CN108165212A - One kind eliminates the unusual smell adhesive - Google Patents

One kind eliminates the unusual smell adhesive Download PDF

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Publication number
CN108165212A
CN108165212A CN201611116371.1A CN201611116371A CN108165212A CN 108165212 A CN108165212 A CN 108165212A CN 201611116371 A CN201611116371 A CN 201611116371A CN 108165212 A CN108165212 A CN 108165212A
Authority
CN
China
Prior art keywords
parts
adhesive
powder
unusual smell
bamboo charcoal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611116371.1A
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Chinese (zh)
Inventor
王素
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Thousands Of Wooden Furniture (tianjin) Co Ltd Ye
Original Assignee
Thousands Of Wooden Furniture (tianjin) Co Ltd Ye
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thousands Of Wooden Furniture (tianjin) Co Ltd Ye filed Critical Thousands Of Wooden Furniture (tianjin) Co Ltd Ye
Priority to CN201611116371.1A priority Critical patent/CN108165212A/en
Publication of CN108165212A publication Critical patent/CN108165212A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • C09J129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

One kind eliminates the unusual smell adhesive, includes the component of following parts by weight：100 150 parts of polyvinyl alcohol resin, 2 50 80 parts of ethyl benzofurans, lead 20 30 parts of dibatyl phithalate, 15 20 parts of polystyrene, 10 15 parts of dixylenyl phosphate, 20 30 parts of isophorone diisocyanate, 5 10 parts of nitrile rubber, 10 15 parts of calcium carbonate, 58 parts of titanium dioxide, 5 20 parts of nano-sized magnesium hydroxide, 15 20 parts of modified Nano bamboo charcoal powder, 10 15 parts of lignin, 35 parts of gas-phase silica, 35 parts of sodium alginate, 20 30 parts of quartz sand, 13 parts of boron powder, 5 10 parts of bath of glass, 0.7 0.9 parts of dibutyl tin laurate, 24 parts of micaceous iron oxide, 13 parts of silane coupling agent, 10 15 parts of modified coal ash.The present invention is by adding in the ingredients to adhesive such as modified Nano bamboo charcoal powder, lignin, the toxicity and pollution on the environment of adhesive can be effectively eliminated, simultaneously, add in modified coal ash, significantly improve the dispersing uniformity of each component, the adhesion intensity of adhesive can be improved, and there is at low cost, excellent effect.The adhesive of the present invention has the characteristics that adhesive strength is high, pollution-free, storage period is longer, harmless to human body, environmentally protective.

Description

One kind eliminates the unusual smell adhesive
Technical field
The present invention relates to eliminate the unusual smell adhesive the present invention relates to a kind of jointing material, particularly one kind.
Background technology
Adhesive is that one kind can be the similar or inhomogeneous combined substance of material tight.With science and technology With the development of national economy, adhesive has been widely used in timber processing, architectural engineering, textile printing and dyeing, shoemaking, leather, electricity The every profession and trades such as son, automobile, machinery, aerospace, biologic medical and high-tech area.At present, in order to improve the certain of adhesive Performance often adds in some modifying agent, thickener, tackifier, emulsifier etc. in adhesive, and some in these substances are toxic , some are even extremely toxic, and most meeting generation environment pollutions.
Invention content
It is more preferable and both resistance to that a kind of feature of environmental protection is provided the purpose of the present invention is to solve above-mentioned the deficiencies in the prior art It is hot, ageing-resistant, but the one kind that can improve adhesive strength eliminates the unusual smell adhesive.
The object of the present invention is achieved like this：
One kind eliminates the unusual smell adhesive, includes the component of following parts by weight：100-150 parts of polyvinyl alcohol resin, 2- ethylo benzenes Parallel furans 50-80 parts, neck 20-30 parts of dibatyl phithalate, 15-20 parts of polystyrene, 10-15 parts of dixylenyl phosphate, 20-30 parts of isophorone diisocyanate, 5-10 parts of nitrile rubber, 10-15 parts of calcium carbonate, 5-8 parts of titanium dioxide, nanometer hydroxide 5-20 parts of magnesium, 15-20 parts of modified Nano bamboo charcoal powder, 10-15 parts of lignin, 3-5 parts of gas-phase silica, 3-5 parts of sodium alginate, stone 20-30 parts of sand, 1-3 parts of boron powder, 5-10 parts of bath of glass, 0.7-0.9 parts of dibutyl tin laurate, 2-4 parts of micaceous iron oxide, 1-3 parts of silane coupling agent, 10-15 parts of modified coal ash.
The preparation method of the modified Nano bamboo charcoal powder is：Bamboo charcoal powder impregnates 5-8h with 10-15% sodium hydroxide solutions, Then it is washed with deionized, dries, add 2,4,6 trisphenols for being equivalent to its weight 1-2%, the a- cyano third of 1-3% The crosslink agent DCP of olefin(e) acid ethyl ester, 1-3%, 3000-5000 revs/min is stirred 30-50 minutes, and drying is ground into nanometer powder, i.e., It can.
The modified coal ash is prepared by following steps：First flyash in 100-110 DEG C of baking oven is dried, then will Flyash after drying is put into high-speed kneading machine, adds in aluminate coupling agent, the 2-4% for being equivalent to flyash weight 3-5% Wooden sodium sulfonate, the triethyl citrate of 2-4%, the atoleine of 1-2% and 2-5% talcum powder, after mixed at high speed, dry Dry, attrition grinding is into superfines.
A kind of preparation method for the adhesive that eliminates the unusual smell, including following preparation process：
(1) by recipe ratio will by polyvinyl alcohol resin, 2- ethyls benzofuran, neck dibatyl phithalate, polystyrene, Dixylenyl phosphate, isophorone diisocyanate, nitrile rubber, dibutyl tin laurate are added to reaction kettle and are heated to 100-130 DEG C, high-speed stirred 3-4h；
(2) other compositions are added in the reaction kettle in step (1) again, stir 1-2h, be cooled to room temperature, packaging is It can.
The advantages and positive effects of the present invention are：
The present invention can effectively eliminate gluing by adding in the ingredients to adhesive such as modified Nano bamboo charcoal powder, lignin The toxicity and pollution on the environment of agent, meanwhile, add in modified coal ash, hence it is evident that the dispersing uniformity of each component is improved, The adhesion intensity of adhesive can be improved, and there is at low cost, excellent effect.The adhesive of the present invention has bonding by force The features such as degree is high, pollution-free, storage period is longer, it is harmless to human body, it is environmentally protective.
Specific embodiment
The embodiment of the present invention is described in detail below；It should be noted that the present embodiment is narrative, it is not limited , it is impossible to protection scope of the present invention is limited with this.
Embodiment 1：
Following percentage is weight percentage, and the method not referred to is the known method of those skilled in the art.
Include the component of following parts by weight：130 parts of polyvinyl alcohol resin, 70 parts of 2- ethyls benzofuran, neck phthalic acid 20 parts of dibutyl ester, 15 parts of polystyrene, 13 parts of dixylenyl phosphate, 25 parts of isophorone diisocyanate, nitrile rubber 7 Part, 10 parts of calcium carbonate, 5 parts of titanium dioxide, 6 parts of nano-sized magnesium hydroxide, 18 parts of modified Nano bamboo charcoal powder, 15 parts of lignin, gas phase are white 4 parts of carbon black, 4 parts of sodium alginate, 25 parts of quartz sand, 2 parts of boron powder, 6 parts of bath of glass, 0.8 part of dibutyl tin laurate, mica oxygen Change 3 parts of iron, 2 parts of silane coupling agent, 13 parts of modified coal ash.
Wherein, the preparation method of modified Nano bamboo charcoal powder is：Bamboo charcoal powder impregnates 8h, Ran Houyong with 15% sodium hydroxide solution Deionized water wash, drying, add 2,4,6 trisphenols for being equivalent to its weight 2%, 3% a- cyanacrylates, 3% crosslink agent DCP, 5000 revs/min are stirred 50 minutes, and drying is ground into nanometer powder, you can.
Modified coal ash is prepared by following steps：First flyash is dried in 110 DEG C of baking ovens, then by the powder after drying Coal ash is put into high-speed kneading machine, add in be equivalent to the aluminate coupling agent of flyash weight 5%, 3% wooden sodium sulfonate, 3% triethyl citrate, 2% atoleine and 4% talcum powder, after mixed at high speed, drying, attrition grinding is into superfine powder End.
A kind of preparation method for the adhesive that eliminates the unusual smell, including following preparation process：It (1) will be by polyvinyl alcohol tree by recipe ratio Fat, 2- ethyls benzofuran, neck dibatyl phithalate, polystyrene, dixylenyl phosphate, isophorone diisocyanate Ester, nitrile rubber, dibutyl tin laurate are added to reaction kettle and are heated to 130 DEG C, high-speed stirred 3h；(2) again by other into Divide and be added in the reaction kettle in step (1), stir 1h, be cooled to room temperature, packaging.
Embodiment 2：
One kind eliminates the unusual smell adhesive, includes the component of following parts by weight：100 parts of polyvinyl alcohol resin, 2- ethylo benzene a pair of horses going side by side furans Mutter 50 parts, neck 20 parts of dibatyl phithalate, 15 parts of polystyrene, 10 parts of dixylenyl phosphate, isophorone diisocyanate 20 parts of ester, 5 parts of nitrile rubber, 10 parts of calcium carbonate, 7 parts of titanium dioxide, nano-sized magnesium hydroxide 5, part, 15 parts of modified Nano bamboo charcoal powder, 10 parts of lignin, 3 parts of gas-phase silica, 3 parts of sodium alginate, 20 parts of quartz sand, 1 part of boron powder, 5 parts of bath of glass, tin dilaurate two 0.7 part of butyl tin, 2 parts of micaceous iron oxide, 2 parts of silane coupling agent, 10 parts of modified coal ash.
Wherein, the preparation method of modified Nano bamboo charcoal powder is：Bamboo charcoal powder impregnates 7h, Ran Houyong with 10% sodium hydroxide solution Deionized water wash, drying, add 2,4,6 trisphenols for being equivalent to its weight 2%, 1% a- cyanacrylates, 1% crosslink agent DCP, 3000 revs/min are stirred 30 minutes, and drying is ground into nanometer powder, you can.
Modified coal ash is prepared by following steps：First flyash is dried in 100 DEG C of baking ovens, then by the powder after drying Coal ash is put into high-speed kneading machine, add in be equivalent to the aluminate coupling agent of flyash weight 3%, 2% wooden sodium sulfonate, 2% triethyl citrate, 1% atoleine and 2% talcum powder, after mixed at high speed, drying, attrition grinding is into superfine powder End.
A kind of preparation method for the adhesive that eliminates the unusual smell, including following preparation process：It (1) will be by polyvinyl alcohol tree by recipe ratio Fat, 2- ethyls benzofuran, neck dibatyl phithalate, polystyrene, dixylenyl phosphate, isophorone diisocyanate Ester, nitrile rubber, dibutyl tin laurate are added to reaction kettle and are heated to 100 DEG C, high-speed stirred 3h；(2) again by other into Divide and be added in the reaction kettle in step (1), stir 1h, be cooled to room temperature, packaging.

Claims (4)

  1. The adhesive 1. one kind eliminates the unusual smell, it is characterised in that：Include the component of following parts by weight：100-150 parts of polyvinyl alcohol resin, 50-80 parts of 2- ethyl benzofurans, 20-30 parts of dibatyl phithalate of neck, 15-20 parts of polystyrene, dixylenyl phosphate 10-15 parts, 20-30 parts of isophorone diisocyanate, 5-10 parts of nitrile rubber, 10-15 parts of calcium carbonate, 5-8 parts of titanium dioxide, receive 5-20 parts of magnesium hydroxide of rice, 15-20 parts of modified Nano bamboo charcoal powder, 10-15 parts of lignin, 3-5 parts of gas-phase silica, sodium alginate 3-5 parts, 20-30 parts of quartz sand, 1-3 parts of boron powder, 5-10 parts of bath of glass, 0.7-0.9 parts of dibutyl tin laurate, mica oxidation 2-4 parts of iron, 1-3 parts of silane coupling agent, 10-15 parts of modified coal ash.
  2. The adhesive 2. one kind according to claim 1 eliminates the unusual smell, it is characterised in that：The system of the modified Nano bamboo charcoal powder Preparation Method is：Bamboo charcoal powder impregnates 5-8h with 10-15% sodium hydroxide solutions, is then washed with deionized, and dries, adds phase When in 2,4,6 trisphenols of its weight 1-2%, the a- cyanacrylates of 1-3%, 1-3% crosslink agent DCP, 3000- 5000 revs/min are stirred 30-50 minutes, and drying is ground into nanometer powder, you can.
  3. The adhesive 3. one kind according to claim 1 eliminates the unusual smell, it is characterised in that：The modified coal ash is by following step It is rapid to prepare：First flyash in 100-110 DEG C of baking oven is dried, then the flyash after drying is put into high-speed kneading machine, Add in the lemon triethylenetetraminehexaacetic acid for being equivalent to the aluminate coupling agent of flyash weight 3-5%, the wooden sodium sulfonate of 2-4%, 2-4% The talcum powder of ester, the atoleine of 1-2% and 2-5%, after mixed at high speed, drying, attrition grinding is into superfines.
  4. 4. a kind of preparation method for the adhesive that eliminates the unusual smell, it is characterised in that：Including following preparation process：
    It (1) will be by polyvinyl alcohol resin, 2- ethyls benzofuran, neck dibatyl phithalate, polystyrene, diformazan by recipe ratio Phenyl phosphate ester, isophorone diisocyanate, nitrile rubber, dibutyl tin laurate are added to reaction kettle and are heated to 100- 130 DEG C, high-speed stirred 3-4h；
    (2) other compositions are added in the reaction kettle in step (1) again, stir 1-2h, be cooled to room temperature, packaging.
CN201611116371.1A 2016-12-07 2016-12-07 One kind eliminates the unusual smell adhesive Pending CN108165212A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611116371.1A CN108165212A (en) 2016-12-07 2016-12-07 One kind eliminates the unusual smell adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611116371.1A CN108165212A (en) 2016-12-07 2016-12-07 One kind eliminates the unusual smell adhesive

Publications (1)

Publication Number Publication Date
CN108165212A true CN108165212A (en) 2018-06-15

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CN201611116371.1A Pending CN108165212A (en) 2016-12-07 2016-12-07 One kind eliminates the unusual smell adhesive

Country Status (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113862824A (en) * 2021-10-22 2021-12-31 广州明晖新材料有限公司 High-temperature-resistant brush wire and preparation method thereof
CN114292608A (en) * 2022-02-18 2022-04-08 大茂环保新材料股份有限公司 Water-based environment-friendly runway surface layer adhesive and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113862824A (en) * 2021-10-22 2021-12-31 广州明晖新材料有限公司 High-temperature-resistant brush wire and preparation method thereof
CN114292608A (en) * 2022-02-18 2022-04-08 大茂环保新材料股份有限公司 Water-based environment-friendly runway surface layer adhesive and preparation method thereof

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Application publication date: 20180615