CN103265884A - Lens hardening antireflection liquid - Google Patents
Lens hardening antireflection liquid Download PDFInfo
- Publication number
- CN103265884A CN103265884A CN2013102225700A CN201310222570A CN103265884A CN 103265884 A CN103265884 A CN 103265884A CN 2013102225700 A CN2013102225700 A CN 2013102225700A CN 201310222570 A CN201310222570 A CN 201310222570A CN 103265884 A CN103265884 A CN 103265884A
- Authority
- CN
- China
- Prior art keywords
- parts
- reflection liquid
- water
- eyeglass
- silane coupling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses lens hardening antireflection liquid which comprises the following components in parts by mass: 3-15 parts of silane coupling agent, 5-15 parts of water-soluble silica sol, 0-1 part of aluminum salt, 65-85 parts of solvent, 0.5-5 parts of pH regulator and calculated amount of water. The hardening antireflection liquid disclosed by the invention has good stability and strong film forming property and can realize perfect antireflection and hardening effects.
Description
Technical field
The invention belongs to the anti-reflection liquid of stiffened in glass or the resin treatment industry, relate in particular to the anti-reflection liquid of stiffened of glass or resin lens.
Background technology
Along with development of science and technology, it is very universal that electronic product becomes, and most electronic product has various eyeglasses, and these eyeglasses are easy to break, and shortcoming such as scratches.In addition, at spectacles industry, the eyeglass of use is easy to wearing and tearing owing to wear everyday, if cracked in wearing process, may damage eyes.May the transmitance of eyeglass be exerted an influence in the hardening solution of selecting for use at present, also do not have similar patent to namely can protecting by anti-reflection product again by stiffened.
Summary of the invention
The present invention seeks to solve the perviousness problem that eyeglass produces in adding hard process, make eyeglass in stiffened, can reach anti-reflection effect again.
For achieving the above object, the technical solution used in the present invention is: the anti-reflection liquid of a kind of eyeglass stiffened comprises that by weight percentage following component is formulated:
Silane coupling agent 3-15 part
Water-soluble silicon colloidal sol 5-15 part
Aluminium salt 0-1 part
Solvent 65-85 part
PH regulator agent 0.5-5 part
Calculate water gaging.
Press such scheme, described silane coupling agent is preferably several composite the forming among KH550, KH560, KH570, KH792, DL602, the DL171 etc.
Press such scheme, described water-soluble silicon colloidal sol particle diameter is preferably 90-120nm, and solid content is at 25-35%.
Press such scheme, described aluminium salt is preferably a kind of in aluminium acetylacetonate, aluminum isopropylate, the aluminum stearate.
Press such scheme, described solvent is preferably and is a kind of in ethanol, the Virahol or their mixture.
Press such scheme, described pH regulator agent is preferably nitric acid, and consumption is preferably 0.5-2 part.
Press such scheme, described calculating water gaging is according to the needed water yield of silane coupling agent hydrolysis that adds.
Because technique scheme is used, the present invention compared with prior art has following advantage: add silane coupling agent hydrolysis film forming, antireflective effect is better, and the homogeneity of film is better; Wear resisting property also is improved, and prevents from use scratching.
Embodiment
Use the present invention of embodiment to be further described below, but content of the present invention is not limited to the following examples:
Embodiment one
The anti-reflection liquid of a kind of eyeglass stiffened comprises that following preparation of raw material forms:
8 parts of silane coupling agents (5 parts of KH560,2 parts of KH550,1 part of DL171)
10 parts of water-soluble silicon colloidal sols (90-120nm, solid content 34%)
1 part of aluminum stearate
78 parts of solvents (77 parts of Virahols, 1 part of ethanol)
1 part of pH regulator agent
2 parts in the water of calculated amount (5 parts of KH560 of hydrolysis need about 1.1 parts of water, and 2 parts of KH550 of hydrolysis need about 0.5 part of water, and 1 part of DL171 of hydrolysis needs about 0.4 part of water)
By the anti-reflection liquid of said ratio preparation stiffened, antireflective effect can reach 5-6%, and hardness can reach more than the 5H.
Embodiment two
The anti-reflection liquid of a kind of eyeglass stiffened comprises that following preparation of raw material forms:
9 parts of silane coupling agents (6 parts of KH570,1 part of KH550,1 part of DL171,1 part of KH792)
12 parts of water-soluble silicon colloidal sols (90-120nm, solid content 25%)
1 part of aluminum isopropylate
77 parts of solvents (75 parts of Virahols, 2 parts of ethanol)
1 part of pH regulator agent
2 parts in the water of calculated amount (pressing a kind of method of embodiment calculates)
By the anti-reflection liquid of said ratio preparation stiffened, two-sided antireflective effect can increase 5-6%, and hardness can reach more than the 6H.
Embodiment three
The anti-reflection liquid of a kind of eyeglass stiffened comprises that following preparation of raw material forms:
5 parts of silane coupling agents (4 parts of KH560,1 part of KH590)
10 parts of water silica sols (90-120nm, solid content 34%)
1 part of aluminium acetylacetonate
81.2 parts of Virahols
0.8 part of pH regulator agent
2 parts in the water of calculated amount (pressing a kind of method of embodiment calculates)
By the anti-reflection liquid of said ratio preparation stiffened, two-sided antireflective effect can increase 4-5%, and hardness can reach more than the 3H.
Embodiment four
The anti-reflection liquid of a kind of eyeglass stiffened comprises that following preparation of raw material forms:
15 parts of silane coupling agents (8 parts of KH550,5 parts of KH560,2 parts of KH-171)
15 parts of water-soluble silicon colloidal sols (90-120nm, solid content 25%)
0.5 part of aluminium acetylacetonate
64 parts of solvents (30 parts of ethanol, 34 parts of Virahols)
1.5 parts of pH regulator agent
4 parts in the water of calculated amount (pressing a kind of method of embodiment calculates)
By the anti-reflection liquid of said ratio preparation stiffened, two-sided antireflective effect can increase 6-8%, and hardness can reach more than the 4H.
Embodiment five
The anti-reflection liquid of a kind of eyeglass stiffened comprises that following preparation of raw material forms:
10 parts of silane coupling agents (8 parts of KH570,1 part of KH792)
15 parts of water silica sols (90-120nm, solid content 25%)
1 part of aluminum isopropylate
71 parts of ethanol
1 part of pH regulator agent
Calculate 2 parts of water gagings (pressing a kind of method of embodiment calculates)
By the anti-reflection liquid of said ratio preparation stiffened, two-sided antireflective effect can increase 5-7%, and hardness can reach more than the 4H.
Claims (7)
1. the anti-reflection liquid of eyeglass stiffened is characterized in that, comprises following component by weight percentage: silane coupling agent 3-15 part, and water-soluble silicon colloidal sol 5-15 part, aluminium salt 0-1 part, solvent 65-85 part, pH regulator agent 0.5-5 part is calculated water gaging.
2. the anti-reflection liquid of a kind of eyeglass stiffened according to claim 1, it is characterized in that described silane coupling agent is one or more among KH550, KH560, KH570, KH-580, KH590, KH792, KH-912, KH-902, KH-69, KH-171, KH-172, KH-42, KH-103, KH-104, KH-108, DL602, the DL171 etc.
3. the anti-reflection liquid of a kind of eyeglass stiffened according to claim 1 is characterized in that, described water-soluble silicon colloidal sol particle diameter is no more than 150nm, and solid content is between 20-40%, and pH is between 3.0 ~ 11.0.
4. the anti-reflection liquid of a kind of eyeglass stiffened according to claim 1 is characterized in that, described aluminium salt is in aluminum nitrate, Tai-Ace S 150, tartrate aluminium, aluminium acetylacetonate, aluminum isopropylate, the aluminum stearate etc. one or more.
5. the anti-reflection liquid of a kind of eyeglass stiffened according to claim 1 is characterized in that, described solvent is one or more in the alcohols materials such as methyl alcohol, ethanol, Virahol, 2-butanols, propyl carbinol, ethylene glycol, glycerol.
6. the anti-reflection liquid of a kind of eyeglass stiffened according to claim 1 is characterized in that, described pH regulator agent is a kind of in nitric acid, sulfuric acid, hydrochloric acid, hydrofluoric acid or the phosphoric acid.
7. the anti-reflection liquid of a kind of eyeglass stiffened according to claim 1 is characterized in that, described calculating water gaging is the summation according to the needed water yield of various silane coupling agent hydrolytic processes that adds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102225700A CN103265884A (en) | 2013-06-06 | 2013-06-06 | Lens hardening antireflection liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102225700A CN103265884A (en) | 2013-06-06 | 2013-06-06 | Lens hardening antireflection liquid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103265884A true CN103265884A (en) | 2013-08-28 |
Family
ID=49009551
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102225700A Pending CN103265884A (en) | 2013-06-06 | 2013-06-06 | Lens hardening antireflection liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103265884A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104099015A (en) * | 2014-07-15 | 2014-10-15 | 王锶源 | Optical lens coating |
| CN104629500A (en) * | 2015-01-28 | 2015-05-20 | 江苏可奥熙光学材料科技有限公司 | Method for preparing hardening liquid for lens |
| CN106398370A (en) * | 2016-08-30 | 2017-02-15 | 东兴华鸿光学科技有限公司 | Hardening anti-reflective liquid for optical lenses |
| CN108841307A (en) * | 2018-06-08 | 2018-11-20 | 东莞市久为纳米材料有限公司 | A kind of aqueous photovoltaic anti-reflection coating of the closed pore of hydrolysis and preparation method thereof |
| CN115999872A (en) * | 2019-12-27 | 2023-04-25 | 厦门谨德光电科技有限公司 | Preparation method and preparation device of UV (ultraviolet) curing hardened spectacle lens |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1398935A (en) * | 2001-07-25 | 2003-02-26 | 张祖依 | Normal temperature hardened paint composition |
| CN101578343A (en) * | 2007-02-22 | 2009-11-11 | 株式会社德山 | Coating composition and photochromic optical article |
| CN101898869A (en) * | 2010-08-03 | 2010-12-01 | 东莞南玻太阳能玻璃有限公司 | Preparation method of composite sol and method for producing solar battery packaging glass by using same |
| CN102086093A (en) * | 2009-12-07 | 2011-06-08 | Hytc株式会社 | Method for preparing coating solution for solar cell module and coating solution composition prepared by the method |
| CN102850894A (en) * | 2012-07-03 | 2013-01-02 | 杭州和合玻璃工业有限公司 | Composite sol for anti-reflection coating and anti-reflection coated photovoltaic glass |
-
2013
- 2013-06-06 CN CN2013102225700A patent/CN103265884A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1398935A (en) * | 2001-07-25 | 2003-02-26 | 张祖依 | Normal temperature hardened paint composition |
| CN101578343A (en) * | 2007-02-22 | 2009-11-11 | 株式会社德山 | Coating composition and photochromic optical article |
| CN102086093A (en) * | 2009-12-07 | 2011-06-08 | Hytc株式会社 | Method for preparing coating solution for solar cell module and coating solution composition prepared by the method |
| CN101898869A (en) * | 2010-08-03 | 2010-12-01 | 东莞南玻太阳能玻璃有限公司 | Preparation method of composite sol and method for producing solar battery packaging glass by using same |
| CN102850894A (en) * | 2012-07-03 | 2013-01-02 | 杭州和合玻璃工业有限公司 | Composite sol for anti-reflection coating and anti-reflection coated photovoltaic glass |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104099015A (en) * | 2014-07-15 | 2014-10-15 | 王锶源 | Optical lens coating |
| CN104629500A (en) * | 2015-01-28 | 2015-05-20 | 江苏可奥熙光学材料科技有限公司 | Method for preparing hardening liquid for lens |
| CN106398370A (en) * | 2016-08-30 | 2017-02-15 | 东兴华鸿光学科技有限公司 | Hardening anti-reflective liquid for optical lenses |
| CN108841307A (en) * | 2018-06-08 | 2018-11-20 | 东莞市久为纳米材料有限公司 | A kind of aqueous photovoltaic anti-reflection coating of the closed pore of hydrolysis and preparation method thereof |
| CN115999872A (en) * | 2019-12-27 | 2023-04-25 | 厦门谨德光电科技有限公司 | Preparation method and preparation device of UV (ultraviolet) curing hardened spectacle lens |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103265884A (en) | Lens hardening antireflection liquid | |
| WO2020016431A3 (en) | Progressive spectacle lens having a variable refractive index and method for the design and production thereof | |
| CN102732125A (en) | Aqueous epoxy resin anticorrosion coating | |
| CN103145944B (en) | PMC (Polymer-matrix composite) radiation-proof resin lens and manufacturing process thereof | |
| CN101892593A (en) | Matt villus waxy feel finishing agent used for synthetic leather and preparation method thereof | |
| CN102796459A (en) | Optical lens polishing solution | |
| JP2016008157A (en) | Method for producing colloidal silica containing core-shell type silica particles | |
| KR20160005697A (en) | Optical article comprising an acrylic substrate coated with a specific hard-coat | |
| CN105086728A (en) | Water-based environment-friendly matte aluminum powder metallic paint and preparing method thereof | |
| KR100907357B1 (en) | Method for Producing a Coating Agent for Anti-Glare Coating, and the Coating Agent and Anti-Glare Film | |
| JP2015157715A (en) | Dispersion solution and manufacturing method therefor, manufacturing method of coating liquid and mesoporous silica porous film | |
| CN109096821A (en) | A kind of ageing-resistant additive of building inorganic coating graphene and preparation method | |
| CN106398370A (en) | Hardening anti-reflective liquid for optical lenses | |
| CN104945974A (en) | UV-curable rust-proof environment-friendly coating | |
| CN111032801A (en) | Coating composition for forming hard coat layer and optical member | |
| CN103553361A (en) | Preparation method of Al2O3-SiO2-TiO2 inorganic antireflection film | |
| CN102134447B (en) | Methyl-terminated acryloyloxy silsesquioxane/titanium dioxide nano anticorrosion protective film | |
| CN102690633A (en) | Deicing aerosol | |
| CN102876182A (en) | Formula and preparation process of single-component zinc-aluminum paint | |
| CN104945976A (en) | High-strength UV (Ultraviolet) curing coating for terrace | |
| CN105088244A (en) | Polishing liquid | |
| CN102899655A (en) | Aluminum passivator | |
| JP2013241315A (en) | Microparticle group and method for producing microparticle group | |
| CN101979352A (en) | Organic coating material capable of reducing light reflectivity of glass surface and glass | |
| CN103059057B (en) | Silicon tetrafluoride, ethanol and magnesium prepare the method for tetraethyl silicate and magnesium fluoride |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130828 |