CN103254665B - 硅烷偶联剂组合物及其制备方法和用途 - Google Patents
硅烷偶联剂组合物及其制备方法和用途 Download PDFInfo
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- CN103254665B CN103254665B CN201310177798.2A CN201310177798A CN103254665B CN 103254665 B CN103254665 B CN 103254665B CN 201310177798 A CN201310177798 A CN 201310177798A CN 103254665 B CN103254665 B CN 103254665B
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- 239000006087 Silane Coupling Agent Substances 0.000 title claims abstract description 78
- 238000002360 preparation method Methods 0.000 title claims abstract description 5
- 239000002131 composite material Substances 0.000 title abstract 5
- 239000000843 powder Substances 0.000 claims abstract description 109
- 239000000126 substance Substances 0.000 claims abstract description 53
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 52
- 239000001301 oxygen Substances 0.000 claims abstract description 52
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 50
- 238000000034 method Methods 0.000 claims abstract description 38
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010445 mica Substances 0.000 claims abstract description 4
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 44
- -1 acryloxy Chemical group 0.000 claims description 20
- 229920000642 polymer Polymers 0.000 claims description 17
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 14
- 125000003368 amide group Chemical group 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 239000003960 organic solvent Substances 0.000 claims description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 6
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 6
- 125000000101 thioether group Chemical group 0.000 claims description 6
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 claims description 2
- 229910018557 Si O Inorganic materials 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical group CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 229910010272 inorganic material Inorganic materials 0.000 claims description 2
- 239000011147 inorganic material Substances 0.000 claims description 2
- 238000003760 magnetic stirring Methods 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 239000011368 organic material Substances 0.000 claims description 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 2
- 125000005504 styryl group Chemical group 0.000 claims description 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 230000008569 process Effects 0.000 abstract description 30
- 238000004519 manufacturing process Methods 0.000 abstract description 19
- 238000012986 modification Methods 0.000 abstract description 10
- 230000004048 modification Effects 0.000 abstract description 9
- 239000002245 particle Substances 0.000 abstract description 7
- 229910052710 silicon Inorganic materials 0.000 abstract description 7
- 239000010703 silicon Substances 0.000 abstract description 7
- 238000004381 surface treatment Methods 0.000 abstract description 5
- 239000003365 glass fiber Substances 0.000 abstract description 2
- 238000000053 physical method Methods 0.000 abstract description 2
- 229920006158 high molecular weight polymer Polymers 0.000 abstract 2
- 239000010954 inorganic particle Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- 238000011156 evaluation Methods 0.000 description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 11
- 239000012756 surface treatment agent Substances 0.000 description 11
- 239000002904 solvent Substances 0.000 description 9
- 238000005227 gel permeation chromatography Methods 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 5
- 239000011152 fibreglass Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 238000007385 chemical modification Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002990 reinforced plastic Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide Chemical group NNC(N)=O DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
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- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
样品 | 经实施例5处理后粉体 | 经比较例2处理后粉体 |
相对安息角 | 72 | 100 |
样品 | 经实施例6处理后粉体 | 经比较例3处理后粉体 |
相对安息角 | 90 | 100 |
Claims (14)
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CN104927801B (zh) * | 2014-03-21 | 2018-05-08 | 中国石油化工股份有限公司 | 一种钻井液用摩擦改性剂及钻井液 |
CN108165068A (zh) * | 2017-11-24 | 2018-06-15 | 安徽江南泵阀有限公司 | 一种化工泵用涂料的填料的制备工艺 |
CN111868141A (zh) * | 2018-07-27 | 2020-10-30 | 浙江三时纪新材科技有限公司 | 一种球形粉体填料的制备方法、由此得到的球形粉体填料及其应用 |
CN110666159B (zh) * | 2019-09-30 | 2022-04-01 | 元颉新材料科技(浙江)有限公司 | 一种可用于酸脱脂处理过程的复合铜粉及其制法和应用 |
CN113526977A (zh) * | 2020-04-16 | 2021-10-22 | 中集绿建环保新材料(连云港)有限公司 | 发泡陶瓷的制备方法及其干法制粉方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2006070846A1 (ja) * | 2004-12-27 | 2006-07-06 | Konishi Chemical Ind. Co., Ltd. | ポリシルセスキオキサン微粒子有機溶媒分散液及びその製造方法、並びにポリシルセスキオキサン微粒子水分散液及びその製造方法 |
CN1891626A (zh) * | 2005-07-04 | 2007-01-10 | 日产化学工业株式会社 | 疏水性二氧化硅粉末的制造法 |
CN101497444A (zh) * | 2009-03-04 | 2009-08-05 | 中国科学院广州能源研究所 | 一种真空冷冻干燥法制备大比表面积纳米多孔材料的方法 |
EP2365016A1 (en) * | 2010-03-08 | 2011-09-14 | Ricoh Company, Limited | Polymer and method for producing the same |
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CN101711374B (zh) * | 2007-03-08 | 2011-11-02 | 澳加光学有限公司 | 乙二醇改性聚酯眼镜和眼镜镜架 |
DE102009053782A1 (de) * | 2009-11-19 | 2011-06-01 | BSH Bosch und Siemens Hausgeräte GmbH | Poröses SiO2-Xerogel mit charakteristischer Porengröße, dessen trocknungsstabile Vorstufen und dessen Anwendung |
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WO2006070846A1 (ja) * | 2004-12-27 | 2006-07-06 | Konishi Chemical Ind. Co., Ltd. | ポリシルセスキオキサン微粒子有機溶媒分散液及びその製造方法、並びにポリシルセスキオキサン微粒子水分散液及びその製造方法 |
CN1891626A (zh) * | 2005-07-04 | 2007-01-10 | 日产化学工业株式会社 | 疏水性二氧化硅粉末的制造法 |
CN101497444A (zh) * | 2009-03-04 | 2009-08-05 | 中国科学院广州能源研究所 | 一种真空冷冻干燥法制备大比表面积纳米多孔材料的方法 |
EP2365016A1 (en) * | 2010-03-08 | 2011-09-14 | Ricoh Company, Limited | Polymer and method for producing the same |
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Inventor after: Chen Kexin Inventor after: Cui Wei Inventor after: Chen Ying Inventor before: Chen Kexin Inventor before: Liu Ronglong Inventor before: Cui Wei |
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Effective date of registration: 20150309 Address after: 100084 Beijing city Haidian District Tsinghua University Yifu Building Room 2519 Applicant after: Liu Ronglong Applicant after: Cui Wei Address before: 100080, room 1, building 3, 801 Haidian Avenue, Beijing, Haidian District, -810L-033 Applicant before: Hing Ching Yong Bao (Beijing) Technology Co., Ltd. |
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