetting agent, 50%, 0.3 part of thickening material of whole total amounts of 0.2 part of defoamer adds in container, mixing and stirring;
, under the speed of 500r/min, add successively 20 parts of titanium dioxides, 0.1 part of PH conditioning agent, 30 parts of water-ground limestones, 5 parts of kaolin, 5 parts of talcum powder, mixing and stirring;
, be greater than under the speed of 1000r/min, disperse or sand milling to fineness<50 μ m;
(4), be less than under the speed of 500r/min, add successively 15 parts of emulsions, 1.5 part film coalescence aid, 1.5 part frostproofer, 0.2 portion of sanitas, 0.5 part of geranial solution, 0.1 flow agent, 0.2 remain residue 10% mixing and stirring in the total amount of 50%, 20 part of water in the total amount of part defoamer, can obtain product of the present invention.
The preparation method of above-mentioned geranial solution is as follows: the ethanolic soln that is 97% by 90 parts of concentration adds in another container, adds while stirring 10 parts of geranials, and heating is no more than under 70 ℃, and geranial is dissolved in ethanolic soln fully, forms clear solution.
Embodiment 7
Water-borne coatings with repelling effect, it is made by the raw material of following weight proportioning:
The above-mentioned preparation method with water-borne coatings of repelling effect, it comprises following step of sequentially carrying out:
, be less than under the speed of 500r/min, by 90%, 0.6 part of dispersion agent of whole total amounts of 10 parts of water, 0.1 part of wetting agent, 50%, 0.4 part of thickening material of whole total amounts of 0.4 part of defoamer adds in container, mixing and stirring;
, under the speed of 1000r/min, add successively 30 parts of titanium dioxides, 0.05 part of PH conditioning agent, 5 parts of water-ground limestones, 15 parts of kaolin, 15 parts of talcum powder, mixing and stirring;
, be greater than under the speed of 1000r/min, disperse or sand milling to fineness<50 μ m;
(4), be less than under the speed of 500r/min, add successively 20 parts of emulsions, 1.5 part film coalescence aid, 0.5 part frostproofer, 0.1 portion of sanitas, 1 part of geranial solution, 0.7 flow agent, 0.4 remain residue 10% mixing and stirring in the total amount of 50%, 10 part of water in the total amount of part defoamer, can obtain product of the present invention.
The preparation method of above-mentioned geranial solution is as follows: the ethanolic soln that is 97% by 80 parts of concentration adds in another container, adds while stirring 30 parts of geranials, and heating is no more than under 70 ℃, and geranial is dissolved in ethanolic soln fully, forms clear solution.
Embodiment 8
Water-borne coatings with repelling effect, it is made by the raw material of following weight proportioning:
The above-mentioned preparation method with water-borne coatings of repelling effect, it comprises following step of sequentially carrying out:
, be less than under the speed of 500r/min, by 90%, 0.4 part of dispersion agent of whole total amounts of 23 parts of water, 0.1 part of wetting agent, 50%, 0.4 part of thickening material of whole total amounts of 0.4 part of defoamer adds in container, mixing and stirring;
, under the speed of 900r/min, add successively 15 parts of titanium dioxides, 0.1 part of PH conditioning agent, 10 parts of water-ground limestones, 5 parts of kaolin, 5 parts of talcum powder, mixing and stirring;
, be greater than under the speed of 1000r/min, disperse or sand milling to fineness<50 μ m;
(4), be less than under the speed of 500r/min, add successively 35 parts of emulsions, 2.5 part film coalescence aid, 1.5 part frostproofer, 0.2 portion of sanitas, 1 part of geranial solution, 0.5 flow agent, 0.4 remain residue 10% mixing and stirring in the total amount of 50%, 23 part of water in the total amount of part defoamer, can obtain product of the present invention.
The preparation method of above-mentioned geranial solution is as follows: the ethanolic soln that is 97% by 80 parts of concentration adds in another container, adds while stirring 30 parts of geranials, and heating is no more than under 70 ℃, and geranial is dissolved in ethanolic soln fully, forms clear solution.
The above-mentioned performance that will obtain product of the present invention to embodiment 1-embodiment 8 is measured, and the experimental data of mensuration sees the following form:
Above-described embodiment 1-embodiment 8 is owing to containing geranial in the present invention, this geranial is dissolved in ethanolic soln, thereby has reduced the content of geranial, harmless; The present invention has the effect of long-term mosquito repellent, has aromatic odour simultaneously and plays and cover other smells, and dispel in water-borne coatings and contain irritating smell; The present invention has good material performance, the air in decontamination chamber that can be suitable, and can also meet the requirement of upholstery.
Claims (7)
1. the water-borne coatings with repelling effect, is characterized in that: contain geranial solution in the raw material for the preparation of coating.
2. the water-borne coatings with repelling effect according to claim 1, it is characterized in that: described geranial solution is that the ethanolic soln that is 97%-99% by geranial and concentration is formulated according to the ratio of weight and number of 10-40:60-90.
3. the water-borne coatings with repelling effect according to claim 2, it is characterized in that: the described raw material for the preparation of coating also comprises water, dispersion agent, wetting agent, defoamer, thickening material, titanium dioxide, PH conditioning agent, water-ground limestone, kaolin, talcum powder, emulsion, film coalescence aid, frostproofer, mould inhibitor and flow agent, and the weight proportion of each raw material is as follows:
4. have according to claim 3 the water-borne coatings of repelling effect, it is characterized in that: described dispersion agent is the polycarboxylate sodium; Described water-ground limestone adopts 800 purpose water-ground limestones; Described kaolin adopts calcined kaolin or water-washed kaoline.
5. have according to claim 4 the water-borne coatings of repelling effect, it is characterized in that: described polycarboxylate sodium adopts the SN-5040 of Nuo Puke; The described wetting agent employing peaceful PE100 of section; Described defoamer adopts the CF-246 of Blackburn; Described mould inhibitor adopts the EPW of Sol; Described thickening material adopts inferior to imperial 250HBR; Described titanium dioxide adopts the R706 of Dupont; Described PH conditioning agent adopts the AMP-95 of DOW Chemical; Described emulsion adopts the rich RS998 of Ahmedabad; Described film coalescence aid adopts Yi Shiman Texno1.
6. one kind for the preparation of the described preparation method with water-borne coatings of repelling effect of any one in claim 1-5, and it is characterized in that: it comprises following step of sequentially carrying out:
(1) be less than under the speed of 500r/min, by 90% of whole total amounts of 10-35 part water, 0.4-0.8 part dispersion agent, 0.1-0.2 part wetting agent, 50% of whole total amounts of 0.2-0.5 part defoamer, 0.3-0.6 part thickening material adds in container, mixing and stirring;
(2), under the speed of 500r/min-1000r/min, add successively 8-30 part titanium dioxide, 0.05-0.15 part PH conditioning agent, 5-30 part water-ground limestone, 5-15 part kaolin, 5-15 part talcum powder, mixing and stirring;
(3) be greater than under the speed of 1000r/min, dispersion or sand milling are to fineness<50 μ m;
(4) be less than under the speed of 500r/min, add successively 10-35 part emulsion, 0.5-2.5 part film coalescence aid, 0.5-2.5 part frostproofer, 0.1-0.4 part sanitas, 0.5-2.5 part geranial solution, 0.1-1.5 part flow agent, 0.2-0.5 part defoamer whole total amounts 50%, whole total amounts of 10-35 part water 10%, mixing and stirring, obtain product of the present invention.
7. there is according to claim 6 the preparation method of the water-borne coatings of repelling effect, it is characterized in that: the preparation method of described geranial solution is as follows: the ethanolic soln that is 97%-99% by 60-90 part concentration adds in another container, add while stirring 10-40 part geranial, heating is no more than under 70 ℃, geranial is dissolved in ethanolic soln fully, forms clear solution.
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Cited By (6)
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| CN104356779A (en) * | 2014-11-05 | 2015-02-18 | 三棵树涂料股份有限公司 | Healthy environment-friendly water-based latex paint composition for physically expelling mosquitoes and flies and preparation method thereof |
| CN105462382A (en) * | 2015-12-10 | 2016-04-06 | 三棵树涂料股份有限公司 | Insect repelling water-based composition with healthcare function and preparation method of composition |
| CN106189734A (en) * | 2016-07-18 | 2016-12-07 | 贵州合润铝业新材料科技股份有限公司 | A kind of can the building wall water paint of expelling mosquito |
| CN106220129A (en) * | 2016-07-27 | 2016-12-14 | 谢彩红 | A kind of environment friendly mildew resistant fluorescent paint |
| CN106242370A (en) * | 2016-07-27 | 2016-12-21 | 谢彩红 | A kind of Environment-friendlywear-resistant wear-resistant fluorescent paint |
| CN109135442A (en) * | 2018-07-18 | 2019-01-04 | 湖南漆雕氏制造股份有限公司 | Aqueous mosquito-proof coating |
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| CN101045841A (en) * | 2007-04-30 | 2007-10-03 | 黄戴宇 | Emusion paint with mosquito preventing and antibiosis function and production process thereof |
| CN102786624A (en) * | 2011-05-19 | 2012-11-21 | 东北林业大学 | Preparation method of mosquito repellent for high-temperature and high-ultraviolet environment |
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| CN101045841A (en) * | 2007-04-30 | 2007-10-03 | 黄戴宇 | Emusion paint with mosquito preventing and antibiosis function and production process thereof |
| CN102786624A (en) * | 2011-05-19 | 2012-11-21 | 东北林业大学 | Preparation method of mosquito repellent for high-temperature and high-ultraviolet environment |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104356779A (en) * | 2014-11-05 | 2015-02-18 | 三棵树涂料股份有限公司 | Healthy environment-friendly water-based latex paint composition for physically expelling mosquitoes and flies and preparation method thereof |
| CN104356779B (en) * | 2014-11-05 | 2016-11-23 | 三棵树涂料股份有限公司 | Health environment-friendly physics anophelifuge fly water based emulsion coating compositions and preparation method thereof |
| CN105462382A (en) * | 2015-12-10 | 2016-04-06 | 三棵树涂料股份有限公司 | Insect repelling water-based composition with healthcare function and preparation method of composition |
| CN106189734A (en) * | 2016-07-18 | 2016-12-07 | 贵州合润铝业新材料科技股份有限公司 | A kind of can the building wall water paint of expelling mosquito |
| CN106220129A (en) * | 2016-07-27 | 2016-12-14 | 谢彩红 | A kind of environment friendly mildew resistant fluorescent paint |
| CN106242370A (en) * | 2016-07-27 | 2016-12-21 | 谢彩红 | A kind of Environment-friendlywear-resistant wear-resistant fluorescent paint |
| CN109135442A (en) * | 2018-07-18 | 2019-01-04 | 湖南漆雕氏制造股份有限公司 | Aqueous mosquito-proof coating |
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Application publication date: 20131225 |
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