CN1034529A - Pottery wire trailing and goods thereof - Google Patents

Pottery wire trailing and goods thereof Download PDF

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Publication number
CN1034529A
CN1034529A CN 88100249 CN88100249A CN1034529A CN 1034529 A CN1034529 A CN 1034529A CN 88100249 CN88100249 CN 88100249 CN 88100249 A CN88100249 A CN 88100249A CN 1034529 A CN1034529 A CN 1034529A
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China
Prior art keywords
solvent
color base
wire
blue
goods
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CN 88100249
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Chinese (zh)
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张福平
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CERAMIC INDUSTRY SCIENTIFIC RESEARCH INST MINISTRY OF LIGHT INDUSTRY
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CERAMIC INDUSTRY SCIENTIFIC RESEARCH INST MINISTRY OF LIGHT INDUSTRY
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Priority to CN 88100249 priority Critical patent/CN1034529A/en
Publication of CN1034529A publication Critical patent/CN1034529A/en
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Abstract

The present invention relates to a kind of ceramic wire trailing and goods thereof, particularly a kind of ceramic wire is in conjunction with the comprehensive also goods of usefulness of trailings such as ceramic over-glaze decoration, under glazed, colour enamels, high and low temperature coloured glaze and blue-and-white rice pattern.Be suitable for producing pottery, especially display art porcelain, ceramic mural and top-grade building pottery.

Description

Pottery wire trailing and goods thereof
The present invention relates to a kind of ceramic wire trailing and goods thereof, particularly a kind of ceramic wire is in conjunction with the comprehensive also goods of usefulness of trailings such as ceramic over-glaze decoration, under glazed, colour enamels, high low temperature coloured glaze and blue-and-white rice pattern, be suitable for producing pottery, especially display art porcelain, ceramic mural and top-grade building pottery.
Existing cloisonne goods are that embedded wire imposes the colour enamels material on the metal tire, form through roasting burning of low temperature and polishing.Because its complex manufacturing technology, material cost height, price are expensive, ordinary consumer is difficult to accept.
Task of the present invention to provide exactly a kind of on the ceramic decoration face phase embedded wire, make pattern tough and tensile strong, natural and tripping; Decoration by various ceramic pigments, color glaze, make goods have dense national characters, can also reach cloisonne, colour enamels and the perfect artistic effect of ceramic triplicity in conjunction with the comprehensive also usefulness of decorative forms such as over-glaze decoration, under glazed, colour enamels, high and low temperature coloured glaze and blue-and-white rice pattern.Because, be carcass with the pottery, decoration technique is abundant, and is simple for production, and cost is low, can satisfy the demand of ordinary consumer.
The present invention is achieved in that at first, describe grain pattern at ceramic matrix or on the ceramic matrix of combined decoration, wire is pressed the moulding of grain pattern kneading (during batch process, can finalize the design specially and produce the wire product of various patterns, as animal, flowers etc.), adopt caking agent that wire is bonded on the porcelain body grain pattern, do the back and in grain pattern, execute various colorants, then polish, polish and form through 730~830 ℃ of decoration firing again.Goods also can carry out anti-oxidation processing.Because ceramic wire decorated articles, its wire is a conductor, so electrodepositable is handled (as: plating gold and silver etc.), makes its excellent decoration effect.
Below with reference to specific embodiment the present invention is described in further detail.
Fig. 1 is the synoptic diagram of a kind of goods of the present invention.
With reference to Fig. 1, adopt caking agent that wire (2) is bonded on the porcelain body (1), remove sizing unnecessary on the wire limit, can in wire (2) pattern, execute various colorants (3) after waiting to do, the a little higher than wire of colorant (2) upper surface is lower than the wire upper surface after making its decoration firing slightly.
Fig. 2 is process chart of the present invention.
Square frame is represented respectively:
1, grain pattern designs 2, prepares sizing 3, handles wire well
4, select tire tracing 5, pinch silk by grain pattern
6, the silk of moulding dip in sizing 7, will be the silk of moulding be bonded on the porcelain body
8, execute look 9, decoration firing 10, corase grind fine grinding
11, anti-oxidation processing
In the technological process of the present invention, the following points technical problem must be made detailed descriptionthe:
1, the selection of porcelain body
According to the requirement of decorative content and form, the mold performance of selecting for use is had nothing in common with each other.As: the mold in conjunction with combined decoration forms such as blue and white, exquisite, color glaze all has higher requirements to plasticity-, physical strength etc.
2, caking agent selects for use
As everyone knows, metal is completely different with the character of pottery, and general caking agent is (730-830 ℃) at high temperature, it can not be combined securely, therefore, selecting caking agent for use is one of key of the present invention, finds that through test the mineral compound adhesives is comparatively desirable.Its chemical formula is:
The chemical formula of the inorganic chemical combination caking agent that the specific embodiment of the invention is selected for use is:
Use proof through the certain period, this caking agent has stronger bonding force, and colloid concentrates fast.Trace Sodium, lead can soak into the metallic surface well during decoration firing, generate sticking solution with metal function, are bonded at securely on the wire, simultaneously, combine well with colorant solvent and porcelain body.
3, the selection of wire material
The present invention requires wire to have good bendability, and indeformable through 730~830 ℃ of decoration firing, wires such as spun gold, filamentary silver, copper wire all can be used for the present invention.Copper is a kind of henna metal, and its property is hard, has good attribute and the bendability of prolonging, and can reel off raw silk from cocoons also can break into thin slice, is one of desirable material.The alloy of copper has the branch of bronze, copper-nickel alloy, red copper, and each is variant because of the different performance of filling a prescription.Insulated wire is that its bending property is good by 94% fine copper and 6% zinc synthetic, but very easily oxidation need be electroplated antirust processing and just can be obtained the ideal effect.Brass contains zinc 50%, is golden yellow, is exactly like gold in appearance, at normal temperatures can be acidproof alkaline-resisting, and protection against corrosion, anti-oxidation, very hard after the cooling but brass wire generally reels off raw silk from cocoons, in order to adapt to wire technology, can use after need handling.The specific embodiment of the invention is selected the brass wire material.
4, the preparation of colorant
The ornamental colorant of pottery wire generally is to have the strong metal oxide of color development power for seeing toner (being color base) with various, and adding is formulated with the solvent that its performance adapts.The present invention directly imposes on the porcelain body with colorant, so solvent, color base and porcelain body are fused necessary good.The chemical formula of solvent of the present invention is:
Figure 881002496_IMG5
The chemical formula of specific embodiment of the invention solvent is:
Figure 881002496_IMG6
Color base major ingredient weight ratio of the present invention is:
Vanadium orchid: ZrO 2: SiO 2: NH 4VO 3=(9~12): (4.5~6.3): 1 also contains small amount of N aF catalyzer.
Praseodymium yellow: ZrO 2: SiO 2: Pr 6O 11=(6.4~9): (3.8~5): 1 also contains small amount of N aF, NH 4The Cl catalyzer.
Zirconium iron pink: ZrO 2: SiO 2: FeSO 47H 2O=(2~3.8): (1~2.1): 1 also contains small amount of N aF, NaCl, NaNO 3Catalyzer.
Blue: Al 2O 3: Co 2O 3: ZnO=(5.8~7.5): (2.8~4.5): 1
Green: Cr 2O 3: Co 2O 3: Al 2O 3: ZnO
=(7.2~8.7)∶(2.8~3.8)∶(1.8~2.6)∶1
Black: Fe 2O 3: Cr 2O 3: Co 2O 3: CuO
=(7.8~9.3)∶(7.1~9.5)∶(1.8~3)∶1
The important ratio of specific embodiment of the invention color base major ingredient is:
Vanadium orchid: ZrO 2: SiO 2: NH 4VO 3=11.8: 5.9: 1, also contain 4.8% NaF catalyzer in the component.
Praseodymium yellow: ZrO 2: SiO 2: Pr 6O 11=8.3: 4.2: 1, also contain 4.44% NaF, 3.73% NH in the component 4The Cl catalyzer.
Zirconium iron pink: ZrO 2: SiO 2: FeSO 47H 2O=2.5: 1.2: 1, also contain 3.49% NaCl in the component, 3.1% NaF, 2.06% NaNO 3Catalyzer.
Blue: Al 2O 3: Co 2O 3: ZnO=7.1: 3: 1, also contain 2.45% H in the component 3Bo 3Catalyzer.
Green: Cr 2O 3: Co 2O 3: Al 2O 3: ZnO=8.4: 3.3: 2.4: 1
Black: Fe 2O 3: Cr 2O 3: Co 2O 3: CuO=9.1: 8.9: 2: 1
Solvent of the present invention with the important ratio of color base is:
The blue colorant solvent of vanadium: color base=(3~68): 1
Pr-yellow material solvent: color base=(3~50): 1
Zirconium-iron pink pigment solvent: color base=(5~9): 1
Blue colorant solvent: color base=(5~42): 1
Green material solvent: color base=(6~56): 1
Black material solvent: color base=(30~76): 1
Specific embodiment of the invention solvent with the important ratio of color base is:
The blue colorant solvent of vanadium: color base=26: 1
Pr-yellow material solvent: color base=10: 1
Zirconium-iron pink pigment solvent: color base=19: 1
Blue colorant solvent: color base=7: 1
Green material solvent: color base=11: 1
Black material solvent: color base=56: 1

Claims (8)

1, a kind of is the ceramic wire trailing of carcass with the pottery, it is characterized in that adopting inorganic chemical combination caking agent that wire is fixed on the ceramic matrix, then executes colorant, decoration firing, surface treatment.
2, the method for claim 1 is characterized in that colorant is made up of solvent and color base, and the chemical formula of solvent is:
Figure 881002496_IMG1
Color base major ingredient weight ratio is:
The blue ZrO of vanadium 2: SiO 2: NH 4VO 3=(9~12): (4.5~6.3): 1
Praseodymium yellow ZrO 2: SiO 2: Pr 6O 11=(6.4~9): (3.8~5): 1
Zirconium iron pink ZrO 2: SiO 2: FeSO 47H 2O=(2~3.8): (1~2.1): 1
Blue Al 2O 3: Co 2O 3: ZnO=(5.8~7.5): (2.8~4.5): 1
Green Cr 2O 3: Co 2O 3: Al 2O 3: ZnO=(7.2~8.7): (2.8~3.8): (1.8~2.6): 1
Black Fe 2O 3: Cr 2O 3: Co 2O 3: CuO=(7.8~9.3): (7.1~9.5): (1.8~3): 1
The weight ratio of solvent and color base is:
The blue colorant solvent of vanadium: color base=(3~68): 1
Pr-yellow material solvent: color base=(3~50): 1
Zirconium-iron pink pigment solvent: color base=(5~42): 1
Blue colorant solvent: color base=(5~42): 1
Green material solvent: color base=(6~56): 1
Black material solvent: color base=(30~76): 1
3,, it is characterized in that the chemical formula of inorganic chemical combination caking agent is as claim 1,2 described methods:
4,, it is characterized in that wire can be a brass wire as claim 1,2 described methods.
5,, it is characterized in that the decoration firing temperature range is: 730~830 ℃ as claim 1,2 described methods.
6,, it is characterized in that surface treatment can carry out anti-oxidation processing or electroplating processes behind the sanding and polishing as claim 1,2 described methods.
7, the goods of ceramic wire trailing as claimed in claim 1 is characterized in that phase embedded wire between the decorative cover color.
8, goods as claimed in claim 7 is characterized in that the decorative cover part adopts over-glaze decoration, under glazed, colour enamels, high and low temperature coloured glaze and blue-and-white rice pattern to decorate or combined decoration respectively.
CN 88100249 1988-01-30 1988-01-30 Pottery wire trailing and goods thereof Pending CN1034529A (en)

Priority Applications (1)

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CN 88100249 CN1034529A (en) 1988-01-30 1988-01-30 Pottery wire trailing and goods thereof

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Application Number Priority Date Filing Date Title
CN 88100249 CN1034529A (en) 1988-01-30 1988-01-30 Pottery wire trailing and goods thereof

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CN1034529A true CN1034529A (en) 1989-08-09

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101875568A (en) * 2010-06-23 2010-11-03 平定莹玉陶瓷有限公司 Preparation method of green pigment for ceramic high-temperature glaze
CN102602216A (en) * 2012-03-09 2012-07-25 斯达高瓷艺发展(深圳)有限公司 Method for manufacturing enamel painted porcelain
CN102658753A (en) * 2012-05-24 2012-09-12 斯达高瓷艺发展(深圳)有限公司 Production method of carved colored-glaze artistic porcelain
CN112759261A (en) * 2021-03-01 2021-05-07 福建省德化顺意发陶瓷有限公司 Cloisonne enamel color porcelain and preparation process thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101875568A (en) * 2010-06-23 2010-11-03 平定莹玉陶瓷有限公司 Preparation method of green pigment for ceramic high-temperature glaze
CN102602216A (en) * 2012-03-09 2012-07-25 斯达高瓷艺发展(深圳)有限公司 Method for manufacturing enamel painted porcelain
CN102602216B (en) * 2012-03-09 2014-07-09 斯达高瓷艺发展(深圳)有限公司 Method for manufacturing enamel painted porcelain
CN102658753A (en) * 2012-05-24 2012-09-12 斯达高瓷艺发展(深圳)有限公司 Production method of carved colored-glaze artistic porcelain
CN112759261A (en) * 2021-03-01 2021-05-07 福建省德化顺意发陶瓷有限公司 Cloisonne enamel color porcelain and preparation process thereof

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