CN103980074A - Smokeless firework lead powder and firing line thereof - Google Patents
Smokeless firework lead powder and firing line thereof Download PDFInfo
- Publication number
- CN103980074A CN103980074A CN201410243463.0A CN201410243463A CN103980074A CN 103980074 A CN103980074 A CN 103980074A CN 201410243463 A CN201410243463 A CN 201410243463A CN 103980074 A CN103980074 A CN 103980074A
- Authority
- CN
- China
- Prior art keywords
- parts
- lead
- firing line
- zylonite
- medicament
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000010304 firing Methods 0.000 title claims abstract description 18
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 claims abstract description 24
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 22
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920002160 Celluloid Polymers 0.000 claims abstract description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- 238000001914 filtration Methods 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 4
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 4
- 239000003814 drug Substances 0.000 claims description 22
- 229920013662 Zylonite Polymers 0.000 claims description 14
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 claims description 14
- 239000006166 lysate Substances 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 229920002472 Starch Polymers 0.000 claims description 5
- 239000012046 mixed solvent Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 229920000742 Cotton Polymers 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 2
- 229910002651 NO3 Inorganic materials 0.000 abstract 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 2
- 238000004090 dissolution Methods 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 1
- 239000000796 flavoring agent Substances 0.000 abstract 1
- 235000019634 flavors Nutrition 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 235000019504 cigarettes Nutrition 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention relates to smokeless firework lead powder and a firing line thereof. The smokeless firework lead powder comprises the following compositions in parts by weight: (A) 40-65 parts of monomer powder, (B) ammonium perchlorate, (C) 10-20 parts of carbon powder and (D) 10-30 parts of rare earth, wherein the ammonium perchlorate is obtained by adopting the following methods: evenly spraying celluloid nitrate dissolution liquor onto 20-40 parts of ammonium perchlorate and evenly mixing, wherein the celluloid nitrate dissolution liquor is obtained by dissolving celluloid nitrate through an acetone and alcohol mixing solvent; the carbon powder is obtained by adopting the methods: mixing carbon powder and nitric acid, filtering off acid liquor and drying. In burning, the smokeless firework lead powder is smokeless and has no sulfur flavor, the ornamental effect of fireworks can be improved, no sulfur dioxide is generated, the dampness-proof effect of a lead is good, and the safety performance is good.
Description
Technical field
The present invention relates to a kind of firework firework medicament composition, be specifically related to the micro-cigarette lead medicament of a kind of fireworks.
Background technology
In the prior art, adopt of fireworks firing line has the preparation of cigarette medicine more.When using these lead-in wires, the effect of smoke less fire cracker will be subject to very large impact.A large amount of smog and sulfurous gas can cause larger pollution to air.
Summary of the invention
The object of this invention is to provide the lead medicament and the firing line thereof that only have micro-cigarette after a kind of burning.
The micro-cigarette lead medicament of fireworks provided by the invention, comprises following component by weight:
(A) single original washing powder is 40 ~ 65 parts;
(B) ammoniumper chlorate obtaining as follows: be evenly sprayed on 20 ~ 40 parts of ammoniumper chlorate and mix with zylonite lysate, described zylonite lysate is obtained with the mixed solvent dissolving of acetone and alcohol by xylonite;
(C) 10 ~ 20 parts of the powdered carbons obtaining as follows: by mix and blend under powdered carbon and nitric acid normal temperature, filtering acid solution is also dry; With
(D) rare earth is 10 ~ 30 parts.
Ammoniumper chlorate is high energy oxidizer, and its shortcoming is that water absorbability is strong, and lead-in wire because moisture absorption has a strong impact on lead quality, by processing of the present invention, makes to wrap up a skim on its microparticle after making, and no longer moisture absorption, plays moisture-proof role.Common powdered carbon is by nitric acid treatment, and while making its burning, combustion speed is accelerated, and reduces smog during burning.
Can adopt following method to obtain ammoniumper chlorate: with 1.5 ~ 3.5 parts of zylonite lysates, be evenly sprayed on ammoniumper chlorate, in described zylonite lysate, the mass ratio of acetone, alcohol and xylonite is 1:2 ~ 4:0.8 ~ 1.2.
Can obtain as follows powdered carbon: by powdered carbon and nitric acid 6 ~ 8:3 mix and blend 10 ~ 20 minutes in mass ratio.
Described rare earth can be cerium or lanthanum.
The present invention also provides a kind of firing line, adopts above-mentioned lead medicament.The making method of firing line, comprising: with lead-in wire paper or cotton yarn, lead medicament is wrapped up and made wire, then starch and draw, be dried.
Micro-cigarette firing line of the present invention, micro-cigarette during burning, without sulphur taste, improves fireworks appreciation effect, does not produce sulfurous gas, and protection of the environment is harmless.Ammoniumper chlorate is by processing, and the moisture effect that makes to go between is good, and with conventional black powder contrast, its rate of moisture absorption has reduced by 80%.By component proportion, can control combustionvelocity, safety performance is good.
Embodiment
embodiment 1
Xylonite is dissolved to (acetone, alcohol and xylonite are 1:3:1 in mass ratio) with the mixed solvent of acetone and alcohol and make zylonite lysate.With 2.5 parts of zylonite lysates, be evenly sprayed on 30 parts of ammoniumper chlorate and mix by weight.
By powdered carbon and nitric acid (massfraction is 69.2%) mix and blend 10 minutes under 7:3 normal temperature in mass ratio, filtering acid solution is air-dry.
Get by weight 50 parts of single original washing powders, 20 parts of rare earths, the ammoniumper chlorate of above-mentioned preparation, and 15 parts of the powdered carbons of above-mentioned preparation mix, and cross 160 mesh sieves, make lead medicament.Make routinely the method for firing line, with lead-in wire paper, lead medicament wrap up and twisted into wire, the consumption of lead medicament is 3 grams/1 meter lead-in wire paper, then starches and draws, is dried and makes firing line.Firing line combustionvelocity: 0.80m/s; Rate of moisture absorption is pressed GB10631-2004, QB/T1941 ~ 1941. 61994 standard detection, and the firing line of the present embodiment is that to have cigarette lead-in wire be 1.92% to 0.78%(routine).
Embodiment 2
Xylonite is dissolved to (acetone, alcohol and xylonite are 1:2:0.8 in mass ratio) with the mixed solvent of acetone and alcohol and make zylonite lysate.With 1.5 parts of zylonite lysates, be evenly sprayed on 20 parts of ammoniumper chlorate and mix by weight.
By powdered carbon and nitric acid (massfraction is 69.2%) mix and blend 20 minutes under 7.5:3 normal temperature in mass ratio, filtering acid solution is air-dry.
Get by weight 40 parts of single original washing powders, 10 parts of rare earths, the ammoniumper chlorate of above-mentioned preparation, and 20 parts of the powdered carbons of above-mentioned preparation mix, and cross 160 mesh sieves, make lead medicament.With combed cotton yarn, lead medicament is wrapped up and twisted into wire, the consumption of lead medicament is 3 grams/1 meter cotton yarn, then starch draw, the dry firing line that makes.Firing line combustionvelocity: 0.78m/s; Rate of moisture absorption is 0.80%.
Embodiment 3
Xylonite is dissolved to (acetone, alcohol and xylonite are 1:4:1.2 in mass ratio) with the mixed solvent of acetone and alcohol and make zylonite lysate.With 3.5 parts of zylonite lysates, be evenly sprayed on 40 parts of ammoniumper chlorate and mix by weight.
By powdered carbon and nitric acid (massfraction is 69.2%) mix and blend 10 minutes under 6.5:3 normal temperature in mass ratio, filtering acid solution is air-dry.
Get by weight 65 parts of single original washing powders, 30 parts of rare earths, the ammoniumper chlorate of above-mentioned preparation, and 10 parts of the powdered carbons of above-mentioned preparation mix, and cross 160 mesh sieves, make lead medicament.With lead-in wire paper, lead medicament wrap up and twisted into wire, the consumption of lead medicament is 3 grams/1 meter lead-in wire paper, then starches and draws, is dried and makes firing line.Firing line combustionvelocity: 0.81m/s; Rate of moisture absorption is 0.77%.
Claims (5)
1. the micro-cigarette lead medicament of fireworks, comprises following component by weight:
(A) single original washing powder is 40 ~ 65 parts;
(B) ammoniumper chlorate obtaining as follows: be evenly sprayed on 20 ~ 40 parts of ammoniumper chlorate and mix with zylonite lysate, described zylonite lysate is obtained with the mixed solvent dissolving of acetone and alcohol by xylonite;
(C) 10 ~ 20 parts of the powdered carbons obtaining as follows: by powdered carbon and nitric acid mix and blend, filtering acid solution is also dry; With
(D) rare earth is 10 ~ 30 parts.
2. the micro-cigarette lead medicament of fireworks according to claim 1, it is characterized in that obtaining as follows ammoniumper chlorate: with 1.5 ~ 3.5 parts of zylonite lysates, be evenly sprayed on ammoniumper chlorate, in described zylonite lysate, the mass ratio of acetone, alcohol and xylonite is 1:2 ~ 4:0.8 ~ 1.2.
3. the micro-cigarette lead medicament of fireworks according to claim 1 and 2, is characterized in that obtaining as follows powdered carbon: by powdered carbon and nitric acid 6 ~ 8:3 mix and blend in mass ratio.
4. a firing line, is characterized in that the lead medicament that adopts one of claim 1 ~ 3 described.
5. a making method for firing line described in claim 4, comprising: with lead-in wire paper or cotton yarn, lead medicament is wrapped up and made wire, then starch and draw, be dried.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410243463.0A CN103980074B (en) | 2014-06-04 | 2014-06-04 | Smokeless firework lead powder and firing line thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410243463.0A CN103980074B (en) | 2014-06-04 | 2014-06-04 | Smokeless firework lead powder and firing line thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103980074A true CN103980074A (en) | 2014-08-13 |
| CN103980074B CN103980074B (en) | 2015-03-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410243463.0A Active CN103980074B (en) | 2014-06-04 | 2014-06-04 | Smokeless firework lead powder and firing line thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103980074B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104876780A (en) * | 2015-04-13 | 2015-09-02 | 喻自达 | Pyrotechnic explosive composition prepared by using environment-friendly bamboo charcoals |
| CN110966896A (en) * | 2019-12-05 | 2020-04-07 | 江西吉润花炮新材料科技有限公司 | Smokeless, sulfur-free and soundless firing cable and preparation method thereof |
| CN114394878A (en) * | 2022-01-25 | 2022-04-26 | 上栗县金圆花炮制造有限公司 | Novel mould pressing type combined firework ignition charge and laying process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3715984A (en) * | 1969-06-09 | 1973-02-13 | Pains Wessex Ltd | Pyrotechnic devices |
| RU2001899C1 (en) * | 1992-01-16 | 1993-10-30 | Научно-исследовательский институт прикладной химии | Pyrotechnic composition for safety fuse |
| CN101275820A (en) * | 2008-05-06 | 2008-10-01 | 湖南省浏阳金生花炮有限公司 | Environment protection type micro-fume firecrackers |
| CN101481286A (en) * | 2008-09-26 | 2009-07-15 | 浏阳市龙腾花炮科技开发有限公司 | Smokeless lead medicament composition of firework |
| CN102219623A (en) * | 2011-04-13 | 2011-10-19 | 南京理工大学 | Smokeless and quick lead medicament for fireworks and firecrackers |
-
2014
- 2014-06-04 CN CN201410243463.0A patent/CN103980074B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3715984A (en) * | 1969-06-09 | 1973-02-13 | Pains Wessex Ltd | Pyrotechnic devices |
| RU2001899C1 (en) * | 1992-01-16 | 1993-10-30 | Научно-исследовательский институт прикладной химии | Pyrotechnic composition for safety fuse |
| CN101275820A (en) * | 2008-05-06 | 2008-10-01 | 湖南省浏阳金生花炮有限公司 | Environment protection type micro-fume firecrackers |
| CN101481286A (en) * | 2008-09-26 | 2009-07-15 | 浏阳市龙腾花炮科技开发有限公司 | Smokeless lead medicament composition of firework |
| CN102219623A (en) * | 2011-04-13 | 2011-10-19 | 南京理工大学 | Smokeless and quick lead medicament for fireworks and firecrackers |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104876780A (en) * | 2015-04-13 | 2015-09-02 | 喻自达 | Pyrotechnic explosive composition prepared by using environment-friendly bamboo charcoals |
| CN110966896A (en) * | 2019-12-05 | 2020-04-07 | 江西吉润花炮新材料科技有限公司 | Smokeless, sulfur-free and soundless firing cable and preparation method thereof |
| CN114394878A (en) * | 2022-01-25 | 2022-04-26 | 上栗县金圆花炮制造有限公司 | Novel mould pressing type combined firework ignition charge and laying process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103980074B (en) | 2015-03-11 |
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| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Effective date of registration: 20211123 Address after: 410300 West Bank Group, Xihuan village, Hehua sub district office, Liuyang City, Changsha City, Hunan Province Patentee after: Liuyang Jixiang environmental protection material development Co.,Ltd. Address before: 410300 401, building 3, bijingwan community, Tangjia group, Liuyang City, Changsha City, Hunan Province Patentee before: Yang Peijiang |