CN103314957B - A kind of sodium abietate insecticide and preparation method thereof - Google Patents
A kind of sodium abietate insecticide and preparation method thereof Download PDFInfo
- Publication number
- CN103314957B CN103314957B CN201310250801.9A CN201310250801A CN103314957B CN 103314957 B CN103314957 B CN 103314957B CN 201310250801 A CN201310250801 A CN 201310250801A CN 103314957 B CN103314957 B CN 103314957B
- Authority
- CN
- China
- Prior art keywords
- sodium
- rosin acid
- acid sodium
- insecticide
- water dispersible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of sodium abietate insecticide, this sodium abietate insecticide is containing 15%(quality) water dispersible granules of rosin acid sodium.Its preparation method is A, gets 20%(quality) rosin acid sodium soluble powder, mechanical crushing is to 180-200 order; B, by consumption by 20%(quality) rosin acid sodium soluble powder, desugar sodium lignin sulfonate, sodium sulphate and filler or dispersant even, mixture is pulverized under 600kg pressure with airslide disintegrating mill; C, dropping liquid, stir, use rotary granulator granulation; D, be placed in insulating box, 54
Description
Technical field
The present invention relates to a kind of sodium abietate insecticide and preparation method thereof.
Background technology
Rosin acid sodium be based on natural material novel low-toxicity vegetalitas biological insecticides, active ingredient is rosin acid sodium, and the formulation invented at present has missible oil, aqueous emulsion, microemulsion, soluble powder.But these formulations of rosin acid sodium have many inevitable shortcomings: rosin acid sodium missible oil, use a large amount of organic solvents to drop into environment, cause environmental pollution and serious waste of resources; Rosin acid sodium water emulsion pesticide is unstable in water, the easy decomposition failure of long storage periods; Rosin acid sodium microemulsion is in storage process, and following change often occurs: layering, flocculation, phase inversion, breakdown of emulsion, becomes sour.And the agricultural chemicals of liquid state is unfavorable for storing and transport; Rosin acid sodium soluble powder shortcoming is also clearly: 1. medicinal powder is easily become estranged easily by rain drop erosion by wind, and therefore, the amount that medicinal powder is attached to crop table body reduces, and shortens the longevity of residure of medicament, reduces control efficiency; 2. unit powder consumption is many, worthwhile not as spraying economically; 3. contaminated environment and dispenser personnel itself.
Pesticide water dispersible granule is a kind of pesticides new formulation of the exploitation eighties in last century, and advantages such as because its safety is good, not containing organic solvent, without dust, packing, transport, be easy to use is developed rapidly.As an important development direction of novel agrochemical environmental protection formulation, water dispersible granules has become the leading formulation of agricultural chemicals of recent domestic.In theory, rosin acid sodium is processed into water dispersible granules, just can overcome the defect existing for other formulations, and there is the series of advantages of pesticide water dispersible granule, but commercially, sodium abietate insecticide does not but occur water dispersible granules all the time.
Summary of the invention
Technical problem to be solved by this invention is, provide a kind of new sodium abietate insecticide and preparation method thereof, water dispersible granules made by this insecticide, and water dispersible is good, and active constituent content is high, and its preparation method is simple, easily realizes.
Technical scheme of the present invention:
First, sodium abietate insecticide of the present invention, for containing 15%(quality) water dispersible granules of rosin acid sodium.
Further, described sodium abietate insecticide is prepared with mass parts calculating by following compositions:
20%(quality) rosin acid sodium soluble powder (Wettable Powder; WP) 40-80 part;
Desugar sodium lignin sulfonate 2-3 part;
Sodium sulphate 5-55 part;
Filler or dispersant 3-37 part;
Adhesion promoter 10 parts.
Further, described adhesion promoter is any one in deionized water, ethanol or methyl alcohol.
The preparation method of aforementioned sodium abietate insecticide, comprises the steps:
A, get 20%(quality) rosin acid sodium soluble powder, mechanical crushing is to 180-200 order;
B, by consumption by 20%(quality) rosin acid sodium soluble powder, desugar sodium lignin sulfonate, sodium sulphate and filler or dispersant even, mixture is pulverized under 600kg pressure with airslide disintegrating mill;
C, dropping adhesion promoter, stir, use rotary granulator granulation;
D, be placed in insulating box, 54 ± DEG C at dry 8-10 hour, obtain 15%(quality) rosin acid sodium water dispersible granules.
Further, after granulation described in step C, gained grain diameter is 0.8-1.2 millimeter.
Sodium abietate insecticide has been made water dispersible granules by the present invention, has many unrivaled features: 1. have directionality during dispenser, makes spreading medicament can fully arrive target organisms and to beneficial organism safety such as natural enemies; 2. powder is not attached on the cauline leaf of plant, avoids directly contact to produce poisoning; 3. during dispenser without dust from flying, free from environmental pollution; 4. can reduce the attachment of operating personnel's health in dispenser process or suck dose, avoiding intoxication accident; 5. make that high-toxic pesticide is low to be poisoned, avoid person poultry poisoning; 6. the rate of release of active ingredient in controlled granulation agent, extends the lasting period; 7. easy to use, efficiency is high.This formulation has the advantage of the suspension of soluble powder and suspension concentrates, dispersiveness, good stability concurrently, and overcomes the shortcoming of the two; Compared with soluble powder, it has good fluidity, is easy to pour out from container and without advantages such as dust from flying; Compared with suspension concentrates, freeze and shortcoming that freight charges are high when it can overcome duration of storage deposition caking, low temperature.Rosin acid sodium water dispersible granules of the present invention, by China's pesticide toxicity grading criteria, belong to low toxic pesticide, desinsection is main, have bactericidal action concurrently, be a kind of novel pesticide based on natural material, to insect to tag, have adhesion concurrently, suffocate, corrode insect epicutile wax layer to make the effect of polypide death.This product is to people and animals, plant safety, and noresidue, has good preventive effect to the aphid on fruit tree, cotton, vegetables, two spotted spider mite, safer to natural enemy.The present invention adopts rational technical process, make rosin acid sodium water dispersible granules have good water dispersible, and active constituent content is high.In a word, the present invention highly applies.
Embodiment
embodiment 1:
1, by 20%(quality) rosin acid sodium soluble powder mechanical crushing to 200 orders.
2,50 parts of rosin acid sodium soluble powders, 37 parts of kaolin (filler), 3 parts of desugar sodium lignin sulfonates, 10 parts of sodium sulphate are mixed, divide cracker to pulverize under 600kg pressure with air-flow.
3, drip 10 parts of deionized waters, stir, with the granulation of ZLB rotary granulator, particle diameter is 1.2mm.
4, in constant temperature oven with 54 ± DEG C dry 10h, obtain 15%(quality) rosin acid sodium water dispersible granules.
embodiment 2:
1, by 20%(quality) rosin acid sodium soluble powder mechanical crushing to 200 orders.
2,50 parts of rosin acid sodium soluble powders, 37 parts of bentonites (filler), 3 parts of desugar sodium lignin sulfonates, 10 parts of sodium sulphate are mixed, divide cracker to pulverize under 600kg pressure with air-flow.
3, drip 10 parts of deionized waters, stir, with the granulation of ZLB rotary granulator, particle diameter is 1.2mm.
4, in constant temperature oven with 54 ± DEG C dry 10h, obtain 15%(quality) rosin acid sodium water dispersible granules.
embodiment 3:
1, by 20%(quality) rosin acid sodium soluble powder mechanical crushing to 200 orders.
2,50 parts of rosin acid sodium soluble powders, 2 parts of desugar sodium lignin sulfonates, 3 parts of D-425 (naphthalenesulfonate dispersant), 45 parts of sodium sulphate are mixed, divide cracker to pulverize under 600kg pressure with air-flow.
3, drip 10 parts of deionized waters, stir, with the granulation of ZLB rotary granulator, particle diameter is 1.2mm.
4, in constant temperature oven with 54 ± DEG C dry 10h, obtain 15%(quality) rosin acid sodium water dispersible granules.
embodiment 4:
1, by 20%(quality) rosin acid sodium soluble powder mechanical crushing to 200 orders.
2,50 parts of rosin acid sodium soluble powders, 3 parts of desugar sodium lignin sulfonates, 37 parts of kaolin (filler), 10 parts of sodium sulphate are mixed, divide cracker to pulverize under 600kg pressure with air-flow.
3, drip 10 parts of methyl alcohol, stir, with the granulation of ZLB rotary granulator, particle diameter is 1.2mm.
4, in constant temperature oven with 54 ± DEG C dry 10h, obtain 15%(quality) rosin acid sodium water dispersible granules.
embodiment 5:
1, by 20%(quality) rosin acid sodium soluble powder mechanical crushing to 200 orders.
2,50 parts of rosin acid sodium soluble powders, 3 parts of desugar sodium lignin sulfonates, 25 parts of bentonites (filler), 22 parts of sodium sulphate are mixed, divide cracker to pulverize under 600kg pressure with air-flow.
3, drip 10 parts of methyl alcohol, stir, with the granulation of ZLB rotary granulator, particle diameter is 1.2mm.
4, in constant temperature oven with 54 ± DEG C dry 10h, obtain 15%(quality) rosin acid sodium water dispersible granules.
embodiment 6:
1, by 20%(quality) rosin acid sodium soluble powder mechanical crushing to 200 orders.
2,50 parts of rosin acid sodium soluble powders, 3 parts of desugar sodium lignin sulfonates, 37 parts of kaolin (filler), 10 parts of sodium sulphate are mixed, divide cracker to pulverize under 600kg pressure with air-flow.
3, drip 10 parts of ethanol, stir, with the granulation of ZLB rotary granulator, particle diameter is 1.2mm.
4, in constant temperature oven with 54 ± DEG C dry 10h, obtain 15%(quality) rosin acid sodium water dispersible granules.
embodiment 7:
1, by 20%(quality) rosin acid sodium soluble powder mechanical crushing to 200 orders.
2,50 parts of rosin acid sodium soluble powders, 3 parts of desugar sodium lignin sulfonates, 25 parts of bentonites (filler), 22 parts of sodium sulphate are mixed, divide cracker to pulverize under 600kg pressure with air-flow.
3, drip 10 parts of ethanol, stir, with the granulation of ZLB rotary granulator, particle diameter is 1.2mm.
4, in constant temperature oven with 54 ± DEG C dry 10h, obtain 15%(quality) rosin acid sodium water dispersible granules.
embodiment 8:
1, by 20%(quality) rosin acid sodium soluble powder mechanical crushing to 200 orders.
2,50 parts of rosin acid sodium soluble powders, 2 parts of desugar sodium lignin sulfonates, 3 parts of D-425 (naphthalenesulfonate dispersant), 45 parts of sodium sulphate are mixed, divide cracker to pulverize under 600kg pressure with air-flow.
3, drip 10 parts and remove methyl alcohol, stir, with the granulation of ZLB rotary granulator, particle diameter is 1.2mm.
4, in constant temperature oven with 54 ± DEG C dry 10h, obtain 15%(quality) rosin acid sodium water dispersible granules.
embodiment 9:
1, by 20%(quality) rosin acid sodium soluble powder mechanical crushing to 200 orders.
2,50 parts of rosin acid sodium soluble powders, 2 parts of desugar sodium lignin sulfonates, 3 parts of D-425 (naphthalenesulfonate dispersant), 45 parts of sodium sulphate are mixed, divide cracker to pulverize under 600kg pressure with air-flow.
3, drip 10 parts of ethanol, stir, with the granulation of ZLB rotary granulator, particle diameter is 1.2mm.
4, in constant temperature oven with 54 ± DEG C dry 10h, obtain 15%(quality) rosin acid sodium water dispersible granules.
The preparation-obtained 15%(quality of above embodiment 1-9) rosin acid sodium water dispersible granules, its quality and technical index is as shown in table 1:
table 1 15%(quality) rosin acid sodium WDG agent quality and technical index
drug effect is reported
One, indoor biological is active
As shown in table 2 is 15%(quality) rosin acid sodium
wDGwith other several pesticides, to river former genus amblyseius berlese Toxicity Determination comparative result, table 3 is for the present invention is to Panonychus citri worm, ooecium endogenous toxic material Force meansurement result:
The former genus amblyseius berlese Toxicity Determination in table 2 pair river
| Process | Female mite number (head) | Corrected mortality (%) |
| 15% rosin acid sodium WDG × 100 | 39 | 96.2 |
| 40% isocarbophos emulsion × 1000 | 45 | 44.2 |
| 15% dicofol pulvis × 800 | 45 | 58.1 |
| 40% omethoate emulsion × 1000 | 45 | 95.4 |
Table 3 15% rosin acid sodium
wDGto Panonychus citri worm, ovum Toxicity Determination
Two, field control effectiveness test
1, Jie-Li enzyme-SQ is prevented and treated
15% rosin acid sodium water dispersible granules working concentration establishes 100,150 and 200 times of liquid three process, contrasts with 15% dicofol emulsion 800 times and clear water, often processes 1-3 strain, repeats 3 times.With 20 times of hand magnifiers, spray checks that the worm of 10 leaf backs, ovum number are as insect population radix at random in the different azimuth of every strain process tree before wanting; Within after medicine 2 days, check each process insecticidal effect, checked preventive effect every 10 days with same method later, observe the term of validity of medicament.Its control efficiency is as shown in table 4, and the term of validity is observed as shown in table 5, and wherein CK represents blank.
Table 4 15% rosin acid sodium
wDGfield control Jie-Li enzyme-SQ effect (%)
Therefore 15% rosin acid sodium WDG is to the effect of Jie-Li enzyme-SQ, 100 times of liquid is obviously better than dicofol (× 800) effect commonly used, and 150-200 times of liquid is then similar or slightly excellent.
The table 5 15% rosin acid sodium WDG field control Jie-Li enzyme-SQ term of validity observes (three mean value)
2, red cured a red-spotted lizard is prevented and treated
Red cured coccid age is 2-3 children's a red-spotted lizard phase age, establishes 60,100,150,200 times four process for examination concentration, with 40% isocarbophos emulsion, 1000 times of liquid and clear water for contrasting.Often process 1-3 strain, repeat 3 times, within after medicine 15 days, check lethality, calculate reproductive effect.Table 6 is depicted as red cured a red-spotted lizard 2-3 children's a red-spotted lizard effect in age (unit: %) of 15% rosin acid sodium WDG field control oranges and tangerines.
Red cured a red-spotted lizard 2-3 children's a red-spotted lizard effect in age (unit: %) of table 6 15% rosin acid sodium WDG field control oranges and tangerines
Therefore 15% rosin acid sodium WDG × 60, × 100, × 150 preventive effects between 93.4%-99.7%, slightly excellent or suitable with positive control 40% isocarbophos emulsion × 1000 drug effect.15% rosin acid sodium WDG × 200, drug effect is slightly poor.
Three, brief summary
1,15% rosin acid sodium WDG prevents and treats result to citrus pest and shows, this medicament to the harmful mite taking Jie-Li enzyme-SQ as representative, and with a red-spotted lizard class pest that red cured a red-spotted lizard is representative, has good control efficiency.
2,15% rosin acid sodium WDG is a kind of plant insecticide, and the working concentration recommended mite, a red-spotted lizard class pest is 100-150 doubly left and right.This formulation is extremely low to person poultry toxicity, easily decomposes in field.Environmentally safe, and to advantages such as insect not easily develop immunity to drugs, efficacy stability, can prevent and treat oranges and tangerines various pests, can play when particularly multiple insect pest is concurrent in citrus orchard and doublely control effect.In addition, this formulation is to oranges and tangerines gummosis, and the sick worm of Wintering Period has good imitation, is the good medicine in citrus orchard clear garden in winter.In addition, the mite a red-spotted lizard class pest of this medicine to the crop such as tea tree, red bayberry has good preventive effect.
Claims (3)
1. a sodium abietate insecticide, is characterized in that: this sodium abietate insecticide is the water dispersible granules containing mass fraction 10% rosin acid sodium, and described sodium abietate insecticide is prepared with mass parts calculating by following compositions:
Described adhesion promoter is any one in deionized water, ethanol or methyl alcohol;
The preparation method of described sodium abietate insecticide comprises the steps:
A, get the rosin acid sodium soluble powder of mass fraction 20%, mechanical crushing is to 180-200 order;
B, by consumption, the rosin acid sodium soluble powder of mass fraction 20%, desugar sodium lignin sulfonate, sodium sulphate and filler to be mixed, under 600kg pressure, mixture is pulverized with airslide disintegrating mill;
C, dropping adhesion promoter, stir, use rotary granulator granulation;
D, be placed in insulating box, dry 8-10 hour at 54 ± 2 DEG C, obtain the rosin acid sodium water dispersible granules of mass fraction 10%.
2. a preparation method for sodium abietate insecticide described in claim 1, is characterized in that, the preparation method of described sodium abietate insecticide comprises the steps:
A, get the rosin acid sodium soluble powder of mass fraction 20%, mechanical crushing is to 180-200 order;
B, by consumption, the rosin acid sodium soluble powder of mass fraction 20%, desugar sodium lignin sulfonate, sodium sulphate and filler to be mixed, under 600kg pressure, mixture is pulverized with airslide disintegrating mill;
C, dropping adhesion promoter, stir, use rotary granulator granulation;
D, be placed in insulating box, dry 8-10 hour at 54 ± 2 DEG C, obtain the rosin acid sodium water dispersible granules of mass fraction 10%.
3. the preparation method of sodium abietate insecticide according to claim 2, is characterized in that: after granulation described in step C, gained grain diameter is 0.8-1.2 millimeter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310250801.9A CN103314957B (en) | 2013-03-27 | 2013-06-24 | A kind of sodium abietate insecticide and preparation method thereof |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100999251 | 2013-03-27 | ||
| CN201310099925.1 | 2013-03-27 | ||
| CN201310099925 | 2013-03-27 | ||
| CN201310250801.9A CN103314957B (en) | 2013-03-27 | 2013-06-24 | A kind of sodium abietate insecticide and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103314957A CN103314957A (en) | 2013-09-25 |
| CN103314957B true CN103314957B (en) | 2015-08-26 |
Family
ID=49184246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310250801.9A Active CN103314957B (en) | 2013-03-27 | 2013-06-24 | A kind of sodium abietate insecticide and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103314957B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022165396A1 (en) * | 2021-02-01 | 2022-08-04 | Valent Biosciences Llc | Process for preparing 1-amino-1-cyclopropanecarboxylic acid granules |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104705335B (en) * | 2015-03-23 | 2018-04-27 | 广东中迅农科股份有限公司 | A kind of Pesticidal combination containing rosin acid sodium and dinotefuran |
| CN104705333A (en) * | 2015-03-23 | 2015-06-17 | 广东中迅农科股份有限公司 | Pesticide composition containing sodium abietate and sulfoxaflor |
| CN106172485A (en) * | 2016-07-15 | 2016-12-07 | 方永贵 | A kind of solid resin soap emulsifiable concentrate and its preparation method and application |
| CN106259335B (en) * | 2016-08-03 | 2019-04-02 | 顾爱国 | A kind of rosin acid sodium microemulsion |
| CN114208850A (en) * | 2021-12-09 | 2022-03-22 | 福建省农业科学院果树研究所 | Preparation and use method of mixed agent for preventing and treating peach gummosis |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1903042A (en) * | 2006-07-31 | 2007-01-31 | 叶大伟 | Method for preparing soluble powder of sodium rosinate |
| CN100998340A (en) * | 2006-12-31 | 2007-07-18 | 华南理工大学 | Aqueous dispersion granulated insecticide containing Rhaponticum uniflorum |
| CN101044855A (en) * | 2006-03-30 | 2007-10-03 | 云南省农业科学院农业环境资源研究所 | Agricultural chemical composition containing nimbin and abamectin and its application |
| CN101044860A (en) * | 2006-03-30 | 2007-10-03 | 云南省农业科学院农业环境资源研究所 | Agricultural chemical composition containing natural pyrethrum and admire and its application |
| CN101167471A (en) * | 2007-11-21 | 2008-04-30 | 张少武 | Cyhalothrin water dispersible granule insecticide |
| CN101518236A (en) * | 2008-02-28 | 2009-09-02 | 北京绿色农华植保科技有限责任公司 | Imidacloprid water dispersible granule |
| WO2011128644A1 (en) * | 2010-04-13 | 2011-10-20 | Arch Timber Protection Limited | Wood preservative formulations comprising isothiazolones which provide protectin against surface staining |
-
2013
- 2013-06-24 CN CN201310250801.9A patent/CN103314957B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101044855A (en) * | 2006-03-30 | 2007-10-03 | 云南省农业科学院农业环境资源研究所 | Agricultural chemical composition containing nimbin and abamectin and its application |
| CN101044860A (en) * | 2006-03-30 | 2007-10-03 | 云南省农业科学院农业环境资源研究所 | Agricultural chemical composition containing natural pyrethrum and admire and its application |
| CN1903042A (en) * | 2006-07-31 | 2007-01-31 | 叶大伟 | Method for preparing soluble powder of sodium rosinate |
| CN100998340A (en) * | 2006-12-31 | 2007-07-18 | 华南理工大学 | Aqueous dispersion granulated insecticide containing Rhaponticum uniflorum |
| CN101167471A (en) * | 2007-11-21 | 2008-04-30 | 张少武 | Cyhalothrin water dispersible granule insecticide |
| CN101518236A (en) * | 2008-02-28 | 2009-09-02 | 北京绿色农华植保科技有限责任公司 | Imidacloprid water dispersible granule |
| WO2011128644A1 (en) * | 2010-04-13 | 2011-10-20 | Arch Timber Protection Limited | Wood preservative formulations comprising isothiazolones which provide protectin against surface staining |
Non-Patent Citations (1)
| Title |
|---|
| 何永梅.植物性杀虫剂—松脂酸钠.《科学种养》.2011,(第3期), * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022165396A1 (en) * | 2021-02-01 | 2022-08-04 | Valent Biosciences Llc | Process for preparing 1-amino-1-cyclopropanecarboxylic acid granules |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103314957A (en) | 2013-09-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103314957B (en) | A kind of sodium abietate insecticide and preparation method thereof | |
| WO2015043986A1 (en) | Pesticide based on natural extracts | |
| CN102640762A (en) | Hot fogging concentrate containing acetamiprid | |
| CN103271077A (en) | Complex acaricide for farmland and fruiters | |
| CN103430943A (en) | Synergistic kasugamycin composition containing tea saponin | |
| CN102246825A (en) | Biopesticide and preparation method thereof | |
| CN104082300B (en) | Insecticide acaricide composition containing pyriproxyfen and spirodiclofen | |
| CN109221140A (en) | A kind of Pesticidal combination containing (R)-4-isopropenyl-1-methyl-1-cyclohexene and pyridine quinazoline | |
| CN106376565B (en) | A kind of Pesticidal combination containing capillary and Celastrus angulatus | |
| CN101015297A (en) | Biological insecticide with synergistic effect and preparing method thereof | |
| CN106376590B (en) | A kind of Pesticidal combination containing Celastrus angulatus and indoxacarb | |
| CN104115861A (en) | Insect and mite killing composition containing xiaochongthion and cyflumetofen | |
| CN104381294B (en) | A kind of insecticide acaricide composition containing sulfur-phosphor and Envidor | |
| CN102246826A (en) | Biological pesticide having natural phytotoxin and preparation method thereof | |
| CN102669157A (en) | Mite-killing composition and preparation thereof | |
| CN104115850A (en) | Insect and mite killing composition containing etoxazole and spirotetramat | |
| CN102630676A (en) | Efficient insecticidal composition | |
| CN102805089A (en) | Insect and mite killing composition containing Cyflumetofen and emamectin benzoate | |
| CN105104422A (en) | Micro-capsule suspending agent containing fosthiazate and pyraclostrobin | |
| CN102217596B (en) | Blended pesticide preparation of TDS and tebufenozide | |
| CN101228873A (en) | Combination acarus-killing compound containing hexythiazox | |
| CN104186493A (en) | Broad-spectrum herbicide | |
| CN104012551B (en) | A kind of containing paichongding with the composition pesticide of cyflumetofen | |
| CN103651544A (en) | Acaricidal composition of profenofos and etoxazole and formula instance | |
| CN104012568A (en) | A pesticide composition comprising dinetofuran and cyflumetofen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |