CN103214725B - The long-acting mulch film of a kind of special resistance to oxidation of sugarcane - Google Patents

The long-acting mulch film of a kind of special resistance to oxidation of sugarcane Download PDF

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Publication number
CN103214725B
CN103214725B CN201310171413.1A CN201310171413A CN103214725B CN 103214725 B CN103214725 B CN 103214725B CN 201310171413 A CN201310171413 A CN 201310171413A CN 103214725 B CN103214725 B CN 103214725B
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mulch film
raw material
film
hindered amine
district
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CN201310171413.1A
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Chinese (zh)
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CN103214725A (en
Inventor
李如丹
张跃彬
刘少春
樊仙
邓军
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Yunnan Zhongzhe Agricultural Science And Technology Co ltd
Sugarcane Research Institute of Yunnan Academy of Agricultural Sciences
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Yunnan Zhongzhe Agricultural Science And Technology Co ltd
Sugarcane Research Institute of Yunnan Academy of Agricultural Sciences
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Abstract

The invention provides the long-acting mulch film of the special resistance to oxidation of a kind of sugarcane, be made up of following raw material: polyethylene raw material polyethylene LLDPE? 7042:95-99%, oxidation inhibitor: 0.1-2%, UV light absorber: 0.01-1%, hindered amine as light stabilizer: 0.05-5% and whiteruss or vegetables oil 0.01-0.05%; Owing to adding anti-oxidant, the auxiliary agent such as uvioresistant and hindered amine as light stabilizer in mulch film blown film raw material, effectively can reduce the generation of free radical in mulch film, suppress the too fast oxidative degradation of mulch film, the oxidation resistent susceptibility of the mulch film of production is primarily of the common Coordinated Play of antioxidant, uvioresistant and hindered amine as light stabilizer.In mulch film production building-up process, Heating temperature lower than 180 DEG C, should prevent antioxidant component pyrolytic decomposition, and the thickness of mulch film ensures that Sugarcane Seedlings mulch film can be emerged by rupture of membranes smoothly.

Description

The long-acting mulch film of a kind of special resistance to oxidation of sugarcane
Technical field
The present invention relates to plastic material and water-saving agricultural technology field, especially a kind of resistance to oxidation, the long-acting mulch film of the special resistance to oxidation of radiation-resistant sugarcane.
Background technology
Along with Global warming, the increase of extreme freakish weather frequency, Sugarcane planting area seasonal drought becomes normality, and within 2009 to 2012, the rainfall of Yunnan Sugarcane Area anniversary is than 2000 young 30%-50%.Yunnan Province's sugarcane district drought resisting has become the work of annual.Mulch film is the drought resisting means of agricultural production of a kind of water conservation insulation, and sugarcane district of current sugarcane plastic-film mulching cultivation Yunnan Province pushes open comprehensively, serves obvious the effect of increasing income.But due to the crop (ripening stage 300-400 days) that sugarcane is a kind of growth cycle length, water consumption consumption is fertile, when arid continues aggravation, needs anniversary drought-resistant water-preserving, just can guarantee that sugarcane stable yields is increased production.Therefore need a kind of mulch film that can cover for a long time on producing, and coordinate rational film-mulching technique, reduce the effect that soil water evaporation plays anniversary drought-resistant water-preserving, guarantee that sugarcane is given stable high yields irrespective of drought or water logging.
The long-lived film sold in the market, by adding long-lived master batch in blown film process, improves the wearing quality of film, but is monopolized by developed country due to technology, and market value is higher.Long-lived film is mainly used in the canopy film of facility cultivation, such as remunerative crops such as anti-season fruit, vegetables, flowers.Because cost is high, the general economic crops growing cycle is short, and the long-lived mulch film for covered ground is not very general.Sugarcane is as a kind of crop of growth cycle length, and a kind of long-acting type mulch film that can meet the sugarcane production cycle plays obvious effect to sugarcane combating drought and raising yields.
Summary of the invention
The invention provides the long-acting mulch film of the special resistance to oxidation of a kind of sugarcane, owing to adding anti-oxidant, the auxiliary agent such as uvioresistant and hindered amine as light stabilizer in mulch film blown film raw material, effectively can reduce the generation of free radical in mulch film, suppress the too fast oxidative degradation of mulch film, the oxidation resistent susceptibility of the mulch film of production is primarily of the common Coordinated Play of antioxidant, uvioresistant and hindered amine as light stabilizer.In mulch film production building-up process, Heating temperature lower than 180 DEG C, should prevent antioxidant component pyrolytic decomposition; The thickness of mulch film ensures that Sugarcane Seedlings mulch film can be emerged by rupture of membranes smoothly.
The present invention is achieved through the following technical solutions its goal of the invention:
The long-acting mulch film of a kind of special resistance to oxidation of sugarcane, is characterized in that, made by the raw material of following weight percent:
Polyethylene raw material polyethylene LLDPE7042:95-99%, oxidation inhibitor: 0.1-2%, UV light absorber: 0.01-1%, hindered amine as light stabilizer: 0.05-5% and whiteruss or vegetables oil 0.01-0.05%, preparation process is as follows: (1), preparation of raw material: in screw blender with vegetables oil or whiteruss by polyethylene LLDPE7042 wetting of particulates, ensure that polyethylene particle has good tackiness to pulvis raw material, add the oxidation inhibitor of powder form, UV light absorber and hindered amine as light stabilizer afterwards, all pulvis and particle are fully mixed;
(2), mulch film is produced: adopt conventional mulch film inflation film manufacturing machine group, first mulch film unit is preheated, warm up time 1-2.5 hour, Heating temperature is lower than 180 DEG C, and wherein heating district's temperature modulation is 160 DEG C, two district's temperature 165 DEG C, three district's temperature 175 DEG C, head temperature 170 DEG C, puts into hopper by the raw material of mixing after preheating, plant capacity regulates from low to high, produces the mulch film meeting national standard.
Described oxidation inhibitor selects model to be: one or more 1076, in 1010,168 and 1098 are composite.
Described UV light absorber selects model to be: one or more in UV9, U-V531, U-VP, U-V320, U-V324, U-V326, U-V327, U-V328, UV329 and U-V360 are composite.
Described hindered amine as light stabilizer selects model to be: one or more in GW-622, GW-744, GW-770, GW-944, GW-120, GW-544, GW-540 and GW-480 are composite.
Described ground film thickness reaches 0.008-0.01mm, width 0.3-6m, effective cover time 10-15 month.By the mulch film black plastic packaging casing packaging of having produced, preserve under lucifuge condition.
Embodiment
Embodiment 1
1, preparation of raw material:
25kg polyethylene (LLDPE7042) particle is added in screw blender, add 5ml whiteruss slightly to soak, then add 37.5g antioxidant 1010,37.5g ultraviolet absorbent uv-326,25g hindered amine GW-770, by all particles and pulvis mixing.
2, mulch film is produced
Adopt Laiwu in Shandong province Lu Guan plastics machinery company limited SJ-50 mulch film blown film unit, first by mulch film unit heat, 1.5 hours warm up time, in Heating temperature lower than 180 DEG C: wherein by heating one district temperature modulation 160 DEG C, two district's temperature 165 DEG C, three district's temperature 170 DEG C, linker 175 DEG C, head temperature 170 DEG C.During preheating, fully traction on debugging unit, lower traction and taking-up equipment are to normal operating conditions, and the debugging of air pump air feed is normal.After preheating, well-mixed raw material is put into hopper, plant capacity regulates from low to high, and ensure that the film thickness produced reaches 0.008-0.01mm, width 0.3-1.6m, the technical parameter of film meets national standard.By the mulch film black plastic packaging casing packaging of having produced, preserve under lucifuge condition.
Embodiment 2
1, preparation of raw material:
25kg polyethylene (LLDPE7042) particle is added in screw blender, add 5ml whiteruss slightly to soak, then add 37.5g antioxidant 1076,37.5g ultraviolet absorbent UV-531,37.5g hindered amine GW-622, by all particles and pulvis mixing.
2, mulch film is produced
Adopt Laiwu in Shandong province Lu Guan plastics machinery company limited SJ-60 mulch film blown film unit, first by mulch film unit heat, 2 hours warm up time, in Heating temperature lower than 180 DEG C: wherein by heating one district temperature modulation 160 DEG C, two district's temperature 165 DEG C, three 175 DEG C, districts, 170 DEG C, head one district, 170 DEG C, head two district.During preheating, fully normally whether, the debugging of air pump air feed is normal for traction on debugging unit, lower traction, taking-up equipment.After preheating, well-mixed raw material is put into hopper, plant capacity regulates from low to high, and ensure that the film thickness produced reaches 0.008-0.01mm, width 0.4-3m, the technical parameter of film meets national standard.By the mulch film black plastic packaging casing packaging of having produced, preserve under lucifuge condition.
Embodiment 3
1, preparation of raw material:
25kg polyethylene (LLDPE7042) particle is added in screw blender, add 5ml refined vegetable oil slightly to soak, add 12.5g antioxidant 1076 again, 12.5g irgasfos 168,25g ultraviolet absorbent UV-531,37.5g hindered amine GW-944, by all particles and pulvis mixing.
2, mulch film is produced
Adopt Laiwu in Shandong province Lu Guan plastics machinery company limited SJ-75 mulch film blown film unit, first by mulch film unit heat, 2.5 hours warm up time, in Heating temperature lower than 180 DEG C: wherein by heating one district temperature modulation 155 DEG C, two district's temperature 160 DEG C, three 175 DEG C, districts, 170 DEG C, head one district, 175 DEG C, head two district.During preheating, fully normally whether, the debugging of air pump air feed is normal for traction on debugging unit, lower traction, taking-up equipment.After preheating, well-mixed raw material is put into hopper, plant capacity regulates from low to high, and ensure that the film thickness produced reaches 0.008-0.01mm, width 0.6-4m, the technical parameter of film meets national standard.By the mulch film black plastic packaging casing packaging of having produced, preserve under lucifuge condition.
Embodiment 4
1, preparation of raw material:
25kg polyethylene (LLDPE7042) particle is added in screw blender, add 5ml whiteruss slightly to soak, add 12.5g antioxidant 1010 again, 12.5g irgasfos 168,12.5g ultraviolet absorbent UV-531,12.5g ultraviolet absorbent uv-326,25g hindered amine GW-622, by all particles and pulvis mixing.
2, mulch film is produced:
Adopt Laiwu in Shandong province Lu Guan plastics machinery company limited SJ-75 mulch film blown film unit, first by mulch film unit heat, 2.5 hours warm up time, in Heating temperature lower than 180 DEG C: wherein by heating one district temperature modulation 155 DEG C, two district's temperature 165 DEG C, three 170 DEG C, districts, 175 DEG C, head one district, 170 DEG C, head two district.During preheating, fully normally whether, the debugging of air pump air feed is normal for traction on debugging unit, lower traction, taking-up equipment.After preheating, well-mixed raw material is put into hopper, plant capacity regulates from low to high, and ensure that the film thickness produced reaches 0.008-0.01mm, width 0.6-4m, the technical parameter of film meets national standard.By the mulch film black plastic packaging casing packaging of having produced, preserve under lucifuge condition.
Embodiment 5
1, preparation of raw material:
In screw blender, add 25kg polyethylene (LLDPE7042) particle, add 5ml whiteruss and slightly soak, then add 12.5g irgasfos 168,12.5g oxidation inhibitor 1098,25g UV light absorber U-VP, 12.5g hindered amine GW-944, by all particles and pulvis mixing.
2, mulch film is produced
Adopt Laiwu in Shandong province Lu Guan plastics machinery company limited SJ-50 mulch film blown film unit, first by mulch film unit heat, 1.5 hours warm up time, in Heating temperature lower than 180 DEG C: wherein by heating one district temperature modulation 160 DEG C, two district's temperature 165 DEG C, three 170 DEG C, districts, linker 175 DEG C, head temperature 170 DEG C.During preheating, fully normally whether, the debugging of air pump air feed is normal for traction on debugging unit, lower traction, taking-up equipment.After preheating, well-mixed raw material is put into hopper, plant capacity regulates from low to high, and ensure that the film thickness produced reaches 0.008-0.01mm, width 0.3-1.6m, the technical parameter of film meets national standard.By the mulch film black plastic packaging casing packaging of having produced, preserve under lucifuge condition.
Embodiment 6
1, preparation of raw material:
25kg polyethylene (LLDPE7042) particle is added in screw blender, add 5ml whiteruss slightly to soak, add 12.5g irgasfos 168 again, 12.5g antioxidant 1010,12.5g antioxidant 1076,12.5g ultraviolet absorbent UV-531,25g hindered amine GW-480, by all particles and pulvis mixing.
2, mulch film is produced
Adopt Laiwu in Shandong province Lu Guan plastics machinery company limited SJ-50 mulch film blown film unit, first by mulch film unit heat, 1.5 hours warm up time, in Heating temperature lower than 180 DEG C: wherein by heating one district temperature modulation 160 DEG C, two district's temperature 165 DEG C, three 175 DEG C, districts, linker 175 DEG C, head temperature 170 DEG C.During preheating, fully normally whether, the debugging of air pump air feed is normal for traction on debugging unit, lower traction, taking-up equipment.After preheating, well-mixed raw material is put into hopper, plant capacity regulates from low to high, and ensure that the film thickness produced reaches 0.008-0.01mm, width 0.3-1.6m, the technical parameter of film meets national standard.By the mulch film black plastic packaging casing packaging of having produced, preserve under lucifuge condition.
Embodiment 7
1, preparation of raw material:
25kg polyethylene (LLDPE7042) particle is added in screw blender, add 5ml refined vegetable oil slightly to soak, add 12.5g antioxidant 1010,12.5g UV light absorber UV-328,12.5g hindered amine GW-622,12.5g hindered amine GW-770, by all particles and pulvis mixing.
2, mulch film is produced
Adopt Laiwu in Shandong province Lu Guan plastics machinery company limited SJ-75 mulch film blown film unit, first by mulch film unit heat, 2.5 hours warm up time, in Heating temperature lower than 180 DEG C: wherein by heating one district temperature modulation 155 DEG C, two district's temperature 160 DEG C, three 175 DEG C, districts, 170 DEG C, head one district, 175 DEG C, head two district.During preheating, fully normally whether, the debugging of air pump air feed is normal for traction on debugging unit, lower traction, taking-up equipment.After preheating, well-mixed raw material is put into hopper, plant capacity regulates from low to high, and ensure that the film thickness produced reaches 0.008-0.01mm, width 0.6-4m, the technical parameter of film meets national standard.By the mulch film black plastic packaging casing packaging of having produced, preserve under lucifuge condition.
Embodiment 8
1, preparation of raw material:
25kg polyethylene (LLDPE7042) particle is added in screw blender, add 5ml whiteruss slightly to soak, add 25g antioxidant 1076 again, 12.5g ultraviolet absorbent UV-531,12.5g UV light absorber UV-327,12.5g hindered amine GW-120,12.5g hindered amine GW-544, by all particles and pulvis mixing.
2, mulch film is produced:
Adopt Laiwu in Shandong province Lu Guan plastics machinery company limited SJ-75 mulch film blown film unit, first by mulch film unit heat, 2.5 hours warm up time, in Heating temperature lower than 180 DEG C: wherein by heating one district temperature modulation 155 DEG C, two district's temperature 165 DEG C, three 175 DEG C, districts, 170 DEG C, head one district, 175 DEG C, head two district.During preheating, fully normally whether, the debugging of air pump air feed is normal for traction on debugging unit, lower traction, taking-up equipment.After preheating, well-mixed raw material is put into hopper, plant capacity regulates from low to high, and ensure that the film thickness produced reaches 0.008-0.01mm, width 0.6-4m, the technical parameter of film meets national standard.By the mulch film black plastic packaging casing packaging of having produced, preserve under lucifuge condition.

Claims (1)

1. the long-acting mulch film of the special resistance to oxidation of sugarcane, is characterized in that, is made by the raw material of following weight percent:
Polyethylene raw material polyethylene LLDPE7042:95-99%, oxidation inhibitor: 0.1-2%, UV light absorber: 0.01-1%, hindered amine as light stabilizer: 0.05-5% and whiteruss or vegetables oil 0.01-0.05%;
Preparation process is as follows:
(1), preparation of raw material: in screw blender with vegetables oil or whiteruss by polyethylene LLDPE7042 wetting of particulates, ensure that polyethylene particle has good tackiness to pulvis raw material, add the oxidation inhibitor of powder form, UV light absorber and hindered amine as light stabilizer afterwards, all pulvis and particle are fully mixed;
(2), mulch film is produced: adopt conventional mulch film inflation film manufacturing machine group, first mulch film unit is preheated, preheating time 1-2.5 hour, pre-heating temperature is lower than 180 DEG C, and wherein heating district's temperature modulation is 160 DEG C, two district's temperature 165 DEG C, three district's temperature 175 DEG C, head temperature 170 DEG C, during preheating, on abundant debugging unit, traction, lower traction and taking-up equipment are to normal operating conditions, and the debugging of air pump air feed is normal; After preheating, the raw material of mixing is put into hopper, plant capacity regulates from low to high, produces and obtains the mulch film meeting national standard, ground film thickness 0.008-0.01mm, width 0.3-6m, effective cover time 10-15 month;
Described oxidation inhibitor selects model to be: one or more 1076, in 1010,168 and 1098 are composite;
Described UV light absorber selects model to be: one or more in UV9, U-V531, U-VP, U-V320, U-V324, U-V326, U-V327, U-V328, UV329 and U-V360 are composite;
Described hindered amine as light stabilizer selects model to be: one or more in GW-622, GW-744, GW-770, GW-944, GW-120, GW-544, GW-540 and GW-480 are composite.
CN201310171413.1A 2013-05-11 2013-05-11 The long-acting mulch film of a kind of special resistance to oxidation of sugarcane Expired - Fee Related CN103214725B (en)

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Publication number Priority date Publication date Assignee Title
CN106957478B (en) * 2017-05-08 2020-04-10 云南省农业科学院甘蔗研究所 Agricultural degradable mulching film with controllable degradation time and preparation method thereof
CN110637555A (en) * 2019-10-21 2020-01-03 广西南亚热带农业科学研究所 Coating breeding method for improving stress resistance of sugarcane buds

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CN102432945B (en) * 2011-10-28 2013-03-20 甘肃福雨塑业有限责任公司 Dry farming anti-aging long-acting autumn mulching film, and preparation process thereof
CN102660074B (en) * 2012-05-18 2014-01-15 天水天宝塑业有限责任公司 Special weather-resisting functional mulching film capable of being used for two years
CN102964669B (en) * 2012-11-17 2014-06-25 云南中蔗农业科技有限责任公司 Production method of agricultural land surface covered weeding degradable mulching film

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