CN103254536A - High-low-temperature-resisting sizing material for rubber soles - Google Patents

High-low-temperature-resisting sizing material for rubber soles Download PDF

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Publication number
CN103254536A
CN103254536A CN201310190744XA CN201310190744A CN103254536A CN 103254536 A CN103254536 A CN 103254536A CN 201310190744X A CN201310190744X A CN 201310190744XA CN 201310190744 A CN201310190744 A CN 201310190744A CN 103254536 A CN103254536 A CN 103254536A
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CN
China
Prior art keywords
parts
sizing material
temperature
rubber
low
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CN201310190744XA
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Chinese (zh)
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CN103254536B (en
Inventor
肖伟荣
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South Foshan City Xie Cai Co Ltd
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WUJIANG DEZUO DAILY CHEMICAL PRODUCT CO Ltd
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Priority to CN201310190744.XA priority Critical patent/CN103254536B/en
Publication of CN103254536A publication Critical patent/CN103254536A/en
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Publication of CN103254536B publication Critical patent/CN103254536B/en
Expired - Fee Related legal-status Critical Current
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  • Compositions Of Macromolecular Compounds (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The invention discloses a high-low-temperature-resisting sizing material for rubber soles. The high-low-temperature-resisting sizing material is characterized by comprising the following raw materials in parts by weight: 60 to 70 parts of acrylic rubber, 40 to 50 parts of natural rubber, 10 to 18 parts of coumarone resin, 0.2 to 2 parts of promoter, 0.01 to 0.5 part of antioxidant, 1 to 3 parts of anti-aging agent, 20 to 40 parts of magnesium hydroxide, 10 to 20 parts of carbon black, 2 to 5 parts of reinforcing agent, 1 to 4 parts of liquid softener and 5 to 8 parts of nano zinc oxide. According to the high-low-temperature-resisting sizing material, the natural rubber and the acrylic rubber are used as main materials, and the physical property of the sizing material is guaranteed by addition of the reinforcing agent and the softener, so that the product has the characteristics of abrasion resistance and wear resistance; and the nano magnesium hydroxide is used as a flame retardant, so that the soles have an excellent flame retardant property, and the high-temperature-resisting effect of the sizing material is good.

Description

A kind of high-low temperature resistant rubber soles sizing material
?
Technical field
The invention belongs to technical field of shoe making, specifically is a kind of high-low temperature resistant rubber soles sizing material.
Background technology
Existing high-low temperature resistant rubber soles mostly is high temperature resistant product more than 250 ℃, and used sizing material is main raw material with saturated hydrogenated nitrile-butadiene rubber of height etc. generally, with the dicumyl peroxide vulcanization system.Along with the raising that people require shoes, still there are some problems in existing rubber soles sizing material, and wear resistance, anti-skid, resistant of high or low temperature and oil-proofness have much room for improvement.
The elastomerics that urethanes has polyester and diisocyanate compound to be polymerized is characterized in that wear resistance is good, is best in various rubber, intensity height, good springiness, oil-proofness are good, and anti-ozone is ageing-resistant, shortcoming is that heat resistance is relatively poor, and is water-fast poor with alkali resistance.Be applied to the every performance that to improve rubber soles in the rubber soles sizing material, to satisfy people's multiple demand.
Summary of the invention
The object of the present invention is to provide a kind of high-low temperature resistant rubber soles sizing material.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of high-low temperature resistant rubber soles sizing material, it is characterized in that, comprise the raw material of following weight part: acrylic rubber 60-70 part, natural rubber 40-50 part, coumarone indene resin 10-18 part, promotor 0.2-2 part, oxidation inhibitor 0.01-0.5 part, anti-aging agent 1-3 part, nano-sized magnesium hydroxide 20-40 part, carbon black 10-20 part, strengthening agent 2-5 part, liquid softener 1-4 part, nano zine oxide 5-8 part.
The present invention includes the raw material of following weight part: 65 parts of acrylic rubbers, 45 parts of natural rubbers, 15 parts of coumarone indene resins, 1 part of promotor, 0.5 part in oxidation inhibitor, 2 parts in anti-aging agent, 35 parts of nano-sized magnesium hydroxides, 15 parts of carbon blacks, 4 parts of strengthening agents, 2 parts of liquid softeners, 6 parts of nano zine oxides.
Beneficial effect of the present invention: the present invention is major ingredient with natural rubber and acrylic rubber, ensure physical properties of rubber compound by interpolation strengthening agent, tenderizer, make product have characteristics such as wear-resisting, endurable, added nano-sized magnesium hydroxide as fire retardant, make sole have excellent flame-retardant, high-temperature resistant result of the present invention is good.
Embodiment
Below in conjunction with specific embodiment the present invention is further described.
Embodiment 1
A kind of high-low temperature resistant rubber soles sizing material takes off the raw material of row weight part: 65 parts of acrylic rubbers, 45 parts of natural rubbers, 15 parts of coumarone indene resins, 1 part of promotor, 0.5 part in oxidation inhibitor, 2 parts in anti-aging agent, 35 parts of nano-sized magnesium hydroxides, 15 parts of carbon blacks, 4 parts of strengthening agents, 2 parts of liquid softeners, 6 parts of nano zine oxides.Above-mentioned raw materials is dropped in the Banbury mixer banburying 10 minutes, namely obtain high-low temperature resistant rubber soles sizing material of the present invention.
Embodiment 2
A kind of high-low temperature resistant rubber soles sizing material takes off the raw material of row weight part: acrylic rubber 60-70 part, 40 parts of natural rubbers, 18 parts of coumarone indene resins, 0.2 part of promotor, 0.01 part in oxidation inhibitor, 1 part in anti-aging agent, 20 parts of magnesium hydroxides, 20 parts of carbon blacks, 2 parts of strengthening agents, 4 parts of liquid softeners, 8 parts of nano zine oxides.Above-mentioned raw materials is dropped in the Banbury mixer banburying 10 minutes, namely obtain high-low temperature resistant rubber soles sizing material of the present invention.

Claims (2)

1. high-low temperature resistant rubber soles sizing material, it is characterized in that, comprise the raw material of following weight part: acrylic rubber 60-70 part, natural rubber 40-50 part, coumarone indene resin 10-18 part, promotor 0.2-2 part, oxidation inhibitor 0.01-0.5 part, anti-aging agent 1-3 part, magnesium hydroxide 20-40 part, carbon black 10-20 part, strengthening agent 2-5 part, liquid softener 1-4 part, nano zine oxide 5-8 part.
2. high-low temperature resistant rubber soles sizing material according to claim 1, it is characterized in that, comprise the raw material of following weight part: 65 parts of acrylic rubbers, 45 parts of natural rubbers, 15 parts of coumarone indene resins, 1 part of promotor, 0.5 part in oxidation inhibitor, 2 parts in anti-aging agent, 35 parts of magnesium hydroxides, 15 parts of carbon blacks, 4 parts of strengthening agents, 2 parts of liquid softeners, 6 parts of nano zine oxides.
CN201310190744.XA 2013-05-22 2013-05-22 A kind of high-low temperature resistant sizing material for rubber shoe sole Expired - Fee Related CN103254536B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310190744.XA CN103254536B (en) 2013-05-22 2013-05-22 A kind of high-low temperature resistant sizing material for rubber shoe sole

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310190744.XA CN103254536B (en) 2013-05-22 2013-05-22 A kind of high-low temperature resistant sizing material for rubber shoe sole

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CN103254536A true CN103254536A (en) 2013-08-21
CN103254536B CN103254536B (en) 2015-09-30

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103497366A (en) * 2013-10-11 2014-01-08 昆山纯柏精密五金有限公司 Environment-friendly flame retardant rubber for soles and preparation method thereof
CN104086842A (en) * 2014-06-27 2014-10-08 胡红辉 Nano-material modified rubber composition and rubber belt prepared from same
CN105331079A (en) * 2015-11-13 2016-02-17 吴江市风尚鞋厂 Oil-resistant and flame-retardant rubber shoe material
CN107501827A (en) * 2017-08-24 2017-12-22 芜湖凯奥尔环保科技有限公司 A kind of anti-aging ACM of oil resistant and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005040267A1 (en) * 2003-10-29 2005-05-06 Asahi Kasei Chemicals Corporation Rubber composition for footwear
CN102504375A (en) * 2011-10-18 2012-06-20 山东省自主创新促进中心 Flame-retardant cushion formula for stereo garage
CN102863722A (en) * 2012-09-24 2013-01-09 吴江市信许塑料鞋用配套有限公司 Anti-aging anti-puncturing sole material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005040267A1 (en) * 2003-10-29 2005-05-06 Asahi Kasei Chemicals Corporation Rubber composition for footwear
CN102504375A (en) * 2011-10-18 2012-06-20 山东省自主创新促进中心 Flame-retardant cushion formula for stereo garage
CN102863722A (en) * 2012-09-24 2013-01-09 吴江市信许塑料鞋用配套有限公司 Anti-aging anti-puncturing sole material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103497366A (en) * 2013-10-11 2014-01-08 昆山纯柏精密五金有限公司 Environment-friendly flame retardant rubber for soles and preparation method thereof
CN104086842A (en) * 2014-06-27 2014-10-08 胡红辉 Nano-material modified rubber composition and rubber belt prepared from same
CN105331079A (en) * 2015-11-13 2016-02-17 吴江市风尚鞋厂 Oil-resistant and flame-retardant rubber shoe material
CN107501827A (en) * 2017-08-24 2017-12-22 芜湖凯奥尔环保科技有限公司 A kind of anti-aging ACM of oil resistant and preparation method thereof

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Publication number Publication date
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C41 Transfer of patent application or patent right or utility model
CB03 Change of inventor or designer information

Inventor after: Lun Yongqian

Inventor before: Xiao Weirong

COR Change of bibliographic data
TR01 Transfer of patent right

Effective date of registration: 20160621

Address after: Ping Industrial Park Port Road in Nanhai District of Guicheng city of Foshan province Guangdong 528251

Patentee after: South, Foshan City Xie Cai Co., Ltd

Address before: Lili Town Industrial Park of Wujiang City, Suzhou City, Jiangsu province 215212

Patentee before: Wujiang Dezuo Daily Chemical Product Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150930

Termination date: 20210522