CN103319966A - Environment-friendly electro-plated silver paint and preparation method thereof - Google Patents
Environment-friendly electro-plated silver paint and preparation method thereof Download PDFInfo
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- CN103319966A CN103319966A CN2013102839825A CN201310283982A CN103319966A CN 103319966 A CN103319966 A CN 103319966A CN 2013102839825 A CN2013102839825 A CN 2013102839825A CN 201310283982 A CN201310283982 A CN 201310283982A CN 103319966 A CN103319966 A CN 103319966A
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Abstract
The invention relates to the technical field of paint and in particular relates to environment-friendly electro-plated sliver paint. The environment-friendly electro-plated sliver paint consists of modified acrylic resin, aluminum sliver paste, ethyl acetate, butyl acetate, propylene glycol methyl ether acetate and a flatting agent. A stirring device with rotation speed of 500 revolutions/minute-600 revolutions/minute is used for sufficiently and uniformly stirring for at least 20 minutes; the uniformly stirred electro-plated sliver paint is sprayed and roasted for 30 minutes at 65 DEG C-80 DEG C to obtain a paint film. The environment-friendly electro-plate sliver paint is energy-saving and environment-friendly, simple in spraying process, convenient to operate and provided with a spraying effect equal to that of an electro-plated product, and therefore, the environment-friendly electro-plated sliver paint is a substitute product of the conventional electro-plating process. Besides, the environment-friendly electro-plated sliver paint can be used for the products including a television, a washing machine, an air conditioner, a bicycle, an electric bicycle, a motorcycle, a small household appliance, hardware, plastic and the like.
Description
Technical field
The present invention relates to a kind of coating, relate in particular to a kind of environment-friendly type electrosilvering coating and preparation method thereof.
Background technology
It is the important foundation that material surface is handled that tradition is electroplated, coverage is extremely wide, and from the characteristics of industry production, electroplating industry is produced required raw material sodium cyanide improper use makes the people disable easily, the waste water,waste gas and industrial residue that produces is very big, seriously polluted to the environmental influence of human existence.Along with the ornamental raising of people to material surface, for the continuous increase of the demand of the surface decoration effect with metal-like, traditional electroplating technology has not satisfied its environmental requirement.
Summary of the invention
The technical problem to be solved in the present invention is: along with the ornamental raising of people to material surface, continuous increase for the demand of the surface decoration effect with metal-like, traditional electroplating technology has not satisfied its environmental requirement, and a kind of environment-friendly type electrosilvering coating and preparation method thereof is provided.
In order to overcome the defective that exists in the background technology, the technical solution adopted for the present invention to solve the technical problems is: the described electrosilvering coating of this environment-friendly type electrosilvering coating and preparation method thereof is made up of following one-component parts by weight:
Acrylic resin modified 8 ~ 18 parts
0.8 ~ 3 part of aluminium-silver slurry
40 ~ 50 parts of vinyl acetic monomers
15 ~ 25 parts of acetate butyls
20 ~ 30 parts of 1-Methoxy-2-propyl acetates
0.2 ~ 1 part of flow agent.
According to another embodiment of the invention, further comprise described acrylic resin modified acrylic resin modified by nitrocellulose, cellaburate is acrylic resin modified and vinyl cellulose one or both in acrylic resin modified are formed.
According to another embodiment of the invention, comprise that further described aluminium-silver slurry is by electroplating aluminium-silver slurry, imitatively electroplating in aluminium-silver slurry and the floating silver one or both and form.
According to another embodiment of the invention, comprise that further described electrosilvering coating is made up of following one-component parts by weight:
Acrylic resin modified 8 parts
Electroplate 1.2 parts of aluminium-silver slurrys
48 parts of vinyl acetic monomers
19.5 parts of acetate butyls
23 parts of 1-Methoxy-2-propyl acetates
0.3 part of flow agent
According to another embodiment of the invention, comprise that further described electrosilvering coating is made up of following one-component parts by weight:
Acrylic resin modified 10 parts
Electroplate 2 parts of aluminium-silver slurrys
45 parts of vinyl acetic monomers
19.5 parts of acetate butyls
23 parts of 1-Methoxy-2-propyl acetates
0.3 part of flow agent
According to another embodiment of the invention, comprise that further described electrosilvering coating is made up of following one-component parts by weight:
Acrylic resin modified 17 parts
Electroplate 2.1 parts of aluminium-silver slurrys
41 parts of vinyl acetic monomers
17.5 parts of acetate butyls
22 parts of 1-Methoxy-2-propyl acetates
0.4 part of flow agent
According to another embodiment of the invention, further comprise
The first step, produce and prepare:
Prepare acrylic resin modified 8 ~ 12 parts, 0.8 ~ 3 part of aluminium-silver slurry, 40 ~ 50 parts of vinyl acetic monomers, 15 ~ 25 parts of acetate butyls, 20 ~ 30 parts of 1-Methoxy-2-propyl acetates, 0.2 ~ 1 part of flow agent; And whipping device;
Second step, mixing of materials:
To stir in acrylic resin modified, plating aluminium-silver slurry, vinyl acetic monomer, acetate butyl, 1-Methoxy-2-propyl acetate and the flow agent input stirrer, its rotating speed is 500-600 rev/min, and churning time was at least 20 minutes, stirred;
The 3rd step, spraying:
The electrosilvering coating that stirs is sprayed, utilize 65 ~ 80 degree temperature bakings 30 minutes, can obtain paint film.
The invention has the beneficial effects as follows: the present invention has following effect, and first, the present invention adopts poisonous material production, to produce and non-wastewater discharge during construction, the feature of environmental protection is good; The second, outward appearance of the present invention has simple to operately, makes the metal sense of electroplating effect easily at product, and apparent brightness is good; Three, the present invention can select different aluminium-silver slurrys for use, reach different metal effects, adopt the method for location spraying, spray into the pattern of different colours and effect at same product, remedy the defective that the traditional electrical depositing process can not parcel plating, realized the individual decoration effect; Four, sticking power of the present invention is good, can have well at ABS, PC, ABS/PC, metal substrate to adhere to.
Energy-conserving and environment-protective of the present invention, spraying coating process is simple, and easy to operate spraying effect is equal to plated item, becomes the substitute products of traditional electrical depositing process.Can be used for products such as televisor, washing machine, air-conditioning, bike, power truck, motorcycle, small household appliances, five metals, plastics.
Embodiment
This environment-friendly type electrosilvering coating, formed by following one-component parts by weight:
Acrylic resin modified 8 ~ 18 parts
0.8 ~ 3 part of aluminium-silver slurry
40 ~ 50 parts of vinyl acetic monomers
15 ~ 25 parts of acetate butyls
20 ~ 30 parts of 1-Methoxy-2-propyl acetates
0.2 ~ 1 part of flow agent
Wherein acrylic resin modified can be acrylic resin modified by nitrocellulose, cellaburate is acrylic resin modified and vinyl cellulose one or both in acrylic resin modified are formed.
Wherein aluminium-silver slurry is by electroplating aluminium-silver slurry, imitatively electroplating in aluminium-silver slurry and the floating silver one or both and form.Aluminium-silver slurry is selected different composition materials for use, can reach different metal effects, adopt the method for location spraying, spray into the pattern of different colours and effect at same product, remedy the defective that the traditional electrical depositing process can not parcel plating, realized the individual decoration effect.
That the present invention adopts is acrylic resin modified, aluminium-silver slurry, vinyl acetic monomer, acetate butyl, 1-Methoxy-2-propyl acetate and flow agent all are poisonous material production, produces and non-wastewater discharge during construction, and the feature of environmental protection is good.
Implementation column one:
Electrosilvering coating is made up of following one-component parts by weight:
Acrylic resin modified 8 parts
Electroplate 1.2 parts of aluminium-silver slurrys
48 parts of vinyl acetic monomers
19.5 parts of acetate butyls
23 parts of 1-Methoxy-2-propyl acetates
0.3 part of flow agent
Wherein, acrylic resin modified by the acrylic resin modified combo one-tenth processed of nitrocellulose, aluminium-silver slurry becomes by electroplating aluminium-silver slurry combo processed.
Implementation column two:
Electrosilvering coating is made up of following one-component parts by weight:
Acrylic resin modified 10 parts
Electroplate 2 parts of aluminium-silver slurrys
45 parts of vinyl acetic monomers
19.5 parts of acetate butyls
23 parts of 1-Methoxy-2-propyl acetates
0.3 part of flow agent
Wherein, acrylic resin modified by becoming with the acrylic resin modified combo processed of cellaburate by nitrocellulose is acrylic resin modified, aluminium-silver slurry is by electroplating aluminium-silver slurry and imitative plating aluminium-silver slurry combo processed becomes.
Implementation column three:
Acrylic resin modified 17 parts
Electroplate 2.1 parts of aluminium-silver slurrys
41 parts of vinyl acetic monomers
17.5 parts of acetate butyls
22 parts of 1-Methoxy-2-propyl acetates
0.4 part of flow agent
Wherein acrylic resin modified can be by cellaburate acrylic resin modified and vinyl cellulose is acrylic resin modified form.
Wherein aluminium-silver slurry is electroplated aluminium-silver slurry and floating silver-colored the composition by imitative.
The first step, produce and prepare:
Prepare acrylic resin modified 8 ~ 12 parts, 0.8 ~ 3 part of aluminium-silver slurry, 40 ~ 50 parts of vinyl acetic monomers, 15 ~ 25 parts of acetate butyls, 20 ~ 30 parts of 1-Methoxy-2-propyl acetates, 0.2 ~ 1 part of flow agent; And whipping device;
Second step, mixing of materials:
To stir in acrylic resin modified, plating aluminium-silver slurry, vinyl acetic monomer, acetate butyl, 1-Methoxy-2-propyl acetate and the flow agent input stirrer, its rotating speed is 500-600 rev/min, and churning time was at least 20 minutes, stirred;
The 3rd step, spraying:
The electrosilvering coating that stirs is sprayed, utilize 65 ~ 80 degree temperature bakings 30 minutes, can obtain paint film.
When system is joined this environment-friendly type electrosilvering coating, each material of described single component dropped in the stirrer by formulation ratio stir, with in the implementation column one acrylic resin modified 8 parts, electroplate in 1.2 parts of aluminium-silver slurrys, 48 parts of vinyl acetic monomers, 19.5 parts of acetate butyls, 23 parts of 1-Methoxy-2-propyl acetates and 0.3 part of input stirrer of flow agent and stir, the rotating speed of stirrer is 500-600 rev/min, and churning time is can obtain electrosilvering coating of the present invention to stirring in 20 minutes.
When system is joined this environment-friendly type electrosilvering coating, each material of described single component dropped in the stirrer by formulation ratio stir, with acrylic resin modified 10 parts, electroplate in 2 parts of aluminium-silver slurrys, 45 parts of vinyl acetic monomers, 19.5 parts of acetate butyls, 23 parts of 1-Methoxy-2-propyl acetates and 0.3 part of input stirrer of flow agent and stir, the rotating speed of stirrer is 500-600 rev/min, and churning time is can obtain electrosilvering coating of the present invention to stirring in 20 minutes.
When system is joined this environment-friendly type electrosilvering coating, each material of described single component dropped in the stirrer by formulation ratio stir, with acrylic resin modified 17 parts, electroplate in 2.1 parts of aluminium-silver slurrys, 41 parts of vinyl acetic monomers, 17.5 parts of acetate butyls, 22 parts of 1-Methoxy-2-propyl acetates and 0.4 part of input stirrer of flow agent and stir, the rotating speed of stirrer is 500-600 rev/min, and churning time is can obtain electrosilvering coating of the present invention to stirring in 20 minutes.
Outward appearance of the present invention has simple to operate, makes the metal sense of electroplating effect easily at product, and apparent brightness is good.Sticking power of the present invention is good, can have well at ABS, PC, ABS/PC, metal substrate to adhere to.
Energy-conserving and environment-protective of the present invention, spraying coating process is simple, and easy to operate spraying effect is equal to plated item, becomes the substitute products of traditional electrical depositing process.Can be used for products such as televisor, washing machine, air-conditioning, bike, power truck, motorcycle, small household appliances, five metals, plastics.
Claims (7)
1. environment-friendly type electrosilvering coating, it is characterized in that: described electrosilvering coating is made up of following one-component parts by weight:
Acrylic resin modified 8 ~ 18 parts
0.8 ~ 3 part of aluminium-silver slurry
40 ~ 50 parts of vinyl acetic monomers
15 ~ 25 parts of acetate butyls
20 ~ 30 parts of 1-Methoxy-2-propyl acetates
0.2 ~ 1 part of flow agent.
2. environment-friendly type electrosilvering coating as claimed in claim 1 is characterized in that: described acrylic resin modified acrylic resin modified by nitrocellulose, cellaburate is acrylic resin modified and vinyl cellulose one or both in acrylic resin modified are formed.
3. environment-friendly type electrosilvering coating as claimed in claim 1 is characterized in that: described aluminium-silver slurry is by electroplating aluminium-silver slurry, imitatively electroplating in aluminium-silver slurry and the floating silver one or both and form.
4. environment-friendly type electrosilvering coating as claimed in claim 1, it is characterized in that: described electrosilvering coating is made up of following one-component parts by weight:
Acrylic resin modified 8 parts
Electroplate 1.2 parts of aluminium-silver slurrys
48 parts of vinyl acetic monomers
19.5 parts of acetate butyls
23 parts of 1-Methoxy-2-propyl acetates
0.3 part of flow agent.
5. environment-friendly type electrosilvering coating as claimed in claim 1, it is characterized in that: described electrosilvering coating is made up of following one-component parts by weight:
Acrylic resin modified 10 parts
Electroplate 2 parts of aluminium-silver slurrys
45 parts of vinyl acetic monomers
19.5 parts of acetate butyls
23 parts of 1-Methoxy-2-propyl acetates
0.3 part of flow agent.
6. environment-friendly type electrosilvering coating as claimed in claim 1, it is characterized in that: described electrosilvering coating is made up of following one-component parts by weight:
Acrylic resin modified 17 parts
Electroplate 2.1 parts of aluminium-silver slurrys
41 parts of vinyl acetic monomers
17.5 parts of acetate butyls
22 parts of 1-Methoxy-2-propyl acetates
0.4 part of flow agent.
7. environment-friendly type electrosilvering coating as claimed in claim 1 and preparation method thereof is characterized in that:
The first step, produce and prepare:
Prepare acrylic resin modified 8 ~ 12 parts, 0.8 ~ 3 part of aluminium-silver slurry, 40 ~ 50 parts of vinyl acetic monomers, 15 ~ 25 parts of acetate butyls, 20 ~ 30 parts of 1-Methoxy-2-propyl acetates, 0.2 ~ 1 part of flow agent; And whipping device;
Second step, mixing of materials:
To stir in acrylic resin modified, plating aluminium-silver slurry, vinyl acetic monomer, acetate butyl, 1-Methoxy-2-propyl acetate and the flow agent input stirrer, its rotating speed is 500-600 rev/min, and churning time was at least 20 minutes, stirred;
The 3rd step, spraying:
The electrosilvering coating that stirs is sprayed, utilize 65 ~ 80 degree temperature bakings 30 minutes, can obtain paint film.
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| CN2013102839825A CN103319966A (en) | 2013-07-08 | 2013-07-08 | Environment-friendly electro-plated silver paint and preparation method thereof |
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| CN2013102839825A CN103319966A (en) | 2013-07-08 | 2013-07-08 | Environment-friendly electro-plated silver paint and preparation method thereof |
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| CN103319966A true CN103319966A (en) | 2013-09-25 |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103736646A (en) * | 2013-11-27 | 2014-04-23 | 四川长虹模塑科技有限公司 | Treatment method for simulation metal effect on surface of plastic part |
| CN104031502A (en) * | 2014-06-26 | 2014-09-10 | 昆山市万胜化工有限公司 | Electrosilvering paint |
| CN106010131A (en) * | 2016-07-27 | 2016-10-12 | 无锡市虎皇漆业有限公司 | Three-coating-one-baking electrosilvering coating material and preparation method thereof |
| CN106243838A (en) * | 2015-09-18 | 2016-12-21 | 廊坊立邦涂料有限公司 | A kind of electrosilvering coating composition, preparation method and applications |
| CN106590390A (en) * | 2016-12-23 | 2017-04-26 | 安徽康瑞高科新材料技术工程有限公司 | Highly wear-resistant silver-electroplated paint and preparation method thereof |
| CN106955832A (en) * | 2017-03-31 | 2017-07-18 | 维沃移动通信有限公司 | Shell processing method and mobile terminal case |
| CN107118639A (en) * | 2017-06-16 | 2017-09-01 | 安徽康瑞高科新材料技术工程有限公司 | A kind of Electrosilvering-likpaint paint with mirror effect |
| CN107245262A (en) * | 2017-05-26 | 2017-10-13 | 上海天地涂料有限公司 | A kind of minute surface silver coating and preparation method thereof |
| CN107793861A (en) * | 2017-09-29 | 2018-03-13 | 东来涂料技术（上海）有限公司 | A kind of water high light metallic paint applied to aluminium alloy luggage rack and preparation method thereof |
| TWI645003B (en) * | 2016-05-31 | 2018-12-21 | Ｐｐｇ塗料（天津）有限公司 | 3c1b coating, method of applying the same and substrate coated therewith |
| CN111842074A (en) * | 2020-07-31 | 2020-10-30 | 太仓市天丝利塑化有限公司 | Electroplating-imitating spraying process for processing automotive upholstery |
| CN112410775A (en) * | 2020-10-30 | 2021-02-26 | 中科丰阳(福建)科技有限公司 | Application of silver electroplating paint on shoe mold and construction process thereof |
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| CN101372597A (en) * | 2008-10-07 | 2009-02-25 | 俞岳兴 | Flash gold lacquer and preparation thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103736646A (en) * | 2013-11-27 | 2014-04-23 | 四川长虹模塑科技有限公司 | Treatment method for simulation metal effect on surface of plastic part |
| CN104031502A (en) * | 2014-06-26 | 2014-09-10 | 昆山市万胜化工有限公司 | Electrosilvering paint |
| CN106243838B (en) * | 2015-09-18 | 2019-09-10 | 廊坊立邦涂料有限公司 | A kind of electrosilvering coating composition, preparation method and applications |
| CN106243838A (en) * | 2015-09-18 | 2016-12-21 | 廊坊立邦涂料有限公司 | A kind of electrosilvering coating composition, preparation method and applications |
| TWI645003B (en) * | 2016-05-31 | 2018-12-21 | Ｐｐｇ塗料（天津）有限公司 | 3c1b coating, method of applying the same and substrate coated therewith |
| CN106010131A (en) * | 2016-07-27 | 2016-10-12 | 无锡市虎皇漆业有限公司 | Three-coating-one-baking electrosilvering coating material and preparation method thereof |
| CN106590390A (en) * | 2016-12-23 | 2017-04-26 | 安徽康瑞高科新材料技术工程有限公司 | Highly wear-resistant silver-electroplated paint and preparation method thereof |
| CN106955832A (en) * | 2017-03-31 | 2017-07-18 | 维沃移动通信有限公司 | Shell processing method and mobile terminal case |
| CN107245262A (en) * | 2017-05-26 | 2017-10-13 | 上海天地涂料有限公司 | A kind of minute surface silver coating and preparation method thereof |
| CN107118639A (en) * | 2017-06-16 | 2017-09-01 | 安徽康瑞高科新材料技术工程有限公司 | A kind of Electrosilvering-likpaint paint with mirror effect |
| CN107793861A (en) * | 2017-09-29 | 2018-03-13 | 东来涂料技术（上海）有限公司 | A kind of water high light metallic paint applied to aluminium alloy luggage rack and preparation method thereof |
| CN107793861B (en) * | 2017-09-29 | 2020-12-25 | 东来涂料技术（上海）有限公司 | Water-based high-gloss metallic paint applied to aluminum alloy luggage rack and preparation method thereof |
| CN111842074A (en) * | 2020-07-31 | 2020-10-30 | 太仓市天丝利塑化有限公司 | Electroplating-imitating spraying process for processing automotive upholstery |
| CN112410775A (en) * | 2020-10-30 | 2021-02-26 | 中科丰阳(福建)科技有限公司 | Application of silver electroplating paint on shoe mold and construction process thereof |
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Application publication date: 20130925 |