CN103192199A - Absorbent for cutting ceramics by aid of fiber laser - Google Patents

Absorbent for cutting ceramics by aid of fiber laser Download PDF

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Publication number
CN103192199A
CN103192199A CN2013101348101A CN201310134810A CN103192199A CN 103192199 A CN103192199 A CN 103192199A CN 2013101348101 A CN2013101348101 A CN 2013101348101A CN 201310134810 A CN201310134810 A CN 201310134810A CN 103192199 A CN103192199 A CN 103192199A
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oily material
absorbent
mass percent
ceramic
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CN103192199B (en
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王华杰
王荣
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Suzhou Guangyunda Optoelectronics Technology Co Ltd
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Suzhou Guangyunda Optoelectronics Technology Co Ltd
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Abstract

Disclosed is an absorbent for cutting ceramics by the aid of fiber laser. The absorbent is coated on the surface of a ceramic in a technological process for cutting the ceramic by the aid of the fiber laser. The absorbent is characterized in that an oily material and acetone are proportioned to manufacture the absorbent, and colorants, colorant assistants, stabilizers, resists, wetting agents and preservatives are proportioned to manufacture the oily material. The absorbent has the advantages that a light absorption effect of the ceramic is excellent after the absorbent is used for the ceramic, a phenomenon of light interruption is prevented, the ceramic can be cut by the aid of the laser at one step, the absorbent is environment-friendly, can be easily coated on the surface of the ceramic and is easy to clean, the ceramic can be cleaned in alcohol after being cut, intrinsic characteristics of the ceramic cannot be changed, corrosion is prevented, the appearance of the ceramic is identical to that of a ceramic which is not coated with the absorbent, and the like.

Description

A kind of absorbent for optical-fiber laser cutting pottery
Technical field
The present invention relates to optical-fiber laser cutting ceramic field, relate in particular to a kind of absorbent for optical-fiber laser cutting pottery.
Background technology
Laser cutting parameter is that the energy that discharges when adopting laser beam to shine ceramic surface makes pottery fusing and evaporation, pass through focus set, make laser beam concentrate on very little zone, energy height is concentrated cutting part is carried out rapid local heat, make the material evaporation, along with light beam moves relative to linear with material, make hole form the joint-cutting of narrower in width continuously, side cut is influenced by heat very little, and laser beam does not apply any power to material, be untouchable processing, so it is little or not have an advantage of being out of shape that the pottery of Laser Processing has distortion, in current laser cutting ceramic industry, what great majority adopted is traditional carbon dioxide laser cutting ceramic technology, lasing light emitter generally adopts the carbon dioxide high-power laser beam, because its cutting speed and smooth substantially cutting section efficiently at present also are the main flow technology that pottery divides plate processing.
Yet the carbon dioxide laser cutting has for the ceramic cutting processing of some requirements at the higher level
Following shortcoming: cost is higher, efficient is low, the cut edge is uneven, for example the straight cuts of circuit unit profile just can't be suitable for, concavo-convex with as the ceramic substrate marginal existence stamp edge of carbon dioxide high power laser light cutting, the fluctuating scope is bigger, for the while efficiently at assurance laser cutting ceramic substrate, reduce similar stamp edge, someone has proposed to use optical-fiber laser to cut the method for pottery, but because the problem of ceramic material behavior own, absorption efficiency to laser is not high enough, disconnected optical phenomenon can appear, can't disposable cutting pottery, and efficient is not high enough.
Summary of the invention
Technical problem solved by the invention is: at the existing fiber laser cutting technique exist disconnected optical phenomenon cause can't disposable cutting pottery problem, provide a kind of new absorbent to be coated in ceramic surface, assurance improves cutting efficiency to the absorption of ceramic surface to laser.
The technical solution used in the present invention is, a kind of absorbent for optical-fiber laser cutting pottery, in the technological process of optical-fiber laser cutting pottery, absorbent is coated in ceramic surface, described absorbent is formed by oily material and acetone proportioning, and described oily material is formed by pigment, pigment auxiliary agent, stabilizing agent, resist, wetting agent and anticorrisive agent proportioning.
As further optimization of the present invention, the volume ratio of described oily material and acetone be 1:500 to 1:550, stirring after the dilution gets final product.
As further optimization of the present invention, described pigment adopts ferric tannate and gallic acid iron, described pigment auxiliary agent adopts dark blue dyestuff, described stabilizing agent adopts oxalic acid solution, described resist adopts the resin type cure polymer, described wetting agent adopts glycerine, and described anticorrisive agent adopts the penta sodium pentachlorophenate medicament.
As further optimization of the present invention, the mass percent that described pigment accounts for oily material is 10% to 30%, the mass percent that the pigment auxiliary agent accounts for oily material is 10% to 30%, the mass percent of stabilizer comprises oily material is 10% to 30%, the mass percent that resist accounts for oily material is 10% to 30%, the mass percent that wetting agent accounts for oily material is 10% to 30%, and the mass percent that anticorrisive agent accounts for oily material is 10% to 30%, and being added in stirs in the container can obtain oily material.
The invention has the beneficial effects as follows, use the extinction effect of pottery behind this absorbent fine, disconnected optical phenomenon no longer appears, the laser cutting pottery can disposablely be finished, and this absorbent itself also has advantages such as environmental protection, easy Tu, easy cleaning, and pottery can be placed directly in and clean in the alcohol after cutting is finished, and can not change the characteristic of pottery itself, also corrosion phenomenon can not take place, outward appearance is the same with the pottery that is not coated with absorbent.
Description of drawings
Fig. 1 is the flow chart of fiber cut ceramic methods;
Fig. 2 is the schematic diagram that nozzle is connected with cutting head;
Fig. 3 is the contact-making surface schematic diagram of nozzle;
Fig. 4 is the structure of nozzle schematic diagram;
Among the figure: 1, gas channel; 2, cutting head; 3, nozzle body; 4, gas port; 5, Cutting platform; 6, fumarole; 7, cross recess; 8, contact-making surface.
The specific embodiment
Below in conjunction with accompanying drawing the present invention is further set forth.
Embodiment 1, and a kind of method of optical-fiber laser cutting pottery referring to accompanying drawing 1-4, may further comprise the steps:
S1, commissioning device, parameters such as the frequency of setting laser, pulsewidth, speed and focal height, the frequency of laser is 10kHz, pulsewidth is 28ms, speed is 50mm/s, and focal height is 20000step, the standard unit when step is laser cutting device adjustment focal height herein in the parameter database;
S2, load onto cutting nozzles, the cutting head 2 of nozzle and laser equipment is by being threaded, this nozzle and traditional nozzle are also inequality, redesign, nozzle is processed by copper product, comprise nozzle body 3, gas channel 1 and fumarole 6, nozzle, fumarole 6 and gas port 4 all are circular, 4 gas ports 4 and cross recess 7 are arranged on the contact-making surface 8 of described nozzle, fumarole 6 diameters are 0.8mm, gas port 4 diameters are 0.6mm, this cutting nozzles utilizes venturi principle, make gas form one " vacuum " district at the rear side of venturi outlet exactly, can make unlimited the tapping into nozzle of ceramic substrate, make the ceramic substrate of cutting can not blown power, in practical operation, there is not shock wave in the gas flowfield of nozzle, the jet expansion air-flow is even, the border is neat, the while exit flow does not have masterpiece and is used on the workpiece, and in the cutting process of reality, cutting speed is improved significantly, cut quality is also improved significantly, and is little as the roughness of otch section, the dross of joint-cutting lower limb seldom waits; Under same laser power and supply gas pressure, the thickness of slab that new type nozzle is cut than conventional spout also increases; Nozzle and variation has been taken place by the distance between the cut spare, cutting performance is also more stable; New type nozzle is unlimited approach but do not contact in nozzle and workpiece distance, also can cut finely simultaneously, and conventional spout the distance between nozzle and the workpiece must be greater than 1mm when cutting;
S3, clamping pallet smelting tool find relative position on cutting table top 5;
S4, ceramic substrate is placed on the pallet smelting tool, fix, ceramic substrate is before being placed into pallet smelting tool, need coat homemade absorbent, because the laser that pottery emits laser equipment can not absorb fully, so we will be by special surface treatment, help pottery and absorb laser, thereby can cut continuously and wear pottery, we have found a kind of special material-----surperficial blacking to handle optical absorbing agent, described absorbent is formed by oily material and acetone proportioning, the volume ratio of oily material and acetone is 1:525, stir after the dilution and get final product, oily material is by pigment, the pigment auxiliary agent, stabilizing agent, resist, wetting agent and anticorrisive agent proportioning form, pigment adopts ferric tannate and gallic acid iron, the pigment auxiliary agent adopts dark blue dyestuff, stabilizing agent adopts oxalic acid solution, resist adopts the resin type cure polymer, wetting agent adopts glycerine, anticorrisive agent adopts the penta sodium pentachlorophenate medicament, the mass percent that described pigment accounts for oily material is 16.7%, the mass percent that the pigment auxiliary agent accounts for oily material is 16.7%, the mass percent of stabilizer comprises oily material is 16.7%, the mass percent that resist accounts for oily material is 16.7%, the mass percent that wetting agent accounts for oily material is 16.7%, the mass percent that anticorrisive agent accounts for oily material is 16.5%, being added in stirs in the container can obtain oily material, this optical absorbing agent characteristics are environmental protection, easily be coated with, clean easily etc., the pottery that coats can be placed directly on the cutting machine and process, the absorption laser effect is fine, not disconnected optical phenomenon, cutting us directly is placed in the alcohol liquid and cleans and can remove, can not change the characteristic of pottery itself, do not have corrosion phenomenon yet, outward appearance with do not do the same that blacking handles, do not have what pollution;
S5, begin the cutting.
 
Embodiment 2: the difference of itself and embodiment 1 is,
The frequency of laser is 5kHz among the step S1, and pulsewidth is 10ms, and speed is 8mm/s, and focal height is 18000step;
Fumarole 6 diameters are 0.7mm among the step S2, and gas port 4 diameters are 0.5mm;
The volume ratio of oily material and acetone is 1:500 among the step S4, the mass percent that described pigment accounts for oily material is 10%, the mass percent that the pigment auxiliary agent accounts for oily material is 10%, the mass percent of stabilizer comprises oily material is 30%, the mass percent that resist accounts for oily material is 30%, the mass percent that wetting agent accounts for oily material is 10%, and the mass percent that anticorrisive agent accounts for oily material is 10%.
 
Embodiment 3: the difference of itself and embodiment 1 is,
The frequency of laser is 15kHz among the step S1, and pulsewidth is 50ms, and speed is 80mm/s, and focal height is 18000step;
Fumarole 6 diameters are 1mm among the step S2, and gas port 4 diameters are 0.8mm;
The volume ratio of oily material and acetone is 1:550 among the step S4, the mass percent that described pigment accounts for oily material is 30%, the mass percent that the pigment auxiliary agent accounts for oily material is 30%, the mass percent of stabilizer comprises oily material is 10%, the mass percent that resist accounts for oily material is 10%, the mass percent that wetting agent accounts for oily material is 10%, and the mass percent that anticorrisive agent accounts for oily material is 10%.
 
Embodiment 4: the difference of itself and embodiment 1 is,
The frequency of laser is 12kHz among the step S1, and pulsewidth is 20ms, and speed is 60mm/s, and focal height is 21000step;
Fumarole 6 diameters are 0.9mm among the step S2, and gas port 4 diameters are 0.7mm;
The volume ratio of oily material and acetone is 1:530 among the step S4, the mass percent that described pigment accounts for oily material is 10%, the mass percent that the pigment auxiliary agent accounts for oily material is 10%, the mass percent of stabilizer comprises oily material is 10%, the mass percent that resist accounts for oily material is 10%, the mass percent that wetting agent accounts for oily material is 30%, and the mass percent that anticorrisive agent accounts for oily material is 30%.
In the description of this specification, concrete feature, structure, material or characteristics that the description of reference term " embodiment ", " some embodiment ", " example ", " concrete example " or " some examples " etc. means in conjunction with this embodiment or example description are contained at least one embodiment of the present invention or the example.In this manual, the schematic statement to above-mentioned term not necessarily refers to identical embodiment or example.And concrete feature, structure, material or the characteristics of description can be with the suitable manner combination in any one or more embodiment or example.
Although illustrated and described embodiments of the invention, those having ordinary skill in the art will appreciate that: can carry out multiple variation, modification, replacement and modification to these embodiment under the situation that does not break away from principle of the present invention and aim, scope of the present invention is limited by claim and equivalent thereof.

Claims (4)

1. one kind is used for the ceramic absorbent of optical-fiber laser cutting, in the technological process of optical-fiber laser cutting pottery, absorbent is coated in ceramic surface, it is characterized in that, described absorbent is formed by oily material and acetone proportioning, and described oily material is formed by pigment, pigment auxiliary agent, stabilizing agent, resist, wetting agent and anticorrisive agent proportioning.
2. absorbent according to claim 1, it is characterized in that, described pigment adopts ferric tannate and gallic acid iron, described pigment auxiliary agent adopts dark blue dyestuff, described stabilizing agent adopts oxalic acid solution, described resist adopts the resin type cure polymer, and described wetting agent adopts glycerine, and described anticorrisive agent adopts the penta sodium pentachlorophenate medicament.
3. absorbent according to claim 2, it is characterized in that, the mass percent that described pigment accounts for oily material is 10% to 30%, the mass percent that the pigment auxiliary agent accounts for oily material is 10% to 30%, the mass percent of stabilizer comprises oily material is 10% to 30%, the mass percent that resist accounts for oily material is 10% to 30%, the mass percent that wetting agent accounts for oily material is 10% to 30%, the mass percent that anticorrisive agent accounts for oily material is 10% to 30%, and being added in stirs in the container can obtain oily material.
4. absorbent according to claim 1 is characterized in that, the volume ratio of described oily material and acetone be 1:500 to 1:550, stirring after the dilution gets final product.
CN201310134810.1A 2013-04-18 2013-04-18 Absorbent for cutting ceramics by aid of fiber laser Active CN103192199B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104646824A (en) * 2015-01-26 2015-05-27 武汉华工激光工程有限责任公司 Absorbent for ceramic laser cutting and preparation method for absorbent
CN105481473A (en) * 2015-12-08 2016-04-13 苏州德龙激光股份有限公司 Coating liquid for promoting infrared laser absorption capacity on ceramic, preparation method and application thereof
CN107903673A (en) * 2017-12-04 2018-04-13 南充三环电子有限公司 A kind of dyestuff for promoting ceramic substrate to absorb infrared laser
DE102020128772A1 (en) 2020-11-02 2022-05-05 Friedrich-Alexander-Universität Erlangen-Nürnberg - Selbstverwaltungskörperschaft des öffentlichen Rechts Process for pretreating and structuring an alumina-based substrate

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CN102372918A (en) * 2010-08-12 2012-03-14 湖南华曙高科技有限责任公司 Nylon/aluminum powder composite powdery material based on selective laser sintering
CN102513707A (en) * 2011-12-19 2012-06-27 深圳市木森科技有限公司 Method for cutting ceramic by laser
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EP0567129A2 (en) * 1992-04-23 1993-10-27 Sumitomo Electric Industries, Ltd. Method of working diamond
JPH0780670A (en) * 1993-09-17 1995-03-28 Fujitsu Ltd Resin film machining method by laser
CN1703773A (en) * 2002-06-03 2005-11-30 3M创新有限公司 Laminate body, method, and apparatus for manufacturing ultrathin substrate using the laminate body
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104646824A (en) * 2015-01-26 2015-05-27 武汉华工激光工程有限责任公司 Absorbent for ceramic laser cutting and preparation method for absorbent
CN105481473A (en) * 2015-12-08 2016-04-13 苏州德龙激光股份有限公司 Coating liquid for promoting infrared laser absorption capacity on ceramic, preparation method and application thereof
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CN107903673A (en) * 2017-12-04 2018-04-13 南充三环电子有限公司 A kind of dyestuff for promoting ceramic substrate to absorb infrared laser
DE102020128772A1 (en) 2020-11-02 2022-05-05 Friedrich-Alexander-Universität Erlangen-Nürnberg - Selbstverwaltungskörperschaft des öffentlichen Rechts Process for pretreating and structuring an alumina-based substrate

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