CN103468016B - A kind of environment-protective rubber material and preparation method thereof - Google Patents
A kind of environment-protective rubber material and preparation method thereof Download PDFInfo
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- CN103468016B CN103468016B CN201310444078.8A CN201310444078A CN103468016B CN 103468016 B CN103468016 B CN 103468016B CN 201310444078 A CN201310444078 A CN 201310444078A CN 103468016 B CN103468016 B CN 103468016B
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 47
- 239000000463 material Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 26
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 13
- 239000006229 carbon black Substances 0.000 claims abstract description 13
- 235000019241 carbon black Nutrition 0.000 claims abstract description 13
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 13
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 13
- 238000004073 vulcanization Methods 0.000 claims abstract description 13
- -1 7 ~ 10 parts Chemical compound 0.000 claims abstract description 12
- 238000013019 agitation Methods 0.000 claims abstract description 12
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 12
- 235000014121 butter Nutrition 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 230000015271 coagulation Effects 0.000 claims abstract description 12
- 238000005345 coagulation Methods 0.000 claims abstract description 12
- 230000018044 dehydration Effects 0.000 claims abstract description 12
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 12
- 235000013312 flour Nutrition 0.000 claims abstract description 12
- 238000005469 granulation Methods 0.000 claims abstract description 12
- 230000003179 granulation Effects 0.000 claims abstract description 12
- 239000004816 latex Substances 0.000 claims abstract description 12
- 229920000126 latex Polymers 0.000 claims abstract description 12
- 239000004575 stone Substances 0.000 claims abstract description 12
- 239000011787 zinc oxide Substances 0.000 claims abstract description 12
- 230000007613 environmental effect Effects 0.000 abstract description 6
- 239000013536 elastomeric material Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000010057 rubber processing Methods 0.000 abstract description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 150000001907 coumarones Chemical class 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000010092 rubber production Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The present invention relates to a kind of environment-protective rubber material and preparation method thereof, belong to rubber processing, wherein the weight portion of each component is 40 ~ 45 parts of rubber, 2 ~ 5 parts, zinc oxide, 7 ~ 10 parts, calcium carbonate, 12 ~ 17 parts, butter, 10 ~ 15 parts of albumen stone flours, 3 ~ 6 parts of carbon blacks, 2 ~ 5 parts of polyvinyl chloride, 3 ~ 6 parts of vulcanization aids, its preparation method, under agitation adding above-mentioned material, reacts 22 ~ 25 hours at 55 DEG C ~ 58 DEG C temperature; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8 ~ 7.2, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, be dried 48 ~ 55h at 65 DEG C ~ 70 DEG C; This elastomeric material cost is low, and manufacture craft is simple, and performance is good, and environmental protection can be recycled again.
Description
Technical field
The present invention relates to a kind of elastomeric material, be specifically related to a kind of environment-protective rubber material and preparation method thereof, belong to rubber processing.
Background technology
Rubber industry is one of important foundation industry of national economy. It not only provides daily life the indispensable light industry rubber product such as daily, medical for people, and provides various rubber production equipment processed or rubber components to the heavy industry such as digging, traffic, building, machinery, electronics and new industry. Visible, the product category of rubber industry is various, and backward industry is very wide. In recent years, rubber industry was much developed, and the existing segmented industry is steadily increasing, new develop rapidly of the raw rubber segmented industry, but simultaneously, yet there is the problems such as environment, resource, disaster, innovation in rubber industry.
Country advocates rubber industry safety, energy-saving and environmental protection and cleaner production policy, and is attended by the most momentous results. Especially Rubber Chemicals Industries is actively adjusted the product mix, and environmental type auxiliary agent increases substantially, and age resistor improved seeds output ratio has reached 80%, and promoter reaches 50%, and poisonous, harmful, high carcinogenic NOBS output is effectively controlled; Scrap rubber comprehensive utilization ratio reaches more than 65%, and after reclaimed rubber and rubber powder, processing and utilization field expands.
Environment-protective rubber material is an important ring of whole adjustment of industrial structure, is related to the development of whole industry to high-tech, sustainability. At present the research and development of environment-friendly rubber are constantly heated up. 201210459394.8 disclose a kind of novel environment friendly elastomeric material, with ethylene propylene diene rubber, and fiber, sulphur, coumarones etc. are primary raw material; 201210322305.5 disclose a kind of environment-protective rubber material, and main component is fire retardant, coalescents, talcum powder, plasticizer, carbon black, calcium carbonate, polyvinyl chloride and vulcanization aid. They all exist that preparation cost is high, the problem of complex process etc., thereby cost performance is not high, can not meet consumer's requirement, is difficult to promote on market. Therefore, the present invention is directed to above situation, develop the environment-protective rubber material of a kind of reasonable price, environmental protection, be suitable for the development trend in market.
Summary of the invention
The object of this invention is to provide kind of environment-protective rubber material and preparation method thereof, this elastomeric material cost is low, and manufacture craft is simple, and performance is good, and environmental protection can be recycled again.
In order to address the above problem, the technical solution adopted in the present invention is:
A kind of environment-protective rubber material, the weight portion of each component is:
40 ~ 45 parts of rubber, 2 ~ 5 parts, zinc oxide, 7 ~ 10 parts, calcium carbonate, 12 ~ 17 parts, butter, 10 ~ 15 parts of albumen stone flours, 3 ~ 6 parts of carbon blacks, 2 ~ 5 parts of polyvinyl chloride, 3 ~ 6 parts of vulcanization aids.
A preparation method for environment-protective rubber material, comprises the steps:
Under agitation add above-mentioned material, at 55 DEG C ~ 58 DEG C temperature, react 22 ~ 25 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8 ~ 7.2, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, be dried 48 ~ 55h at 65 DEG C ~ 70 DEG C.
The invention has the beneficial effects as follows:
The invention provides a kind of environment-protective rubber material, its good springiness, strong, the acidproof corruption of anti-aging power be high, resistance to wear, good flame retardation effect, nontoxic to human body, guarantee to eliminate consumer and user's potential safety hazard, can again reclaim, be conducive to save the energy, be conducive to environmental protection, be conducive to increase economic efficiency. The preparation method of environment-friendly rubber of the present invention,, preparation technology is simple, and cost is low, suitable to industrial large-scale production.
Detailed description of the invention
Below by embodiment, the present invention is described in further details, these embodiment are only used for illustrating the present invention, do not limit the scope of the invention.
Embodiment 1
A kind of environment-protective rubber material, the weight portion of each component is:
45 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 15 parts, butter, 10 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 5 parts of vulcanization aids.
Its preparation method comprises the steps:
Under agitation add above-mentioned material, at 55 DEG C of temperature, react 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, at 65 DEG C of dry 48h.
Embodiment 2
A kind of environment-protective rubber material, the weight portion of each component is:
44 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 16 parts, butter, 10 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 5 parts of vulcanization aids.
Its preparation method comprises the steps:
Under agitation add above-mentioned material, at 56 DEG C of temperature, react 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, at 65 DEG C of dry 48h.
Embodiment 3
A kind of environment-protective rubber material, the weight portion of each component is:
44 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 16 parts, butter, 11 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 4 parts of vulcanization aids.
Its preparation method comprises the steps:
Under agitation add above-mentioned material, at 56 DEG C of temperature, react 24 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, at 65 DEG C of dry 53h.
Embodiment 4
A kind of environment-protective rubber material, the weight portion of each component is:
43 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 16 parts, butter, 10 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 6 parts of vulcanization aids.
Its preparation method comprises the steps:
Under agitation add above-mentioned material, at 55 DEG C of temperature, react 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.9, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, at 65 DEG C of dry 50h.
Embodiment 5
A kind of environment-protective rubber material, the weight portion of each component is:
43 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 15 parts, butter, 10 parts of albumen stone flours, 6 parts of carbon blacks, 5 parts of polyvinyl chloride, 6 parts of vulcanization aids.
Its preparation method comprises the steps:
Under agitation add above-mentioned material, at 55 DEG C of temperature, react 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.9, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, at 68 DEG C of dry 51h.
Claims (5)
1. an environment-protective rubber material, is characterized in that: the weight portion of each component is:
45 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 15 parts, butter, 10 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 5 parts of vulcanization aids;
Its preparation method comprises the steps:
Under agitation add above-mentioned material, at 55 DEG C of temperature, react 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, at 65 DEG C of dry 48h.
2. an environment-protective rubber material, is characterized in that: the weight portion of each component is:
44 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 16 parts, butter, 10 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 5 parts of vulcanization aids;
Under agitation add above-mentioned material, at 56 DEG C of temperature, react 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, at 65 DEG C of dry 48h.
3. an environment-protective rubber material, is characterized in that: the weight portion of each component is:
44 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 16 parts, butter, 11 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 4 parts of vulcanization aids;
Its preparation method comprises the steps:
Under agitation add above-mentioned material, at 56 DEG C of temperature, react 24 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.8, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, at 65 DEG C of dry 53h.
4. an environment-protective rubber material, is characterized in that: the weight portion of each component is:
43 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 16 parts, butter, 10 parts of albumen stone flours, 5 parts of carbon blacks, 5 parts of polyvinyl chloride, 6 parts of vulcanization aids;
Its preparation method comprises the steps:
Under agitation add above-mentioned material, at 55 DEG C of temperature, react 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.9, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, at 65 DEG C of dry 50h.
5. an environment-protective rubber material, is characterized in that: the weight portion of each component is:
43 parts of rubber, 5 parts, zinc oxide, 10 parts, calcium carbonate, 15 parts, butter, 10 parts of albumen stone flours, 6 parts of carbon blacks, 5 parts of polyvinyl chloride, 6 parts of vulcanization aids;
Its preparation method comprises the steps:
Under agitation add above-mentioned material, at 55 DEG C of temperature, react 22 hours; After reaction finishes, adopt ammoniacal liquor that the pH value of solution is adjusted to 6.9, pass into steam heated to latex coagulation, dehydration, rinsing, granulation, at 68 DEG C of dry 51h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310444078.8A CN103468016B (en) | 2013-09-26 | 2013-09-26 | A kind of environment-protective rubber material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310444078.8A CN103468016B (en) | 2013-09-26 | 2013-09-26 | A kind of environment-protective rubber material and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN103468016A CN103468016A (en) | 2013-12-25 |
| CN103468016B true CN103468016B (en) | 2016-05-18 |
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| CN201310444078.8A Expired - Fee Related CN103468016B (en) | 2013-09-26 | 2013-09-26 | A kind of environment-protective rubber material and preparation method thereof |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107083069A (en) * | 2017-06-29 | 2017-08-22 | 合肥达户电线电缆科技有限公司 | A kind of environment-friendly rubber and preparation method thereof |
| CN112321923A (en) * | 2020-11-23 | 2021-02-05 | 牟南征 | Green and environment-friendly rubber material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898687A (en) * | 2011-07-24 | 2013-01-30 | 天津民生科技发展有限公司 | Novel rubber material |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898687A (en) * | 2011-07-24 | 2013-01-30 | 天津民生科技发展有限公司 | Novel rubber material |
Non-Patent Citations (1)
| Title |
|---|
| 碳酸钙与炭黑补强丁腈橡胶/废聚氯乙烯共混物物理性能的研究;谢小花等;《橡胶参考资料》;20130415;第43卷(第2期);2.2、表1、图3、2.6、图9 * |
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| CN103468016A (en) | 2013-12-25 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
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Inventor after: Wang Shaohuang Inventor before: Chen Lijing |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170627 Address after: 523876 Guangdong Province, Dongguan city Changan town ha community Ao tou Yongye Street No. 2 A Patentee after: Dongguan Wenxi rubber roller Product Co., Ltd. Address before: 521000, Xiangqiao District, Guangdong province Chaozhou Tak middle school dormitory Patentee before: Chen Lijing |
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Granted publication date: 20160518 Termination date: 20200926 |