CN103467107A - Ceramic sheet sintering process - Google Patents

Ceramic sheet sintering process Download PDF

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Publication number
CN103467107A
CN103467107A CN2013104534978A CN201310453497A CN103467107A CN 103467107 A CN103467107 A CN 103467107A CN 2013104534978 A CN2013104534978 A CN 2013104534978A CN 201310453497 A CN201310453497 A CN 201310453497A CN 103467107 A CN103467107 A CN 103467107A
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Prior art keywords
thin plate
temperature
kiln
ceramic thin
firing process
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CN2013104534978A
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CN103467107B (en
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陈志翰
周小昊
苏梓敬
苏逸侃
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Fujian Jiamei Group Co Ltd
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Fujian Jiamei Group Co Ltd
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Priority to CN201310453497.8A priority Critical patent/CN103467107B/en
Publication of CN103467107A publication Critical patent/CN103467107A/en
Priority to PCT/CN2014/086507 priority patent/WO2015043388A1/en
Priority to US15/025,556 priority patent/US9718736B2/en
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Publication of CN103467107B publication Critical patent/CN103467107B/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/24Producing shaped prefabricated articles from the material by injection moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/243Setting, e.g. drying, dehydrating or firing ceramic articles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562Heating rate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6565Cooling rate

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention relates to a ceramic sheet sintering process. A blank body after biscuit firing and glazing is placed in a kiln, wherein the temperature of the kiln is controlled according to the principles that when the kiln temperature is 100-400 DEG C, the temperature rise duration is 1-2 hours; when the kiln temperature is 400-900 DEG C, the temperature rise duration is 2-3 hours; when the kiln temperature is 900-1100 DEG C, the temperature rise duration must reach more than 3 hours; when the kiln temperature is 1100-1350 DEG C, the temperature rise duration is controlled to be 3-4 hours; after the temperature reaches 1320-1350 DEG C, heat-preservation cooling is conducted; when lowered to 1230-1270 DEG C, the temperature is raised to 1290-1310 DEG C; when the temperature is lowered again to 880-920 DEG C, a kiln cover is opened for cooling, and a finished product is taken out. By means of the sintering mode of the ceramic sheet sintering process, the success rate of sintering of a ceramic sheet is increased effectively, the glaze of the sintered ceramic sheet is bright, smooth and as clear as a mirror, and the length and width specification of the sintered ceramic sheet is at least 1.5*1.5 meters.

Description

The firing process of ceramic thin plate
Technical field
The present invention relates to a kind of ceramic sintering process, refer to especially a kind of firing process of ceramic thin plate.
Background technology
Burn till is to make one of ceramic most important operation.In sintering process, base substrate is often experiencing and is dewatering, organic volatilization, burning, carbonate decomposition, the variation of the physics and chemistries such as the formation of mineral composition, densification and microstructural formation.When ceramic thin plate burns till, because its thickness is less, a series of variation occurs in sintering process and probably make the thin plate base substrate occur that slight crack is even broken.How improper because of the firing temperatures control of firing process in the process of prior art production ceramic thin plate, make the thin plate base substrate that Fragmentation Phenomena occur because densification is inhomogeneous, product qualified rate is very low, and scrap rate is high, and the ceramic thin plate production cost is high.And the thickness of ceramic thin plate also has some limitations therefrom.In addition, for ceramic thin plate in uneven thickness, the success ratio of existing thin plate firing technology is lower.
Summary of the invention
The invention provides a kind of firing process of ceramic thin plate, frangible to overcome the thin plate that existing ceramic thin plate firing technology exists, success ratio is very low, the problem that production cost is high.
The present invention adopts following technical scheme:
The firing process of ceramic thin plate, will put to kiln through the base substrate of biscuiting and glazing, and the temperature of kiln is controlled and comprised the following step of carrying out successively:
When a. kiln temperature is 100~400 ℃, slowly heat up, the intensification duration is 1~2 hour;
When b. kiln temperature is 400~900 ℃, can be rapidly heated, the intensification duration is 2~3 hours;
That when c. kiln temperature is 900~1100 ℃, need control is very slow, and the intensification duration must reach more than 3 hours;
When d. kiln temperature is 1100~1350 ℃, the control of intensification duration is 3~4 hours;
E. after reaching 1320~1350 ℃, temperature needs the heat preserving type cooling;
When f. temperature is down to 1230~1270 ℃ again by temperature increase to 1290~1310 ℃;
Open the cooling of kiln lid while g. being cooled to again 880~920 ℃ and take out finished product.
Further:
Above-mentioned ceramic thin plate thickness is less than 5.1 millimeters.Further, this ceramic thin plate thickness is 1.0~4.0 millimeters.
Above-mentioned ceramic thin plate comprises internal surface and outside surface, the uneven formation rule pattern of the outside surface of this ceramic thin plate.Further, this regular pattern is figure picture or scenery picture.
Above-mentioned base substrate is positioned in mould.The preparation method of this base substrate is: first smear the reagent of being convenient to the demoulding on this mould, then on mould, inject mud and put down to appointed thickness, move to kiln and carry out biscuiting after mud parches the formation openpore naturally, impose transparent water after biscuiting.Further, this reagent of being convenient to the demoulding is celestial water; This mud is greater than porcelain mud more than 280 orders by fineness, and to add weight percent be that 1.0~4.0% tackiness agent make, and concentration of hydraulic mixture is that moisture percentage is not more than 30%; This openpore is slightly repaired at not dry unhardened previous crops only, after base substrate parches, any finishing vestige must not be arranged again, can not glue water and touch water.
Finally, above-mentioned biscuiting temperature is 1000 ℃.
From the above-mentioned description of this invention, compared to the prior art, the present invention has following advantage: firing mode of the present invention, not only effectively improved the success ratio that ceramic thin plate burns till, and the ceramic thin plate glaze burnt till is bright, lubricious, limpid as mirror, the ceramic thin plate length and width specification that can burn till is at least 1.5 * 1.5 meters; In addition, by process for calcining of the present invention, can make ceramic thin plate thin as a piece of paper and that transparence is extremely strong, the thickness degree of thin plate is: the thinnest recessed part is no more than 1 millimeter, and bossing is no more than 3 millimeters; In addition, can light source be set at ceramic thin plate, so just can be under the effect of light source the view picture works embody very gentle, light, penetrating shadow carving stereoeffect, impose warm light make especially porcelain thoroughly warm as thin,tough silk as jade.
Embodiment
Embodiment one
The firing process of ceramic thin plate, [U.S. Xian Shui is a kind of new and effective pottery ionogen that China introduces in recent years first first to smear celestial water on this mould.Can not damage plaster mold as the ceramic mud ionogen; But fast demoulding during grouting operation, increased the slip casting number of times; While changing slurry, easily pull an oar, good fluidity; Can increase the good article rate of slip casting base substrate, can make base substrate retain 24h in plaster mould and not chap.They are all water white liquid, and tasteless, odorless, nontoxic, have soapy feeling, and proportion is (25 ℃) 1.16, and ultimate viscosity number is 75Pas, in water, very easily dissolve.], then on mould, inject mud and put down to appointed thickness, move to kiln and carry out biscuiting after mud parches the formation openpore naturally, the biscuiting temperature is 1000 ℃, imposes transparent water after biscuiting.This mud is greater than porcelain mud more than 280 orders by fineness, and to add weight percent be that 3.0% tackiness agent makes, and concentration of hydraulic mixture is that moisture percentage is not more than 30%; This openpore is slightly repaired at not dry unhardened previous crops only, after base substrate parches, any finishing vestige must not be arranged again, can not glue water and touch water.Finally, will put to kiln through the base substrate of glazing, the temperature of kiln is controlled and is comprised the following step of carrying out successively:
When a. kiln temperature is 100~400 ℃, slowly heat up, the intensification duration is 2 hours;
When b. kiln temperature is 400~900 ℃, can be rapidly heated, the intensification duration is 2 hours;
That when c. kiln temperature is 900~1100 ℃, need control is very slow, intensification duration preferably 5 hours;
When d. kiln temperature is 1100~1350 ℃, the control of intensification duration is 3.5 hours;
E. after reaching 1320 ℃, temperature carries out the heat preserving type cooling;
When f. temperature is down to 1250 ℃ again by temperature increase to 1300 ℃;
Open the cooling of kiln lid while g. being cooled to again 900 ℃ and take out finished product.
Ceramic thin plate comprises internal surface and outside surface, the outside surface of this ceramic thin plate uneven formation figure picture or scene patterns.This figure picture or scene patterns can be full of the whole outside surface of this finished product ceramic thin plate, also can be arranged at the centre of ceramic thin plate outside surface, and the part outside pattern part is the outer part.The outer part mainly plays a supportive role and decoration function.The thickness of outer part is preferably 3.0~5.0 millimeters, and preferred thickness is 4.0 millimeters; The thickness of pattern part is preferably 1.0~3.0 millimeters, and its thinnest recessed part is no more than 1.0 millimeters, and bossing is no more than 3.0 millimeters.
Embodiment two
The firing process of ceramic thin plate is first first smeared celestial water on this mould, then on mould, injects mud and puts down to appointed thickness, moves to kiln and carry out biscuiting after mud parches the formation openpore naturally, and the biscuiting temperature is 1000 ℃, imposes transparent water after biscuiting.This mud is greater than porcelain mud more than 280 orders by fineness, and to add weight percent be that 4.0% tackiness agent makes, and concentration of hydraulic mixture is that moisture percentage is not more than 30%; This openpore is slightly repaired at not dry unhardened previous crops only, after base substrate parches, any finishing vestige must not be arranged again, can not glue water and touch water.Finally, will put to kiln through the base substrate of glazing, the temperature of kiln is controlled and is comprised the following step of carrying out successively:
When a. kiln temperature is 100~400 ℃, slowly heat up, the intensification duration is 1.5 hours;
When b. kiln temperature is 400~900 ℃, can be rapidly heated, the intensification duration is 2.5 hours;
That when c. kiln temperature is 900~1100 ℃, need control is very slow, and the intensification duration is 3 hours;
When d. kiln temperature is 1100~1350 ℃, the control of intensification duration is 3 hours;
E. after reaching 1350 ℃, temperature carries out the heat preserving type cooling;
When f. temperature is down to 1270 ℃ again by temperature increase to 1310 ℃;
Open the cooling of kiln lid while g. being cooled to again 920 ℃ and take out finished product.The thickness of finished product ceramic thin plate outer part is 3.0 millimeters; The recessed part that pattern part is the thinnest is no more than 1.0 millimeters, and bossing is no more than 3.0 millimeters.
Embodiment three
The firing process of ceramic thin plate is first first smeared celestial water on this mould, then on mould, injects mud and puts down to appointed thickness, moves to kiln and carry out biscuiting after mud parches the formation openpore naturally, and the biscuiting temperature is 1000 ℃, imposes transparent water after biscuiting.This mud is greater than porcelain mud more than 280 orders by fineness, and to add weight percent be that 1.0% tackiness agent makes, and concentration of hydraulic mixture is that moisture percentage is not more than 30%; This openpore is slightly repaired at not dry unhardened previous crops only, after base substrate parches, any finishing vestige must not be arranged again, can not glue water and touch water.Finally, will put to kiln through the base substrate of glazing, the temperature of kiln is controlled and is comprised the following step of carrying out successively:
When a. kiln temperature is 100~400 ℃, slowly heat up, the intensification duration is 1 hour;
When b. kiln temperature is 400~900 ℃, can be rapidly heated, the intensification duration is 3 hours;
That when c. kiln temperature is 900~1100 ℃, need control is very slow, and the intensification duration is 6 hours;
When d. kiln temperature is 1100~1350 ℃, the control of intensification duration is 4 hours;
E. after reaching 1335 ℃, temperature needs the heat preserving type cooling;
When f. temperature is down to 1230 ℃ again by temperature increase to 1290 ℃;
Open the cooling of kiln lid while g. being cooled to again 880 ℃ and take out finished product.The thickness of finished product ceramic thin plate outer part is 5.0 millimeters; The recessed part that pattern part is the thinnest is no more than 1.0 millimeters, and bossing is no more than 3.0 millimeters.
Above are only the specific embodiment of the present invention, but design concept of the present invention is not limited to this, allly utilizes this design to carry out the change of unsubstantiality to the present invention, all should belong to the behavior of invading protection domain of the present invention.

Claims (11)

1. the firing process of ceramic thin plate, will put to kiln through the base substrate of biscuiting and glazing, it is characterized in that, the temperature of kiln is controlled and comprised the following step of carrying out successively:
When a. kiln temperature is 100~400 ℃, the intensification duration is 1~2 hour;
When b. kiln temperature is 400~900 ℃, the intensification duration is 2~3 hours;
When c. kiln temperature is 900~1100 ℃, the intensification duration must reach more than 3 hours;
When d. kiln temperature is 1100~1350 ℃, the control of intensification duration is 3~4 hours;
E. after reaching 1320~1350 ℃, temperature carries out the heat preserving type cooling;
When f. temperature is down to 1230~1270 ℃ again by temperature increase to 1290~1310 ℃;
Open the cooling of kiln lid while g. being cooled to again 880~920 ℃ and take out finished product.
2. the firing process of ceramic thin plate as claimed in claim 1, it is characterized in that: described ceramic thin plate thickness is less than 5.1 millimeters.
3. the firing process of ceramic thin plate as claimed in claim 2, it is characterized in that: described ceramic thin plate thickness is 1.0~4.0 millimeters.
4. the firing process of ceramic thin plate as claimed in claim 1, is characterized in that: the uneven formation rule pattern of described ceramic thin plate outside surface.
5. the firing process of ceramic thin plate as claimed in claim 4, it is characterized in that: described regular pattern is figure picture or scenery picture.
6. the firing process of ceramic thin plate as claimed in claim 1, it is characterized in that: described base substrate is positioned in mould.
7. the firing process of ceramic thin plate as claimed in claim 6, it is characterized in that: first smear the reagent of being convenient to the demoulding on described mould, then inject mud and put down to appointed thickness on mould, moving to kiln and carry out biscuiting after mud parches the formation openpore naturally, imposing transparent water after biscuiting.
8. the firing process of ceramic thin plate as claimed in claim 7, it is characterized in that: the described reagent of being convenient to the demoulding is celestial water.
9. the firing process of ceramic thin plate as claimed in claim 7 is characterized in that: described mud is greater than porcelain mud more than 280 orders by fineness, and to add weight percent be that 1.0~4.0% tackiness agent make, and concentration of hydraulic mixture is that moisture percentage is not more than 30%.
10. the firing process of ceramic thin plate as claimed in claim 7, it is characterized in that: described openpore is slightly repaired at not dry unhardened previous crops only, can not glue water after base substrate parches and touch water.
11. the firing process of ceramic thin plate as claimed in claim 1 is characterized in that: described biscuiting temperature is 1000 ℃.
CN201310453497.8A 2013-09-29 2013-09-29 Ceramic sheet sintering process Active CN103467107B (en)

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CN201310453497.8A CN103467107B (en) 2013-09-29 2013-09-29 Ceramic sheet sintering process
PCT/CN2014/086507 WO2015043388A1 (en) 2013-09-29 2014-09-15 Sintering process for ceramic sheets
US15/025,556 US9718736B2 (en) 2013-09-29 2014-09-15 Sintering process for ceramic sheets

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015043388A1 (en) * 2013-09-29 2015-04-02 福建省佳美集团公司 Sintering process for ceramic sheets
CN106220189A (en) * 2016-07-28 2016-12-14 山东工业陶瓷研究设计院有限公司 The once-firing method of large scale thick-walled quartz pottery revolving body parts
CN112939616A (en) * 2021-02-22 2021-06-11 北京北方华创微电子装备有限公司 Ceramic sintering method and ceramic part manufactured by adopting same
CN114987099A (en) * 2022-07-11 2022-09-02 苏州金螳螂软装艺术有限公司 Manufacturing method of ultrathin ceramic book applied to exhibition

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110981420B (en) * 2019-12-10 2022-06-17 陆金喜 Firing process of obsidian cup

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CN102190507A (en) * 2010-03-12 2011-09-21 广东蒙娜丽莎陶瓷有限公司 Glaze material, ceramic sheet and manufacturing method for ceramic sheet
CN103121833A (en) * 2012-12-27 2013-05-29 厦门三荣陶瓷开发有限公司 Ceramic thin plate manufacturing method

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WO1996026909A1 (en) * 1995-02-27 1996-09-06 Toray Industries, Inc. Thin flat ceramic plate and method of manufacturing the same
CN101898887A (en) * 2009-05-31 2010-12-01 广东蒙娜丽莎陶瓷有限公司 Semitransparent ceramic material, imitation jadeite ceramic sheet and preparation thereof
CN102190507A (en) * 2010-03-12 2011-09-21 广东蒙娜丽莎陶瓷有限公司 Glaze material, ceramic sheet and manufacturing method for ceramic sheet
CN103121833A (en) * 2012-12-27 2013-05-29 厦门三荣陶瓷开发有限公司 Ceramic thin plate manufacturing method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015043388A1 (en) * 2013-09-29 2015-04-02 福建省佳美集团公司 Sintering process for ceramic sheets
US9718736B2 (en) 2013-09-29 2017-08-01 Fujian Jiamei Group Corporation Sintering process for ceramic sheets
CN106220189A (en) * 2016-07-28 2016-12-14 山东工业陶瓷研究设计院有限公司 The once-firing method of large scale thick-walled quartz pottery revolving body parts
CN106220189B (en) * 2016-07-28 2019-01-29 山东工业陶瓷研究设计院有限公司 The once-firing method of large scale thick-walled quartz ceramics revolution body component
CN112939616A (en) * 2021-02-22 2021-06-11 北京北方华创微电子装备有限公司 Ceramic sintering method and ceramic part manufactured by adopting same
CN114987099A (en) * 2022-07-11 2022-09-02 苏州金螳螂软装艺术有限公司 Manufacturing method of ultrathin ceramic book applied to exhibition
CN114987099B (en) * 2022-07-11 2024-04-16 苏州金螳螂软装艺术有限公司 Manufacturing method of ultrathin ceramic book applied to exhibition

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WO2015043388A1 (en) 2015-04-02
US20160207839A1 (en) 2016-07-21
CN103467107B (en) 2014-11-26
US9718736B2 (en) 2017-08-01

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