CN103468016A - Environment-friendly rubber material and preparation method thereof - Google Patents
Environment-friendly rubber material and preparation method thereof Download PDFInfo
- Publication number
- CN103468016A CN103468016A CN2013104440788A CN201310444078A CN103468016A CN 103468016 A CN103468016 A CN 103468016A CN 2013104440788 A CN2013104440788 A CN 2013104440788A CN 201310444078 A CN201310444078 A CN 201310444078A CN 103468016 A CN103468016 A CN 103468016A
- Authority
- CN
- China
- Prior art keywords
- parts
- environment
- rubber material
- preparation
- zinc oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 47
- 239000005060 rubber Substances 0.000 title claims abstract description 47
- 239000000463 material Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 22
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 239000011787 zinc oxide Substances 0.000 claims abstract description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 10
- 239000006229 carbon black Substances 0.000 claims abstract description 10
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 10
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 10
- 235000014121 butter Nutrition 0.000 claims abstract description 9
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 8
- 239000004816 latex Substances 0.000 claims abstract description 8
- 229920000126 latex Polymers 0.000 claims abstract description 8
- 235000019241 carbon black Nutrition 0.000 claims description 9
- 238000004073 vulcanization Methods 0.000 claims description 9
- -1 7 ~ 10 parts Chemical compound 0.000 claims description 8
- 235000013312 flour Nutrition 0.000 claims description 8
- 239000004575 stone Substances 0.000 claims description 8
- 241001253206 Andrias Species 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 7
- 230000015271 coagulation Effects 0.000 claims description 7
- 238000005345 coagulation Methods 0.000 claims description 7
- 230000018044 dehydration Effects 0.000 claims description 7
- 238000006297 dehydration reaction Methods 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 238000010057 rubber processing Methods 0.000 abstract description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000011022 opal Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 description 5
- 239000013536 elastomeric material Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000003712 anti-aging effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 150000001907 coumarones Chemical class 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000010092 rubber production Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention relates to an environment-friendly rubber material and a preparation method thereof, and belongs to the field of rubber processing. The environment-friendly rubber material comprises the components in parts by weight: 40-45 parts of rubber, 2-5 parts of zinc oxide, 7-10 parts of calcium carbonate, 12-17 parts of butter, 10-15 parts of opal powder, 3-6 parts of carbon black, 2-5 parts of polyvinyl chloride and 3-6 parts of an assistant vulcanizing agent. The preparation method comprises: adding the materials with stirring, reacting at 55 DEG C-58 DEG C for 22-25 h; after the reaction is finished, adjusting pH of the solution to 6.8-7.2 with ammonia water, introducing steam and heating until the latex is solidified, dehydrating, rinsing, granulating, and drying at 65 DEG C-70 DEG C for 48-55 h. The environment-friendly rubber material is low in cost, simple in manufacture technology, good in performances, green and environment-friendly, and can be recycled again.
Description
Technical field
The present invention relates to a kind of elastomeric material, be specifically related to a kind of environment-protective rubber material and preparation method thereof, belong to rubber processing.
Background technology
Rubber industry is one of important foundation industry of national economy.It not only provides daily life the indispensable light industry rubber product such as daily, medical for people, and provides various rubber production unit processed or rubber components to the heavy industry such as digging, traffic, building, machinery, electronics and new industry.Visible, the product category of rubber industry is various, and backward industry is very wide.In recent years, rubber industry was much developed, and the existing segmented industry is steadily increasing, new develop rapidly of the untreated rubber segmented industry, but simultaneously, yet there are the problems such as environment, resource, disaster, innovation in rubber industry.
Country advocates rubber industry safety, energy-saving and environmental protection and cleaner production policy, and is attended by the most momentous results.Especially Rubber Chemicals Industries is actively adjusted the product mix, and the environmental type auxiliary agent increases substantially, and anti-aging agent improved seeds output ratio has reached 80%, and promotor reaches 50%, and poisonous, harmful, high carcinogenic NOBS turnout is effectively controlled; The waste rubber comprehensive utilization ratio reaches more than 65%, and reclaimed rubber and rubber powder post-treatment utilize field to enlarge.
Environment-protective rubber material is an important ring of whole adjustment of industrial structure, is related to the development of whole industry to high-tech, sustainability.At present the research and development of environment-friendly rubber constantly heated up.201210459394.8 a kind of novel environment friendly elastomeric material is disclosed, with terpolymer EP rubber, fiber, sulphur, coumarones etc. are main raw material; 201210322305.5 disclose a kind of environment-protective rubber material, main component is fire retardant, film coalescence aid, talcum powder, softening agent, carbon black, calcium carbonate, polyvinyl chloride and vulcanization aid.They all exist that preparation cost is high, the problem of complex process etc., thereby cost performance is not high, can not meet human consumer's requirement, is difficult to promote on market.Therefore, the present invention is directed to above situation, develop the environment-protective rubber material of a kind of reasonable price, environmental protection, the development trend in applicable market.
Summary of the invention
The purpose of this invention is to provide kind of environment-protective rubber material and preparation method thereof, this elastomeric material cost is low, and manufacture craft is simple, and performance is good, and environmental protection can be recycled again.
In order to address the above problem, the technical solution adopted in the present invention is:
A kind of environment-protective rubber material, the weight part of each component is:
40 ~ 45 parts of rubber, 2 ~ 5 parts, zinc oxide, 7 ~ 10 parts, calcium carbonate, 12 ~ 17 parts, butter, 10 ~ 15 parts of albumen stone flours, 3 ~ 6 parts of carbon blacks, 2 ~ 5 parts of polyvinyl chloride, 3 ~ 6 parts of vulcanization aids.
A kind of preparation method of environment-protective rubber material, comprise the steps:
Under agitation add above-mentioned materials, react 22 ~ 25 hours at 55 ℃ ~ 58 ℃ temperature; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8 ~ 7.2, pass into steam-heated cal(l)andria to latex coagulation, dehydration, rinsing, granulation, get final product at 65 ℃ ~ 70 ℃ drying 48 ~ 55h.
The invention has the beneficial effects as follows:
the invention provides a kind of environment-protective rubber material, its good springiness, strong, the acidproof corruption of anti-aging power be high, resistance to wear, good flame retardation effect, nontoxic to human body, guarantee to eliminate human consumer and user's potential safety hazard, can again reclaim, be conducive to save energy, be conducive to environmental protection, be conducive to increase economic efficiency.The preparation method of environment-friendly rubber of the present invention,, preparation technology is simple, and cost is low, suitable to industrial scale operation.
Embodiment
Below by embodiment, the present invention is described in further details, these embodiment only are used for illustrating the present invention, do not limit the scope of the invention.
embodiment 1
A kind of environment-protective rubber material, the weight part of each component is:
45 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 15 parts, butter, 10 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 5 parts of vulcanization aids.
Its preparation method comprises the steps:
Under agitation add above-mentioned materials, at 55 ℃ of temperature, reaction is 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8, pass into steam-heated cal(l)andria to latex coagulation, dehydration, rinsing, granulation, get final product at 65 ℃ of dry 48h.
embodiment 2
A kind of environment-protective rubber material, the weight part of each component is:
44 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 16 parts, butter, 10 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 5 parts of vulcanization aids.
Its preparation method comprises the steps:
Under agitation add above-mentioned materials, at 56 ℃ of temperature, reaction is 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8, pass into steam-heated cal(l)andria to latex coagulation, dehydration, rinsing, granulation, get final product at 65 ℃ of dry 48h.
embodiment 3
A kind of environment-protective rubber material, the weight part of each component is:
44 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 16 parts, butter, 11 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 4 parts of vulcanization aids.
Its preparation method comprises the steps:
Under agitation add above-mentioned materials, at 56 ℃ of temperature, reaction is 24 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8, pass into steam-heated cal(l)andria to latex coagulation, dehydration, rinsing, granulation, get final product at 65 ℃ of dry 53h.
embodiment 4
A kind of environment-protective rubber material, the weight part of each component is:
43 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 16 parts, butter, 10 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 6 parts of vulcanization aids.
Its preparation method comprises the steps:
Under agitation add above-mentioned materials, at 55 ℃ of temperature, reaction is 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.9, pass into steam-heated cal(l)andria to latex coagulation, dehydration, rinsing, granulation, get final product at 65 ℃ of dry 50h.
embodiment 5
A kind of environment-protective rubber material, the weight part of each component is:
43 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 15 parts, butter, 10 parts of albumen stone flours, 6 parts of carbon blacks, 5 parts of polyvinyl chloride, 6 parts of vulcanization aids.
Its preparation method comprises the steps:
Under agitation add above-mentioned materials, at 55 ℃ of temperature, reaction is 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.9, pass into steam-heated cal(l)andria to latex coagulation, dehydration, rinsing, granulation, get final product at 68 ℃ of dry 51h.
Claims (5)
1. an environment-protective rubber material, it is characterized in that: the weight part of each component is:
40 ~ 45 parts of rubber, 2 ~ 5 parts, zinc oxide, 7 ~ 10 parts, calcium carbonate, 12 ~ 17 parts, butter, 10 ~ 15 parts of albumen stone flours, 3 ~ 6 parts of carbon blacks, 2 ~ 5 parts of polyvinyl chloride, 3 ~ 6 parts of vulcanization aids.
2. an environment-protective rubber material, it is characterized in that: the weight part of each component is:
43 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 15 parts, butter, 10 parts of albumen stone flours, 6 parts of carbon blacks, 5 parts of polyvinyl chloride, 6 parts of vulcanization aids.
3. a kind of environment-protective rubber material according to claim 1 and 2 is characterized in that: it is the zinc oxide more than 95% that described zinc oxide adopts mass content.
4. the method for the preparation of claim 1 and 2 described environment-protective rubber materials, is characterized in that: comprise the steps:
Under agitation add above-mentioned materials, react 22 ~ 25 hours at 55 ℃ ~ 58 ℃ temperature; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8 ~ 7.2, pass into steam-heated cal(l)andria to latex coagulation, dehydration, rinsing, granulation, get final product at 65 ℃ ~ 70 ℃ dry certain hours.
5. the preparation method of a kind of environment-protective rubber material according to claim 4, it is characterized in that: described certain hour is 48 ~ 55h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310444078.8A CN103468016B (en) | 2013-09-26 | 2013-09-26 | A kind of environment-protective rubber material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310444078.8A CN103468016B (en) | 2013-09-26 | 2013-09-26 | A kind of environment-protective rubber material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103468016A true CN103468016A (en) | 2013-12-25 |
| CN103468016B CN103468016B (en) | 2016-05-18 |
Family
ID=49793069
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310444078.8A Expired - Fee Related CN103468016B (en) | 2013-09-26 | 2013-09-26 | A kind of environment-protective rubber material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103468016B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107083069A (en) * | 2017-06-29 | 2017-08-22 | 合肥达户电线电缆科技有限公司 | A kind of environment-friendly rubber and preparation method thereof |
| CN112321923A (en) * | 2020-11-23 | 2021-02-05 | 牟南征 | Green and environment-friendly rubber material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898687A (en) * | 2011-07-24 | 2013-01-30 | 天津民生科技发展有限公司 | Novel rubber material |
-
2013
- 2013-09-26 CN CN201310444078.8A patent/CN103468016B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898687A (en) * | 2011-07-24 | 2013-01-30 | 天津民生科技发展有限公司 | Novel rubber material |
Non-Patent Citations (1)
| Title |
|---|
| 谢小花等: "碳酸钙与炭黑补强丁腈橡胶/废聚氯乙烯共混物物理性能的研究", 《橡胶参考资料》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107083069A (en) * | 2017-06-29 | 2017-08-22 | 合肥达户电线电缆科技有限公司 | A kind of environment-friendly rubber and preparation method thereof |
| CN112321923A (en) * | 2020-11-23 | 2021-02-05 | 牟南征 | Green and environment-friendly rubber material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103468016B (en) | 2016-05-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102153792B (en) | Preparation method of wet process mixed natural rubber material | |
| CN103788911B (en) | Environment-friendly adhesive containing modified nanometer bamboo charcoal powder | |
| CN103896265A (en) | Method for producing activated carbon and inorganic silicon compounds from rice hulls | |
| CN109504134A (en) | A kind of waste tire production carbon black treatment process | |
| CN102329439B (en) | Foamed rubber shoe sole | |
| CN104609420A (en) | Preparation method of rice hull-based active carbon | |
| CN103468016A (en) | Environment-friendly rubber material and preparation method thereof | |
| CN103143551B (en) | Original form dechroming method for chrome leather fragment, and application of product thereof in fertilizer aspect | |
| CN102720062B (en) | Preparation method of selvedge sizing agent | |
| CN101386690B (en) | Waste paper sludge composite filler and preparation method and application thereof | |
| CN102942633B (en) | Clean production method of compound modified starch | |
| CN102443182B (en) | Preparation method for chrome shaving and polyacrylamide composite gel | |
| CN102838561A (en) | Production method of rubber vulcanization accelerator NS (N-tertiary butyl-2-benzothiazole sulfenamide) | |
| CN108033721A (en) | A kind of production method for the cement-base concrete that paper fiber using reclaimed waste paper strengthens | |
| CN101638396A (en) | Production process for rubber accelerator 2-thiol group benzothiazole | |
| CN106745245A (en) | A kind of preparation method of sodium pyroantimonate and sodium metaantimonate | |
| CN105086093A (en) | Novel modified plastic prepared by waste plastic | |
| CN102816095B (en) | Preparation method for organic thiosulfate | |
| CN102516612A (en) | Preparation method for porous starch/natural rubber compound | |
| CN107118418A (en) | A kind of recycling technique of waste and old fishing net | |
| CN102898687A (en) | Novel rubber material | |
| CN107099120A (en) | A kind of preparation method and applications of light flame-retardant construction material | |
| CN108165212A (en) | One kind eliminates the unusual smell adhesive | |
| CN104804271A (en) | Rubber production technology | |
| CN108722361A (en) | A kind of absorbent-type water pollution inorganic agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Shaohuang Inventor before: Chen Lijing |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170627 Address after: 523876 Guangdong Province, Dongguan city Changan town ha community Ao tou Yongye Street No. 2 A Patentee after: Dongguan Wenxi rubber roller Product Co., Ltd. Address before: 521000, Xiangqiao District, Guangdong province Chaozhou Tak middle school dormitory Patentee before: Chen Lijing |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160518 Termination date: 20200926 |