CN102720062B - Preparation method of selvedge sizing agent - Google Patents
Preparation method of selvedge sizing agent Download PDFInfo
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- CN102720062B CN102720062B CN201210195533.0A CN201210195533A CN102720062B CN 102720062 B CN102720062 B CN 102720062B CN 201210195533 A CN201210195533 A CN 201210195533A CN 102720062 B CN102720062 B CN 102720062B
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- preparation
- selvedge
- sizing agent
- agent
- stirring
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- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000004513 sizing Methods 0.000 title abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229920003023 plastic Polymers 0.000 claims abstract description 18
- 239000004033 plastic Substances 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 9
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 238000001914 filtration Methods 0.000 claims abstract description 4
- 239000004793 Polystyrene Substances 0.000 claims description 8
- 229920002223 polystyrene Polymers 0.000 claims description 8
- 238000000034 method Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000002699 waste material Substances 0.000 abstract description 3
- 239000006260 foam Substances 0.000 abstract 3
- 229920006248 expandable polystyrene Polymers 0.000 abstract 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 239000003570 air Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 230000007096 poisonous effect Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920001893 acrylonitrile styrene Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical class C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention discloses a preparation method of a selvedge sizing agent. The method comprises the following steps of: adding butanone, dispersing agent vinyl chloride-vinyl acetate resin and hardening agent dicumyl peroxide in a stirring barrel, and stirring uniformly; adding expandable polystyrene foam plastic in the stirring process; after charging, and continuously stirring for 20-45 minutes at 10-30 DEG C at a stirring speed of 500-1,000rpm; and filtering to obtain the selvedge sizing agent. 60-120g of the dispersing agent vinyl chloride-vinyl acetate resin, 4-6g of the hardening agent dicumyl peroxide and 300-330g of the expandable polystyrene foam plastic are added into each kilogram of butanone. Through the invention, the prepared selvedge sizing agent can completely replace the traditional selvedge sizing agent in production practice, and the preparation cost is remarkably lowered; and since the recycled foam plastic is used as a raw material, the cost is lowered, thus the preparation method disclosed by the invention turns waste into wealth and has obvious economic and social benefits.
Description
Technical field
The invention belongs to field of textiles, particularly a kind of preparation method of selvedge setting agent.
Background technology
Selvedge setting agent be industrial knitted cloth while cuing open width for the fixing raw material of selvedge, play sizing, prevent the effect of crimping,
In industrial circle extensive uses such as dyeing and finishing, process hides.Traditional selvedge setting agent acrylonitrile-styrene copolymerized resin (AS) resin and the toluene of adopting is allocated more, and approximately 3.5 ten thousand yuan/ton of AS resin market prices are expensive, and cost is improved greatly; Toluene belongs to bio-toxicity organic solvent, produce and use procedure in contaminated environment not only, and have a strong impact on producers' health.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of selvedge setting agent, reduce the pollution to air in the manufacture of traditional selvedge setting agent and use procedure, reduce production costs simultaneously.
To achieve these goals, technical scheme provided by the invention is: a kind of preparation method of selvedge setting agent, butanone (MEK), dispersant vinyl chloride-vinyl acetate resin and curing agent cumyl peroxide are added in agitator, stir and it was mixed in 3 ~ 5 minutes, then progressively add while stirring polystyrene foamed plastics; After having fed in raw material, at 10 ~ 30 ℃, continue to stir 20 ~ 45 minutes, speed of agitator is 500 ~ 1000 revs/min.Reaction finishes, and obtains selvedge setting agent after filtration.If ambient air temperature, lower than 10 ℃, should be taked the measure of heating and thermal insulation.
Every 1kg butanone adds dispersant vinyl chloride-vinyl acetate resin 60 ~ 120g, curing agent cumyl peroxide 4 ~ 6g, polystyrene foamed plastics 300 ~ 330g.
In preparation process, add vinyl chloride-vinyl acetate resin (VINYL), regulate solution viscosity, and the cohesive force of increase and base cloth, add cumyl peroxide (DCP), strengthen the non-deformability of selvedge under 180 ℃ of environment.
Described filtration adopts 200 mesh filter screens to filter.
The polystyrene foamed plastics (EPS) that the present invention adopts can be the foamed plastics reclaiming.
Beneficial effect: it is major ingredient that the inventive method be take polystyrene foamed plastics (EPS), polystyrene foamed plastics can be to reclaim foamed plastics, replace the acrylonitrile-styrene copolymerized resin of expensive propylene, with the lower butanone of bio-toxicity, replace poisonous chemical solvent toluene.The selvedge setting agent of preparation, can tolerate the high temperature of 180 ℃, can substitute traditional selvedge setting agent completely and use, and cost of manufacture declines to a great extent in production practices, and adopting the foamed plastics reclaiming is raw material, is a practicality invention of turning waste into wealth.There is obvious economic benefit and social benefit.
Economic and Efficiency Analysis:
It is main material that tradition selvedge setting agent be take AS resin and poisonous chemical solvent toluene, approximately 12.8 yuan/KG of cost; This law is produced approximately 8.9 yuan/KG of selvedge setting agent cost.With our company, cut open width knitted cloth 400 myriametres year, 30 tons of calculating of selvedge setting agent consumption, cost-saved 13.65 ten thousand yuan.If the present invention is generalized to relevant industries, economic benefits are more remarkable.
Social benefit is analyzed:
Because poisonous chemical solvent toluene in traditional selvedge setting agent can in use all evaporate in air, use the butanone that toxicity is lower instead and can effectively avoid the pollution of toluene to surrounding air.
EPS, as modal amortizing packaging material, is widely used in the internal layer packaging of electric equipment, and after the use of equipment Kaifeng, packaging material lack effectively to be recycled.Because of hard degradation under its natural environment, burn and can discharge black smoke poison gas again, and be difficult to process.The present invention is the effective trial to the recycling of waste plastic, meets the recycling economy thinking of current sustainable development.
Accompanying drawing explanation
Fig. 1 is the preparation flow figure of selvedge setting agent provided by the invention.
The specific embodiment
Below in conjunction with accompanying drawing, the present invention is further described.
Embodiment 1:
The preparation method of selvedge setting agent, concrete steps are as follows:
1, in agitator, add butanone 50KG, then add 0.2 kilogram of dispersant vinyl chloride-vinyl acetate resin 3KG and curing agent cumyl peroxide, stir.
3, stir on one side, Yi Bian add the polystyrene foamed plastics of 16.5 kilograms.
4. after having fed in raw material, by agitator sealing, at 30 ℃, continue to stir 20 minutes.
5, open the outlet valve of agitator below, with 200 mesh filter screens, filter, obtain selvedge setting agent.
Embodiment 2:
The preparation method of selvedge setting agent, concrete steps are as follows:
1, the foamed plastics EPS adopt reclaiming is as raw material, to the foamed plastics reclaiming sort, fragmentation, remove foreign material, standby after draining away the water.
2, in agitator, add butanone 50KG, then add 0.3 kilogram of dispersant vinyl chloride-vinyl acetate resin 6KG and curing agent cumyl peroxide, stir.
3, stir on one side, Yi Bian progressively add the recovery foamed plastics of 15 kilograms.
4,, after having fed in raw material, by agitator sealing, at 10 ℃, continue to stir 45 minutes.
5, open the outlet valve of agitator below, with 200 mesh filter screens, filter, obtain selvedge setting agent.
Claims (3)
1. the preparation method of a selvedge setting agent, it is characterized in that: butanone, dispersant vinyl chloride-vinyl acetate resin and curing agent cumyl peroxide are added in agitator, stir and it was mixed in 3 ~ 5 minutes, then add while stirring polystyrene foamed plastics; After having fed in raw material, at 10 ~ 30 ℃, continue to stir 20 ~ 45 minutes, speed of agitator is 500 ~ 1000 revs/min, filters, and obtains selvedge setting agent.
2. the preparation method of a kind of selvedge setting agent according to claim 1, is characterized in that: every 1kg butanone adds dispersant vinyl chloride-vinyl acetate resin 60 ~ 120g curing agent cumyl peroxide 4 ~ 6g, polystyrene foamed plastics 300 ~ 330g.
3. the preparation method of a kind of selvedge setting agent according to claim 1, is characterized in that: described filtration adopts 200 mesh filter screens to filter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201210195533.0A CN102720062B (en) | 2012-06-14 | 2012-06-14 | Preparation method of selvedge sizing agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210195533.0A CN102720062B (en) | 2012-06-14 | 2012-06-14 | Preparation method of selvedge sizing agent |
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| Publication Number | Publication Date |
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| CN102720062A CN102720062A (en) | 2012-10-10 |
| CN102720062B true CN102720062B (en) | 2014-01-15 |
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| CN201210195533.0A Active CN102720062B (en) | 2012-06-14 | 2012-06-14 | Preparation method of selvedge sizing agent |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106702736A (en) * | 2016-12-28 | 2017-05-24 | 湖州品创孵化器有限公司 | Setting agent used after wool stretch and refinement |
| CN106758190A (en) * | 2016-12-28 | 2017-05-31 | 湖州品创孵化器有限公司 | A kind of setting agent after the stretching for wool fiber |
| CN106758189A (en) * | 2016-12-28 | 2017-05-31 | 湖州多恒服饰有限公司 | A kind of selvedge sizing agent |
| CN107399958A (en) * | 2017-08-08 | 2017-11-28 | 湖南省醴陵市玉果电瓷有限公司 | A kind of porcelain bushing shell and preparation method thereof |
| CN107512901A (en) * | 2017-08-16 | 2017-12-26 | 顾玉城 | A kind of porcelain bushing and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1059383A (en) * | 1991-08-09 | 1992-03-11 | 王祥森 | Knit cap formula of hardening agent and manufacture methods thereof such as crudefiber crop, careless class, paper-straws |
| CN1082587A (en) * | 1992-07-17 | 1994-02-23 | 福建师范大学 | A kind of polystyrene adhesive and production method thereof |
| CN1239131A (en) * | 1999-07-06 | 1999-12-22 | 董金狮 | Dissolving-fusing modification of EPS and process for preparing adhesive |
| CN1659244A (en) * | 2002-06-05 | 2005-08-24 | 巴斯福股份公司 | Printing and coating compositions containing expandable polystyrene |
-
2012
- 2012-06-14 CN CN201210195533.0A patent/CN102720062B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1059383A (en) * | 1991-08-09 | 1992-03-11 | 王祥森 | Knit cap formula of hardening agent and manufacture methods thereof such as crudefiber crop, careless class, paper-straws |
| CN1082587A (en) * | 1992-07-17 | 1994-02-23 | 福建师范大学 | A kind of polystyrene adhesive and production method thereof |
| CN1239131A (en) * | 1999-07-06 | 1999-12-22 | 董金狮 | Dissolving-fusing modification of EPS and process for preparing adhesive |
| CN1659244A (en) * | 2002-06-05 | 2005-08-24 | 巴斯福股份公司 | Printing and coating compositions containing expandable polystyrene |
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| CN102720062A (en) | 2012-10-10 |
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| C06 | Publication | ||
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of selvage setting agent Effective date of registration: 20200812 Granted publication date: 20140115 Pledgee: Jiangsu Credit Financing Guarantee Co.,Ltd. Pledgor: NANTONG YIHUA PLASTIC Co.,Ltd. Registration number: Y2020980004916 |
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Address after: 226371 group 3, East, Sun Li Qiao Cun, Xingdong Town, Tongzhou District, Nantong City, Jiangsu Province Patentee after: Yihua high tech materials (Nantong) Co.,Ltd. Address before: 226300 No.18, sunliqiao Industrial Park, Xingdong Town, Tongzhou District, Nantong City, Jiangsu Province Patentee before: NANTONG YIHUA PLASTIC Co.,Ltd. |
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Date of cancellation: 20210930 Granted publication date: 20140115 Pledgee: Jiangsu Credit Financing Guarantee Co.,Ltd. Pledgor: NANTONG YIHUA PLASTIC Co.,Ltd. Registration number: Y2020980004916 |
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Denomination of invention: A preparation method of edge setting agent Effective date of registration: 20211027 Granted publication date: 20140115 Pledgee: Jiangsu Zaibao South communication Financing Guarantee Co.,Ltd. Pledgor: Yihua high tech materials (Nantong) Co.,Ltd. Registration number: Y2021980011384 |
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Date of cancellation: 20221018 Granted publication date: 20140115 Pledgee: Jiangsu Zaibao South communication Financing Guarantee Co.,Ltd. Pledgor: Yihua high tech materials (Nantong) Co.,Ltd. Registration number: Y2021980011384 |
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