CN103242986A - Calcium sulfate scale cleaning agent and preparation method thereof - Google Patents
Calcium sulfate scale cleaning agent and preparation method thereof Download PDFInfo
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- CN103242986A CN103242986A CN2013101310886A CN201310131088A CN103242986A CN 103242986 A CN103242986 A CN 103242986A CN 2013101310886 A CN2013101310886 A CN 2013101310886A CN 201310131088 A CN201310131088 A CN 201310131088A CN 103242986 A CN103242986 A CN 103242986A
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Abstract
The invention provides a calcium sulfate scale cleaning agent. Based on the total weight of the calcium sulfate scale cleaning agent, the calcium sulfate scale cleaning agent is prepared by mixing the following components in percentage by weight: 20-30% of main cleaning agent, 10-20% of auxiliary cleaning agent, 1-2.5% of buffering agent, 1-2.5% of penetrant, 1-1.5% of stripping agent and 43.5-67% of water, wherein the main cleaning agent is one or some of sodium acetate, sodium humate, sodium nitrilotriacetate, sodium glycolate, sodium polyphosphate and sodium sulfamate. The calcium sulfate scale cleaning agent provided by the invention is high in removal rate, safe and environment-friendly, and has excellent application prospects.
Description
Technical field
The present invention relates to the industrial cleaning agent technical field, relate more specifically to a kind of calcium sulfate scale washing agent of cleaning the GGH heat exchanger tube and preparation method thereof that is specially adapted to.
Background technology
It is a great problem that cleans industry at present both at home and abroad that industry is cleaned, and wherein relates generally to dissolving and the removing of multiple indissoluble dirts such as calcium sulfate, Calucium Silicate powder, ferric oxide, with the amount maximum of calcium sulfate, also the most difficult in these indissoluble dirts.Traditional purging method is to carry out earlier carrying out the pickling proceed step by step after soda boiling makes the transition, and its subject matter is that descaling rate is low, cleans not thorough; Some researchs of adopting thionamic acid or EDTA to clean are also arranged, but its be applied to the GGH interchanger clean in the time, heating and constitute clean cycle loop difficulty, this equipment is only applicable to the spray Cleaning for High Capacity mode, Special Circumstances can be fit to adopt the dismounting soaking and washing.Also can thoroughly not solve the clean-out system of GGH indissoluble dirt at present on the domestic and international market.
Summary of the invention
For overcoming the problems referred to above of the prior art, the invention provides a kind of calcium sulfate scale washing agent and preparation method thereof, this clean-out system descaling rate height uses and makes all more conveniently, has a good application prospect.
The technical solution used in the present invention is: a kind of calcium sulfate scale washing agent, gross weight with the calcium sulfate scale washing agent is benchmark, its component by following percentage composition is mixed and is got: the main lotion of 20-30%, the washing assistant of 10-20%, the buffer reagent of 1-2.5%, the permeate agent of 1-2.5%, the stripper of 1-1.5% and the water of 43.5-67%; Wherein, main lotion is selected from one or more in sodium acetate, Sodium salts humic acids, B,EDTA, sodium glycolate, sodium polyphosphate, the thionamic acid sodium; Washing assistant is selected from one or more in Amino Trimethylene Phosphonic Acid sodium, hydroxy ethylene diphosphonic acid sodium, ethylene diamine tetra methylene phosphonic acid sodium, hexanediamine tetramethyl fork sodium phosphate, the poly (sodium aspartate).
Further, above-mentioned buffer reagent is selected from one or more in vulkacit H, ammonium citrate, ethylenediamine tetraacetic acid (EDTA), the sodium polyacrylate.
Further, above-mentioned permeate agent is selected from one or more in alkyl alcohol Soxylat A 25-7, alkylphenol polyoxyethylene, polyoxyethylene glycol, the petroleum sodium sulfonate.
Preferably, above-mentioned stripper is selected from chlorination dodecyl trimethyl ammonium, chlorination-1, one or more in 3-dialkyl group pyridine, methylacryoyloxyethyl ammonium chloride, dodecyl benzyl dimethyl ammonium chloride, the two octadecyl ammonium chloride of dimethyl.
According to a further aspect in the invention, also provide a kind of preparation method of calcium sulfate scale washing agent, it comprises above-mentioned each component is mixed and dissolving, obtains the step of calcium sulfate scale washing agent.Namely, to be that the component of the following percentage composition of benchmark is fully mixed and dissolved the main lotion that makes calcium sulfate scale washing agent: 20-30% with the gross weight of calcium sulfate scale washing agent, the washing assistant of 10-20%, the buffer reagent of 1-2.5%, the permeate agent of 1-2.5%, the stripper of 1-1.5% and the water of 43.5-67%; Wherein the concrete selection of each composition as mentioned above.
Each component materials among the present invention can directly be buied from commercial channels.And wherein employed water is for accounting for the water of gross weight 43.5-67% under 20-50 ℃ temperature.
Compared with prior art, the present invention has following advantage: the invention provides a kind of calcium sulfate scale washing agent and preparation method thereof, this calcium sulfate scale washing agent is specially adapted to clean the calcium sulfate dirt that produces in the GGH interchanger, it is slow to have solved in the prior art calcium sulfate dirt dissolution rate, clean halfway problem, this calcium sulfate scale washing agent can effectively solve the technical barrier that exists in GGH interchanger normal temperature spray or the soaking and washing.Certainly, this clean-out system also is applicable to the calcium sulfate dirt that other environment of cleaning produce, and to calcium sulfate dirt clearance rate height, cleaning operation is convenient, and preparation is simple, and safety and environmental protection can be widely used in the dirty cleaning of calcium sulfate field.
Embodiment
Below in conjunction with specific embodiment the present invention is described in further detail.Should be understood that the purpose of describing these embodiment is that mode is explained the present invention by way of example, and be not to be construed as limiting the scope of the invention.The implementation condition that adopts among each embodiment can be done further adjustment according to the condition of concrete producer, and not marked implementation condition is generally the condition in the normal experiment.
Embodiment 1
In 300g water, add Sodium salts humic acids 100g, hydroxy ethylene diphosphonic acid sodium 50g, ethylenediamine tetraacetic acid (EDTA) 5g, alkylphenol polyoxyethylene 5g, chlorination-1 successively, 3-dialkyl group pyridine 5g continues down to stir 3 hours at 20 ℃, up to dissolving fully.Cooling discharging namely gets the calcium sulfate scale washing agent.
Embodiment 2
In 300kg water, add sodium acetate 170kg, hydroxy ethylene diphosphonic acid sodium 40kg, ethylene diamine tetra methylene phosphonic acid sodium 60kg, vulkacit H 8kg, polyoxyethylene glycol 6kg, methylacryoyloxyethyl ammonium chloride 8kg successively, continue down to stir 3 hours at 50 ℃, up to dissolving fully.Cooling discharging namely gets the calcium sulfate scale washing agent.
Embodiment 3
In 300kg water, add thionamic acid sodium 90kg, sodium glycolate 70kg, poly (sodium aspartate) 60kg, ammonium citrate 5.6kg, polyoxyethylene glycol 6kg, dodecyl benzyl dimethyl ammonium chloride 8kg successively, continue down to stir 3 hours at 30 ℃, up to dissolving fully.Cooling discharging namely gets the calcium sulfate scale washing agent.
Embodiment 4
In 300kg water, add sodium glycolate 150kg, Amino Trimethylene Phosphonic Acid sodium 60kg, sodium polyacrylate 7kg, petroleum sodium sulfonate 6kg, chlorination dodecyl trimethyl ammonium 7kg successively, continue down to stir 3 hours at 40 ℃, up to dissolving fully.Cooling discharging namely gets the calcium sulfate scale washing agent.
Embodiment 5
In 300g water, add sodium polyphosphate 150g, hydroxy ethylene diphosphonic acid sodium 15g, ethylene diamine tetra methylene phosphonic acid sodium 60g, vulkacit H 6g, alkyl alcohol Soxylat A 25-7 6g, the two octadecyl ammonium chloride 6.5g of dimethyl successively, continue down to stir 3 hours at 35 ℃, up to dissolving fully.Cooling discharging namely gets the calcium sulfate scale washing agent.
Above-described embodiment gained calcium sulfate scale washing agent is specially adapted to clean the ducted calcium sulfate dirt of GGH, adopts the calcium sulfate scale washing agent of contrast application examples and above-described embodiment gained to carry out the comparison of cleaning performance aspect below.
The contrast application examples
As calcium sulfate dirt sample, get that resulting five kinds of clean-out systems soak the effect comparison with 5% hydrofluoric acid among above-mentioned 5 each embodiment with the dirty sample that takes off on the Baosteel GGH heat exchanger plates, the results are shown in following table:
Table 1 clean-out system is to calcium sulfate dirt soaking and washing effectiveness results
Confirm that by above contrast application examples the clean-out system that the present invention obtains has the effect of better removing calcium sulfate dirt than existing 5% hydrofluoric acid clean agent, solved the difficult technical barrier of removing of calcium sulfate dirt.Than caustic acid clean-out systems such as hydrofluoric acid, the present invention is Environmental Safety not only, and the calcium sulfate dirt is had stronger argillization cleanup action, and cleaning operation is easy, has purposes widely.
More than specific embodiment of the present invention is illustrated; but protection content of the present invention is not only limited to above embodiment; in the technical field, the common knowledge of a GPRS just can be carried out diversified change in its technology main idea scope under of the present invention.
Claims (6)
1. a calcium sulfate scale washing agent is characterized in that, is benchmark with the gross weight of described calcium sulfate scale washing agent, and its component by following percentage composition is mixed and got:
The main lotion of 20-30%;
The washing assistant of 10-20%;
The buffer reagent of 1-2.5%;
The permeate agent of 1-2.5%;
The stripper of 1-1.5%; And
The water of 43.5-67%;
Wherein, described main lotion is selected from one or more in sodium acetate, Sodium salts humic acids, B,EDTA, sodium glycolate, sodium polyphosphate, the thionamic acid sodium;
Described washing assistant is selected from one or more in Amino Trimethylene Phosphonic Acid sodium, hydroxy ethylene diphosphonic acid sodium, ethylene diamine tetra methylene phosphonic acid sodium, hexanediamine tetramethyl fork sodium phosphate, the poly (sodium aspartate).
2. calcium sulfate scale washing agent according to claim 1, it is characterized in that: described buffer reagent is selected from one or more in vulkacit H, ammonium citrate, ethylenediamine tetraacetic acid (EDTA), the sodium polyacrylate.
3. calcium sulfate scale washing agent according to claim 1, it is characterized in that: described permeate agent is selected from one or more in alkyl alcohol Soxylat A 25-7, alkylphenol polyoxyethylene, polyoxyethylene glycol, the petroleum sodium sulfonate.
4. calcium sulfate scale washing agent according to claim 1, it is characterized in that: described stripper is selected from chlorination dodecyl trimethyl ammonium, chlorination-1, one or more in 3-dialkyl group pyridine, methylacryoyloxyethyl ammonium chloride, dodecyl benzyl dimethyl ammonium chloride, the two octadecyl ammonium chloride of dimethyl.
5. the preparation method of a calcium sulfate scale washing agent as claimed in claim 1 is characterized in that: comprise component listed in the claim 1 is mixed and dissolving, obtain the step of calcium sulfate scale washing agent.
6. the preparation method of calcium sulfate scale washing agent according to claim 5, it is characterized in that: the step of described mixing and dissolving is carried out under 20-50 ℃ temperature.
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| CN201310131088.6A CN103242986B (en) | 2013-04-16 | 2013-04-16 | Calcium sulfate scale cleaning agent and preparation method thereof |
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| CN201310131088.6A CN103242986B (en) | 2013-04-16 | 2013-04-16 | Calcium sulfate scale cleaning agent and preparation method thereof |
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Cited By (24)
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| CN103525599A (en) * | 2013-09-23 | 2014-01-22 | 杨桂望 | Boiler scale remover |
| CN104017677A (en) * | 2014-06-30 | 2014-09-03 | 深圳职业技术学院 | Detergent for removing gypsum residues on dewaxing handicraft |
| CN104450293A (en) * | 2014-10-15 | 2015-03-25 | 四川省西南建安防腐工程有限公司 | Descaling agent for brine transportation pipeline, as well as usage method thereof |
| CN104880123A (en) * | 2015-04-22 | 2015-09-02 | 大唐淮北发电厂 | Method for treating ash deposition and scaling of GGH (gas-gas heater) |
| CN105602741A (en) * | 2015-12-29 | 2016-05-25 | 山东英联化学科技有限公司 | Environment-friendly sulfate scale cleaning agent |
| CN105802748A (en) * | 2016-03-24 | 2016-07-27 | 刘应才 | Calcium sulfate scale chemical cleaning agent and preparation method thereof |
| CN106215707A (en) * | 2016-08-31 | 2016-12-14 | 上海交通大学 | Improve the short-cut method of tin plating poaching wastewater online resource embrane method closed-system performance |
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| CN106277528A (en) * | 2016-08-31 | 2017-01-04 | 上海交通大学 | The short-cut method of ferronickel electroplate rinsing wastewater online resource embrane method closed-system performance improvement |
| CN106348511A (en) * | 2016-08-31 | 2017-01-25 | 上海交通大学 | Method for improving efficiency of online recycling membrane-process closed system for copper-nickel-chromium electroplating rinse wastewater |
| CN106497699A (en) * | 2016-09-30 | 2017-03-15 | 陈甦 | A kind of Compositional type boiler chimney soot cleaning agent and preparation method thereof |
| CN106854603A (en) * | 2016-11-28 | 2017-06-16 | 北京蓝星清洗有限公司 | A kind of normal temperature ardealite cleaning agent and its application |
| CN107652959A (en) * | 2017-09-26 | 2018-02-02 | 天津亿利科能源科技发展股份有限公司 | A kind of oilfield transportation system and the neutral scale remover of flood pattern |
| CN107858698A (en) * | 2016-09-22 | 2018-03-30 | 中国石油化工股份有限公司 | A kind of cleaning agent for removing sulphur removal dirt |
| CN110564518A (en) * | 2019-09-16 | 2019-12-13 | 德蓝水技术股份有限公司 | Special cleaning agent for calcium sulfate and preparation method thereof |
| CN110701486A (en) * | 2019-10-22 | 2020-01-17 | 湖北富邦科技股份有限公司 | High-concentration long-distance additive for phosphate concentrate |
| CN111718809A (en) * | 2020-06-28 | 2020-09-29 | 兰州宁远化工有限责任公司 | Household cleaning agent and manufacturing process thereof |
| CN112553011A (en) * | 2020-12-08 | 2021-03-26 | 广西蒲公英环保科技有限公司 | Cleaning agent for non-stop cleaning of blast furnace circulating cooling water system in steel plant |
| CN112551707A (en) * | 2020-12-03 | 2021-03-26 | 山东泰和水处理科技股份有限公司 | Neutral calcium scale inhibition cleaning agent |
| CN113502195A (en) * | 2021-08-09 | 2021-10-15 | 朗森特环境科技(山东)有限公司 | Preparation method of neutral cleaning agent for cleaning evaporative condenser |
| CN114045188A (en) * | 2021-11-29 | 2022-02-15 | 胡翠华 | Neutral environment-friendly cleaning agent and preparation method and application thereof |
| CN114100376A (en) * | 2021-11-29 | 2022-03-01 | 胡翠华 | Cleaning agent and preparation method and application thereof |
| CN114712941A (en) * | 2022-04-12 | 2022-07-08 | 聚创(广东)智能装备有限公司 | Method for cleaning monoammonium phosphate filter cloth |
| CN115418277A (en) * | 2022-07-29 | 2022-12-02 | 天津正达科技有限责任公司 | Calcium sulfate scale cleaning agent for evaporative crystallizer and preparation method thereof |
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Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525599A (en) * | 2013-09-23 | 2014-01-22 | 杨桂望 | Boiler scale remover |
| CN104017677A (en) * | 2014-06-30 | 2014-09-03 | 深圳职业技术学院 | Detergent for removing gypsum residues on dewaxing handicraft |
| CN104450293A (en) * | 2014-10-15 | 2015-03-25 | 四川省西南建安防腐工程有限公司 | Descaling agent for brine transportation pipeline, as well as usage method thereof |
| CN104880123A (en) * | 2015-04-22 | 2015-09-02 | 大唐淮北发电厂 | Method for treating ash deposition and scaling of GGH (gas-gas heater) |
| CN105602741A (en) * | 2015-12-29 | 2016-05-25 | 山东英联化学科技有限公司 | Environment-friendly sulfate scale cleaning agent |
| CN105802748A (en) * | 2016-03-24 | 2016-07-27 | 刘应才 | Calcium sulfate scale chemical cleaning agent and preparation method thereof |
| CN106215707A (en) * | 2016-08-31 | 2016-12-14 | 上海交通大学 | Improve the short-cut method of tin plating poaching wastewater online resource embrane method closed-system performance |
| CN106277526A (en) * | 2016-08-31 | 2017-01-04 | 上海交通大学 | A kind of improved method of stannum copper electroplate rinsing wastewater online resource embrane method closed-system performance |
| CN106277528A (en) * | 2016-08-31 | 2017-01-04 | 上海交通大学 | The short-cut method of ferronickel electroplate rinsing wastewater online resource embrane method closed-system performance improvement |
| CN106348511A (en) * | 2016-08-31 | 2017-01-25 | 上海交通大学 | Method for improving efficiency of online recycling membrane-process closed system for copper-nickel-chromium electroplating rinse wastewater |
| CN107858698A (en) * | 2016-09-22 | 2018-03-30 | 中国石油化工股份有限公司 | A kind of cleaning agent for removing sulphur removal dirt |
| CN106497699B (en) * | 2016-09-30 | 2019-02-15 | 陈甦 | A kind of Compositional type boiler chimney soot cleaning agent and preparation method thereof |
| CN106497699A (en) * | 2016-09-30 | 2017-03-15 | 陈甦 | A kind of Compositional type boiler chimney soot cleaning agent and preparation method thereof |
| CN106854603A (en) * | 2016-11-28 | 2017-06-16 | 北京蓝星清洗有限公司 | A kind of normal temperature ardealite cleaning agent and its application |
| CN106854603B (en) * | 2016-11-28 | 2019-09-06 | 北京蓝星清洗有限公司 | A kind of room temperature ardealite cleaning agent and its application |
| CN107652959A (en) * | 2017-09-26 | 2018-02-02 | 天津亿利科能源科技发展股份有限公司 | A kind of oilfield transportation system and the neutral scale remover of flood pattern |
| CN110564518A (en) * | 2019-09-16 | 2019-12-13 | 德蓝水技术股份有限公司 | Special cleaning agent for calcium sulfate and preparation method thereof |
| CN110701486A (en) * | 2019-10-22 | 2020-01-17 | 湖北富邦科技股份有限公司 | High-concentration long-distance additive for phosphate concentrate |
| CN111718809A (en) * | 2020-06-28 | 2020-09-29 | 兰州宁远化工有限责任公司 | Household cleaning agent and manufacturing process thereof |
| CN112551707A (en) * | 2020-12-03 | 2021-03-26 | 山东泰和水处理科技股份有限公司 | Neutral calcium scale inhibition cleaning agent |
| CN112551707B (en) * | 2020-12-03 | 2022-07-26 | 山东泰和水处理科技股份有限公司 | Neutral calcium scale inhibition cleaning agent |
| CN112553011A (en) * | 2020-12-08 | 2021-03-26 | 广西蒲公英环保科技有限公司 | Cleaning agent for non-stop cleaning of blast furnace circulating cooling water system in steel plant |
| CN113502195A (en) * | 2021-08-09 | 2021-10-15 | 朗森特环境科技(山东)有限公司 | Preparation method of neutral cleaning agent for cleaning evaporative condenser |
| CN114045188A (en) * | 2021-11-29 | 2022-02-15 | 胡翠华 | Neutral environment-friendly cleaning agent and preparation method and application thereof |
| CN114100376A (en) * | 2021-11-29 | 2022-03-01 | 胡翠华 | Cleaning agent and preparation method and application thereof |
| CN114712941A (en) * | 2022-04-12 | 2022-07-08 | 聚创(广东)智能装备有限公司 | Method for cleaning monoammonium phosphate filter cloth |
| CN115418277A (en) * | 2022-07-29 | 2022-12-02 | 天津正达科技有限责任公司 | Calcium sulfate scale cleaning agent for evaporative crystallizer and preparation method thereof |
| CN115418277B (en) * | 2022-07-29 | 2024-04-16 | 天津正达科技有限责任公司 | Calcium sulfate scale cleaning agent for evaporative crystallizer and preparation method |
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