CN103329932A - Nematicide composition containing fosthiazate and furfural - Google Patents
Nematicide composition containing fosthiazate and furfural Download PDFInfo
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- CN103329932A CN103329932A CN2013103279303A CN201310327930A CN103329932A CN 103329932 A CN103329932 A CN 103329932A CN 2013103279303 A CN2013103279303 A CN 2013103279303A CN 201310327930 A CN201310327930 A CN 201310327930A CN 103329932 A CN103329932 A CN 103329932A
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- furfural
- fosthiazate
- dodecylphenol
- polyvinylether
- water
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Abstract
The invention provides a nematicide composition containing fosthiazate and furfural. The nematicide composition comprises active ingredients including fosthiazate and furfural, wherein the weight percent ratio of the fosthiazate to the furfural is 1:18-300, the total content of the active ingredients is 80 to 98 weight percent, and the rest is auxiliary materials. The auxiliary materials consist of calcium dodecyl benzene sulfonate, triphenyl ethyl phenol polypropylene ether, dodecylphenol polyvinyl ether, antifreezing agents and water. The nematicide composition has the advantages that the advantages of each medicament can be realized, the cost is reduced, the time and the labor are also saved, and the economic benefit is improved. The action mechanisms of the fosthiazate and the furfural are similar, the additive effect is shown after the two ingredients are combined, and the data in the table obviously shows the advantages of the fosthiazate and furfural composition in the sterilization effect.
Description
Technical field
The present invention relates to agricultural chemicals, is a kind of nematicidal composition that contains fosthiazate and furfural.
Background technology
At present, single agricultural chemicals has certain limitation to the kill activity of plant root-knot nematode, particularly use a period of time after, the pesticide resistance of plant root-knot nematode is also in continuous enhancing, long-term use separately descends gradually to the control efficiency of nematode, and the pesticide resistance of nematode increases year by year.The average preventive effect of fosthiazate can not surpass 85%; The average imitation of furfural can not surpass 90%.
Summary of the invention
The objective of the invention is, provide a kind of nematicidal composition that contains fosthiazate and furfural, in order to prevent and treat root-knot nematode.
The present invention for achieving the above object, be achieved through the following technical solutions: a kind of nematicidal composition that contains fosthiazate and furfural, its active ingredient is: fosthiazate and furfural, both percentage by weights are: fosthiazate: furfural is 1:18-300, the total content of active ingredient is 80-98wt%, and all the other are auxiliary material.
Described auxiliary material is made up of calcium dodecyl benzene sulfonate, triphen ethyl-phenol polypropylene ether, dodecylphenol polyvinylether, antifreezing agent and water, the content of each auxiliary material is calcium dodecyl benzene sulfonate 0.5-4.5wt%, triphen ethyl-phenol polypropylene ether 0.2-2.5wt%, dodecylphenol polyvinylether 0.1-2wt%, antifreezing agent 0.2-4wt%, water 1-7wt%.
Described a kind of nematicidal composition that contains fosthiazate and furfural, described antifreezing agent is ammonium sulfate and/or ethylene glycol.
Described a kind of nematicidal composition that contains fosthiazate and furfural, the percentage by weight of described fosthiazate and furfural is 1:18-97.
Described a kind of nematicidal composition that contains fosthiazate and furfural, fosthiazate 0.48kg in per 100 kilograms of compositions, furfural 96kg, calcium dodecyl benzene sulfonate 0.8kg, triphen ethyl-phenol polypropylene ether 0.2kg, dodecylphenol polyvinylether 0.5kg, ethylene glycol 0.5kg, water 1.52kg.
Described a kind of nematicidal composition that contains fosthiazate and furfural, fosthiazate 0.5kg in per 100 kilograms of compositions, furfural 85kg, calcium dodecyl benzene sulfonate 3kg, triphen ethyl-phenol polypropylene ether 2kg, dodecylphenol polyvinylether 2kg, ethylene glycol 3kg, water 4.5kg.
Described a kind of nematicidal composition that contains fosthiazate and furfural, fosthiazate 5kg in per 100 kilograms of compositions, furfural 90kg, calcium dodecyl benzene sulfonate 1kg, triphen ethyl-phenol polypropylene ether 0.8kg, dodecylphenol polyvinylether 0.6kg, ammonium sulfate 0.6kg, ethylene glycol 0.7kg, water 1.3kg.
Described a kind of nematicidal composition that contains fosthiazate and furfural, fosthiazate 0.8kg in per 100 kilograms of compositions, furfural 86.4kg, calcium dodecyl benzene sulfonate 2.8kg, triphen ethyl-phenol polypropylene ether 1.8kg, dodecylphenol polyvinylether 1.2kg, ammonium sulfate 1kg, ethylene glycol 1kg, water 5kg.
Described a kind of nematicidal composition that contains fosthiazate and furfural, fosthiazate 0.6kg in per 100 kilograms of compositions, furfural 82.8kg, calcium dodecyl benzene sulfonate 3kg, triphen ethyl-phenol polypropylene ether 2kg, dodecylphenol polyvinylether 2kg, ammonium sulfate 1.8kg, ethylene glycol 1.2kg, water 6.6kg.
Described a kind of nematicidal composition that contains fosthiazate and furfural, fosthiazate 1kg in per 100 kilograms of compositions, furfural 79kg, calcium dodecyl benzene sulfonate 4.5kg, triphen ethyl-phenol polypropylene ether 2.5kg, dodecylphenol polyvinylether 2kg, ammonium sulfate 2kg, ethylene glycol 2kg, water 7kg.
The invention has the advantages that: the bactericidal composition that contains fosthiazate and furfural has good control efficiency to root-knot nematode, pratylenchus, stem eelworm, Cyst nematode etc., and bactericidal range is wide, effect is obviously on average imitated and is higher than 96%; Can delay the disease nematode to the pesticide resistance of fosthiazate, furfural; The present invention has fine conduction in plant, can effectively prevent in the nematode invaded plants body, also can effectively kill the nematode in the intrusive body simultaneously; It is long to kill the nematode lasting period, and annual crop 2-3 month, individual month of perennial crop 4-6; And kill the influence that the nematode effect is not subjected to soil temperature; Easy to use, need not ventilation; Directly field planting after the chemicals treatment; To the person poultry safety, the microorganism of having a mind in the soil is not influenced environmentally safe; The present invention easily degrades, and avoids the residue of pesticide toxicity problem, and crop is not produced poisoning basically yet, and the use suitable time is before crop-planting or before transplanting, application method is identical with Avermectin, adopts soil treatment.The present invention is exclusively used in fruit such as root-knot nematodes such as watermelon, strawberry, root-knot nematodes such as vegetables such as tomato, wild cabbage, cucumber, pepper, potato, capsicum, the control of root-knot nematodes such as economic crops such as cotton, peanut, ginger, soybean, tobacco, sweet potato.Various auxiliary materials can improve emulsifiability and dispersiveness, and meltage is big; Ethylene glycol also has solubilization to former medicine, and helps emulsification; Equal consumption drug effect is obvious, and little to human toxicity, and is better to target crop or polypide permeability, and it is cheap.
The field experiment of the present composition is as follows:
The present invention is 10% fosthiazate wetting powder of effective ingredient processing with fosthiazate and furfural, 90% furfural wetting powder and 5% fosthiazate add 90% furfural (1:18), two single agent with use composite preparation with and compare, composition is under the situation of the usage amount of usage amount 1000 grams/mu, the effect of field control strawberry root-knot nematode is remarkable usage amount (table 1) greater than usage amount 1500 grams/mu all, show that fosthiazate and furfural composition are more suitable for field control strawberry root-knot nematode, according to other effect contrast, also can doublely control tomato root-knot eelworm (table 2), sweet potato root-knot nematode (table 3), peanut root-knot nematode (table 4), cucumber root-knot nematode (table 5), big race tie lines worm (table 6), potato root-knot nematode (table 7), capsicum root-knot nematode (table 8 and table 9) also can delay pathogen to the resistance generation of fosthiazate and furfural.
Can obviously draw from above tables of data, the preventive effect of the complex preparation control root-knot nematode of fosthiazate and furfural obviously is better than single agent, has significant synergies.
The present composition can be brought into play various medicament strong points, reduces cost, and is also time saving and energy saving, increases economic efficiency.Fosthiazate is similar with the furfural mechanism of action, and two kinds of compositions are together composite, show adduction, on show data and shown fosthiazate and the advantage of furfural composition on bactericidal effect significantly.
Embodiment
A kind of nematicidal composition that contains fosthiazate and furfural of the present invention, its active ingredient is: fosthiazate and furfural, both percentage by weights are: fosthiazate: furfural is 1:18-300, and the total content of active ingredient is 80-98wt%, and all the other are auxiliary material.Described auxiliary material is made up of calcium dodecyl benzene sulfonate, triphen ethyl-phenol polypropylene ether, dodecylphenol polyvinylether, antifreezing agent and water, the content of each auxiliary material is calcium dodecyl benzene sulfonate 0.5-4.5wt%, triphen ethyl-phenol polypropylene ether 0.2-2.5wt%, dodecylphenol polyvinylether 0.1-2wt%, antifreezing agent 0.2-4wt%, water 1-7wt%.Described antifreezing agent is ammonium sulfate and/or ethylene glycol.The percentage by weight of described fosthiazate and furfural is 1:18-97.
Described auxiliary material is made up of calcium dodecyl benzene sulfonate, triphen ethyl-phenol polypropylene ether, dodecylphenol polyvinylether, ammonium sulfate, ethylene glycol and water, the content of each auxiliary material is calcium dodecyl benzene sulfonate 0.5-4.5wt%, and the structural formula of triphen ethyl-phenol polypropylene ether is:
, its content is 0.2-2.5wt%, the structural formula of dodecylphenol polyvinylether is:
, its content is 0.1-2wt%, ammonium sulfate 0.1-2wt%, ethylene glycol 0.1-1.5wt%, water 1-7wt%.
The nematicidal composition that contains fosthiazate and furfural of the present invention can have following multiple combination:
1. fosthiazate 5kg in per 100 kilograms of compositions, furfural 90kg, the total content of fosthiazate and furfural are 95%, calcium dodecyl benzene sulfonate 1kg, triphen ethyl-phenol polypropylene ether 0.8kg, dodecylphenol polyvinylether 0.6kg, ammonium sulfate 0.6kg, ethylene glycol 0.7kg, water 1.3kg.
2. fosthiazate 2kg in per 100 kilograms of compositions, furfural 96kg, the total content of fosthiazate and furfural are 98%, calcium dodecyl benzene sulfonate 0.5kg, triphen ethyl-phenol polypropylene ether 0.2kg, dodecylphenol polyvinylether 0.1kg, ammonium sulfate 0.2kg, water 1kg.
3. fosthiazate 1kg in per 100 kilograms of compositions, furfural 79kg, the total content of fosthiazate and furfural are 80%, calcium dodecyl benzene sulfonate 4.5kg, triphen ethyl-phenol polypropylene ether 2.5kg, dodecylphenol polyvinylether 2kg, ammonium sulfate 2kg, ethylene glycol 2kg, water 7kg.
4. fosthiazate 0.8kg in per 100 kilograms of compositions, furfural 86.4kg, the total content of fosthiazate and furfural are 87.2%, calcium dodecyl benzene sulfonate 2.8kg, triphen ethyl-phenol polypropylene ether 1.8kg, dodecylphenol polyvinylether 1.2kg, ammonium sulfate 1kg, ethylene glycol 1kg, water 5kg.
5. fosthiazate 0.6kg in per 100 kilograms of compositions, furfural 82.8kg, the total content of fosthiazate and furfural are 83.4%, calcium dodecyl benzene sulfonate 3kg, triphen ethyl-phenol polypropylene ether 2kg, dodecylphenol polyvinylether 2kg, ammonium sulfate 1.8kg, ethylene glycol 1.2kg, water 6.6kg.
6. fosthiazate 0.5kg in per 100 kilograms of compositions, furfural 85kg, the total content of fosthiazate and furfural are 85.5%, calcium dodecyl benzene sulfonate 3kg, triphen ethyl-phenol polypropylene ether 2kg, dodecylphenol polyvinylether 2kg, ethylene glycol 3kg, water 4.5kg.
7. fosthiazate 0.48kg in per 100 kilograms of compositions, furfural 96kg, the total content of fosthiazate and furfural are 96.48%, calcium dodecyl benzene sulfonate 0.8kg, triphen ethyl-phenol polypropylene ether 0.2kg, dodecylphenol polyvinylether 0.5kg, ethylene glycol 0.5kg, water 1.52kg.
8. fosthiazate 0.4kg in per 100 kilograms of compositions, furfural 92kg, the total content of fosthiazate and furfural are 92.4%, calcium dodecyl benzene sulfonate 1kg, triphen ethyl-phenol polypropylene ether 1kg, dodecylphenol polyvinylether 1kg, ammonium sulfate 1kg, ethylene glycol 1kg, water 2.6kg.
9. fosthiazate 0.3kg in per 100 kilograms of compositions, furfural 81kg, the total content of fosthiazate and furfural are 81.3%, calcium dodecyl benzene sulfonate 4.5kg, triphen ethyl-phenol polypropylene ether 2.5kg, dodecylphenol polyvinylether 2kg, ammonium sulfate 2kg, ethylene glycol 2kg, water 6.7kg.
10. fosthiazate 0.3kg in per 100 kilograms of compositions, furfural 90kg, the total content of fosthiazate and furfural are 90.3%, calcium dodecyl benzene sulfonate 1.5kg, triphen ethyl-phenol polypropylene ether 1.7kg, dodecylphenol polyvinylether 1.5kg, ammonium sulfate 0.5kg, ethylene glycol 0.5kg, water 4kg.
11. fosthiazate 0.9kg in per 100 kilograms of compositions, furfural 88.2kg, the total content of fosthiazate and furfural are 89.1%, calcium dodecyl benzene sulfonate 2kg, triphen ethyl-phenol polypropylene ether 1kg, dodecylphenol polyvinylether 1kg, ammonium sulfate 1.5kg, ethylene glycol 1.5kg, water 3.9kg.
12. fosthiazate 4.8kg in per 100 kilograms of compositions, furfural 89.28kg, the total content of fosthiazate and furfural are 94.08%, calcium dodecyl benzene sulfonate 1kg, triphen ethyl-phenol polypropylene ether 1kg, dodecylphenol polyvinylether 0.5kg, ammonium sulfate 0.5kg, ethylene glycol 1kg, water 1.92kg.
13. fosthiazate 0.45kg in per 100 kilograms of compositions, furfural 87.75kg, the total content of fosthiazate and furfural are 88.2%, calcium dodecyl benzene sulfonate 0.5kg, triphen ethyl-phenol polypropylene ether 0.5kg, dodecylphenol polyvinylether 2kg, ammonium sulfate 1.5kg, ethylene glycol 1.5kg, water 5.8kg.
14. fosthiazate 0.38kg in per 100 kilograms of compositions, furfural 92.72kg, the total content of fosthiazate and furfural are 93.1%, calcium dodecyl benzene sulfonate 1kg, triphen ethyl-phenol polypropylene ether 1kg, dodecylphenol polyvinylether 1kg, ammonium sulfate 0.5kg, ethylene glycol 0.5kg, water 2.9kg.
15. fosthiazate 0.322kg in per 100 kilograms of compositions, furfural 97.175kg, the total content of fosthiazate and furfural is 97.497%, calcium dodecyl benzene sulfonate 0.5kg, triphen ethyl-phenol polypropylene ether 0.4kg, dodecylphenol polyvinylether 0.103kg, ammonium sulfate 0.4kg, ethylene glycol 0.1kg, water 1kg.
16. fosthiazate 0.6kg in per 100 kilograms of compositions, furfural 94.6kg, the total content of fosthiazate and furfural are 95.2%, calcium dodecyl benzene sulfonate 1kg, triphen ethyl-phenol polypropylene ether 0.5kg, dodecylphenol polyvinylether 0.5kg, ammonium sulfate 0.5kg, ethylene glycol 0.5kg, water 1.8kg.
The nematicidal composition that contains fosthiazate and furfural of the present invention can be used by common method, as blade face, dipping, cast, injection, spray, be fuming, distribution or dusting, select according to destination object and main environment.The nematicidal composition that the present invention contains fosthiazate and furfural can be processed into suspending agent, water dispersant and wetting powder according to known method.
Claims (10)
1. nematicidal composition that contains fosthiazate and furfural, it is characterized in that: its active ingredient is: fosthiazate and furfural, both percentage by weights are: fosthiazate: furfural is 1:18-300, and the total content of active ingredient is 80-98wt%, and all the other are auxiliary material.
2. a kind of nematicidal composition that contains fosthiazate and furfural according to claim 1, it is characterized in that: described auxiliary material is made up of calcium dodecyl benzene sulfonate, triphen ethyl-phenol polypropylene ether, dodecylphenol polyvinylether, antifreezing agent and water, the content of each auxiliary material is calcium dodecyl benzene sulfonate 0.5-4.5wt%, triphen ethyl-phenol polypropylene ether 0.2-2.5wt%, dodecylphenol polyvinylether 0.1-2wt%, antifreezing agent 0.2-4wt%, water 1-7wt%.
3. a kind of nematicidal composition that contains fosthiazate and furfural according to claim 2, it is characterized in that: described antifreezing agent is ammonium sulfate and/or ethylene glycol.
4. according to the described a kind of nematicidal composition that contains fosthiazate and furfural of antifreezing agent claim 1, it is characterized in that: the percentage by weight of described fosthiazate and furfural is 1:18-97.
5. a kind of nematicidal composition that contains fosthiazate and furfural according to claim 1, it is characterized in that: fosthiazate 0.48kg in per 100 kilograms of compositions, furfural 96kg, calcium dodecyl benzene sulfonate 0.8kg, triphen ethyl-phenol polypropylene ether 0.2kg, dodecylphenol polyvinylether 0.5kg, ethylene glycol 0.5kg, water 1.52kg.
6. a kind of nematicidal composition that contains fosthiazate and furfural according to claim 1, it is characterized in that: fosthiazate 0.5kg in per 100 kilograms of compositions, furfural 85kg, calcium dodecyl benzene sulfonate 3kg, triphen ethyl-phenol polypropylene ether 2kg, dodecylphenol polyvinylether 2kg, ethylene glycol 3kg, water 4.5kg.
7. a kind of nematicidal composition that contains fosthiazate and furfural according to claim 1, it is characterized in that: fosthiazate 5kg in per 100 kilograms of compositions, furfural 90kg, calcium dodecyl benzene sulfonate 1kg, triphen ethyl-phenol polypropylene ether 0.8kg, dodecylphenol polyvinylether 0.6kg, ammonium sulfate 0.6kg, ethylene glycol 0.7kg, water 1.3kg.
8. a kind of nematicidal composition that contains fosthiazate and furfural according to claim 1, it is characterized in that: fosthiazate 0.8kg in per 100 kilograms of compositions, furfural 86.4kg, calcium dodecyl benzene sulfonate 2.8kg, triphen ethyl-phenol polypropylene ether 1.8kg, dodecylphenol polyvinylether 1.2kg, ammonium sulfate 1kg, ethylene glycol 1kg, water 5kg.
9. a kind of nematicidal composition that contains fosthiazate and furfural according to claim 1, it is characterized in that: fosthiazate 0.6kg in per 100 kilograms of compositions, furfural 82.8kg, calcium dodecyl benzene sulfonate 3kg, triphen ethyl-phenol polypropylene ether 2kg, dodecylphenol polyvinylether 2kg, ammonium sulfate 1.8kg, ethylene glycol 1.2kg, water 6.6kg.
10. a kind of nematicidal composition that contains fosthiazate and furfural according to claim 1, it is characterized in that: fosthiazate 1kg in per 100 kilograms of compositions, furfural 79kg, calcium dodecyl benzene sulfonate 4.5kg, triphen ethyl-phenol polypropylene ether 2.5kg, dodecylphenol polyvinylether 2kg, ammonium sulfate 2kg, ethylene glycol 2kg, water 7kg.
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| CN2013103279303A CN103329932A (en) | 2013-07-23 | 2013-07-31 | Nematicide composition containing fosthiazate and furfural |
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| CN201310310292.4 | 2013-07-23 | ||
| CN201310310292 | 2013-07-23 | ||
| CN2013103279303A CN103329932A (en) | 2013-07-23 | 2013-07-31 | Nematicide composition containing fosthiazate and furfural |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106342882A (en) * | 2016-08-25 | 2017-01-25 | 山东省联合农药工业有限公司 | Nematicidal composition and application thereof |
| CN106665584A (en) * | 2016-11-17 | 2017-05-17 | 广州市真格农业科技有限公司 | Nematicidal composition containing fluopyram and furfural |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1992008351A1 (en) * | 1990-11-19 | 1992-05-29 | Great Lakes Chemical Corporation | Method for the treatment of nematodes in soil using furfural |
| CN102388912A (en) * | 2011-10-19 | 2012-03-28 | 广东中迅农科股份有限公司 | Fosthiazate aqueous emulsion and preparation method thereof |
-
2013
- 2013-07-31 CN CN2013103279303A patent/CN103329932A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1992008351A1 (en) * | 1990-11-19 | 1992-05-29 | Great Lakes Chemical Corporation | Method for the treatment of nematodes in soil using furfural |
| CN102388912A (en) * | 2011-10-19 | 2012-03-28 | 广东中迅农科股份有限公司 | Fosthiazate aqueous emulsion and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106342882A (en) * | 2016-08-25 | 2017-01-25 | 山东省联合农药工业有限公司 | Nematicidal composition and application thereof |
| CN106342882B (en) * | 2016-08-25 | 2019-05-21 | 山东省联合农药工业有限公司 | A kind of nematicidal composition and application thereof |
| CN106665584A (en) * | 2016-11-17 | 2017-05-17 | 广州市真格农业科技有限公司 | Nematicidal composition containing fluopyram and furfural |
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Application publication date: 20131002 |