CN103450976A - Cold rolling lubricating agent for tungsten and tungsten alloy foils - Google Patents
Cold rolling lubricating agent for tungsten and tungsten alloy foils Download PDFInfo
- Publication number
- CN103450976A CN103450976A CN2013104152846A CN201310415284A CN103450976A CN 103450976 A CN103450976 A CN 103450976A CN 2013104152846 A CN2013104152846 A CN 2013104152846A CN 201310415284 A CN201310415284 A CN 201310415284A CN 103450976 A CN103450976 A CN 103450976A
- Authority
- CN
- China
- Prior art keywords
- tungsten
- alloy foil
- agent
- rolling lubricant
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 19
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 229910052721 tungsten Inorganic materials 0.000 title claims abstract description 19
- 239000010937 tungsten Substances 0.000 title claims abstract description 19
- 238000005097 cold rolling Methods 0.000 title claims abstract description 17
- 239000011888 foil Substances 0.000 title claims abstract description 17
- 229910001080 W alloy Inorganic materials 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 239000003921 oil Substances 0.000 claims abstract description 8
- 239000002199 base oil Substances 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 5
- 239000006185 dispersion Substances 0.000 claims abstract description 5
- 239000003755 preservative agent Substances 0.000 claims abstract description 5
- 230000002335 preservative effect Effects 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 15
- 239000000956 alloy Substances 0.000 claims description 15
- 235000019198 oils Nutrition 0.000 claims description 7
- -1 Triazole lipid Chemical class 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- MZWDAEVXPZRJTQ-WUXMJOGZSA-N 4-[(e)-(4-fluorophenyl)methylideneamino]-3-methyl-1h-1,2,4-triazole-5-thione Chemical compound CC1=NNC(=S)N1\N=C\C1=CC=C(F)C=C1 MZWDAEVXPZRJTQ-WUXMJOGZSA-N 0.000 claims description 2
- 239000004593 Epoxy Chemical class 0.000 claims description 2
- SRTXXUBDPVIROV-UHFFFAOYSA-N S=C1C(C=CC=C1)[O-].[Ca+2].S=C1C(C=CC=C1)[O-] Chemical group S=C1C(C=CC=C1)[O-].[Ca+2].S=C1C(C=CC=C1)[O-] SRTXXUBDPVIROV-UHFFFAOYSA-N 0.000 claims description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 2
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical group [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 125000002897 diene group Chemical group 0.000 claims description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 150000003751 zinc Chemical class 0.000 claims description 2
- 238000000137 annealing Methods 0.000 abstract description 7
- 238000001816 cooling Methods 0.000 abstract description 4
- 238000005461 lubrication Methods 0.000 abstract description 4
- 231100000956 nontoxicity Toxicity 0.000 abstract description 4
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 230000000881 depressing effect Effects 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000006078 metal deactivator Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 239000010729 system oil Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- 230000000994 depressogenic effect Effects 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention relates to a cold rolling lubricating agent for tungsten and tungsten alloy foils. No. 10 full-loss system oil is adopted as base oil, a variety of compound additives are used for matching, and the compound additives comprise an anti-wear agent, an oiliness agent, a friction modifier, an antioxidant preservative, a metal deactivator, a defoaming agent, a detergent, a dispersant and the like. The lubricating agent has the advantages of good wear resistance, adsorption, cleaning property, cooling property, dispersion, depressing property, bearing capacity and thermal oxidation stability and no production of annealing stains and can be used for simultaneously improving the process lubrication performance, increasing the strength of an oil film in a deformation area, reducing the friction coefficient, reducing the adhesion of a rolled piece and a roller, realizing stable composition and performances, and realizing no corrosion against metals and equipment, no toxicity and no irritating odor.
Description
Technical field
The invention belongs to tungsten and alloy foil cold-rolling lubricant field thereof.
Background technology
Tungsten, a kind of metallic element, belong to non-ferrous metal, is also typical rare metal, is national grand strategy resource.Steel Grey or silvery white, hardness is high, and fusing point is high, not corroded by air; Main application, for manufacturing filament and high speed cutting steel alloy, superhard mould, also for opticinstrument, has very important purposes.It is the important component part of contemporary high technology novel material, and a series of electron optics materials, specific alloy, new function material and organometallic compound etc. all need to use the tungsten of special performance.Though consumption is little, most important, lacking it can not.Thereby be widely used in contemporary mechanics of communication, robot calculator, aerospace exploitation, medical and health, sensitive materials, photoelectric material, energy and material and catalystic material etc.Relate to mine, metallurgy, machinery, building, traffic, electronics, chemical industry, light industry, weaving, military project, space flight, science and technology, each industrial circle.
The cold rolling foil of tungsten requires higher for product surface quality, the work hardening phenomenon can be more serious.Therefore, select suitable general working rate and pass reduction particularly important.Can take full advantage of Plastic Deformation and mill capacity, the general working rate between twice annealing can reach more than 50%; With the rolled piece attenuation, work hardening is also increasing, the corresponding minimizing of pass reduction.Do not corroded or stain when guaranteeing its flash annealing, requiring the refined mineral oil extremely low by sulphur content, lubricant requires resistance to abrasion, adsorptivity, spatter property, cooling, diffustivity, the property depressed, supporting capacity and thermal oxidation stability good; Do not produce annealing stain; Simultaneously, improve the technological lubrication performance, increase oil film strength in distorted area, reduce frictional coefficient; Reduce rolled piece and roll adhesion; Form and stable performance; Corrosion-free to metal and equipment; Nontoxicity, have no irritating odor.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of have good resistance to abrasion, adsorptivity, diffustivity, spatter property, cooling, the property depressed, supporting capacity and thermal oxidation stability, does not produce annealing stain; Simultaneously, can improve the technological lubrication performance, increase oil film strength in distorted area, reduce frictional coefficient; Reduce rolled piece and roll adhesion; Form and stable performance; Corrosion-free to metal and equipment; Nontoxicity, the tungsten had no irritating odor and alloy foil cold-rolling lubricant thereof.
The present invention is usingd following technical scheme and is solved the problems of the technologies described above: adopt No. 10 total loss systems with oil as base oil, coordinate multiple composite additive, its each component and mass percent thereof are:
| Component | Content (mass percent) |
| Base oil | 70%～78% |
| Anti-wear agent | 3.0%～5.0% |
| Oiliness improver | 8.0%～10.0% |
| Friction improver | 3.0%～5.0% |
| Antioxidant preservative | 0.8%～1.2% |
| Metal passivator | 0.5%～1.0% |
| Kilfoam | 0.001%～0.005% |
| Non-emulsifying agent | 0.1%～0.5% |
| Purification agent | 2.0%～3.0% |
| Dispersion agent | 4.0%～6.0% |
Base oil is No. 10 oil for the total loss system.
Anti-wear agent is that tritolyl phosphate and 30%～40% the Sulphurized Oxymolybdenum Dialkylthiophosphate of mass ratio 70%～60% is compound.
Oiliness improver is that dimeracid and 80%～70% the soybean oil of mass ratio 20%～30% is compound.
Friction improver is 124 Triazole lipid acid amine salt.
Antioxidant preservative is sulphur phosphorus brothers base zinc salt.
Metal passivator is the 124 Triazole derivative.
Kilfoam is dimethyl silicone oil.
Non-emulsifying agent is amine and epoxy compounds condenses.
Purification agent is calcium sulfenyl phenolate; Dispersion agent is diene base succimide.
Tungsten of the present invention and alloy foil cold-rolling lubricant thereof, do not corroded or stain when guaranteeing its flash annealing, requires the refined mineral oil extremely low by sulphur content; Lubricant has good resistance to abrasion, adsorptivity, diffustivity, spatter property, cooling, the property depressed, supporting capacity and thermal oxidation stability, does not produce annealing stain; Simultaneously, can improve the technological lubrication performance, increase oil film strength in distorted area, reduce frictional coefficient; Reduce rolled piece and roll adhesion; Form and stable performance; Corrosion-free to metal and equipment; Nontoxicity, have no irritating odor.
Embodiment
Embodiment 1:
Following component is in harmonious proportion and forms by mass percentage:
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion and forms by mass percentage:
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion and forms by mass percentage:
Above component summation is 100%.
Below the main physical and chemical index of embodiment 1 product:
| Project | Quality index |
| Moisture, % | Vestige |
| 40 ℃ of kinematic viscosity mm 2/s | 10.1 |
| Flash-point (opening) ℃, | 134 |
| Mechanical impurity, % | Nothing |
| Last non seizure load (Pb), Kg | 81 |
| Pour point, ℃, | -11 |
| Water soluble acid or alkali | Nothing |
| Corrosion test (copper sheet, 100 ℃, 3h), level | 1 |
| Viscosity index, | 90 |
Claims (10)
1. a tungsten and alloy foil cold-rolling lubricant thereof, it is characterized in that adopting No. 10 total loss systems with oil as base oil, coordinate multiple composite additive, its each component and mass percent thereof are:
2. tungsten as claimed in claim 1 and alloy foil cold-rolling lubricant thereof, is characterized in that base oil is No. 10 oil for the total loss system.
3. tungsten as claimed in claim 1 and alloy foil cold-rolling lubricant thereof, is characterized in that anti-wear agent is that tritolyl phosphate and 30%～40% the Sulphurized Oxymolybdenum Dialkylthiophosphate of mass ratio 70%～60% is compound.
4. tungsten as claimed in claim 1 and alloy foil cold-rolling lubricant thereof, is characterized in that oiliness improver is that dimeracid and 80%～70% the soybean oil of mass ratio 20%～30% is compound.
5. tungsten as claimed in claim 1 and alloy foil cold-rolling lubricant thereof, is characterized in that friction improver is 124 Triazole lipid acid amine salt.
6. tungsten as claimed in claim 1 and alloy foil cold-rolling lubricant thereof, is characterized in that antioxidant preservative is sulphur phosphorus brothers base zinc salt.
7. tungsten as claimed in claim 1 and alloy foil cold-rolling lubricant thereof, is characterized in that metal passivator is the 124 Triazole derivative.
8. tungsten as claimed in claim 1 and alloy foil cold-rolling lubricant thereof, is characterized in that kilfoam is dimethyl silicone oil.
9. tungsten as claimed in claim 1 and alloy foil cold-rolling lubricant thereof, is characterized in that non-emulsifying agent is amine and epoxy compounds condenses.
10. tungsten as claimed in claim 1 and alloy foil cold-rolling lubricant thereof, is characterized in that purification agent is calcium sulfenyl phenolate; Dispersion agent is diene base succimide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310415284.6A CN103450976B (en) | 2013-09-12 | 2013-09-12 | Cold rolling lubricating agent for tungsten and tungsten alloy foils |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310415284.6A CN103450976B (en) | 2013-09-12 | 2013-09-12 | Cold rolling lubricating agent for tungsten and tungsten alloy foils |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103450976A true CN103450976A (en) | 2013-12-18 |
| CN103450976B CN103450976B (en) | 2014-12-24 |
Family
ID=49733820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310415284.6A Expired - Fee Related CN103450976B (en) | 2013-09-12 | 2013-09-12 | Cold rolling lubricating agent for tungsten and tungsten alloy foils |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103450976B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105001958A (en) * | 2015-07-20 | 2015-10-28 | 广西大学 | Rotating cold-forging tungsten alloy lubricant composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1357610A (en) * | 2000-12-08 | 2002-07-10 | 刘凤梅 | Jilibao series of lubricant oil |
| JP2004263087A (en) * | 2003-03-03 | 2004-09-24 | Kao Corp | Lubricating oil for use in hot rolling oil for aluminum plate |
| CN102977974A (en) * | 2011-09-02 | 2013-03-20 | 中国石油化工股份有限公司 | Hot rolling lubricating oil composition and use thereof |
-
2013
- 2013-09-12 CN CN201310415284.6A patent/CN103450976B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1357610A (en) * | 2000-12-08 | 2002-07-10 | 刘凤梅 | Jilibao series of lubricant oil |
| JP2004263087A (en) * | 2003-03-03 | 2004-09-24 | Kao Corp | Lubricating oil for use in hot rolling oil for aluminum plate |
| CN102977974A (en) * | 2011-09-02 | 2013-03-20 | 中国石油化工股份有限公司 | Hot rolling lubricating oil composition and use thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105001958A (en) * | 2015-07-20 | 2015-10-28 | 广西大学 | Rotating cold-forging tungsten alloy lubricant composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103450976B (en) | 2014-12-24 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141224 |