CN103307931A - Grape-shaped slight-smoke and environment-friendly firecracker - Google Patents
Grape-shaped slight-smoke and environment-friendly firecracker Download PDFInfo
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- CN103307931A CN103307931A CN2013102076496A CN201310207649A CN103307931A CN 103307931 A CN103307931 A CN 103307931A CN 2013102076496 A CN2013102076496 A CN 2013102076496A CN 201310207649 A CN201310207649 A CN 201310207649A CN 103307931 A CN103307931 A CN 103307931A
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Abstract
The invention discloses a grape-shaped slight-smoke and environment-friendly firecracker. The firecracker shaped like grape particles consists of a powder body made of a slight-smoke and environment-friendly powder mixture, soft wrappage, a protective layer and a leading wire, wherein one end of the leading wire is placed at a proper part inside the powder body; the surfaces of the grape-shaped particles of the powder are wrapped with the soft wrappage; the outer surface of the soft wrappage is wrapped with the protective layer in a bonding manner, so that the firecracker is a whole body; the protective layer has the function of increasing the explosive force of the powder body and the dampproof function; the powder body is formed through mixing hydrazine-nickel composition, chimney soot, 128 powder and diethylene glycol with the constituent and parts by weight as follows: 5-80 parts of hydrazine-nickel composition, 2-80 parts of chimney soot, 2-8 parts of 128 powder and 2-20 parts of diethylene glycol; the powder body is shaped like round grapes, elliptical grapes or elongated grapes, and is red, green, yellow, blue, white, purple, grey or black; and the soft wrappage is tissue paper or a capsule cylinder tube. The grape-shaped slight-smoke and environment-friendly firecracker has the advantages of slight/no smoke, safety, environmental protection, and the like.
Description
Technical field
The little cigarette environmental protection whip that the present invention relates to a kind of grape shape is quick-fried, and this technology belongs to the fireworks field.
Background technology
In the prior art, traditional whip quick-fried (be commonly called as compile big gun) all be adopt the paper web tubular type the cigarette medication preparation arranged, be the mixture of oxidant and metal powder and sulphur because be basically with potassium chlorate or potassium hyperchlorate and potassium nitrate etc. in the quick-fried production of the traditional whip preparation, metal oxide microparticle is resolved in the mixed combustion of these medicines, because thermal decomposition effect, its susceptibility is very high, security incident very easily takes place, cause casualties and property loss, and the material that generates in the burning can produce bigger dense smoke and pungent smell, also have many medicine residues after setting off, on earth and the paper scrap stand-down, serious environment pollution.
At present, there are many people to begin research and development and the patent application of smoke less fire cracker and the quick-fried medicament composition of smoke less fire cracker whip, in these patent applications and the patent of having authorized, its preparation combination mainly is to be main component with nitrocellulose/nitrocotton/single original washing powder and ammonium perchlorate, is equipped with titanium, iron, zirconium, aluminium, chromium, nickel, thermite etc. and fuel agent again.This smoke less fire cracker or smokeless medicament composition, production cost is higher, and firework display effect is single, influences the business economic benefit, and still produces more smog and medicine residue and paper scrap in setting off.
Summary of the invention
In order to solve the problems of the technologies described above, the present inventor has carried out studying repeatedly for many years and testing to the medicine that can be used as the quick-fried preparation use of whip, wish to develop and to overcome the defective that produces thick smoke when existing whip detonation is put, change the single product form of having only tubulose paper web serially connected knitting in the prior art, provide a kind of safe, firework display effect is better, and it is quick-fried to have little cigarette environmental protection whip of the grape shape (or capsule shape) that can construct different size.Consequently, discovery has the hydrazine hydrate of the smokeless effect of specific priming system and nickel nitrate composition and is applied to the whip explosive and can achieves the above object, little cigarette/smokeless effect can be reached thereby can produce, the firecrackers of grape shape structure of quick-fried loud works very well can be produced again or/and paper tube shape whip is quick-fried.
For achieving the above object, technical solution of the present invention is:
A kind of little cigarette environmental protection whip of grape shape is quick-fried, its special character is: profile is grape shape graininess, this whip quick-fried medicine body, software wrappage, overcoat, lead-in wire contexture by little cigarette environmental protection pharmaceutical mixture mold pressing configuration, described lead-in wire one end places suitable position in the medicine body, the software wrappage is along the particle surface parcel of medicine body, overcoat is bonding to be wrapped on the outer surface of software wrappage, forms a whole shape, and described overcoat has the medicine body explosive force of increasing and dampproof effect.
Among the present invention program, specifically, described medicine body is made up of hydrazine nickel composition, chimney soot, single original washing powder, diethylene glycol, and its component and ratio of weight and number are:
Among the present invention program, more preferably, described medicine body be shaped as round grape shape or for oval grape shape or for lady's fingers shape.
Among the present invention program, specifically, the quick-fried color of described little cigarette environmental protection whip is red, or green or yellow or blue look or white or purple or grey or black etc.
More preferably, described software wrappage is versicolor tissue paper, or is the capsule bobbin.
More preferably, the granular size of described medicine body can be decided according to the different size needs that the whip detonation is put, be preferably φ 5mm-30mm, its every extension/Series Code footing amount is 10-10000 and does not wait, its string knot mode is the mechanical woollen yarn knitting serial connection of employing structure, or the employing arrangement is adhered to rectangular cardboard or moulds serial connection structure on the plate.
Above each component all can easily be purchased on the raw material market, draws materials extensively.Wherein,
Hydrazine nickel composition: described nickel hydrazine composition is to adopt specifically to provide the production technology preparation for oneself, it is the composition that hydrazine hydrate and nickel nitrate hybrid reaction generate, its reaction equation is as follows: Ni (NO3) 2+3N2+H4H2O → [Ni (N2H4) 3]+3H2O, nickel hydrazine nitrate is the abbreviation that nitric acid three hydrazines close two nickel, locate mode is [Ni (N2H4) 3] (NO3) 2, is a kind of peach powder.Because nickel hydrazine nitrate does not contain the charcoal atom, it does not have cigarette when burning, and explosive nature thereof is good, and friction sensitivity is not high, and mechanical sensitivity is low, and quick-fried to producing paper housing whip, it is strong to have resistance to pressure, makes properties of product stable, and can reduce and press quick-fried number of times to take place frequently, safe like this.Its characteristic is: quick-fried sound is changeed in detonation rapidly, high energy output, the sensitiveness of initially dashing energy to external world, the free-running property of crystalline particle spheroidization; And good heat resistance, stable performance, fast light shine etc.Therefore, nickel hydrazine nitrate in the present invention can medicine for containing of Main Ingredients and Appearance and smokeless combustible, is combined with good roadholding with chimney soot, diethylene glycol and an amount of single original washing powder, and good dispersion degree in chimney soot can be improved the quick-fried sensitivity to initiation of whip.
Chimney soot: the chimney soot among the present invention, it is very extensive, inexpensive to draw materials, and is a kind of solid debris that sprays in the factory chimney, the tiny picture dust of particle, light weight is mainly as the density of filling mixture, and can improve the exothermicity of medicine, therefore, also be one of Main Ingredients and Appearance in the present invention.
Diethylene glycol: described diethylene glycol is colourless viscous liquid, rises in the present invention and helps heat, gas energy, adds fast burn speed, strengthens quick-fried loud dynamics effect.
Single original washing powder: for containing the energy medicament, be smokeless combustible also, further keep stabilized with mixture with a small amount of cooperation among the present invention, because single original washing powder is military discarded medicine, the resting period is long, needs just can use safely after processing, therefore only makes an amount of component and cooperates.
Specifically, as a kind of structure of the present invention, when moulding, can be round grape shape particle or for oval grape shape particle or for lady's fingers shape particle, as of the present invention a kind of preferred, the fineness of powder of above each component should be optimum efficiency more than 100 orders.
Advantage and good effect that the present invention has are:
1, adopts technical scheme of the present invention, since be to use hydrazine hydrate and nickel nitrate and adopt the hydrazine nickel composition of special process preparation be Main Ingredients and Appearance contain energy medicine and smokeless flammable medicament, do not contain the charcoal atom, preparation whip quick-fried medicine after-burning decrepitate can not produce smog when ringing, and efficiently solves traditional whip whip detonation quick-fried and chlorate+charcoal+sulphur big, dense black difficult problem of cigarette of cigarette when putting.
2, the not chloride hydrochlorate composition of the medicine components among the present invention, mechanical sensitivity is very low, resistance to pressure is strong, good heat resistance, so security performance height, preparing whip quick-fried production, accumulating and setting off to reduce in the process and press quick-fried number of times to take place frequently, reduce and press the quick-fried causality loss that causes, for enterprise has saved production cost, cooperate the little cigarette whip of production quick-fried with chimney soot and diethylene glycol with hydrazine nickel composition, can reduce potential safety hazard and danger in production and the use greatly, be conducive to safety in production, improve workman's production operation condition, be conducive to direct labor's physical and mental health.
3, because one of another Main Ingredients and Appearance among the present invention chimney soot is a large amount of chimney soots that adopt industrial enterprise discarded, because particle is tiny, play the hybrid medicine density effect of adjusting, so raw material sources are extensive, cheapness can make discarded chimney dust be able to the reclaiming utilization simultaneously.
4, adopt technical scheme of the present invention, also can produce and the tubular string knot quick-fried same structure form of whip of conventional paper and firework display effect, but overcome the defective that cigarette is big, cigarette is dense.
5, the skin parcel of the quick-fried medicine body of little cigarette whip of the present invention mainly is to adopt the double wrapped mode, be that configuration is wrapped up with tissue paper in the medicine surface, then at the bonding parcel one deck of the outer surface of tissue paper overcoat, can increase quick-fried loud dynamics and the moisture-proof role of medicine body like this, also can adopt medical capsule parcel configural way, therefore after setting off, there are not paper scrap and medicine residue, more there is not the appearance of dense smoke, even adopt traditional paper tube powder charge string knot, also have only a small amount of paper scrap residual after setting off, and do not have earth, dense smoke, medicine residue and pungent smell, and firework display effect is: little cigarette, sound is clear and melodious strong, likeness in form the flue red green or red green alternate spark that spues.
Description of drawings:
Fig. 1 is sectional structure front view of the present invention.
Fig. 2 is another version sectional structure schematic diagram of the present invention.
Fig. 3 is another version sectional structure schematic diagram of the present invention.
Fig. 4 is the schematic diagram that serially connected knitting of the present invention is shaped to the quick-fried finished product of little cigarette environmental protection whip.
Accompanying drawing marking explanation: 1-medicine body, 2-software wrappage, 3-overcoat, 4-lead-in wire.
The specific embodiment
Below in conjunction with specific embodiment the present invention is described in further detail explanation.
Fig. 1, Fig. 2, Fig. 3, Fig. 4 show embodiments of the invention.Its formation: formed by medicine body 1, software wrappage 2, overcoat 3, lead-in wire 4 structures.
A kind of little cigarette environmental protection whip of grape shape is quick-fried, design feature is: profile is grape shape graininess, the quick-fried medicine body 1 by little cigarette environmental protection pharmaceutical mixture mold pressing configuration of this whip, software wrappage 2, overcoat 3, lead-in wire 4 contextures, described lead-in wire 4 one ends place suitable position in the medicine body 1, software wrappage 2 is along the particle surface parcel of medicine body 1, overcoat 3 is bonding to be wrapped on the outer surface of software wrappage 2, forms a whole shape, and described overcoat 3 has the medicine body explosive force of increasing and dampproof effect.
In the present embodiment, described medicine body 1 is made up of hydrazine nickel composition, chimney soot, single original washing powder, diethylene glycol, and its component and ratio of weight and number are:
In the present embodiment, specifically, described medicine body 1 be shaped as round grape shape or for oval grape shape or for lady's fingers shape.
In the present embodiment, more preferably, the quick-fried color of described little cigarette environmental protection whip is red, or green or yellow or blue look or white or purple or grey or black etc.
In the present embodiment, more preferably, described software wrappage 2 is versicolor tissue paper, or is the capsule bobbin.
In the present embodiment, described overcoat is varnish or moistureproof glue.
In the present embodiment, the granular size of described medicine body can be decided according to the different size needs that the whip detonation is put, be preferably φ 5mm-30mm, its every extension/Series Code footing amount is 10-10000 and does not wait, its string knot mode is the mechanical woollen yarn knitting serial connection of employing structure, or the employing arrangement is adhered to rectangular cardboard or moulds serial connection structure on the plate.
Claims (6)
1. little cigarette environmental protection whip of a grape shape is quick-fried, it is characterized in that: profile is grape shape graininess, this whip quick-fried medicine body, software wrappage, overcoat, lead-in wire contexture by little cigarette environmental protection pharmaceutical mixture mold pressing configuration, described lead-in wire one end places suitable position in the medicine body, the software wrappage is along the particle surface parcel of medicine body, overcoat is bonding to be wrapped on the outer surface of software wrappage, forms a whole shape, and described overcoat has the medicine body explosive force of increasing and dampproof effect.
2. little cigarette environmental protection whip of a kind of grape shape according to claim 1 is quick-fried, and it is characterized in that: described medicine body is made up of hydrazine nickel composition, chimney soot, single original washing powder, diethylene glycol, and its component and ratio of weight and number are:
3. little cigarette environmental protection whip of a kind of grape shape according to claim 1 is quick-fried, it is characterized in that: described medicine body be shaped as round grape shape or for oval grape shape or for lady's fingers shape.
4. little cigarette environmental protection whip of a kind of grape shape according to claim 1 is quick-fried, it is characterized in that: the quick-fried color of described little cigarette environmental protection whip is redness, or green or yellow or blue look or white or purple or grey or black etc.
5. little cigarette environmental protection whip of a kind of grape shape according to claim 1 is quick-fried, and it is characterized in that: described software wrappage is versicolor tissue paper, or is the capsule bobbin, and described overcoat is varnish or moistureproof glue.
6. little cigarette environmental protection whip of a kind of grape shape according to claim 1 is quick-fried, it is characterized in that: the granular size of described medicine body can be decided according to the different size needs that the whip detonation is put, be preferably φ 5mm-30mm, its every extension/Series Code footing amount is 10-10000 and does not wait, its string knot mode is the mechanical woollen yarn knitting serial connection of employing structure, or the employing arrangement is adhered to rectangular cardboard or moulds serial connection structure on the plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310207649.6A CN103307931B (en) | 2013-05-21 | 2013-05-21 | A kind of micro-cigarette environmental protection whip of grape shape is quick-fried |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310207649.6A CN103307931B (en) | 2013-05-21 | 2013-05-21 | A kind of micro-cigarette environmental protection whip of grape shape is quick-fried |
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| CN103307931A true CN103307931A (en) | 2013-09-18 |
| CN103307931B CN103307931B (en) | 2015-07-29 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1673664A (en) * | 2004-03-25 | 2005-09-28 | 马思聪 | Paper free fire crackers |
| JP2007192524A (en) * | 2006-01-23 | 2007-08-02 | Kaneko:Kk | Crime preventing marker pellet shooting device |
| CN101215211A (en) * | 2007-01-04 | 2008-07-09 | 邹建文 | Smokeless flameless gunpowder agent |
| CN101275820A (en) * | 2008-05-06 | 2008-10-01 | 湖南省浏阳金生花炮有限公司 | Environment protection type micro-fume firecrackers |
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2013
- 2013-05-21 CN CN201310207649.6A patent/CN103307931B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1673664A (en) * | 2004-03-25 | 2005-09-28 | 马思聪 | Paper free fire crackers |
| JP2007192524A (en) * | 2006-01-23 | 2007-08-02 | Kaneko:Kk | Crime preventing marker pellet shooting device |
| CN101215211A (en) * | 2007-01-04 | 2008-07-09 | 邹建文 | Smokeless flameless gunpowder agent |
| CN101275820A (en) * | 2008-05-06 | 2008-10-01 | 湖南省浏阳金生花炮有限公司 | Environment protection type micro-fume firecrackers |
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| CN103307931B (en) | 2015-07-29 |
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