CN106398370A - Hardening anti-reflective liquid for optical lenses - Google Patents

Hardening anti-reflective liquid for optical lenses Download PDF

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Publication number
CN106398370A
CN106398370A CN201610759772.2A CN201610759772A CN106398370A CN 106398370 A CN106398370 A CN 106398370A CN 201610759772 A CN201610759772 A CN 201610759772A CN 106398370 A CN106398370 A CN 106398370A
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CN
China
Prior art keywords
parts
stiffened
acetylacetone
regulator
optical glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610759772.2A
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Chinese (zh)
Inventor
刘德兴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DONGXING HUAHONG OPTICAL TECHNOLOGY Co Ltd
Original Assignee
DONGXING HUAHONG OPTICAL TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DONGXING HUAHONG OPTICAL TECHNOLOGY Co Ltd filed Critical DONGXING HUAHONG OPTICAL TECHNOLOGY Co Ltd
Priority to CN201610759772.2A priority Critical patent/CN106398370A/en
Publication of CN106398370A publication Critical patent/CN106398370A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a hardening anti-reflective liquid for optical lenses. The hardening anti-reflective liquid comprises the following components in parts by weight: 20-35 parts of cetyl trimethyl ammonium bromide, 3-6 parts of a sol composed of a silicon dioxide and acetylacetone mixed material, 3-4 parts of an adhesion promoter, 6-8 parts of a solvent, 4-7 parts of a hardening agent, 7-10 parts of silane coupling agent, 20-22 parts of anhydrous ethanol, 10-13 parts of zirconium dioxide, 3-6 parts of soluble citrate, and 1-3 parts of pH regulator. The hardening agent is added into the anti-reflective liquid, so that the hardness of the product can be improved, meanwhile the silane coupling agent and the zirconium dioxide are added, the anti-reflection effect is good, and the wear resistance is high.

Description

Optical glass stiffened antireflection liquid
Technical field
The present invention relates to glass or resin processing technique field are and in particular to a kind of optical glass stiffened antireflection liquid.
Background technology
With scientific and technological development, electronic product becomes to popularize very much, and most electronic product has various mirrors Piece, these eyeglasses are easy to break, the shortcomings of scratching.In addition, in spectacles industry, the eyeglass of use, due to wearing everyday, holds very much Easy to wear, if fragmentation during wearing, eyes may be damaged.May be to eyeglass in the hardening liquid selected at present Transmitance produce impact, be also similar to patent to anti-reflection product can protecting with stiffened again.
Content of the invention
For the variety of problems facing described in background technology, it is an object of the invention to provide one kind is gone back while stiffened The optical glass stiffened antireflection liquid of the light transmittance of eyeglass can be improved.
For reaching above-mentioned purpose, the technical solution adopted in the present invention is:A kind of optical glass stiffened antireflection liquid, including Each component of following weight portion:Cetyl trimethylammonium bromide 20-35 part, by silicon dioxide and acetylacetone,2,4-pentanedione mixing material group Colloidal sol 3-6 part of one-tenth, adhesion promoter 3-4 part, solvent 6-8 part, hardening accelerator 4-7 part, silane coupler 7-10 part, anhydrous second Alcohol 20-22 part, zirconium dioxide 10-13 part, soluble citrate 3-6 part, PH regulator 1-3 part.
Further, also include component:Fluorocarbon surfactant 3-4 part.
Further, including each component of following weight portion:20 parts of cetyl trimethylammonium bromide, by silicon dioxide With acetylacetone,2,4-pentanedione mixing material composition 3 parts of colloidal sol, 3 parts of adhesion promoter, 6 parts of solvent, 5 parts of hardening accelerator, silane coupler 8 Part, 20 parts of dehydrated alcohol, 11 parts of zirconium dioxide, 3 parts of soluble citrate, 1 part of PH regulator, 3 parts of surfactant.
Further, including each component of following weight portion:26 parts of cetyl trimethylammonium bromide, by silicon dioxide With 5 parts of the colloidal sol of acetylacetone,2,4-pentanedione mixing material composition, 3.5 parts of adhesion promoter, 7 parts of solvent, 4 parts of hardening accelerator, silane coupled 7 parts of agent, 21 parts of dehydrated alcohol, 10 parts of zirconium dioxide, 6 parts of soluble citrate, 2 parts of PH regulator, surfactant 3.5 Part.
Further, including each component of following weight portion:35 parts of cetyl trimethylammonium bromide, by silicon dioxide With acetylacetone,2,4-pentanedione mixing material composition 6 parts of colloidal sol, 4 parts of adhesion promoter, 8 parts of solvent, 7 parts of hardening accelerator, silane coupler 10 parts, 22 parts of dehydrated alcohol, 13 parts of zirconium dioxide, 5 parts of soluble citrate, 3 parts of PH regulator, 4 parts of surfactant.
The invention has the beneficial effects as follows:The present invention adds hardening accelerator in antireflection liquid, can improve the hardness of product, simultaneously Add silane coupler and zirconium dioxide, antireflective effect is good, and anti-wear performance is strong.
Specific embodiment
Specific embodiment is described further to optical glass stiffened antireflection liquid of the present invention below.
Embodiment 1
Optical glass of the present invention stiffened antireflection liquid, including each component of following weight portion:Cetyl trimethylammonium bromide 20 Part, 3 parts of colloidal sol being made up of silicon dioxide and acetylacetone,2,4-pentanedione mixing material, 3 parts of adhesion promoter, 6 parts of solvent, hardening accelerator 5 Part, 8 parts of silane coupler, 20 parts of dehydrated alcohol, 11 parts of zirconium dioxide, 3 parts of soluble citrate, 1 part of PH regulator, surface 3 parts of activating agent.
Embodiment 2
Optical glass of the present invention stiffened antireflection liquid, including each component of following weight portion:Cetyl trimethylammonium bromide 26 Part, 5 parts of colloidal sol being made up of silicon dioxide and acetylacetone,2,4-pentanedione mixing material, 3.5 parts of adhesion promoter, 7 parts of solvent, hardening accelerator 4 parts, 7 parts of silane coupler, 21 parts of dehydrated alcohol, 10 parts of zirconium dioxide, 6 parts of soluble citrate, 2 parts of PH regulator, table 3.5 parts of face activating agent.
Embodiment 3
Optical glass of the present invention stiffened antireflection liquid, including each component of following weight portion:Cetyl trimethylammonium bromide 35 Part, 6 parts of colloidal sol being made up of silicon dioxide and acetylacetone,2,4-pentanedione mixing material, 4 parts of adhesion promoter, 8 parts of solvent, hardening accelerator 7 Part, 10 parts of silane coupler, 22 parts of dehydrated alcohol, 13 parts of zirconium dioxide, 5 parts of soluble citrate, 3 parts of PH regulator.
Implement 4
Optical glass of the present invention stiffened antireflection liquid, including each component of following weight portion:Cetyl trimethylammonium bromide 20 Part, 3 parts of colloidal sol being made up of silicon dioxide and acetylacetone,2,4-pentanedione mixing material, 3 parts of adhesion promoter, 6 parts of solvent, hardening accelerator 5 Part, 8 parts of silane coupler, 20 parts of dehydrated alcohol, 11 parts of zirconium dioxide, 3 parts of soluble citrate, 1 part of PH regulator.
Embodiment 5
Optical glass of the present invention stiffened antireflection liquid, including each component of following weight portion:Cetyl trimethylammonium bromide 26 Part, 5 parts of colloidal sol being made up of silicon dioxide and acetylacetone,2,4-pentanedione mixing material, 3.5 parts of adhesion promoter, 7 parts of solvent, hardening accelerator 4 parts, 7 parts of silane coupler, 21 parts of dehydrated alcohol, 10 parts of zirconium dioxide, 6 parts of soluble citrate, 2 parts of PH regulator.
Embodiment 6
Optical glass of the present invention stiffened antireflection liquid, including each component of following weight portion:Cetyl trimethylammonium bromide 35 Part, 6 parts of colloidal sol being made up of silicon dioxide and acetylacetone,2,4-pentanedione mixing material, 4 parts of adhesion promoter, 8 parts of solvent, hardening accelerator 7 Part, 10 parts of silane coupler, 22 parts of dehydrated alcohol, 13 parts of zirconium dioxide, 5 parts of soluble citrate, 3 parts of PH regulator.

Claims (5)

1. a kind of optical glass with stiffened antireflection liquid it is characterised in that include following weight portion each component:Cetyl front three Base ammonium bromide 20-35 part, the colloidal sol 3-6 part being made up of silicon dioxide and acetylacetone,2,4-pentanedione mixing material, adhesion promoter 3-4 Part, solvent 6-8 part, hardening accelerator 4-7 part, silane coupler 7-10 part, dehydrated alcohol 20-22 part, zirconium dioxide 10-13 part, can Dissolubility citrate 3-6 part, PH regulator 1-3 part.
2. optical glass according to claim 1 with stiffened antireflection liquid it is characterised in that:Also include component:Fluorocarbon surface Activating agent 3-4 part.
3. optical glass according to claim 2 with stiffened antireflection liquid it is characterised in that include following weight portion each group Point:20 parts of cetyl trimethylammonium bromide, 3 parts of colloidal sol being made up of silicon dioxide and acetylacetone,2,4-pentanedione mixing material, adhesive force 3 parts of accelerator, 6 parts of solvent, 5 parts of hardening accelerator, 8 parts of silane coupler, 20 parts of dehydrated alcohol, 11 parts of zirconium dioxide, solubility lemon 3 parts of lemon hydrochlorate, 1 part of PH regulator, 3 parts of surfactant.
4. optical glass according to claim 2 with stiffened antireflection liquid it is characterised in that include following weight portion each group Point:26 parts of cetyl trimethylammonium bromide, 5 parts of colloidal sol being made up of silicon dioxide and acetylacetone,2,4-pentanedione mixing material, adhesive force 3.5 parts of accelerator, 7 parts of solvent, 4 parts of hardening accelerator, 7 parts of silane coupler, 21 parts of dehydrated alcohol, 10 parts of zirconium dioxide, solubility 6 parts of citrate, 2 parts of PH regulator, 3.5 parts of surfactant.
5. optical glass according to claim 2 with stiffened antireflection liquid it is characterised in that:Each group including following weight portion Point:35 parts of cetyl trimethylammonium bromide, 6 parts of colloidal sol being made up of silicon dioxide and acetylacetone,2,4-pentanedione mixing material, adhesive force 4 parts of accelerator, 8 parts of solvent, 7 parts of hardening accelerator, 10 parts of silane coupler, 22 parts of dehydrated alcohol, 13 parts of zirconium dioxide, solubility lemon 5 parts of lemon hydrochlorate, 3 parts of PH regulator, 4 parts of surfactant.
CN201610759772.2A 2016-08-30 2016-08-30 Hardening anti-reflective liquid for optical lenses Pending CN106398370A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610759772.2A CN106398370A (en) 2016-08-30 2016-08-30 Hardening anti-reflective liquid for optical lenses

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Application Number Priority Date Filing Date Title
CN201610759772.2A CN106398370A (en) 2016-08-30 2016-08-30 Hardening anti-reflective liquid for optical lenses

Publications (1)

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CN106398370A true CN106398370A (en) 2017-02-15

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109423203A (en) * 2017-09-01 2019-03-05 度恩株式会社 Eyeglass hard masking liquid composition and preparation method thereof without organic solvent
CN115770711A (en) * 2022-11-30 2023-03-10 厦门凌太光学有限公司 Environment-friendly coating process for surface of spectacle lens

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101185723B1 (en) * 2012-03-15 2012-09-26 해안실업(주) Double-fluid stiffening flame proof materials and the manufaturing method thereof
CN102736145A (en) * 2012-06-29 2012-10-17 南京第壹有机光电有限公司 Brightness enhancement film and preparation method thereof, and device using brightness enhancement film
CN103265884A (en) * 2013-06-06 2013-08-28 苏州禾川化工新材料科技有限公司 Lens hardening antireflection liquid
CN104497731A (en) * 2014-12-31 2015-04-08 苏州禾川化学技术服务有限公司 Multifunctional marble crystal face finishing agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101185723B1 (en) * 2012-03-15 2012-09-26 해안실업(주) Double-fluid stiffening flame proof materials and the manufaturing method thereof
CN102736145A (en) * 2012-06-29 2012-10-17 南京第壹有机光电有限公司 Brightness enhancement film and preparation method thereof, and device using brightness enhancement film
CN103265884A (en) * 2013-06-06 2013-08-28 苏州禾川化工新材料科技有限公司 Lens hardening antireflection liquid
CN104497731A (en) * 2014-12-31 2015-04-08 苏州禾川化学技术服务有限公司 Multifunctional marble crystal face finishing agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王淮庆等: "《视光材料及应用技术》", 31 August 2012, 上海科技教育出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109423203A (en) * 2017-09-01 2019-03-05 度恩株式会社 Eyeglass hard masking liquid composition and preparation method thereof without organic solvent
CN109423203B (en) * 2017-09-01 2021-02-05 度恩株式会社 Hard coating liquid composition for spectacle lens without organic solvent and preparation method thereof
CN115770711A (en) * 2022-11-30 2023-03-10 厦门凌太光学有限公司 Environment-friendly coating process for surface of spectacle lens

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Application publication date: 20170215