CN103387419A - Ceramic liquid gold suitable for microwave oven and usage thereof - Google Patents
Ceramic liquid gold suitable for microwave oven and usage thereof Download PDFInfo
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- CN103387419A CN103387419A CN2013103665750A CN201310366575A CN103387419A CN 103387419 A CN103387419 A CN 103387419A CN 2013103665750 A CN2013103665750 A CN 2013103665750A CN 201310366575 A CN201310366575 A CN 201310366575A CN 103387419 A CN103387419 A CN 103387419A
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- jinsui river
- salt
- carboxylic acid
- poly carboxylic
- porcelain
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Abstract
The invention discloses a ceramic liquid gold suitable for a microwave oven and usage thereof. The usage comprises selection of a gold compound, a fluxing agent, a polycarboxylic acid binder, and a surface stabilizer and optimization of the additive amount of the substances. After the raw materials are mixed in a certain proportion, the liquid gold is directly decorated on the surface of a ceramic base material or the liquid gold is prepared into stained paper through silk-screen printing and then is decorated on the surface of the ceramic base material so as to form liquid gold decorative patterns (namely picture moving and printing), utensils with the decorative patterns can be directly heated in the microwave oven and can guarantee the integrity of the precious metal decorative patterns on the utensils and the authenticity of the color, so that the ceramic liquid gold has a broad market prospect.
Description
Technical field
The invention belongs to technical field of ceramic material, be specifically related to a kind of porcelain Jinsui River and using method thereof that is applicable to microwave oven.
Background technology
A few days ago, daily-use fine and Pengyang china stone producer generally use Jinsui River as finishing material both at home and abroad.But the porcelain that traditional Jinsui River is decorated has a great defect, can not use in microwave oven exactly.In case microwave oven is opened, the gold layer that is placed on the porcelain of stove produces strong electrical spark under the microwave severe radiation, make the gold layer be subject to havoc, thereby lose yellow brightness.Along with day by day popularizing of microwave oven, the demand of microwave porcelain constantly enlarges.Domestic each porcelain producer is the way of adopt avoiding at present, namely with ceramic whiteware or the porcelain only decorated with pigment as the microwave porcelain, avoid using Jinsui River.This all seriously is affected the decorative effect of China's microwave ceramics and assortment, has greatly restricted the international competitiveness of China's microwave porcelain.
Summary of the invention
The technical problem to be solved in the present invention is to provide that simple, the synthetic cost of a kind of technique is low, the porcelain that is applicable to microwave oven of stable performance is with Jinsui River and using method thereof.
For solving above technical problem, technical scheme of the present invention is: a kind of porcelain that is applicable to microwave oven is used Jinsui River, it is characterized in that including following component by weight percentage:
Gold compound 15-35%
Fusing assistant 20-40%
Poly carboxylic acid binding agent 20-40%
Surface agent for fixing 1-5%.
Described gold compound is carboxylate salt or sulfonate or sulfuric acid ester salt or the phosphoric acid fat salt of gold.
Described fusing assistant is comprised of the sulfonate of the carboxylate salt of aluminium, silicon, cerium sulfuric acid ester salt, the phosphoric acid fat salt of vanadium, the quaternary ammonium salt of zirconium.
The weight percent of described fusing assistant consists of: the phosphoric acid fat salt 15% of the carboxylate salt 30% of aluminium, the sulfonate 35% of silicon, cerium sulfuric acid ester salt 13%, vanadium, the quaternary ammonium salt 7% of zirconium.
The preparation method of described poly carboxylic acid binding agent is: will dredge basic propionic acid, Sodium Persulfate, isopropylcarbinol, magnesium sulfite and join in 50 ℃ of water and carried out polyreaction 2 hours, then add the potassium polyphosphate termination reaction to obtain co-poly carboxylic acid; Described co-poly carboxylic acid is cooled to 30 ℃, and the pH value that adds hydrochloric acid conditioned reaction system is 4 ~ 5, namely obtains the poly carboxylic acid binding agent.
Described surperficial agent for fixing is benzoate, stearate.
Above-mentioned porcelain, with the using method in Jinsui River, is characterized in that comprising the steps:
The first step: gold compound, fusing assistant, poly carboxylic acid binding agent, surperficial agent for fixing are mixed and made into porcelain according to proportioning at 60 ℃ use Jinsui River;
Second step: Jinsui River is directly decorated in the ceramic base material surface or decorated after marble paper is made in silk screen printing in the ceramic base material surface;
The 3rd step:, with the ceramic base material after Jinsui River is decorated, obtain to be applicable to the ceramic of microwave oven through 750 ℃ of color roastings.
Innovation of the present invention is that Jinsui River that the present invention makes can directly or decorate in the ceramic base material surface after marble paper is made in silk screen printing, this ceramic base material can be directly used in heating in microwave oven, and can keep the integrity of Jinsui River decorative pattern on base material and the verity of color, and this Jinsui River does not have special requirement in the processing requirement of the enterprising luggage decorations of ceramic base material and traditional Jinsui River decoration technology, therefore has wide market outlook.
Embodiment
The present invention is further detailed explanation below in conjunction with embodiment.
Embodiment 1
To dredge basic propionic acid, Sodium Persulfate, isopropylcarbinol, magnesium sulfite joins in 50 ℃ of water and carried out polyreaction 2 hours, then add the potassium polyphosphate termination reaction to obtain co-poly carboxylic acid; Described co-poly carboxylic acid is cooled to 30 ℃, and the pH value that adds hydrochloric acid conditioned reaction system is 4, namely obtains the poly carboxylic acid binding agent;
After being mixed in proportion, the quaternary ammonium salt 7% of the phosphoric acid fat salt 15% of the sulfonate of the carboxylate salt of aluminium 30%, silicon 35%, cerium sulfuric acid ester salt 13%, vanadium, zirconium makes fusing assistant.
Gold-sulfonate, fusing assistant, poly carboxylic acid binding agent, benzoate are mixed and made into porcelain according to proportioning at 60 ℃ use Jinsui River;
Again Jinsui River directly decorated in the ceramic base material surface or decorated after marble paper is made in silk screen printing in the ceramic base material surface;
, with the ceramic base material after Jinsui River is decorated, obtain to be applicable to the ceramic of microwave oven through 750 ℃ of color roastings finally.
Embodiment 2
To dredge basic propionic acid, Sodium Persulfate, isopropylcarbinol, magnesium sulfite joins in 50 ℃ of water and carried out polyreaction 2 hours, then add the potassium polyphosphate termination reaction to obtain co-poly carboxylic acid; Described co-poly carboxylic acid is cooled to 30 ℃, and the pH value that adds hydrochloric acid conditioned reaction system is 5, namely obtains the poly carboxylic acid binding agent;
After being mixed in proportion, the quaternary ammonium salt 7% of the phosphoric acid fat salt 15% of the sulfonate of the carboxylate salt of aluminium 30%, silicon 35%, cerium sulfuric acid ester salt 13%, vanadium, zirconium makes fusing assistant.
Gold-sulfuric acid ester salt, fusing assistant, poly carboxylic acid binding agent, benzoate are mixed and made into porcelain according to proportioning at 60 ℃ use Jinsui River;
Again Jinsui River directly decorated in the ceramic base material surface or decorated after marble paper is made in silk screen printing in the ceramic base material surface;
, with the ceramic base material after Jinsui River is decorated, obtain to be applicable to the ceramic of microwave oven through 750 ℃ of color roastings finally.
Embodiment 3
To dredge basic propionic acid, Sodium Persulfate, isopropylcarbinol, magnesium sulfite joins in 50 ℃ of water and carried out polyreaction 2 hours, then add the potassium polyphosphate termination reaction to obtain co-poly carboxylic acid; Described co-poly carboxylic acid is cooled to 30 ℃, and the pH value that adds hydrochloric acid conditioned reaction system is 4, namely obtains the poly carboxylic acid binding agent;
After being mixed in proportion, the quaternary ammonium salt 7% of the phosphoric acid fat salt 15% of the sulfonate of the carboxylate salt of aluminium 30%, silicon 35%, cerium sulfuric acid ester salt 13%, vanadium, zirconium makes fusing assistant.
Gold-phosphoric acid fat salt, fusing assistant, poly carboxylic acid binding agent, stearate are mixed and made into porcelain according to proportioning at 60 ℃ use Jinsui River;
Again Jinsui River directly decorated in the ceramic base material surface or decorated after marble paper is made in silk screen printing in the ceramic base material surface;
, with the ceramic base material after Jinsui River is decorated, obtain to be applicable to the ceramic of microwave oven through 750 ℃ of color roastings finally.
Claims (7)
1. a porcelain that is applicable to microwave oven is used Jinsui River, it is characterized in that including following component by weight percentage:
Gold compound 15-35%
Fusing assistant 20-40%
Poly carboxylic acid binding agent 20-40%
Surface agent for fixing 1-5%.
2. porcelain according to claim 1 is used Jinsui River, it is characterized in that: described gold compound is carboxylate salt or sulfonate or sulfuric acid ester salt or the phosphoric acid fat salt of gold.
3. porcelain according to claim 1 is used Jinsui River, it is characterized in that: described fusing assistant is comprised of the sulfonate of the carboxylate salt of aluminium, silicon, cerium sulfuric acid ester salt, the phosphoric acid fat salt of vanadium, the quaternary ammonium salt of zirconium.
4. porcelain according to claim 3 is used Jinsui River, it is characterized in that: the weight percent of described fusing assistant consists of: the phosphoric acid fat salt 15% of the carboxylate salt 30% of aluminium, the sulfonate 35% of silicon, cerium sulfuric acid ester salt 13%, vanadium, the quaternary ammonium salt 7% of zirconium.
5. porcelain according to claim 1 is used Jinsui River, it is characterized in that: the preparation method of described poly carboxylic acid binding agent is: will dredge basic propionic acid, Sodium Persulfate, isopropylcarbinol, magnesium sulfite and join in 50 ℃ of water and carried out polyreaction 2 hours, then add the potassium polyphosphate termination reaction to obtain co-poly carboxylic acid; Described co-poly carboxylic acid is cooled to 30 ℃, and the pH value that adds hydrochloric acid conditioned reaction system is 4 ~ 5, namely obtains the poly carboxylic acid binding agent.
6. porcelain according to claim 1 is used Jinsui River, it is characterized in that: described surperficial agent for fixing is benzoate, stearate.
7. according to claim 1-6 arbitrary described porcelain, with the using method in Jinsui River, is characterized in that comprising the steps:
The first step: gold compound, fusing assistant, poly carboxylic acid binding agent, surperficial agent for fixing are mixed and made into porcelain according to proportioning at 60 ℃ use Jinsui River;
Second step: Jinsui River is directly decorated in the ceramic base material surface or decorated after marble paper is made in silk screen printing in the ceramic base material surface;
The 3rd step:, with the ceramic base material after Jinsui River is decorated, obtain to be applicable to the ceramic of microwave oven through 750 ℃ of color roastings.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310366575.0A CN103387419B (en) | 2013-08-21 | 2013-08-21 | A kind of porcelain Jinsui River and its using method suitable for microwave oven |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310366575.0A CN103387419B (en) | 2013-08-21 | 2013-08-21 | A kind of porcelain Jinsui River and its using method suitable for microwave oven |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103387419A true CN103387419A (en) | 2013-11-13 |
| CN103387419B CN103387419B (en) | 2017-04-05 |
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| CN201310366575.0A Expired - Fee Related CN103387419B (en) | 2013-08-21 | 2013-08-21 | A kind of porcelain Jinsui River and its using method suitable for microwave oven |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1072670A (en) * | 1992-11-15 | 1993-06-02 | 山东省硅酸盐研究设计院 | Jinsui River |
| CN1363723A (en) * | 2001-10-23 | 2002-08-14 | 南京大学 | Molten gold resisting high-temp sinter and its preparing process |
| CN1858024A (en) * | 2006-04-28 | 2006-11-08 | 冯建光 | Method for preparing imitating gold water |
-
2013
- 2013-08-21 CN CN201310366575.0A patent/CN103387419B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1072670A (en) * | 1992-11-15 | 1993-06-02 | 山东省硅酸盐研究设计院 | Jinsui River |
| CN1363723A (en) * | 2001-10-23 | 2002-08-14 | 南京大学 | Molten gold resisting high-temp sinter and its preparing process |
| CN1858024A (en) * | 2006-04-28 | 2006-11-08 | 冯建光 | Method for preparing imitating gold water |
Non-Patent Citations (2)
| Title |
|---|
| 邓宇等: "低温烤烧瓷用金水的研究", 《陶瓷工程》 * |
| 陈建文等: "微波瓷用金水的研制", 《陶瓷科学与艺术》 * |
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| CN103387419B (en) | 2017-04-05 |
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Granted publication date: 20170405 Termination date: 20180821 |