CN109439196A - A kind of non-stick pan of imitative die casting depth mouth structure - Google Patents

A kind of non-stick pan of imitative die casting depth mouth structure Download PDF

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Publication number
CN109439196A
CN109439196A CN201811228799.4A CN201811228799A CN109439196A CN 109439196 A CN109439196 A CN 109439196A CN 201811228799 A CN201811228799 A CN 201811228799A CN 109439196 A CN109439196 A CN 109439196A
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CN
China
Prior art keywords
parts
die casting
mouth structure
casting depth
stick pan
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Pending
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CN201811228799.4A
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Chinese (zh)
Inventor
王成
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NINGBO GOLDEN ELEPHANT KITCHENWARE CO Ltd
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NINGBO GOLDEN ELEPHANT KITCHENWARE CO Ltd
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Priority to CN201811228799.4A priority Critical patent/CN109439196A/en
Publication of CN109439196A publication Critical patent/CN109439196A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D187/00Coating compositions based on unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
    • C09D187/005Block or graft polymers not provided for in groups C09D101/00 - C09D185/04
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47JKITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
    • A47J36/00Parts, details or accessories of cooking-vessels
    • A47J36/02Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
    • A47J36/025Vessels with non-stick features, e.g. coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B05D5/061Special surface effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B05D5/083Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/002Priming paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of non-stick pans of imitative die casting depth mouth structure, including pot body and its coating on inner surface, the coating on inner surface includes the bottom and surface layer of imitative die casting depth mouth structure, the surface layer is made of the raw material of following parts by weight: 10~15 parts of acrylic acid, 2~3 parts of polyvinyl resins, 0.5~1.5 part of zirconium oxide, 2~5 parts of aluminium oxide, 1.5~2 parts of silica, 2~3 parts of fatty amide polyoxyethylene ethers, 30~40 parts of polyflons, 10~20 parts of polyethylene glycol, 20~25 parts of deionized waters, 5~8 parts of sodium n-alkylbenzenesulfonates, 3~5 parts of lauroyl glutamates and 2~4 parts of diacetyl tartarate monoglycerides.The present invention imitates the non-stick pan of die casting depth mouth structure, and not only imitative die casting depth mouth structure pattern effect is obvious, and design is abundant, it is bright in luster bright, and paint layer and bottom compatibility are good, and adhesive force is big, whole service life is long, and non-stick, wearability and high temperature resistance are excellent.

Description

A kind of non-stick pan of imitative die casting depth mouth structure
Technical field
The present invention relates to non-stick pan manufacturing technology fields, more particularly to a kind of non-stick pan of imitative die casting depth mouth structure.
Background technique
The non-stick pan utensil one of indispensable as kitchen, non-stick pan coating layer are mostly monochrome, and there are colors and decorative pattern Not abundant enough, the depth of concave-convex setting is presented in the problem that aesthetic effect is not good enough, the inner surface of existing non-stick pan by way of die casting Mouth structure, further by the coating of addition filler and Wear-resistant, high-temperature resistant coating, to keep non-stick pan whole more with wear-resisting Property, its service life is improved, aesthetic effect is increased, but die casting process is often complicated for operation, needs to increase a large amount of labor Power.
With the increasingly raising of living standard and aesthetic requirement, in order to promote the enjoyment of culinary cuisine, therefore need to develop A kind of color and decorative pattern is abundant, non-stick pan of good decorating effect, makes the design and color diversification of the surfaces externally and internally of non-stick pan, full The deeper demand of sufficient the majority of consumers;Needing to design a paint finishing simultaneously is made by way of direct spraying coating Its effect that imitative die casting depth mouth structure is presented.
Summary of the invention
In place of the above the deficiencies in the prior art, one of main object of the present invention is to provide a kind of imitative die casting depth mouth The non-stick pan of structure meets people to the aesthetic requirement under kitchen environment, while improving and not gluing to increase the enjoyment of culinary cuisine The service life of pot.
To achieve the above objectives, the technical solution adopted by the present invention are as follows:
A kind of non-stick pan of imitative die casting depth mouth structure, including pot body and its coating on inner surface, the coating on inner surface include The bottom and surface layer of imitative die casting depth mouth structure, the surface layer are made of the raw material of following parts by weight: 10~15 parts of acrylic acid, 2 ~3 parts of polyvinyl resins, 0.5~1.5 part of zirconium oxide, 2~5 parts of aluminium oxide, 1.5~2 parts of silica, 2~3 parts of fatty acid amides Polyoxyethylene ether, 30~40 parts of polyflons, 10~20 parts of polyethylene glycol, 20~25 parts of deionized waters, 5~8 parts it is straight Alkyl group benzene sulfonic acid sodium salt, 3~5 parts of lauroyl glutamates and 2~4 parts of diacetyl tartarate monoglycerides.
Preferably, the bottom is made of the raw material of following parts by weight: 40~50 parts of polyethylene-copolyamide tree Rouge, 10~15 parts of Petropols, 1.5~3 parts of pigment, 2.5~3.5 parts of titanium dioxide, 3~5 parts of aluminium oxide, 3~6 parts of urea, 1 ~3 parts of N- acetyl ethylenediamines, 8~12 parts of polyethylene glycol, 5~8 parts of deionized waters, 1~2 part of rosin and 4.5~5.5 parts of alkyl phenols Polyoxyethylene poly-oxygen propylene aether.
Preferably, the preparation method of the bottom, comprising the following steps:
S1: Stickless pan surface is subjected to Shot Blasting, its cleannes is made to reach Sa2.5, roughness reaches Ra0.1;
S2: in 60~80 DEG C of stirred tank, by 10~15 parts of polyethylene-copolyamide resin, 2~3 parts of petroleum trees Rouge, 2.5~3.5 parts of titanium dioxide, 3~6 parts of urea, 1~3 part of N- acetyl ethylenediamine, 2~4 parts of polyethylene glycol, 2~3 parts go from Sub- water and 1~2 part of rosin mixing stir 10~30min under the mixing speed of 1200~1300rpm, are squeezed out by high pressure Mode forms thin film in the template of imitative die casting depth mouth structure, after cooling and solidifying in a water bath, is lost using etching solution Quarter processing obtains the template film with imitative die casting depth mouth structure;
The film thickness is 1~10mm, and the cooling and solidifying time is 1~3min in the water-bath;
S3: by the front-end bracket of template film transfer to gun system front position, and pass through the positioning in gun system Device is mounted in pot body;Avoid preset pattern position on template film in the framework part of the front-end bracket;
S4: by 30~35 parts of polyethylene-copolyamide resin, 8~12 parts of Petropols, 3~5 parts of aluminium oxide, 6~8 Part polyethylene glycol, 3~5 parts of deionized waters and 4.5~5.5 parts of alkylphenol-polyethenoxy polyethenoxy ethers mixing, are configured to lotion, 1.5~3 parts of pigment are added in 10~25 parts of lotions, are sprayed on non-stick pan inner surface by gun system, Then the template film on front-end bracket is removed, then remaining lotion is uniformly sprayed on non-stick pan inner surface, after solidification To the bottom of imitative die casting depth mouth structure.
The bottom not only has good adhesive force with the inner surface of non-stick pan, while being added by Petropols and rosin Add, promotes bottom polyethylene-copolyamide resin and paint layer adhesive force.
Spacing between the template film and the pot body is 1~20mm.
Preferably, the pigment is pucherite, nickel titanate, metatitanic acid antimony chromium, carbon black, iron oxide, zinc oxide, more color stone paints One of or many kinds of substance composition.
Preferably, the etching solution is the sodium hypobromite solution of mass concentration 15~20%.Pass through etching solution sodium hypobromite It is reacted with the amido in film, to obtain imitative die casting depth mouth structure pattern effect.
Preferably, the preparation method of the surface layer, comprising the following steps:
S1: by 10~15 parts of acrylic acid, 2~3 parts of polyvinyl resins, 0.5~1.5 part of zirconium oxide, 2~5 parts of aluminium oxide, 1.5~2 parts of silica, 6~8 parts of deionized waters, 5~8 parts of sodium n-alkylbenzenesulfonates and 2~3 parts of fatty acid amide polyoxy second Alkene ether is uniformly mixed, and preparation obtains first component;
S2: by 30~40 parts of polyflons, 10~20 parts of polyethylene glycol, 14~17 parts of deionized waters, 3~5 parts Lauroyl glutamate and 2~4 parts of diacetyl tartarate monoglycerides are uniformly mixed, and preparation obtains second component;
S3: first component and second component are emulsified in mulser and are uniformly mixed, surface layer is obtained.
The gun system includes control device, vertical bar, oblique strut, positioning device, guiding device and spray gun device;
The control device is mounted on vertical bar, and the side of the vertical bar is detachably connected with more oblique struts;
The positioning device include be stuck in the locating piece of pot body open edge apical position and for fixed form film before Bracket is held, the locating piece and the front-end bracket are fixedly connected with the front position in the oblique strut;
The guiding device includes spirally-guided track, guide pad and limited block, and the spirally-guided track is removably It is mounted on the vertical bar lower end, the spirally-guided track is arranged along the front-end bracket downward spiral, and the spirally-guided The helical centre of track is equidistant with front-end bracket outer most edge, the guide pad be it is angularly disposed, the limited block can The end for being mounted on the spirally-guided track of disassembly;The guide pad is mounted on the spirally-guided track close to the pot At body bottom side and pot body side wall delivery position, to utilize guide pad when spray gun device moves to the guide pad The spray gun device is turned to 90 degree, makes the nozzle towards the bottom of pot body by the oblique angle at oblique angle and spray gun device;
The spray gun device is made of gun body and nozzle, and the gun body is equipped with to be slided with spirally-guided track Matched sliding slot, the gun body are provided with the oblique angle to match with the guide pad close to the lower end of nozzle side.
Beneficial effects of the present invention:
The present invention by preparing the template film of imitative die casting depth mouth structure, and according to imitative die casting depth mouth structure using etching solution into This template film transfer to Stickless pan surface is mixed with the lotion of pigment by spraying, realized by row etching, the pattern designed Imitative die casting depth mouth structure pattern effect is presented in lotion after Stickless pan surface solidification, then by the way that residue is not added with the saturating of pigment Bright Emulsion Spraying is in Stickless pan surface, to obtain the bottom with imitative die casting depth mouth structure pattern effect;Finally by will gather It is coated uniformly on bottom after tetrafluoroethylene resin and its filler material mixing by spraying method, obtains surface layer.
The present invention imitates the non-stick pan of die casting depth mouth structure, and not only imitative die casting depth mouth structure pattern effect is obvious, design It is abundant, it is bright in luster bright, and also paint layer and bottom compatibility are good, and adhesive force is big, and whole service life is long, non-stick, wear-resisting Property and high temperature resistance are excellent.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of paint finishing of the present invention;
Fig. 2 is the enlarged drawing of spray gun device in Fig. 1.
Specific embodiment
It is described below for disclosing the present invention so that those skilled in the art can be realized the present invention.It is excellent in being described below Embodiment is selected to be only used as illustrating, it may occur to persons skilled in the art that other obvious modifications.
Embodiment 1
A kind of non-stick pan of imitative die casting depth mouth structure, including pot body and its coating on inner surface, the coating on inner surface include The bottom and surface layer of imitative die casting depth mouth structure, the surface layer are made of the raw material of following parts by weight: 10 parts of acrylic acid, 2 parts it is poly- Vinyl, 0.5 part of zirconium oxide, 2 parts of aluminium oxide, 1.5 parts of silica, 2 parts of fatty amide polyoxyethylene ethers, 30 parts of polytetrafluoros Vinyl, 10 parts of polyethylene glycol, 20 parts of deionized waters, 5 parts of sodium n-alkylbenzenesulfonates, 3 parts of lauroyl glutamates and 2 parts Diacetyl tartarate monoglyceride.
The preparation method of the surface layer, comprising the following steps:
S1: by 10 parts of acrylic acid, 2 parts of polyvinyl resins, 0.5 part of zirconium oxide, 2 parts of aluminium oxide, 1.5 parts of silica, 6 parts Deionized water, 5 parts of sodium n-alkylbenzenesulfonates and 2 parts of fatty amide polyoxyethylene ethers are uniformly mixed, and preparation obtains first component;
S2: by 30 parts of polyflons, 10 parts of polyethylene glycol, 14 parts of deionized waters, 3 parts of lauroyl glutamates and 2 parts of diacetyl tartarate monoglycerides are uniformly mixed, and preparation obtains second component;
S3: first component and second component are emulsified in mulser and are uniformly mixed, surface layer is obtained.
The bottom is made of the raw material of following parts by weight: 40 parts of polyethylene-copolyamide resin, 10 parts of petroleum trees Rouge, 1.5 parts of pigment, 2.5 parts of titanium dioxide, 3 parts of aluminium oxide, 3 parts of urea, 1 part of N- acetyl ethylenediamine, 8 parts of polyethylene glycol, 5 parts Deionized water, 1 part of rosin and 4.5 parts of alkylphenol-polyethenoxy polyethenoxy ethers.
The preparation method of the bottom, comprising the following steps:
S1: Stickless pan surface is subjected to Shot Blasting, its cleannes is made to reach Sa2.5, roughness reaches Ra0.1;
S2: in 60 DEG C of stirred tank, by 10 parts of polyethylene-copolyamide resin, 2 parts of Petropols, 2.5 parts of dioxies Change titanium, 3 parts of urea, 1 part of N- acetyl ethylenediamine, 2 parts of polyethylene glycol, 2 parts of deionized waters and 1 part of rosin mixing, 1200rpm's Under mixing speed, 10min is stirred, forms thin film in the template of imitative die casting depth mouth structure in such a way that high pressure squeezes out, It after cooling and solidifying in a water bath, is etched using etching solution, obtains the template film with imitative die casting depth mouth structure;
S3: will be on the front-end bracket 502 of template film transfer to gun system front position;
S4: by 30 parts of polyethylene-copolyamide resin, 8 parts of Petropols, 3 parts of aluminium oxide, 6 parts of polyethylene glycol, 3 parts Deionized water and 4.5 parts of alkylphenol-polyethenoxy polyethenoxy ether mixing, are configured to lotion, 1.5 parts of pigment are added to 10 parts It in the lotion, is sprayed on non-stick pan inner surface by gun system, then removes the template on front-end bracket 502 Film, then remaining lotion is uniformly sprayed on non-stick pan inner surface, the bottom of imitative die casting depth mouth structure is obtained after solidification.
The pigment is made of pucherite, carbon black and iron oxide, mass ratio 50%:30%:20%.
The etching solution is the sodium hypobromite solution of mass concentration 15%.
As depicted in figs. 1 and 2, the gun system includes control device 1, vertical bar 2, oblique strut 4, positioning device 5, leads To device 6 and spray gun device 3;
The control device 1 is mounted on vertical bar 2, and the side of the vertical bar 2 is detachably connected with more oblique struts 4;
The positioning device 5 includes being stuck in the locating piece 501 of pot body open edge apical position and for fixed form film Front-end bracket 502, the locating piece 501 and the front-end bracket 502 are fixedly connected in the front end of the oblique strut 4 position It sets;
The guiding device 6 includes spirally-guided track 601, guide pad 602 and limited block 603, the spirally-guided rail Road 601 is removably mounted on 2 lower end of vertical bar, and the spirally-guided track 601 is along 502 downward spiral of front-end bracket Setting, and the helical centre of the spirally-guided track 601 and 502 outer most edge of front-end bracket are equidistant, the guiding Block 602 be it is angularly disposed, the limited block 603 is detachably arranged in the end of the spirally-guided track 601;
The spray gun device 3 is made of gun body 301 and nozzle 302, and the gun body 301 is equipped with and leads with spiral To the sliding slot 303 of 601 shiding matching of track, the gun body 301 is provided with and the guiding close to the lower end of 302 side of nozzle The oblique angle 304 that block 602 matches.
Embodiment 2
A kind of non-stick pan of imitative die casting depth mouth structure, including pot body and its coating on inner surface, the coating on inner surface include The bottom and surface layer of imitative die casting depth mouth structure, the surface layer are made of the raw material of following parts by weight: 12 parts of acrylic acid, 2.5 parts Polyvinyl resin, 1 part of zirconium oxide, 3.5 parts of aluminium oxide, 1.8 parts of silica, 2.5 parts of fatty amide polyoxyethylene ethers, 35 parts it is poly- Tetrafluoroethylene resin, 15 parts of polyethylene glycol, 23 parts of deionized waters, 6 parts of sodium n-alkylbenzenesulfonates, 4 parts of lauroyl glutamates With 3 parts of diacetyl tartarate monoglycerides.
The preparation method of the surface layer, comprising the following steps:
S1: by 12 parts of acrylic acid, 2.5 parts of polyvinyl resins, 1 part of zirconium oxide, 3.5 parts of aluminium oxide, 1.8 parts of silica, 7 Part deionized water, 6 parts of sodium n-alkylbenzenesulfonates and 2.5 parts of fatty amide polyoxyethylene ethers are uniformly mixed, and preparation obtains first group Point;
S2: by 35 parts of polyflons, 15 parts of polyethylene glycol, 16 parts of deionized waters, 4 parts of lauroyl glutamates and 3 parts of diacetyl tartarate monoglycerides are uniformly mixed, and preparation obtains second component;
S3: first component and second component are emulsified in mulser and are uniformly mixed, surface layer is obtained.
The bottom is made of the raw material of following parts by weight: 45 parts of polyethylene-copolyamide resin, 12 parts of petroleum trees Rouge, 2 parts of pigment, 3 parts of titanium dioxide, 4 parts of aluminium oxide, 4 parts of urea, 2 parts of N- acetyl ethylenediamines, 10 parts of polyethylene glycol, 6 parts go from Sub- water, 1.5 parts of rosin and 5 parts of alkylphenol-polyethenoxy polyethenoxy ethers.
The preparation method of the bottom, comprising the following steps:
S1: Stickless pan surface is subjected to Shot Blasting, its cleannes is made to reach Sa2.5, roughness reaches Ra0.1;
S2: in 70 DEG C of stirred tank, by 12 parts of polyethylene-copolyamide resin, 2 parts of Petropols, 3 parts of titanium dioxides Titanium, 4 parts of urea, 2 parts of N- acetyl ethylenediamines, 3 parts of polyethylene glycol, 2 parts of deionized waters and the mixing of 1.5 parts of rosin, 1200~ Under the mixing speed of 1300rpm, 10~30min is stirred, in such a way that high pressure squeezes out in the template of imitative die casting depth mouth structure Thin film is formed, after cooling and solidifying in a water bath, is etched using etching solution, is obtained with imitative die casting depth mouth structure Template film;
S3: will be on the front-end bracket 502 of template film transfer to gun system front position;
S4: by 33 parts of polyethylene-copolyamide resin, 10 parts of Petropols, 3~5 parts of aluminium oxide, 7 parts of polyethylene glycol, 4 parts of deionized waters and 5 parts of alkylphenol-polyethenoxy polyethenoxy ether mixing, are configured to lotion, 2 parts of pigment are added to 20 parts of institutes It states in lotion, is sprayed on non-stick pan inner surface by gun system, then remove the template film on front-end bracket 502, Remaining lotion is uniformly sprayed on non-stick pan inner surface again, the bottom of imitative die casting depth mouth structure is obtained after solidification.
The pigment is made of nickel titanate, carbon black, zinc oxide, mass ratio 45%:25%:30%.
The etching solution is the sodium hypobromite solution of mass concentration 18%.
As depicted in figs. 1 and 2, the gun system includes control device 1, vertical bar 2, oblique strut 4, positioning device 5, leads To device 6 and spray gun device 3;
The control device 1 is mounted on vertical bar 2, and the side of the vertical bar 2 is detachably connected with more oblique struts 4;
The positioning device 5 includes being stuck in the locating piece 501 of pot body open edge apical position and for fixed form film Front-end bracket 502, the locating piece 501 and the front-end bracket 502 are fixedly connected in the front end of the oblique strut 4 position It sets;
The guiding device 6 includes spirally-guided track 601, guide pad 602 and limited block 603, the spirally-guided rail Road 601 is removably mounted on 2 lower end of vertical bar, and the spirally-guided track 601 is along 502 downward spiral of front-end bracket Setting, and the helical centre of the spirally-guided track 601 and 502 outer most edge of front-end bracket are equidistant, the guiding Block 602 be it is angularly disposed, the limited block 603 is detachably arranged in the end of the spirally-guided track 601;
The spray gun device 3 is made of gun body 301 and nozzle 302, and the gun body 301 is equipped with and leads with spiral To the sliding slot 303 of 601 shiding matching of track, the gun body 301 is provided with and the guiding close to the lower end of 302 side of nozzle The oblique angle 304 that block 602 matches.
Embodiment 3
A kind of non-stick pan of imitative die casting depth mouth structure, including pot body and its coating on inner surface, the coating on inner surface include The bottom and surface layer of imitative die casting depth mouth structure, the surface layer are made of the raw material of following parts by weight: 15 parts of acrylic acid, 3 parts it is poly- Vinyl, 1.5 parts of zirconium oxides, 5 parts of aluminium oxide, 2 parts of silica, 3 parts of fatty amide polyoxyethylene ethers, 40 parts of polytetrafluoroethyl-nes Olefine resin, 20 parts of polyethylene glycol, 25 parts of deionized waters, 8 parts of sodium n-alkylbenzenesulfonates, 5 parts of lauroyl glutamates and 4 parts are double Acetyltartaric acid monoglyceride.
The preparation method of the surface layer, comprising the following steps:
S1: 15 parts of acrylic acid, 3 parts of polyvinyl resins, 1.5 parts of zirconium oxides, 5 parts of aluminium oxide, 2 parts of silica, 8 parts are gone Ionized water, 8 parts of sodium n-alkylbenzenesulfonates and 3 parts of fatty amide polyoxyethylene ethers are uniformly mixed, and preparation obtains first component;
S2: by 40 parts of polyflons, 20 parts of polyethylene glycol, 17 parts of deionized waters, 5 parts of lauroyl glutamates and 4 parts of diacetyl tartarate monoglycerides are uniformly mixed, and preparation obtains second component;
S3: first component and second component are emulsified in mulser and are uniformly mixed, surface layer is obtained.
The bottom is made of the raw material of following parts by weight: 50 parts of polyethylene-copolyamide resin, 15 parts of petroleum trees Rouge, 3 parts of pigment, 3.5 parts of titanium dioxide, 5 parts of aluminium oxide, 6 parts of urea, 3 parts of N- acetyl ethylenediamines, 12 parts of polyethylene glycol, 8 parts go Ionized water, 2 parts of rosin and 5.5 parts of alkylphenol-polyethenoxy polyethenoxy ethers.
The preparation method of the bottom, comprising the following steps:
S1: Stickless pan surface is subjected to Shot Blasting, its cleannes is made to reach Sa2.5, roughness reaches Ra0.1;
S2: in 80 DEG C of stirred tank, by 15 parts of polyethylene-copolyamide resin, 3 parts of Petropols, 3.5 parts of dioxies Change titanium, 6 parts of urea, 3 parts of N- acetyl ethylenediamines, 4 parts of polyethylene glycol, 3 parts of deionized waters and 2 parts of rosin mixing, 1300rpm's Under mixing speed, 30min is stirred, forms thin film in the template of imitative die casting depth mouth structure in such a way that high pressure squeezes out, It after cooling and solidifying in a water bath, is etched using etching solution, obtains the template film with imitative die casting depth mouth structure;
S3: will be on the front-end bracket 502 of template film transfer to gun system front position;
S4: by 35 parts of polyethylene-copolyamide resin, 12 parts of Petropols, 5 parts of aluminium oxide, 8 parts of polyethylene glycol, 5 parts Deionized water and 5.5 parts of alkylphenol-polyethenoxy polyethenoxy ether mixing, are configured to lotion, 3 parts of pigment are added to 25 parts of institutes It states in lotion, is sprayed on non-stick pan inner surface by gun system, then remove the template film on front-end bracket 502, Remaining lotion is uniformly sprayed on non-stick pan inner surface again, the bottom of imitative die casting depth mouth structure is obtained after solidification.
The pigment is made of metatitanic acid antimony chromium and zinc oxide, mass ratio 60%:40%.
The etching solution is the sodium hypobromite solution of mass concentration 20%.
As depicted in figs. 1 and 2, the gun system includes control device 1, vertical bar 2, oblique strut 4, positioning device 5, leads To device 6 and spray gun device 3;
The control device 1 is mounted on vertical bar 2, and the side of the vertical bar 2 is detachably connected with more oblique struts 4;
The positioning device 5 includes being stuck in the locating piece 501 of pot body open edge apical position and for fixed form film Front-end bracket 502, the locating piece 501 and the front-end bracket 502 are fixedly connected in the front end of the oblique strut 4 position It sets;
The guiding device 6 includes spirally-guided track 601, guide pad 602 and limited block 603, the spirally-guided rail Road 601 is removably mounted on 2 lower end of vertical bar, and the spirally-guided track 601 is along 502 downward spiral of front-end bracket Setting, and the helical centre of the spirally-guided track 601 and 502 outer most edge of front-end bracket are equidistant, the guiding Block 602 be it is angularly disposed, the limited block 603 is detachably arranged in the end of the spirally-guided track 601;
The spray gun device 3 is made of gun body 301 and nozzle 302, and the gun body 301 is equipped with and leads with spiral To the sliding slot 303 of 601 shiding matching of track, the gun body 301 is provided with and the guiding close to the lower end of 302 side of nozzle The oblique angle 304 that block 602 matches.
Embodiment 4
The bottom and surface layer of the present embodiment and embodiment 1, composition of raw materials is similar with preparation method, and the main distinction is The pigment is more color stone paints.
The non-stick pan the performance test results of the resulting imitative die casting depth mouth structure of Examples 1 to 4 are as shown in table 1:
Table 1
The basic principles, main features and advantages of the present invention have been shown and described above.The technical staff of the industry It should be appreciated that the present invention is not limited to the above embodiments, what is described in the above embodiment and the description is only originals of the invention Reason, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these changes and improvements It both falls in the range of claimed invention.The present invention claims protection scope by appended claims and its equivalent Object defines.

Claims (7)

1. a kind of non-stick pan of imitative die casting depth mouth structure, including pot body and its coating on inner surface, which is characterized in that the inner surface Coating includes bottom and surface layer, and the surface layer is made of the raw material of following parts by weight: 10~15 parts of acrylic acid, 2~3 parts of poly- second Olefine resin, 0.5~1.5 part of zirconium oxide, 2~5 parts of aluminium oxide, 1.5~2 parts of silica, 2~3 parts of fatty acid amide polyoxyethylene Ether, 30~40 parts of polyflons, 10~20 parts of polyethylene glycol, 20~25 parts of deionized waters, 5~8 parts of linear alkylbenzene (LAB)s Sodium sulfonate, 3~5 parts of lauroyl glutamates and 2~4 parts of diacetyl tartarate monoglycerides.
2. the non-stick pan of imitative die casting depth mouth structure as described in claim 1, which is characterized in that the preparation method of the surface layer, The following steps are included:
S1: by 10~15 parts of acrylic acid, 2~3 parts of polyvinyl resins, 0.5~1.5 part of zirconium oxide, 2~5 parts of aluminium oxide, 1.5~2 Part silica, 6~8 parts of deionized waters, 5~8 parts of sodium n-alkylbenzenesulfonates and 2~3 parts of fatty amide polyoxyethylene ethers are mixed It closes uniformly, preparation obtains first component;
S2: by 30~40 parts of polyflons, 10~20 parts of polyethylene glycol, 14~17 parts of deionized waters, 3~5 portions of laurels Acyl glutamic acid and 2~4 parts of diacetyl tartarate monoglycerides are uniformly mixed, and preparation obtains second component;
S3: first component and second component are emulsified in mulser and are uniformly mixed, surface layer is obtained.
3. the non-stick pan of imitative die casting depth mouth structure as described in claim 1, which is characterized in that the bottom is by following parts by weight Several raw material composition: 40~50 parts of polyethylene-copolyamide resin, 10~15 parts of Petropols, 1.5~3 parts of pigment, 2.5 ~3.5 parts of titanium dioxide, 3~5 parts of aluminium oxide, 3~6 parts of urea, 1~3 part of N- acetyl ethylenediamine, 8~12 parts of polyethylene glycol, 5 ~8 parts of deionized waters, 1~2 part of rosin and 4.5~5.5 parts of alkylphenol-polyethenoxy polyethenoxy ethers.
4. the non-stick pan of imitative die casting depth mouth structure as claimed in claim 3, which is characterized in that the preparation method of the bottom, The following steps are included:
S1: Stickless pan surface is subjected to Shot Blasting, its cleannes is made to reach Sa2.5, roughness reaches Ra0.1;
S2: in 60~80 DEG C of stirred tank, by 10~15 parts of polyethylene-copolyamide resin, 2~3 parts of Petropols, 2.5~3.5 parts of titanium dioxide, 3~6 parts of urea, 1~3 part of N- acetyl ethylenediamine, 2~4 parts of polyethylene glycol, 2~3 parts of deionizations Water and 1~2 part of rosin mixing stir 10~30min under the mixing speed of 1200~1300rpm, the side squeezed out by high pressure Formula forms thin film in the template of imitative die casting depth mouth structure, after cooling and solidifying in a water bath, is etched using etching solution Processing obtains the template film with imitative die casting depth mouth structure;
S3: will be on the front-end bracket (502) of template film transfer to gun system front position;
S4: 30~35 parts of polyethylene-copolyamide resin, 8~12 parts of Petropols, 3~5 parts of aluminium oxide, 6~8 parts are gathered Ethylene glycol, 3~5 parts of deionized waters and 4.5~5.5 parts of alkylphenol-polyethenoxy polyethenoxy ether mixing, are configured to lotion, will 1.5~3 parts of pigment are added in 10~25 parts of lotions, are sprayed on non-stick pan inner surface by gun system, so The template film on front-end bracket (502) is removed afterwards, then remaining lotion is uniformly sprayed on non-stick pan inner surface, after solidification Obtain the bottom of imitative die casting depth mouth structure.
5. the non-stick pan of imitative die casting depth mouth structure as claimed in claim 4, which is characterized in that the pigment is pucherite, titanium One of sour nickel, metatitanic acid antimony chromium, carbon black, iron oxide, zinc oxide, more color stone paints or many kinds of substance composition.
6. the non-stick pan of imitative die casting depth mouth structure as claimed in claim 4, which is characterized in that the etching solution is mass concentration 15~20% sodium hypobromite solution.
7. the non-stick pan of imitative die casting depth mouth structure as claimed in claim 4, which is characterized in that the gun system includes control Device (1), vertical bar (2), oblique strut (4), positioning device (5), guiding device (6) and spray gun device (3);
The control device (1) is mounted on vertical bar (2), and the side of the vertical bar (2) is detachably connected with more oblique branch Bar (4);
The positioning device (5) includes being stuck in the locating piece (501) of pot body open edge apical position and for fixed form film Front-end bracket (502), the locating piece (501) and the front-end bracket (502) are fixedly connected in the oblique strut (4) Front position;
The guiding device (6) includes that spirally-guided track (601), guide pad (602) and limited block (603), the spiral are led It is removably mounted on the vertical bar (2) lower end to track (601), the spirally-guided track (601) is along the front-end bracket (502) downward spiral is arranged, and the helical centre of the spirally-guided track (601) and front-end bracket (502) outer most edge Be equidistant, the guide pad (602) be it is angularly disposed, the limited block (603) is detachably arranged in the spirally-guided The end of track (601);
The spray gun device (3) is made of gun body (301) and nozzle (302), and the gun body (301) is equipped with and spiral shell The sliding slot (303) of guide rail (601) shiding matching is revolved, the gun body (301) is opened close to the lower end of nozzle (302) side There is the oblique angle (304) to match with the guide pad (602).
CN201811228799.4A 2018-10-22 2018-10-22 A kind of non-stick pan of imitative die casting depth mouth structure Pending CN109439196A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111493640A (en) * 2020-05-19 2020-08-07 安徽永耀电器有限公司 Superhard non-stick electric frying pan and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203088784U (en) * 2012-06-26 2013-07-31 浙江康家宝炊具有限公司 Non-stick pan with three-dimensional pattern
CN108517153A (en) * 2017-11-21 2018-09-11 珠海旭光新材料有限公司 A kind of two layers of non-viscous paint and preparation method making the dispersion of coating surface even heat

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203088784U (en) * 2012-06-26 2013-07-31 浙江康家宝炊具有限公司 Non-stick pan with three-dimensional pattern
CN108517153A (en) * 2017-11-21 2018-09-11 珠海旭光新材料有限公司 A kind of two layers of non-viscous paint and preparation method making the dispersion of coating surface even heat

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111493640A (en) * 2020-05-19 2020-08-07 安徽永耀电器有限公司 Superhard non-stick electric frying pan and preparation method thereof

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