CN103387445B - 一种可降解腐殖酸缓释颗粒的制备方法 - Google Patents
一种可降解腐殖酸缓释颗粒的制备方法 Download PDFInfo
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- CN103387445B CN103387445B CN201310260136.1A CN201310260136A CN103387445B CN 103387445 B CN103387445 B CN 103387445B CN 201310260136 A CN201310260136 A CN 201310260136A CN 103387445 B CN103387445 B CN 103387445B
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- humic acid
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- degradable
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- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000004021 humic acid Substances 0.000 title claims abstract description 36
- 239000008187 granular material Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 238000013268 sustained release Methods 0.000 title abstract 4
- 239000012730 sustained-release form Substances 0.000 title abstract 4
- 238000000576 coating method Methods 0.000 claims abstract description 24
- 239000011248 coating agent Substances 0.000 claims abstract description 23
- 238000001035 drying Methods 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000004971 Cross linker Substances 0.000 claims abstract description 5
- 238000002791 soaking Methods 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims description 32
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 30
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 15
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 102000008186 Collagen Human genes 0.000 claims description 8
- 108010035532 Collagen Proteins 0.000 claims description 8
- 229920001436 collagen Polymers 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 7
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- -1 hydroxypropyl Chemical group 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 229910021538 borax Inorganic materials 0.000 claims description 5
- 239000004328 sodium tetraborate Substances 0.000 claims description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 5
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052796 boron Inorganic materials 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 4
- 239000002689 soil Substances 0.000 abstract description 4
- 239000003337 fertilizer Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 229920002907 Guar gum Polymers 0.000 abstract 2
- 229960002154 guar gum Drugs 0.000 abstract 2
- 235000010417 guar gum Nutrition 0.000 abstract 2
- 239000000665 guar gum Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000001639 boron compounds Chemical class 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000002775 capsule Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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CN201310260136.1A CN103387445B (zh) | 2013-06-26 | 2013-06-26 | 一种可降解腐殖酸缓释颗粒的制备方法 |
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CN201310260136.1A CN103387445B (zh) | 2013-06-26 | 2013-06-26 | 一种可降解腐殖酸缓释颗粒的制备方法 |
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CN103387445B true CN103387445B (zh) | 2015-02-25 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105152752B (zh) * | 2015-08-07 | 2018-05-15 | 沃达农业科技股份有限公司 | 腐殖酸微生物生态肥料及其制备和使用方法 |
CN106396891A (zh) * | 2016-08-30 | 2017-02-15 | 山东胜伟园林科技有限公司 | 一种用于黄河灌区盐碱地的功能性腐殖酸营养颗粒及其制备方法 |
CN110272316B (zh) * | 2019-07-22 | 2021-11-30 | 陕西科技大学 | 一种纸基微量元素聚集型缓释肥及其制备方法 |
CN111296446B (zh) * | 2020-02-19 | 2022-03-01 | 内蒙古中孚明丰农业科技有限公司 | 一种可降解强吸水的双缓释保水肥料及其制备方法 |
CN113072952A (zh) * | 2021-04-02 | 2021-07-06 | 山东农业大学 | 一种适用于中弱碱性土壤镉污染的钝化剂及其使用方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2002329024A1 (en) * | 2001-09-03 | 2003-06-05 | Ben-Gurion University Of The Negev | Multi-layer adjuvants for controlled delivery of agro-materials into plant tissues |
CN1470485A (zh) * | 2002-07-23 | 2004-01-28 | 中国科学院南京土壤研究所 | 载体型缓释肥料及其制备方法 |
CN102180731A (zh) * | 2011-02-16 | 2011-09-14 | 成都正光投资集团有限公司 | 一种以纳米材料为载体的聚合物乳液包覆缓释肥及其制备方法 |
CN102267841A (zh) * | 2011-06-22 | 2011-12-07 | 北京市农林科学院 | 一种微水溶性肥料及其制备方法 |
CN102617249A (zh) * | 2012-03-31 | 2012-08-01 | 山东喜丰田生态肥业有限公司 | 一种新型多糖凝胶保水缓释肥 |
CN103011959A (zh) * | 2012-12-13 | 2013-04-03 | 广西农垦明阳生化集团股份有限公司 | 颗粒状肥料用粘结剂及其制备方法 |
CN103121871A (zh) * | 2011-11-21 | 2013-05-29 | 七台河市荣丰腐植酸有限公司 | 一种腐植酸肥套膜 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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IL145236A0 (en) * | 2001-09-03 | 2002-06-30 | Agro Vant Ltd | Multi-layer adjuvants for controlled delivery of agro-materials into plant tissue |
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Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2002329024A1 (en) * | 2001-09-03 | 2003-06-05 | Ben-Gurion University Of The Negev | Multi-layer adjuvants for controlled delivery of agro-materials into plant tissues |
CN1470485A (zh) * | 2002-07-23 | 2004-01-28 | 中国科学院南京土壤研究所 | 载体型缓释肥料及其制备方法 |
CN102180731A (zh) * | 2011-02-16 | 2011-09-14 | 成都正光投资集团有限公司 | 一种以纳米材料为载体的聚合物乳液包覆缓释肥及其制备方法 |
CN102267841A (zh) * | 2011-06-22 | 2011-12-07 | 北京市农林科学院 | 一种微水溶性肥料及其制备方法 |
CN103121871A (zh) * | 2011-11-21 | 2013-05-29 | 七台河市荣丰腐植酸有限公司 | 一种腐植酸肥套膜 |
CN102617249A (zh) * | 2012-03-31 | 2012-08-01 | 山东喜丰田生态肥业有限公司 | 一种新型多糖凝胶保水缓释肥 |
CN103011959A (zh) * | 2012-12-13 | 2013-04-03 | 广西农垦明阳生化集团股份有限公司 | 颗粒状肥料用粘结剂及其制备方法 |
Non-Patent Citations (1)
Title |
---|
一种改性胍胶的性能评价;陈鹏飞等;《精细石油化工进展》;20070930;第8卷(第9期);第1-3页 * |
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Effective date of registration: 20190515 Address after: 710021 Shaanxi Xi'an Economic and Technological Development Zone Weiyang Road and Fengcheng Nine Road Crossing Northeast Corner via 8 Floors of Block A of Kaiwanke Center Patentee after: Xi'an Yipu Eco-technology Co.,Ltd. Address before: No. 1, Weiyang District university garden, Xi'an, Shaanxi Province, Shaanxi Patentee before: SHAANXI University OF SCIENCE & TECHNOLOGY |
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Address after: 710021 Shaanxi Xi'an Economic and Technological Development Zone Weiyang Road and Fengcheng Nine Road Crossing Northeast Corner via 8 Floors of Block A of Kaiwanke Center Patentee after: Xi'an Yipu Digital Agriculture Co.,Ltd. Address before: 710021 Shaanxi Xi'an Economic and Technological Development Zone Weiyang Road and Fengcheng Nine Road Crossing Northeast Corner via 8 Floors of Block A of Kaiwanke Center Patentee before: Xi'an Yipu Eco-technology Co.,Ltd. |
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