CN107620075A - A kind of environment-friendly type composite stainless steel cleaning agent and preparation method thereof - Google Patents
A kind of environment-friendly type composite stainless steel cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN107620075A CN107620075A CN201610546921.7A CN201610546921A CN107620075A CN 107620075 A CN107620075 A CN 107620075A CN 201610546921 A CN201610546921 A CN 201610546921A CN 107620075 A CN107620075 A CN 107620075A
- Authority
- CN
- China
- Prior art keywords
- stainless steel
- environment
- friendly type
- cleaning agent
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention discloses a kind of environment-friendly type composite stainless steel cleaning agent and preparation method thereof, its composition includes organic sour lime acid, ammoniacal liquor, zinc salt, chelating agent, fluoride additive, surfactant, defoamer and water.Zinc salt is zinc sulfate or zinc dihydrogen phosphate；Chelating agent is hydroxycarboxylic acid material；Fluoride additive is NaF, Na2SiF6Or NH4HF2, surfactant is polyethenoxy ether class material.When preparing cleaning agent of the present invention, first, zinc salt is added to the water and it is completely dissolved uniformly；Add citric acid at moderate temperatures, stirring adds ammoniacal liquor regulation PH to after being completely dissolved, and sequentially adds fluoride additive, chelating agent, surfactant, defoamer, is stirred for homogeneous to solution, that is, completes the preparation of environment-friendly type complex cleaning and washing agent of the present invention.The main acid of the present invention is organic acid citric acid, and environmental pollution is small, small to equipment corrosion, and waste liquid is easily processed, and can complete stainless steel oil removing, derusting, passivation three process in a step in cleaning.
Description
Technical field
The present invention relates to technical field of industrial cleaning agent, more particularly to one kind is nontoxic, cleaning is simply environmentally friendly
Type composite stainless steel cleaning agent.
Background technology
The cleaning of industrial equipment is to reach the requirement of full production technological design, is to create good driving production bar
Part, ensure start-of-run and the necessary means that production is smoothed out.Remove the fouling in equipment, the dimension maintenance and expansion of in-service equipment
Build transformation to be required for carrying out industry cleaning link, so that its operation normally and efficiently.Domestic stainless steel equipment at present, is being constructed and put into operation
It is preceding with that will carry out oil removing, scale removal in maintenance, descale and the Chemical cleaning such as passivation protection is handled, generally lead to
Multiple steps such as degreasing, pickling, passivation are crossed to reach cleaning purpose.
It is than more typical cleaning process at present：
System leak detection → water flushing → degreasing → water flushing → pickling → water flushing → passivation → water rinses
→ dry.
Wherein, alkaline matter such as tertiary sodium phosphate, sodium hydroxide etc. typically are used during degreasing degreasing, acid cleaning process is general
Nitric acid, hydrofluoric acid, hydrochloric acid etc. are used, passivation can use nitric acid, nitrous acid etc..These materials inherently have certain corruption to equipment
Corrosion, toxicity is big and the processing of waste liquid is difficult, and the pollution to environment is very serious, as the use of nitric acid, natrium nitrosum can be
Poisonous oxides of nitrogen gas NO is produced in cleaning processX.Also, this technique needs to complete step by step in different systems clearly
Wash, process is quite cumbersome, can waste the resources such as more water, time, manpower.
As fully visible, a kind of nontoxic, novel environment friendly stainless steel cleaner is needed at present, cleaning process is not produced
Raw poisonous gas, do not pollute the environment, make cleaning simple, cleaning equipment will not be treated and cause corrosion to injure.
The content of the invention
In order to solve the problems of the prior art, it is an object of the invention to provide a kind of cleaning of environment-friendly type composite stainless steel
Agent, its environmental pollution is small, small to equipment corrosion, can be by oil removing degreasing, derusting pickling, antirust passivation three in cleaning
Step process is completed in a step, so as to shorten scavenging period, has saved manpower and materials.
To achieve these goals, the technical solution adopted by the present invention is：
A kind of environment-friendly type composite stainless steel cleaning agent, the percentage by weight difference shared by its each component and each component for being included
For：
Organic acid 6 ~ 10%
Ammoniacal liquor 10 ~ 30%
Zinc salt 2 ~ 5%
Chelating agent 2 ~ 10%
Fluoride additive 1 ~ 3%
Surfactant 0.5 ~ 5%
Defoamer 0.05 ~ 0.07%
Water surplus.
Preferable scheme, the organic acid are citric acid.
Further preferred scheme, the zinc salt are zinc sulfate or zinc dihydrogen phosphate.
Scheme still more preferably, the chelating agent are hydroxycarboxylic acid material, it is preferred that the hydroxycarboxylic acid thing
Matter is one kind in poly-epoxy succinic acid, tartaric acid or sodium gluconate.
Scheme still further preferably, the fluoride additive are NaF, Na2SiF6Or NH4HF2In one kind.
The surfactant is APEO or APES.
The defoamer is organic silicon defoamer.
The water is pure water or deionized water.
The present invention adjusts pH value by adding ammoniacal liquor, and the pH value for making environment-friendly type composite stainless steel cleaning agent of the present invention is 3.5
~ 4。
Present invention also offers a kind of preparation method of environment-friendly type composite stainless steel cleaning agent, it comprises the following steps：
S1, zinc salt is added to the water, and it is completely dissolved uniformly；
S2, control temperature add citric acid into step S1 resulting solutions at 45 ~ 65 DEG C, and stirring is to being completely dissolved；
S3, ammoniacal liquor is added into step S2 resulting solutions, adjust the PH to 3.5 ~ 4 of solution；
S4, fluoride additive, chelating agent, surfactant, defoamer are sequentially added into the solution after regulation pH value, and stirred
Mix homogeneous to solution；
Wherein, the percentage by weight shared by each component used in above step is respectively：Citric acid 6 ~ 10%；Ammoniacal liquor 10 ~
30%；Zinc salt 2 ~ 5%；Chelating agent 2 ~ 10%；Fluoride additive 1 ~ 3%；Surfactant 0.5 ~ 5%；Defoamer 0.05
~ 0.07%；Surplus is water.
By using above technical scheme, a kind of environment-friendly type composite stainless steel cleaning agent of the present invention compared with prior art,
Its advantage is：
1st, the main acid of the present invention uses the citric acid in organic acid, and citric acid is found in the fruit of orange class, relative to environment to pacify
It can degrade entirely and voluntarily, acid mist and poisonous oxides of nitrogen gas NO will not be produced as nitric acidX, the corrosion to equipment
Property is greatly reduced, and is protected equipment well, is greatly reduced the difficulty of liquid waste processing.
2nd, composite stainless steel cleaning agent of the invention can be blunt by oil removing degreasing, derusting pickling, antirust in cleaning
Change three-procedure to complete in a step, so as to shorten scavenging period, save manpower and materials.
3rd, the present invention is nontoxic, does not pollute the environment, and discharge capacity only has 1/5th of Conventional cleaning methods, holds
Easily post processing.
4th, environment-friendly type composite stainless steel cleaning agent of the present invention, is easy to storage to transport, and relatively inorganic acid type cleaning agent is transporting
It is safer in way, it is a kind of efficient environment-friendly cleaning agent.
5th, cleaning agent of the invention is applicable the cleaning of stainless steel unit, pipeline and storage tank；Can be in stainless steel, copper etc.
The system that various material coexists uses, and use range is extensive.
Embodiment
To make the object, technical solutions and advantages of the present invention of greater clarity, with reference to instantiation, to the present invention
It is further described.It should be understood that these descriptions are merely illustrative, and it is not intended to limit the scope of the present invention.In addition,
In illustrating below, the description to known features and technology is eliminated, to avoid unnecessarily obscuring idea of the invention.
Preparing a kind of formula of environment-friendly type composite stainless steel cleaning agent of the present invention can use formula as below to prepare：
Formula one：
Weight percentages of components（%）
Citric acid 6
Ammoniacal liquor 10
Zinc salt（Zinc sulfate） 2
Chelating agent（Poly-epoxy succinic acid） 5
Fluoride additive（Sodium fluoride） 2
Surfactant（APEO） 0.5
Defoamer 0.05
Water surplus.
Formula two：
Weight percentages of components（%）
Citric acid 10
Ammoniacal liquor 30
Zinc salt（Zinc dihydrogen phosphate） 3
Chelating agent（Sodium gluconate） 2
Fluoride additive（Na2SiF6） 1
Surfactant（APES） 0.8
Defoamer 0.06
Water surplus.
Formula three：
Weight percentages of components（%）
Citric acid 8
Ammoniacal liquor 20
Zinc salt（Zinc dihydrogen phosphate） 5
Chelating agent（Sodium gluconate） 10
Fluoride additive（Na2SiF6） 3
Surfactant（APES） 5
Defoamer 0.07
Water surplus.
According to the percentage by weight in above-mentioned formula, first, zinc salt is added to the water and it is completely dissolved uniformly, control
Temperature adds citric acid at 45 ~ 65 DEG C, and stirring adds ammoniacal liquor regulation PH to 3.5 ~ 4 to after being completely dissolved, sequentially added
Fluoride additive, chelating agent, surfactant, defoamer, be stirred for it is homogeneous to solution, that is, complete the present invention environment-friendly type
The preparation of composite stainless steel cleaning agent.
Cleaning agent of the invention is applied to the cleaning ways such as circulation, immersion, spray, brushing.
Generally, cleaned when being circulated or being soaked to equipment, the concentration that cleaning agent of the invention uses is
The 15% ~ 20% of the pure water total amount of cleaning, at 60 ~ 70 DEG C, in general scavenging period is 2 small for the optimum temperature control of cleaning
When；Normal temperature is also capable of washing, and the scavenging period of normal temperature is extended for 4 ~ 6 hours.
When carrying out soaking and washing, cleaning situation proper extension soak time can be regarded, is no more than 10 hours under normal temperature.
When carrying out painting way cleaning, the concentration of cleaning agent of the present invention can be improved to 45 ~ 50%, during processing
Between can foreshorten to 30 minutes to 1 hours.
Another further aspect, when the industrial equipments such as storage tank, pipeline, heat exchanger are cleaned, using the environmental protection of the present invention
Type composite stainless steel cleaning agent, its step are：The cleaning fluid that water is rinsed → is configured to by the invention described above cleaning agent cleans（It is de-
Fat, pickling, passivation）→ water flushing → drying → end.Degreasing therein, pickling, passivation are that a step is completed.
The cleaning agent of the present invention is applied to the cleaning of stainless steel unit, pipeline and storage tank；Can be in stainless steel, copper etc.
The system that various material coexists uses.
Citric acid is a kind of organic acid in the present invention, is found in the fruit of orange class, comparatively safe to environment and can
Voluntarily to degrade, acid mist and poisonous oxides of nitrogen gas NO will not be produced as nitric acidX, to the corrosivity of equipment also significantly
Reduce, protect equipment well, greatly reduce the difficulty of liquid waste processing.
Can be by oil removing degreasing, derusting pickling, antirust in cleaning using the composite stainless steel cleaning agent of the present invention
Passivation three-procedure is completed in a step, so as to shorten scavenging period, has saved manpower and materials.And discharge capacity only has tradition
/ 5th of cleaning method, easily post processing；Environment-friendly type composite stainless steel cleaning agent of the present invention, it is easy to storage to transport, relatively
Inorganic acid type cleaning agent is safer in transit, is a kind of efficient environment-friendly cleaning agent.
Above-mentioned embodiment is exemplary, is to preferably make skilled artisans appreciate that originally
Patent, it is impossible to be not understood as the limitation for including scope to this patent；As long as times made of spirit according to disclosed in this patent
How with change or modification, the scope that this patent includes is each fallen within.
Claims (10)
- A kind of 1. environment-friendly type composite stainless steel cleaning agent, it is characterised in that the weight shared by its each component and each component for being included Measuring percentage is respectively：Organic acid 6 ~ 10%Ammoniacal liquor 10 ~ 30%Zinc salt 2 ~ 5%Chelating agent 2 ~ 10%Fluoride additive 1 ~ 3%Surfactant 0.5 ~ 5%Defoamer 0.05 ~ 0.07%Water surplus.
- 2. a kind of environment-friendly type composite stainless steel cleaning agent according to claim 1, it is characterised in that the organic acid is lemon Lemon acid.
- 3. a kind of environment-friendly type composite stainless steel cleaning agent according to claim 1, it is characterised in that the zinc salt is sulfuric acid Zinc or zinc dihydrogen phosphate.
- 4. a kind of environment-friendly type composite stainless steel cleaning agent according to claim 1, it is characterised in that the chelating agent is hydroxyl Yl carboxylic acid class material, it is preferred that the hydroxycarboxylic acid material is one in poly-epoxy succinic acid, tartaric acid or sodium gluconate Kind.
- A kind of 5. environment-friendly type composite stainless steel cleaning agent according to claim 1, it is characterised in that the fluoride addition Agent is NaF, Na2SiF6Or NH4HF2In one kind.
- A kind of 6. environment-friendly type composite stainless steel cleaning agent according to claim 1, it is characterised in that the surfactant For APEO or APES.
- 7. a kind of environment-friendly type composite stainless steel cleaning agent according to claim 1, it is characterised in that the defoamer is to have Machine silicon class defoamer.
- A kind of 8. environment-friendly type composite stainless steel cleaning agent according to claim 1, it is characterised in that the water be pure water or Deionized water.
- 9. a kind of environment-friendly type composite stainless steel cleaning agent according to claim 1, it is characterised in that the environment-friendly type is compound The pH value of stainless steel cleaner is 3.5 ~ 4.
- 10. a kind of preparation method of environment-friendly type composite stainless steel cleaning agent, it is characterised in that it comprises the following steps：S1, zinc salt is added to the water, and it is completely dissolved uniformly；S2, control temperature add citric acid into step S1 resulting solutions at 45 ~ 65 DEG C, and stirring is to being completely dissolved；S3, ammoniacal liquor is added into step S2 resulting solutions, adjust the PH to 3.5 ~ 4 of solution；S4, fluoride additive, chelating agent, surfactant, defoamer are sequentially added into the solution after regulation pH value, and stirred Mix homogeneous to solution；Wherein, the percentage by weight shared by each component used in above step is respectively：Citric acid 6 ~ 10%；Ammoniacal liquor 10 ~ 30%；Zinc salt 2 ~ 5%；Chelating agent 2 ~ 10%；Fluoride additive 1 ~ 3%；Surfactant 0.5 ~ 5%；Defoamer 0.05 ~ 0.07%；Surplus is water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610546921.7A CN107620075A (en) | 2016-07-13 | 2016-07-13 | A kind of environment-friendly type composite stainless steel cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610546921.7A CN107620075A (en) | 2016-07-13 | 2016-07-13 | A kind of environment-friendly type composite stainless steel cleaning agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107620075A true CN107620075A (en) | 2018-01-23 |
Family
ID=61086566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610546921.7A Pending CN107620075A (en) | 2016-07-13 | 2016-07-13 | A kind of environment-friendly type composite stainless steel cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107620075A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108796519A (en) * | 2018-06-28 | 2018-11-13 | 上海蓝星清洗有限公司 | A kind of environmentally friendly neutral cleaners |
| CN111334806A (en) * | 2020-03-20 | 2020-06-26 | 河北工业大学 | Rust remover and preparation method and application thereof |
| CN112239870A (en) * | 2020-10-16 | 2021-01-19 | 山东大学 | Oil and rust removing agent and preparation method and application thereof |
| JP2021055122A (en) * | 2019-09-27 | 2021-04-08 | 株式会社Adeka | Surface treatment method of stainless steel |
| CN113174296A (en) * | 2021-05-10 | 2021-07-27 | 广东环凯生物技术有限公司 | Low-temperature foam cleaning agent for meat processing place and preparation method thereof |
| CN114921792A (en) * | 2022-04-28 | 2022-08-19 | 台山市科美化学工业有限公司 | Preparation method of environment-friendly battery aluminum foil cleaning agent |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1566301A (en) * | 2003-06-25 | 2005-01-19 | 蓝星清洗工程有限公司 | Three-in-one cleaning agent |
-
2016
- 2016-07-13 CN CN201610546921.7A patent/CN107620075A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1566301A (en) * | 2003-06-25 | 2005-01-19 | 蓝星清洗工程有限公司 | Three-in-one cleaning agent |
Non-Patent Citations (1)
| Title |
|---|
| 邹广严: "《能源大辞典》", 31 January 1997, 四川科学技术出版社 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108796519A (en) * | 2018-06-28 | 2018-11-13 | 上海蓝星清洗有限公司 | A kind of environmentally friendly neutral cleaners |
| JP2021055122A (en) * | 2019-09-27 | 2021-04-08 | 株式会社Adeka | Surface treatment method of stainless steel |
| JP7377658B2 (en) | 2019-09-27 | 2023-11-10 | 株式会社Adeka | Methods for surface treatment of stainless steel, methods for producing surface-treated stainless steel, and solutions used in these methods |
| CN111334806A (en) * | 2020-03-20 | 2020-06-26 | 河北工业大学 | Rust remover and preparation method and application thereof |
| CN111334806B (en) * | 2020-03-20 | 2022-05-17 | 天津市工大镀锌设备有限公司 | Rust remover and preparation method and application thereof |
| CN112239870A (en) * | 2020-10-16 | 2021-01-19 | 山东大学 | Oil and rust removing agent and preparation method and application thereof |
| CN113174296A (en) * | 2021-05-10 | 2021-07-27 | 广东环凯生物技术有限公司 | Low-temperature foam cleaning agent for meat processing place and preparation method thereof |
| CN114921792A (en) * | 2022-04-28 | 2022-08-19 | 台山市科美化学工业有限公司 | Preparation method of environment-friendly battery aluminum foil cleaning agent |
| CN114921792B (en) * | 2022-04-28 | 2023-01-06 | 台山市科美化学工业有限公司 | Preparation method of environment-friendly battery aluminum foil cleaning agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107620075A (en) | A kind of environment-friendly type composite stainless steel cleaning agent and preparation method thereof | |
| CN102212833B (en) | Neutral rust removing detergent | |
| CN101463302B (en) | Aqueous degreasing agent for stainless steel tube | |
| EP3360986B1 (en) | Stainless steel surface oxide coating acid-wash additive, manufacturing method, and acid washing method | |
| CN104277932A (en) | Scale cleaning agent and preparation method thereof | |
| CN102732899B (en) | Water-based anti-rusting type washing agent for metal parts | |
| MX2013011856A (en) | Method of dissolving and/or inhibiting the deposition of scale on a surface of a system. | |
| JP3858047B1 (en) | Rust removal / rust inhibitor and rust removal method using the same | |
| CN108687029A (en) | A kind of cleaning of silicon material | |
| CN104726881A (en) | Efficient environment-friendly chemical cleaning method | |
| CN102766876A (en) | Environment-friendly pickling inhibitor and application thereof in pickling of carbon steel | |
| CN112281167A (en) | Pickling solution for cleaning pipeline and application thereof | |
| CN106400036A (en) | Environment-friendly technology for replacing hydrochloric acid for rust removal | |
| CN106623280A (en) | Cleaning method for air compressor pipeline system | |
| CN101955862A (en) | Neutral cleaning agent for mixed water scale and production method thereof | |
| CN104233450B (en) | A kind of cleaning method before object plating | |
| US3507795A (en) | Composition for removal of copper and copper oxide scales from boilers | |
| CN109706463A (en) | A kind of metal surface cleaning liquid and preparation method thereof | |
| RU2525033C1 (en) | Method of maintenance cleaning and passivation of drum boiler pipe inner surface and method of maintenance cleaning and passivation of pipe inner surface of combined-cycle plant waste-heat boiler (versions) | |
| CN102220589A (en) | Water based anti-rust cleaning agent | |
| CN104949570B (en) | The cleaning method of boiler | |
| CN101705159B (en) | Cleaning agent | |
| CN106011880A (en) | Environment-friendly metal surface cleaning agent and preparation method thereof | |
| CN103320804B (en) | A kind of acid cleaning process of zirconium material pickle solution | |
| CN107988593A (en) | Metal surface treating method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180123 |