CN103307931B - A kind of micro-cigarette environmental protection whip of grape shape is quick-fried - Google Patents
A kind of micro-cigarette environmental protection whip of grape shape is quick-fried Download PDFInfo
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- CN103307931B CN103307931B CN201310207649.6A CN201310207649A CN103307931B CN 103307931 B CN103307931 B CN 103307931B CN 201310207649 A CN201310207649 A CN 201310207649A CN 103307931 B CN103307931 B CN 103307931B
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Abstract
The micro-cigarette environmental protection whip that the invention discloses a kind of grape shape is quick-fried.Profile is grape shape graininess, the quick-fried medicine body constructed by micro-cigarette environmental protection pharmaceutical mixture of this whip, software wrappage, overcoat, wiring configuration forms, lead-in wire one end is placed in suitable position in medicine body, software wrappage wraps up along the particle surface of medicine body, overcoat bonding is wrapped in the outer surface of software wrappage, form a monolithic, this overcoat has increases medicine body explosive force and moisture-proof role, medicine body is by hydrazine nickel composition, chimney soot, single original washing powder, diethylene glycol mixing composition, its component and ratio of weight and number are: hydrazine nickel composition 5-80 part, chimney soot 2-80 part, single original washing powder 2-8 part, diethylene glycol 2-20 part, the shape of medicine body is circle grape shape, or be oval grape shape, or be lady's fingers shape, color is red, green, yellow, blue look, white, purple, grey or black, software wrappage is tissue paper or is capsule bobbin.The present invention has the advantages such as micro-cigarette/smokeless, safety and environmental protection.
Description
Technical field
The micro-cigarette environmental protection whip that the present invention relates to a kind of grape shape is quick-fried, and this technology belongs to fireworks field.
Background technology
In prior art, traditional whip quick-fried (being commonly called as firecracker) is all adopt the cigarette medicine that has of paper web tubular type to prepare, because traditional whip quick-fried production is take potassium chlorate or potassium hyperchlorate and potassium nitrate etc. as the mixture of oxidant and metal powder and sulphur substantially in preparation, metal oxide microparticle is resolved in the mixed combustion of these medicines, due to thermal decomposition effect, its susceptibility is very high, very easily there is security incident, cause casualties and property loss, and the material generated in burning can produce larger dense smoke and pungent smell, many medicine residues are also had after setting off, on earth and paper scrap stand-down, serious environment pollution.
At present, many people are had to start research and development and the patent application of smoke less fire cracker and the quick-fried medicament composition of smoke less fire cracker whip, in these patent applications and the patent of having authorized, its preparation combination mainly with nitrocellulose/nitrocotton/mono-original washing powder and ammonium perchlorate for Main Components, then be equipped with titanium, iron, zirconium, aluminium, chromium, nickel, thermite etc. and fuel agent.This smoke less fire cracker or smokeless medicament composition, production cost is higher, and firework display effect is single, affects Business Economic Benefit, and still produces more smog and medicine residue and paper scrap in setting off.
Summary of the invention
In order to solve the problems of the technologies described above, present inventor has carried out repeatedly studying for many years and testing to the medicine that can be used as the quick-fried preparation use of whip, wish to develop the defect that can overcome and produce thick smoke when existing whip detonation is put, change the single product form only having tubulose paper web serially connected knitting in prior art, there is provided a kind of security high, firework display effect is better, and micro-cigarette environmental protection whip with the grape shape (or capsule shape) that can construct different size is quick-fried.Consequently, find to have the hydrazine hydrate of the smokeless effect of specific priming system and nickel nitrate composition to be applied to whip explosive and can to achieve the above object, thus can produce and can reach micro-cigarette/smokeless effect, the firecrackers of the grape shape design of quick-fried loud works very well can be produced again or/and paper tube shape whip is quick-fried.
For achieving the above object, technical solution of the present invention is:
A kind of micro-cigarette environmental protection whip of grape shape is quick-fried, its special character is: profile is grape shape graininess, the quick-fried medicine body by micro-cigarette environmental protection pharmaceutical mixture mold pressing configuration of this whip, software wrappage, overcoat, wiring configuration form, described lead-in wire one end is placed in suitable position in medicine body, software wrappage wraps up along the particle surface of medicine body, overcoat bonding is wrapped on the outer surface of software wrappage, forms a monolithic, and described overcoat has increases medicine body explosive force and moistureproof effect.
In the present invention program, specifically, described medicine body is made up of hydrazine nickel composition, chimney soot, single original washing powder, diethylene glycol, and its component and ratio of weight and number are:
In the present invention program, more preferably, described medicine body shape for circle grape shape or be oval grape shape or be lady's fingers shape.
In the present invention program, specifically, the quick-fried color of described micro-cigarette environmental protection whip is red, or green or yellow or blue look or white or purple or grey or black etc.
More preferably, described software wrappage is the tissue paper of shades of colour, or is capsule bobbin.
More preferably, the different size that the granular size of described medicine body can be put according to whip detonation needs and determines, be preferably φ 5mm-30mm, it often hangs/Series Code footing amount be 10-10000 not etc., its string knot mode for adopting machinery woollen yarn knitting serial connection structure, or adopts arrangement to be adhered to rectangular cardboard or moulds serial connection structure on plate.
Above each component raw material market all easily can be purchased, draw materials extensively.Wherein,
Hydrazine nickel composition: described nickel hydrazine composition adopts specifically to provide production technology preparation for oneself, it is the composition that hydrazine hydrate and nickel nitrate hybrid reaction generate, its reaction equation is as follows: Ni (NO3) 2+3N2+H4H2O → [Ni (N2H4) 3]+3H2O, nickel hydrazine nitrate is the abbreviation that nitric acid three hydrazine closes two nickel, locate mode is [Ni (N2H4) 3] (NO3) 2, is a kind of peach powder.Because nickel hydrazine nitrate is not containing charcoal atom, it does not have cigarette when burning, and explosive nature thereof is good, and friction sensitivity is not high, and mechanical sensitivity is low, quick-fried to production paper housing whip, has resistance to pressure strong, properties of product are stablized, and can reduce the quick-fried number of times of pressure and take place frequently, and such security is high.Its characteristic is: detonation turns rapidly quick-fried sound, and high energy exports, to external world the sensitiveness of initial punching energy, the free-running property of crystalline particle spheroidization; And good heat resistance, stable performance, resistance to illumination etc.Therefore, nickel hydrazine nitrate, be in the present invention Main Ingredients and Appearance containing can medicine and smokeless combustible, be combined with good roadholding, good dispersion degree in chimney soot with chimney soot, diethylene glycol and appropriate single original washing powder, the sensitivity to initiation that whip is quick-fried can be improved.
Chimney soot: the chimney soot in the present invention, draws materials widely, inexpensive, is a kind of solid debris sprayed in factory chimney, particle tiny dust, light weight, the main density being used as filling mixture, and the exothermicity of medicine can be improved, therefore, be also one of Main Ingredients and Appearance in the present invention.
Diethylene glycol: described diethylene glycol is colourless viscous liquid, rises in the present invention and helps heat, gas energy, add fast burn speed, strengthens quick-fried loud dynamics effect.
Single original washing powder: for containing energy medicament, be also smokeless combustible, maintain stabilized with mixture further in the present invention to coordinate on a small quantity, because of the military discarded medicine of single original washing powder system, the resting period is long, just can need use safely after processing, therefore only makes appropriate component and coordinates.
Specifically, as a kind of structure of the present invention, when shaping, can be round grape shape particle or for oval grape shape particle or for lady's fingers shape particle, preferred as one of the present invention, the fineness of powder of above each component should be optimum efficiency more than 100 orders.
The advantage that the present invention has and good effect are:
1, technical scheme of the present invention is adopted, owing to being use hydrazine hydrate and nickel nitrate and the hydrazine nickel composition adopting special process prepare is Main Ingredients and Appearance contains energy medicine and smokeless flammable medicament, not containing charcoal atom, preparation whip quick-fried medicine after-burning decrepitate can not produce smog when ringing, efficiently solve traditional whip quick-fried and whip detonation that is chlorate+charcoal+sulphur is put time cigarette large, the dense black difficult problem of cigarette.
2, the not chloride hydrochlorate composition of the medicine components in the present invention, mechanical sensitivity is very low, resistance to pressure is strong, good heat resistance, so security performance is high, in quick-fried production, the accumulating of preparation whip and set off in process and can reduce the quick-fried number of times of pressure and take place frequently, reduce the quick-fried causality loss caused of pressure, for enterprise has saved production cost, to coordinate with chimney soot and diethylene glycol with hydrazine nickel composition that to produce micro-cigarette whip quick-fried, greatly can reduce the potential safety hazard in production and use procedure and danger, be conducive to safety in production, improve workman's production operation condition, be conducive to direct labor's physical and mental health.
3, because one of another Main Ingredients and Appearance in the present invention chimney soot is a large amount of chimney soots adopting industrial enterprise discarded, because particle is tiny, play hybrid medicine density effect of adjusting, therefore raw material sources are extensive, cheapness, can make the chimney dust discarded be able to recovery and reusing and recycling simultaneously.
4, adopt technical scheme of the present invention, also can produce go here and there tubular with conventional paper and tie the quick-fried same structure form of whip and firework display effect, but overcome the defect that cigarette is large, cigarette is dense.
5, the outer layer covers of the quick-fried medicine body of micro-cigarette whip of the present invention mainly adopts double wrapped mode, namely medicine surface tissue paper wraps up configuration, then at outer surface bonding parcel one deck overcoat of tissue paper, quick-fried loud dynamics and the moisture-proof role of medicine body can be increased like this, also medical capsule can be adopted to wrap up configural way, therefore after setting off, there is no paper scrap and medicine residue, more there is no the appearance of dense smoke, even adopt traditional paper tube powder charge string knot, also a small amount of paper scrap is only had to remain after setting off, and there is no earth, dense smoke, medicine residue and pungent smell, and firework display effect is: micro-cigarette, sound is effectively clear and melodious, likeness in form flue spues red green or red green alternate spark.
Accompanying drawing illustrates:
Fig. 1 is sectional structure front view of the present invention.
Fig. 2 is another version sectional structure schematic diagram of the present invention.
Fig. 3 is another version sectional structure schematic diagram of the present invention.
Fig. 4 is the schematic diagram that serially connected knitting of the present invention is shaped to that micro-cigarette environmental protection whip bursts into product.
Accompanying drawing mark illustrates: 1-medicine body, 2-software wrappage, 3-overcoat, 4-go between.
Detailed description of the invention
Below in conjunction with specific embodiment, explanation is described in further detail to the present invention.
Fig. 1, Fig. 2, Fig. 3, Fig. 4 show embodiments of the invention.It is formed: formed by medicine body 1, software wrappage 2, overcoat 3, lead-in wire 4 structure.
A kind of micro-cigarette environmental protection whip of grape shape is quick-fried, design feature is: profile is grape shape graininess, this whip quick-fried medicine body 1, software wrappage 2, overcoat 3 by micro-cigarette environmental protection pharmaceutical mixture mold pressing configuration, go between 4 contextures, described lead-in wire 4 one end is placed in suitable position in medicine body 1, software wrappage 2 wraps up along the particle surface of medicine body 1, overcoat 3 bonding is wrapped on the outer surface of software wrappage 2, forms a monolithic, and described overcoat 3 has increases medicine body explosive force and moistureproof effect.
In present embodiment, described medicine body 1 is made up of hydrazine nickel composition, chimney soot, single original washing powder, diethylene glycol, and its component and ratio of weight and number are:
In present embodiment, specifically, described medicine body 1 shape for circle grape shape or be oval grape shape or be lady's fingers shape.
In present embodiment, more preferably, the quick-fried color of described micro-cigarette environmental protection whip is red, or green or yellow or blue look or white or purple or grey or black etc.
In present embodiment, more preferably, described software wrappage 2 is the tissue paper of shades of colour, or is capsule bobbin.
In present embodiment, described overcoat is varnish or moistureproof glue.
In present embodiment, the different size that the granular size of described medicine body can be put according to whip detonation needs and determines, be preferably φ 5mm-30mm, it often hangs/Series Code footing amount be 10-10000 not etc., its string knot mode for adopting machinery woollen yarn knitting serial connection structure, or adopts arrangement to be adhered to rectangular cardboard or moulds serial connection structure on plate.
Claims (6)
1. micro-cigarette environmental protection whip of a grape shape is quick-fried, it is characterized in that: profile is grape shape graininess, the quick-fried medicine body by micro-cigarette environmental protection pharmaceutical mixture mold pressing configuration of this whip, software wrappage, overcoat, wiring configuration forms, described lead-in wire one end is placed in suitable position in medicine body, software wrappage wraps up along the particle surface of medicine body, overcoat bonding is wrapped on the outer surface of software wrappage, form a monolithic, described overcoat has increases medicine body explosive force and moistureproof effect, described medicine body is by hydrazine nickel composition, chimney soot, single original washing powder, diethylene glycol forms, its component and ratio of weight and number are:
2. micro-cigarette environmental protection whip of a kind of grape shape according to claim 1 is quick-fried, it is characterized in that: the shape of described medicine body is for circle grape shape or for oval grape shape or be lady's fingers shape.
3. micro-cigarette environmental protection whip of a kind of grape shape according to claim 1 is quick-fried, it is characterized in that: the quick-fried color of described micro-cigarette environmental protection whip is for red, or green or yellow or blue or white or purple or grey or black.
4. micro-cigarette environmental protection whip of a kind of grape shape according to claim 1 is quick-fried, it is characterized in that: described software wrappage is the tissue paper of shades of colour, or is capsule bobbin, and described overcoat is varnish or moistureproof glue.
5. micro-cigarette environmental protection whip of a kind of grape shape according to claim 1 is quick-fried, it is characterized in that: different size needs that the granular size of described medicine body can be put according to whip detonation and determining, it often hangs/Series Code footing amount be 10-10000 not etc., its string knot mode for adopting machinery woollen yarn knitting serial connection structure, or adopts arrangement to be adhered to rectangular cardboard or moulds serial connection structure on plate.
6. micro-cigarette environmental protection whip of a kind of grape shape according to claim 5 is quick-fried, it is characterized in that: the granular size of described medicine body is φ 5mm-30mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310207649.6A CN103307931B (en) | 2013-05-21 | 2013-05-21 | A kind of micro-cigarette environmental protection whip of grape shape is quick-fried |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310207649.6A CN103307931B (en) | 2013-05-21 | 2013-05-21 | A kind of micro-cigarette environmental protection whip of grape shape is quick-fried |
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| CN103307931A CN103307931A (en) | 2013-09-18 |
| CN103307931B true CN103307931B (en) | 2015-07-29 |
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| CN201310207649.6A Expired - Fee Related CN103307931B (en) | 2013-05-21 | 2013-05-21 | A kind of micro-cigarette environmental protection whip of grape shape is quick-fried |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1673664A (en) * | 2004-03-25 | 2005-09-28 | 马思聪 | Paper free fire crackers |
| CN101215211A (en) * | 2007-01-04 | 2008-07-09 | 邹建文 | Smokeless flameless gunpowder agent |
| CN101275820A (en) * | 2008-05-06 | 2008-10-01 | 湖南省浏阳金生花炮有限公司 | Environment protection type micro-fume firecrackers |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007192524A (en) * | 2006-01-23 | 2007-08-02 | Kaneko:Kk | Crime preventing marker pellet shooting device |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1673664A (en) * | 2004-03-25 | 2005-09-28 | 马思聪 | Paper free fire crackers |
| CN101215211A (en) * | 2007-01-04 | 2008-07-09 | 邹建文 | Smokeless flameless gunpowder agent |
| CN101275820A (en) * | 2008-05-06 | 2008-10-01 | 湖南省浏阳金生花炮有限公司 | Environment protection type micro-fume firecrackers |
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| CN103307931A (en) | 2013-09-18 |
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Granted publication date: 20150729 Termination date: 20160521 |