CN103249822A - Moc组合物 - Google Patents
Moc组合物 Download PDFInfo
- Publication number
- CN103249822A CN103249822A CN2011800594470A CN201180059447A CN103249822A CN 103249822 A CN103249822 A CN 103249822A CN 2011800594470 A CN2011800594470 A CN 2011800594470A CN 201180059447 A CN201180059447 A CN 201180059447A CN 103249822 A CN103249822 A CN 103249822A
- Authority
- CN
- China
- Prior art keywords
- methyl
- composition
- moc
- group
- alkene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 86
- 150000001875 compounds Chemical class 0.000 claims abstract description 48
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002781 deodorant agent Substances 0.000 claims abstract description 13
- ZHOOOLQOWQVYOE-UHFFFAOYSA-N 2-cyclohexylidene-2-phenylacetonitrile Chemical compound C=1C=CC=CC=1C(C#N)=C1CCCCC1 ZHOOOLQOWQVYOE-UHFFFAOYSA-N 0.000 claims abstract description 9
- OHRBQTOZYGEWCJ-UHFFFAOYSA-N 3-(3-propan-2-ylphenyl)butanal Chemical compound CC(C)C1=CC=CC(C(C)CC=O)=C1 OHRBQTOZYGEWCJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- ATYBXHSAIOKLMG-UHFFFAOYSA-N oxepin Chemical compound O1C=CC=CC=C1 ATYBXHSAIOKLMG-UHFFFAOYSA-N 0.000 claims abstract description 5
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 claims description 31
- 230000001166 anti-perspirative effect Effects 0.000 claims description 21
- 239000003213 antiperspirant Substances 0.000 claims description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
- 230000001877 deodorizing effect Effects 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 claims description 8
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 claims description 8
- XKTYXVDYIKIYJP-UHFFFAOYSA-N 3h-dioxole Chemical compound C1OOC=C1 XKTYXVDYIKIYJP-UHFFFAOYSA-N 0.000 claims description 4
- SXSNWLZWVUDNGY-UHFFFAOYSA-N C1(CCCCC1)=C(C#N)C1=C(C=CC=C1)CN Chemical compound C1(CCCCC1)=C(C#N)C1=C(C=CC=C1)CN SXSNWLZWVUDNGY-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical compound OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 claims description 4
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- MJJFUQUHNZMLNS-UHFFFAOYSA-N cyclooct-4-en-1-ylmethyl hydrogen carbonate Chemical compound OC(=O)OCC1CCCC=CCC1 MJJFUQUHNZMLNS-UHFFFAOYSA-N 0.000 claims description 3
- -1 1-Methyl-2-(1,2,2-trimethylbicyclo[3.1.0]-hex-3-ylmethyl)cyclopropyl Chemical group 0.000 abstract description 8
- RNLHVODSMDJCBR-SOFGYWHQSA-N (e)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol Chemical compound CC(O)C(C)\C=C\C1CC=C(C)C1(C)C RNLHVODSMDJCBR-SOFGYWHQSA-N 0.000 abstract 1
- KHQDWCKZXLWDNM-GHXNOFRVSA-N (z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol Chemical compound CC\C(CO)=C\CC1CC=C(C)C1(C)C KHQDWCKZXLWDNM-GHXNOFRVSA-N 0.000 abstract 1
- NUEJKVHPFVKGKP-UHFFFAOYSA-N 1-(2,3,4-trimethylcyclododeca-1,3,5-trien-1-yl)ethanone Chemical compound CC(=O)C1=C(C)C(C)=C(C)C=CCCCCCC1 NUEJKVHPFVKGKP-UHFFFAOYSA-N 0.000 abstract 1
- WPFFGMCNILGTEA-UHFFFAOYSA-N 1-spiro[4.5]dec-8-en-9-ylpent-4-en-1-one Chemical compound C1C(C(=O)CCC=C)=CCCC11CCCC1 WPFFGMCNILGTEA-UHFFFAOYSA-N 0.000 abstract 1
- CFSRLACKBAWQFO-UHFFFAOYSA-N 1-spiro[4.5]dec-9-en-9-ylpent-4-en-1-one Chemical compound C1CCC(C(=O)CCC=C)=CC11CCCC1 CFSRLACKBAWQFO-UHFFFAOYSA-N 0.000 abstract 1
- FUNYLZYOEJSMTO-UHFFFAOYSA-N 2-(2,4-dimethylcyclohexyl)pyridine Chemical compound CC1CC(C)CCC1C1=CC=CC=N1 FUNYLZYOEJSMTO-UHFFFAOYSA-N 0.000 abstract 1
- KNHGOYVXAHUDHP-UHFFFAOYSA-N 2-[2-(4-methylcyclohex-3-en-1-yl)propyl]cyclopentan-1-one Chemical compound C1CC(C)=CCC1C(C)CC1CCCC1=O KNHGOYVXAHUDHP-UHFFFAOYSA-N 0.000 abstract 1
- WJWBVJLPGOYBGM-UHFFFAOYSA-N 2-cyclohexylhepta-1,6-dien-3-one Chemical compound C=CCCC(=O)C(=C)C1CCCCC1 WJWBVJLPGOYBGM-UHFFFAOYSA-N 0.000 abstract 1
- BDIZOKISHHUZPI-UHFFFAOYSA-N 2-cyclohexylidene-2-(2-methylphenyl)acetonitrile Chemical compound CC1=CC=CC=C1C(C#N)=C1CCCCC1 BDIZOKISHHUZPI-UHFFFAOYSA-N 0.000 abstract 1
- VLFBSPUPYFTTNF-UHFFFAOYSA-N 3-(4-methoxyphenyl)-2-methylpropanal Chemical compound COC1=CC=C(CC(C)C=O)C=C1 VLFBSPUPYFTTNF-UHFFFAOYSA-N 0.000 abstract 1
- RMXBJHZOHXVUJJ-CSKARUKUSA-N CCOC1=CC(C=O)=CC=C1OC(=O)\C=C\C1=CC=CC=C1O Chemical compound CCOC1=CC(C=O)=CC=C1OC(=O)\C=C\C1=CC=CC=C1O RMXBJHZOHXVUJJ-CSKARUKUSA-N 0.000 abstract 1
- QILMAYXCYBTEDM-IWQZZHSRSA-N Isoambrettolide Chemical compound O=C1CCCCCCC\C=C/CCCCCCO1 QILMAYXCYBTEDM-IWQZZHSRSA-N 0.000 abstract 1
- BZLYOWSSNHNYKW-UHFFFAOYSA-N [2-[1-(3,3-dimethylcyclohexyl)ethoxy]-2-methylpropyl] cyclopropanecarboxylate Chemical compound C1CCC(C)(C)CC1C(C)OC(C)(C)COC(=O)C1CC1 BZLYOWSSNHNYKW-UHFFFAOYSA-N 0.000 abstract 1
- UUMOACOQIVAMMF-CCEZHUSRSA-N dec-9-enyl (e)-3-(2-hydroxyphenyl)prop-2-enoate Chemical compound OC1=CC=CC=C1\C=C\C(=O)OCCCCCCCCC=C UUMOACOQIVAMMF-CCEZHUSRSA-N 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- KYEZYLFPHRVFBF-UHFFFAOYSA-N ethyl 2,6,6-trimethylcyclohexa-1,3-diene-1-carboxylate Chemical compound CCOC(=O)C1=C(C)C=CCC1(C)C KYEZYLFPHRVFBF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000796 flavoring agent Substances 0.000 description 14
- 235000019634 flavors Nutrition 0.000 description 14
- 238000012360 testing method Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 3
- 238000004332 deodorization Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000035807 sensation Effects 0.000 description 3
- 235000019615 sensations Nutrition 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000002594 sorbent Substances 0.000 description 3
- 239000003981 vehicle Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 2
- 229920000858 Cyclodextrin Polymers 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000002253 acid Chemical class 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- 239000013558 reference substance Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 2
- 238000009991 scouring Methods 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- FQTLCLSUCSAZDY-UHFFFAOYSA-N (+) E(S) nerolidol Natural products CC(C)=CCCC(C)=CCCC(C)(O)C=C FQTLCLSUCSAZDY-UHFFFAOYSA-N 0.000 description 1
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- CRDAMVZIKSXKFV-FBXUGWQNSA-N (2-cis,6-cis)-farnesol Chemical compound CC(C)=CCC\C(C)=C/CC\C(C)=C/CO CRDAMVZIKSXKFV-FBXUGWQNSA-N 0.000 description 1
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- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 1
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- AGNTUZCMJBTHOG-UHFFFAOYSA-N 3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]propane-1,2-diol Chemical compound OCC(O)COCC(O)COCC(O)CO AGNTUZCMJBTHOG-UHFFFAOYSA-N 0.000 description 1
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- MOZDKDIOPSPTBH-UHFFFAOYSA-N Benzyl parahydroxybenzoate Chemical compound C1=CC(O)=CC=C1C(=O)OCC1=CC=CC=C1 MOZDKDIOPSPTBH-UHFFFAOYSA-N 0.000 description 1
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Abstract
抵消恶臭的组合物，特别是除臭组合物，包含总计至少25%w/w的至少3种选自如下A组和B组的化合物：A.总计至少5%的至少一种如下化合物：2-亚环己基-2-苯基乙腈、2-乙酰基-1,2,3,4,5,6,7,8-八氢-1,2,8,8-四甲基萘、亚环己基(2-甲基苯基)乙腈、(E)-3-(2-羟基苯基)丙烯酸2-乙氧基-4-甲酰基苯基酯和3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯；B.任选的至少一种如下化合物：3,8,8,11a-四甲基十二氢-5H-3,5a-环氧基-萘并[2,1-C]氧杂环庚三烯、氧杂环十七碳-10-烯-2-酮、3-甲基-5-(2,2,3-三甲基-3-环戊烯-1-基)-4-戊烯-2-醇、2,6,6-三甲基-1,3-环己二烯-1-羧酸乙酯、2-甲基-3-(4-甲氧基苯基)丙醛,3-(3-异丙基苯基)丁醛、2(6)-甲基-8-(1-甲基乙基)二环[2.2.2]辛-5-烯-2(3)-基-1,3-二氧戊环、1-甲基-2-(1,2,2-三甲基二环[3.1.0]-己-3-基甲基)环丙基)甲醇、3,7-二甲基-2(3),6-壬二烯腈、2-(2-(4-甲基-3-环己烯-1-基)丙基)环戊酮、2-环己基-1,6-庚二烯-3-酮、(2Z)-2-乙基-4-(2,2,3-三甲基环戊-3-烯-1-基)丁-2-烯-1-醇、环丙烷羧酸2-{[1-(3,3-二甲基环己基)乙基]氧基}-2-甲基丙基酯、1-螺[4.5]癸-7-烯-7-基-4-戊烯-1-酮、1-螺[4.5]癸-6-烯-7-基-4-戊烯-1-酮、1-(三甲基环十二碳三烯基)-乙酮、碳酸4-环辛烯-1-基甲基酯、2-(2,4-二甲基环己基)-吡啶，其中在任意稀释剂的存在被忽略的基础上计算每种成分的重量百分比。所述组合物抵消恶臭以及在抵消恶臭的产品中的应用。
Description
发明领域
本发明涉及一些香料化合物在抵消恶臭、特别是身体恶臭中的应用、涉及抵消恶臭的组合物和产品、特别是除臭剂和止汗产品并且涉及抵消恶臭的方法。
发明背景
恶臭是可能是个人和/或环境来源的令人不快的气味。可以在空气和/或许多表面例如织物、硬表面、皮肤和毛发上遇到它们。
工业上正在不断地寻找处理恶臭、特别是身体恶臭的抵消(MOC)特性的化合物或其组合。这种化合物可以用于MOC产品，例如除臭剂和止汗剂。
已知许多香料化合物及其组合物具有MOC特性。然而，对鉴定具有优良恶臭、特别是身体恶臭抵消特性的香料化合物或其组合存在持续需求。这种香料化合物或其组合可以对添加它们的组合物和/或产品的MOC和快乐特性施加正面影响，导致消费者的认可度增加。
详细描述
目前已经发现，当以组合方式使用时，一些已知的香料化合物具有令人惊讶的MOC特性，特别是在用于抵消身体恶臭时。
这一发现能够使得这些化合物用于与MOC组合物和产品、特别是除臭和止汗组合物和产品组合使用，由此可以用于抵消恶臭的方法中，特别是抵消身体恶臭例如腋窝恶臭的方法中。
本文所用的术语MOC是指化合物或组合物消除或减少恶臭感觉的能力。
在本发明的第一个方面中，提供了MOC组合物，特别是除臭组合物，其包含总计至少25%w/w的至少3种选自如下A组和B组的化合物：
A.总计至少5%的至少一种如下化合物：2-亚环己基-2-苯基乙腈、2-乙酰基-1,2,3,4,5,6,7,8-八氢-1,2,8,8-四甲基萘、亚环己基(2-甲基苯基)乙腈、(E)-3-(2-羟基苯基)丙烯酸2-乙氧基-4-甲酰基苯基酯和3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯、2-乙酰基-1,2,3,4,5,6,7,8-八氢-1,2,8,8-四甲基萘，
B.任选的至少一种如下化合物：3,8,8,11a-四甲基十二氢-5H-3,5a-环氧基-萘并[2,1-C]氧杂环庚三烯、氧杂环十七碳-10-烯-2-酮、3-甲基-5-(2,2,3-三甲基-3-环戊烯-1-基)-4-戊烯-2-醇、2,6,6-三甲基-1,3-环己二烯-1-羧酸乙酯、2-甲基-3-(4-甲氧基苯基)丙醛、3-(3-异丙基苯基)丁醛、2(6)-甲基-8-(1-甲基乙基)二环[2.2.2]辛-5-烯-2(3)-基-1,3-二氧戊环、1-甲基-2-(1,2,2-三甲基二环[3.1.0]-己-3-基甲基)环丙基)甲醇、3,7-二甲基-2(3),6-壬二烯腈、2-(2-(4-甲基-3-环己烯-1-基)丙基)环戊酮、2-环己基-1,6-庚二烯-3-酮、(2Z)-2-乙基-4-(2,2,3-三甲基环戊-3-烯-1-基)丁-2-烯-1-醇、环丙烷羧酸2-{[1-(3,3-二甲基环己基)乙基]氧基}-2-甲基丙基酯、1-螺[4.5]癸-7-烯-7-基-4-戊烯-1-酮、1-螺[4.5]癸-6-烯-7-基-4-戊烯-1-酮、1-(三甲基环十二碳三烯基)-乙酮、碳酸4-环辛烯-1-基甲基酯、2-(2,4-二甲基环己基)-吡啶，
其中在任意稀释剂的存在被忽略的基础上计算每种成分的重量百分比。
在本发明的另一个方面中提供了MOC组合物，特别是除臭组合物，其包含总计至少25%或至少30%w/w的至少5种选自如下A组和B组的化合物：
A.总计至少5%的至少一种如下化合物：2-亚环己基-2-苯基乙腈、2-乙酰基-1,2,3,4,5,6,7,8-八氢-1,2,8,8-四甲基萘、亚环己基(2-甲基苯基)乙腈、(E)-3-(2-羟基苯基)丙烯酸2-乙氧基-4-甲酰基苯基酯和3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯、2-乙酰基-1,2,3,4,5,6,7,8-八氢-1,2,8,8-四甲基萘，
B.任选的至少一种如下化合物：3,8,8,11a-四甲基十二氢-5H-3,5a-环氧基-萘并[2,1-C]氧杂环庚三烯、氧杂环十七碳-10-烯-2-酮、3-甲基-5-(2,2,3-三甲基-3-环戊烯-1-基)-4-戊烯-2-醇、2,6,6-三甲基-1,3-环己二烯-1-羧酸乙酯、2-甲基-3-(4-甲氧基苯基)丙醛、3-(3-异丙基苯基)丁醛、2(6)-甲基-8-(1-甲基乙基)二环[2.2.2]辛-5-烯-2(3)-基-1,3-二氧戊环、1-甲基-2-(1,2,2-三甲基二环[3.1.0]-己-3-基甲基)环丙基)甲醇、3,7-二甲基-2(3),6-壬二烯腈、2-(2-(4-甲基-3-环己烯-1-基)丙基)环戊酮、2-环己基-1,6-庚二烯-3-酮、(2Z)-2-乙基-4-(2,2,3-三甲基环戊-3-烯-1-基)丁-2-烯-1-醇、环丙烷羧酸2-{[1-(3,3-二甲基环己基)乙基]氧基}-2-甲基丙基酯、1-螺[4.5]癸-7-烯-7-基-4-戊烯-1-酮、1-螺[4.5]癸-6-烯-7-基-4-戊烯-1-酮、1-(三甲基环十二碳三烯基)-乙酮、4-环辛烯-1-基甲基碳酸酯、2-(2,4-二甲基环己基)-吡啶，
其中在任意稀释剂的存在被忽略的基础上计算每种成分的重量百分比。
根据本发明的示例性实施方案，上文定义的MOC组合物，特别是除臭和/或止汗组合物包含总计至少10%w/w或15%w/w的至少2种如上文所定义的选自A组的化合物。
根据本发明的示例性实施方案，本文定义的MOC组合物，特别是除臭组合物包含至少2.5%w/w、5%w/w、10%w/w或15%w/w的如上文所定义的选自A组的化合物3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯。
根据本发明的示例性实施方案，上文定义的MOC组合物，特别是除臭组合物包含至少2.5%w/w、5%w/w、10%w/w或15%w/w的如上文所定义的选自A组的化合物2-亚环己基-2-苯基乙腈。
根据本发明的示例性实施方案，本文定义的MOC组合物，特别是除臭组合物包含总计至少5%w/w、10%w/w或15%w/w的如上文所定义的选自A组的化合物2-亚环己基-2-苯基乙腈和3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯。
可以将如本文所定义的A和B组化合物以纯的形式或在溶剂中的形式加入到组合物中；或可以首先例如通过用俘获材料例如聚合物、胶囊、微胶囊、纳米胶囊、脂质体、前体、成膜剂、吸附剂例如通过使用碳或沸石、环低聚糖及其混合物改变它们；或可以使它们与适合于在应用于外部刺激例如光、酶等时释放化合物的底物化学结合。
作为本文详细描述所限定的，可以用于上述举出的MOC组合物、特别是除臭组合物的A和B组化合物的浓度将取决于调配者所尝试实现的特定感觉效应。这些化合物是香料化合物且可以影响组合物的总体愉快或感觉效应。
如本文所定义的A和B组化合物可以是组合物中单独的成分。或者，它们可以用于与常用于MOC组合物、更具体地是除臭和/或止汗组合物的其他化合物结合使用，例如其他MOC化合物、其他香料化合物、赋形剂和助剂。
其他MOC化合物包括、但不限于抗微生物剂、恶臭吸附剂、化学中和剂例如酸-碱试剂、硫醇俘获剂等、气味阻断剂(参见TecnoScent)、例如引入本文参考的US5538719中所公开的交叉适应剂、恶臭络合剂例如各种环糊精。
抗微生物剂的实例包括、但不限于金属盐，例如柠檬酸锌、氧化锌、2‐巯基吡啶氧化锌(zinc pyrethiones)和羟甲辛吡酮；有机酸，例如山梨酸、苯甲酸及其盐；对羟基苯甲酸酯类，例如对羟基苯甲酸甲酯、对羟基苯甲酸丙酯、对羟基苯甲酸丁酯、对羟基苯甲酸乙酯、对羟基苯甲酸异丙酯、对羟基苯甲酸异丁酯、对羟基苯甲酸苄酯及其盐；醇类，例如苄醇、苯乙醇；硼酸；2,4,4'-三氯-2-羟基-二苯基醚；酚类化合物，例如苯酚、2-甲基苯酚、4-乙基苯酚；精油，例如迷迭香、百里香、熏衣草、丁香酚、老鹳草、茶树、丁香、柠檬草、薄荷或其活性成分例如茴香脑、麝香草酚、桉叶醇、法尼醇、薄荷醇、柠檬油精、水杨酸甲酯、水杨酸、萜品醇、橙花叔醇、香叶醇及其混合物。
恶臭吸附剂的实例包括、但不限于分子筛，例如沸石、硅酸盐、硅铝酸盐和环糊精；和有机吸附剂，例如活性炭、干燥的柑桔果肉、樱桃核提取物、玉米穗轴及其混合物。
其他香料化合物包括、但不限于天然产物，例如提取物、精油、净油、香膏、树脂、浸膏等且还有合成基础物质例如烃类、醇类、醛类、酮类、醚类、酸类、酯类、缩醛类、缩酮类、腈类等，包括饱和与不饱和化合物、脂族、碳环和杂环化合物。
用于MOC组合物的赋形剂和助剂是本领域众所周知的且包括、但不限于：稀释剂，例如溶剂(包括水、醇、乙醇、油、脂肪、植物油和三甘油辛-癸酸酯(miglyol)、C2-C6多元醇类、碳酸丙烯酯、液体聚亚烷基二醇类、柠檬酸三乙酯、肉豆蔻酸异丙酯、苯甲酸苄酯、邻苯二甲酸二乙酯、一缩二丙二醇(DPG))、粘合剂、崩解剂、润滑剂、着色剂、防腐剂、抗氧化剂、乳化剂、稳定剂、消结块剂等。
常用于与香料和MOC组合物结合使用的其他香料化合物、赋形剂和其他助剂的其他实例可以在如下文献中找到：
S.Arctander,Perfume and Flavor Chemicals(Montclair,N.J.,1969);S.Arctander,Perfume and Flavor Materials of NaturalOrigin(Elizabeth,N.J.,1960);“Flavor and Fragrance Materials-1991”,Allured Publishing Co.Wheaton,Ill.USA;S.Arctander,‘Perfume and Flavour Chemicals’,Vol.I和II,Allured PublishingCorporation,Carol Stream,1994，和J.M.Nikitakis(Ed.),‘CTFACosmetic Ingredient Handbook’,1st ed.,The Cosmetic,Toiletryand Fragrance Association,Inc.,Washington,1988。
本文公开的MOC组合物、特别是除臭和/或止汗组合物可以是其自身形式的MOC产品。然而，更典型地，可以将它们加入到另外的组合物中，该组合物可能包含另外的MOC和香料成分，以形成MOC产品，特别是除臭和/或止汗产品。
因此，在本发明的另一个示例性方面中，提供了生成或改变MOC产品、特别是除臭和/或止汗产品的方法，所述方法包括将如上文所定义的组合物添加到所述产品中的步骤。
可以通过使用常规技术将MOC组合物直接混入MOC产品、特别是除臭和/或止汗产品中，从而将如本文所定义的MOC组合物、特别是除臭组合物加入到MOC产品中。
可以用于MOC产品、特别是除臭和/或止汗产品的如本文所定义的MOC组合物、特别是除臭组合物的量将取决于调配者尝试实现的目的和特定感觉效应。考虑到这些考量和本文的教导，本领域技术人员能够通过常规实验找到适合的浓度。
在一个示例性实施方案中，可以加入到MOC产品、特别是除臭和/或止汗产品的如本文所定义的MOC组合物、特别是除臭组合物的量占总MOC产品组成重量的0.01%-40%、0.01%-2%或0.5%-2%。
这些比例的含义绝不意味着限制且对本领域技术人员而言能够并且允许在这些限制外操作，以达到特定的效果。
本文所用的术语MOC产品是指所有形式的MOC产品，产品的非限制性实例包括：滑石粉、除臭剂和止汗剂、洗剂和油、皂、合成洗涤剂、皂和合成洗涤剂个人洗涤条(bar)、个人洗涤液和个人擦洗液、尿布、卫生护垫和清洁产品、香波、调理剂、定型喷雾剂、摩丝、凝胶、头发擦洗液、喷发剂和润发油、织物洗液和粉末、织物调理剂、擦洗液、洗碗液和洗碗粉末、硬表面清洁液体和粉末、水和非水喷雾剂、蜡烛、凝胶、插入式电装置和用电池做电源的用于将组合物导入位置的装置和液体芯吸系统。
特别地，MOC产品是用于个人护理产品的除臭和/或止汗组合物，例如除臭剂、止汗剂、滑石粉、皂、个人洗涤液和个人擦洗液。
在本发明的一个示例性实施方案中，MOC产品是止汗剂或除臭剂，特别是辅助抵消恶臭的除臭或止汗产品。
在辅助性抵消恶臭的除臭剂中，包含两种A组材料(E)-3-(2-羟基苯基)丙烯酸2-乙氧基-4-甲酰基苯基酯和/或3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯的本发明组合物的有效性特别令人惊讶。
这些材料是在接触UV光时断裂成其他化合物的前香料，公开在EP936211中。需要光活化的材料的应用对应用于腋下产品而言是违反直觉的，例如除臭剂和止汗剂。
已经发现(E)-3-(2-羟基苯基)丙烯酸2-乙氧基-4-甲酰基苯基酯和3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯实现的除臭性优于其分解产物。
本文定义的本发明的MOC组合物和产品可以施用于表面以抵消恶臭。
本文所用的术语“表面”是指任意类型的表面且包括织物、硬表面例如木材和塑料、皮肤、毛发或其任意的组合。
在本发明的一个示例性实施方案中，提供了抵消恶臭的方法，该方法包括对表面施用如本文所定义的组合物或产品。
在本发明的一个示例性实施方案中，所述组合物或产品是除臭和/或止汗组合物或产品且所述表面是皮肤，特别是人体皮肤。
在本发明的另一个示例性实施方案中，所述表面是腋下皮肤且恶臭是腋窝恶臭。
现在通过下列实施例更详细地描述本发明。
实施例1
制备本发明的组合物并且使用一般如US4278658中所述的气味减小值试验(Odour Reduction Value test)测试MOC在腋下产品中的特性。该试验使用约50位使用包含约1%w/w研究中的组合物的醇性除臭剂(alcoholic deodorant)处理的白种男性受试者进行；给每位小组成员腋窝中喷2秒。
评价者所用的恶臭强度等级在0-5，其中5为最高水平的恶臭，0为无恶臭，将强度固定在包含具体浓度的恶臭酸即异戊酸的标准溶液(参见表1)。
表1标准恶臭强度
采样的每种组合物接受0-5的恶臭强度或deo-试验评分(DST)。然后DTS用于如下公式以计算组合物的恶臭抑制值(MIV)。
MIV=(DTSc-DTS)/DTSc
(其中DTSc是不含任何香料化合物的对照品显示的平均恶臭评分)。
不同混合物的组成和观察到的MOC特性(正如气味减小试验(Odour Reduction Test)测定的)如表2(a)、(b)和(c)中所示。在所有情况中，命名为M00的样品代表仅包含溶剂一缩二丙二醇的对照品。
表2(a)和(b)详细描述了本发明的组合物。表2(c)详细描述了不满足本发明需求的组合物。
表2(a)、(b)和(c)的关键词
| DPG：一缩二丙二醇 |
| S：溶剂 |
| MIV：平均抑制值 |
| *：8次实验的平均值 |
表2(a)和(b)中详细描述的本发明组合物显示良好的除臭性(例如在气味减少值试验(Odour Reduction Value Test)中MIV>0.25)，而在表2(c)的详细描述中不满足本发明需要的组合物显示的除臭特性差。
包含约10%的两种A组化合物的组合物显示特别良好的除臭性(MIV>0.4)。
实施例2
表3详细描述了比上述实施例更为复杂的且更适合于满足产品例如除臭和止汗产品的快乐需求的本发明的实施例组合物。
表3
Claims (14)
1.MOC组合物，特别是除臭组合物，包含总计至少25%w/w的至少3种选自如下A组和B组的化合物：
A.总计至少5%的至少一种如下化合物：2-亚环己基-2-苯基乙腈、2-乙酰基-1,2,3,4,5,6,7,8-八氢-1,2,8,8-四甲基萘、亚环己基(2-甲基苯基)乙腈、(E)-3-(2-羟基苯基)丙烯酸2-乙氧基-4-甲酰基苯基酯和3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯、2-乙酰基-1,2,3,4,5,6,7,8-八氢-1,2,8,8-四甲基萘，
B.任选的至少一种如下化合物：3,8,8,11a-四甲基十二氢-5H-3,5a-环氧基-萘并[2,1-C]氧杂环庚三烯、氧杂环十七碳-10-烯-2-酮、3-甲基-5-(2,2,3-三甲基-3-环戊烯-1-基)-4-戊烯-2-醇、2,6,6-三甲基-1,3-环己二烯-1-羧酸乙酯、2-甲基-3-(4-甲氧基苯基)丙醛、3-(3-异丙基苯基)丁醛、2(6)-甲基-8-(1-甲基乙基)二环[2.2.2]辛-5-烯-2(3)-基-1,3-二氧戊环、1-甲基-2-(1,2,2-三甲基二环[3.1.0]-己-3-基甲基)环丙基)甲醇、3,7-二甲基-2(3),6-壬二烯腈、2-(2-(4-甲基-3-环己烯-1-基)丙基)环戊酮、2-环己基-1,6-庚二烯-3-酮、(2Z)-2-乙基-4-(2,2,3-三甲基环戊-3-烯-1-基)丁-2-烯-1-醇、环丙烷羧酸2-{[1-(3,3-二甲基环己基)乙基]氧基}-2-甲基丙基酯、1-螺[4.5]癸-7-烯-7-基-4-戊烯-1-酮、1-螺[4.5]癸-6-烯-7-基-4-戊烯-1-酮、1-(三甲基环十二碳三烯基)-乙酮、碳酸4-环辛烯-1-基甲基酯、2-(2,4-二甲基环己基)-吡啶，
其中在任意稀释剂的存在被忽略的基础上计算每种成分的重量百分比。
2.在本发明的另一个方面中提供了MOC组合物，特别是除臭组合物，包含总计至少25%w/w的至少5种选自如下A组和B组的化合物：
A.总计至少5%的至少一种如下化合物：2-亚环己基-2-苯基乙腈、2-乙酰基-1,2,3,4,5,6,7,8-八氢-1,2,8,8-四甲基萘、亚环己基(2-甲基苯基)乙腈、(E)-3-(2-羟基苯基)丙烯酸2-乙氧基-4-甲酰基苯基酯和3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯、2-乙酰基-1,2,3,4,5,6,7,8-八氢-1,2,8,8-四甲基萘，
B.任选的至少一种如下化合物：3,8,8,11a-四甲基十二氢-5H-3,5a-环氧基-萘并[2,1-C]氧杂环庚三烯、氧杂环十七碳-10-烯-2-酮、3-甲基-5-(2,2,3-三甲基-3-环戊烯-1-基)-4-戊烯-2-醇、2,6,6-三甲基-1,3-环己二烯-1-羧酸乙酯、2-甲基-3-(4-甲氧基苯基)丙醛、3-(3-异丙基苯基)丁醛、2(6)-甲基-8-(1-甲基乙基)二环[2.2.2]辛-5-烯-2(3)-基-1,3-二氧戊环、1-甲基-2-(1,2,2-三甲基二环[3.1.0]-己-3-基甲基)环丙基)甲醇、3,7-二甲基-2(3),6-壬二烯腈、2-(2-(4-甲基-3-环己烯-1-基)丙基)环戊酮、2-环己基-1,6-庚二烯-3-酮、(2Z)-2-乙基-4-(2,2,3-三甲基环戊-3-烯-1-基)丁-2-烯-1-醇、环丙烷羧酸2-{[1-(3,3-二甲基环己基)乙基]氧基}-2-甲基丙基酯、1-螺[4.5]癸-7-烯-7-基-4-戊烯-1-酮、1-螺[4.5]癸-6-烯-7-基-4-戊烯-1-酮、1-(三甲基环十二碳三烯基)-乙酮、碳酸4-环辛烯-1-基甲基酯、2-(2,4-二甲基环己基)-吡啶，
其中在任意稀释剂的存在被忽略的基础上计算每种成分的重量百分比。
3.权利要求2的MOC组合物，包含至少30%的至少5种选自A组和B组的化合物。
4.权利要求1-3任一项的MOC组合物，包含至少10%的至少2种选自A组的化合物。
5.权利要求1-3任一项的MOC组合物，包含至少2.5%的选自A组的3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯。
6.权利要求1-3任一项的MOC组合物，包含至少5%的选自A组的2-亚环己基-2-苯基乙腈。
7.权利要求1-3任一项的MOC组合物，包含至少10%w/w的选自A组的化合物2-亚环己基-2-苯基乙腈和3-(2-羟基苯基)丙烯酸(E)-癸-9-烯基酯。
8.MOC产品、特别是除臭和/或止汗产品的生成或改变方法，包括向所述产品中添加如权利要求1-7任一项中所定义的组合物的步骤。
9.MOC产品，包含如权利要求1-7任一项中所定义的组合物。
10.权利要求8的MOC产品，包含如权利要求1-7任一项中所定义的0.01%-40%的组合物。
11.权利要求9和10的MOC产品，其中该产品是除臭剂或止汗剂。
12.如权利要求1-7任一项中所定义的组合物在抵消恶臭中的应用。
13.抵消恶臭的方法，该方法包括向表面施用如权利要求1-7任一项中所定义的组合物。
14.权利要求13的方法，其中所述表面是人体皮肤。
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| Application Number | Priority Date | Filing Date | Title |
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| GB1021050.8 | 2010-12-13 | ||
| GB201021050A GB201021050D0 (en) | 2010-12-13 | 2010-12-13 | Moc compositions |
| PCT/EP2011/072590 WO2012080235A1 (en) | 2010-12-13 | 2011-12-13 | Moc compositions |
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| EP (1) | EP2652102B1 (zh) |
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| CN111565764A (zh) * | 2017-11-29 | 2020-08-21 | 山本香料株式会社 | 沥青、污泥、污水、银杏、堆肥、海洋动物、蔬菜、垃圾或涂料的气味的转变用臭气转变剂和沥青、污泥、污水、银杏、堆肥、海洋动物、蔬菜、垃圾或涂料的气味的臭气转变方法 |
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| EP2662434B2 (de) * | 2012-05-10 | 2023-08-16 | Symrise AG | Verwendung bestimmter Verbindungen zum Verstärken von Gerüchen |
| JP6202679B2 (ja) * | 2013-02-21 | 2017-09-27 | 花王株式会社 | ４，８−ジメチル−４，９−デカジエンニトリル |
| CN107072911B (zh) * | 2014-10-14 | 2020-12-29 | 奇华顿股份有限公司 | 减少恶臭的组合物 |
| WO2016180893A1 (en) * | 2015-05-13 | 2016-11-17 | Givaudan Sa | Improvements in or relating to organic compounds |
| JP6741458B2 (ja) * | 2016-03-31 | 2020-08-19 | ライオン株式会社 | 繊維製品用処理剤組成物 |
| KR20180062813A (ko) | 2016-12-01 | 2018-06-11 | 박금히 | 액취증의 예방 또는 개선용 조성물 |
| SG11201909335SA (en) | 2017-04-27 | 2019-11-28 | Firmenich & Cie | Odor neutralizer for ammonia and primary or secondary amines |
| GB202104969D0 (en) * | 2021-04-08 | 2021-05-26 | Givaudan Sa | Fragrance composition |
| WO2024078679A1 (en) | 2022-10-10 | 2024-04-18 | Symrise Ag | A fragrance mixture (vi) |
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| JP5937614B2 (ja) | 2016-06-22 |
| WO2012080235A1 (en) | 2012-06-21 |
| EP2652102A1 (en) | 2013-10-23 |
| EP2652102B1 (en) | 2016-09-14 |
| JP2014501233A (ja) | 2014-01-20 |
| KR102001260B1 (ko) | 2019-07-17 |
| ZA201303844B (en) | 2014-02-26 |
| MX2013006036A (es) | 2013-08-01 |
| US20130336911A1 (en) | 2013-12-19 |
| ES2607280T3 (es) | 2017-03-29 |
| BR112013014612B1 (pt) | 2020-10-13 |
| BR112013014612A2 (pt) | 2016-09-20 |
| CN103249822B (zh) | 2015-02-11 |
| MX355214B (es) | 2018-04-10 |
| GB201021050D0 (en) | 2011-01-26 |
| KR20130132848A (ko) | 2013-12-05 |
| US9125828B2 (en) | 2015-09-08 |
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