CN103173696A - Stainless steel hot-rolled steel plate - Google Patents

Stainless steel hot-rolled steel plate Download PDF

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Publication number
CN103173696A
CN103173696A CN2013100969788A CN201310096978A CN103173696A CN 103173696 A CN103173696 A CN 103173696A CN 2013100969788 A CN2013100969788 A CN 2013100969788A CN 201310096978 A CN201310096978 A CN 201310096978A CN 103173696 A CN103173696 A CN 103173696A
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China
Prior art keywords
stainless steel
steel plate
hot
less
rolled steel
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CN2013100969788A
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Chinese (zh)
Inventor
王�华
陈建东
张斌峰
高艳华
张立群
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YIXING HOKKAI HEAD PLATE CO Ltd
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YIXING HOKKAI HEAD PLATE CO Ltd
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Priority to CN2013100969788A priority Critical patent/CN103173696A/en
Publication of CN103173696A publication Critical patent/CN103173696A/en
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Abstract

The invention discloses a stainless steel hot-rolled steel plate. The stainless steel hot-rolled steel plate is characterized by containing the following components in percentage by weight: 0.05-0.09% of C, less than 1.00% of Si, less than 2.00% of Mn, 18.00-23.00% of Cr, 4.50-10.50% of Ni, less than 0.20% of N, 0-3.50% of Mo, less than 0.035% of P, S less than 0.020 of S and the balance of Fe and inevitable impurities. The hot-rolled stainless steel plate disclosed by the invention has the advantages of low rigidity, easiness for processing, good ductile property and high toughness and plasticity.

Description

The stainless steel hot rolled steel plate
Technical field
The present invention relates to a kind of stainless steel hot rolled steel plate.
Background technology
Stainless steel is a kind of special material, have the feature of functional materials and structured material concurrently, be widely used in industry and civilian various fields with the premium properties of the uniquenesses such as its stainless, anti-corrosion, heat-resisting, low temperature resistant, easy processing, recoverable, exquisite appearance, life cycle or cost are low.The whole world stainless steel amount of expending is also to increase year by year.
In stainless steel due to its excellent erosion resistance and anti-toughness and austenite stainless steel (austenitic stainless steel) SUS304 (18%Cr-8%Ni) (Japanese Industrial Standands, JIS G 4305) extensively is used.Although 304 stainless steels have good character, noble metal Ni content is up to 9%, thereby price is high.Along with the increase of stainless steel output, the nickel consumption also constantly increases in recent years, the more and more anxiety that nickel resources is become, and the nickel price sharp rises thereupon, and 304 stainless costs further increase.Affected by the nickel price increase, in order to reduce production costs, global enterprises of producing stainless steel is all at Devoting Major Efforts To Developing and development low nickel or without the stainless steel of nickel cheaply.
Austenitic stainless steel when containing Cr, Ni, C in steel, has stable austenite structure.Austenitic stainless steel is nonmagnetic and have high tenacity and plasticity.
Summary of the invention
The object of the present invention is to provide a kind of stainless steel hot rolled steel plate.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of stainless steel hot rolled steel plate is characterized in that, according to quality percentage composition meter, contain C:0.05-0.09%, below Si:1.00%, below Mn:2.00%, Cr:18.00-23.00%, Ni:4.50-10.50%, below N:0.20%, Mo:0-3.50% is below P:0.035%, below S:0.020%, all the other are Fe and inevitable impurity.
The present invention is according to quality percentage composition meter, C:0.005-0.019%, and below Si:0.75%, Cr:21.00-23.00%, Ni:4.50-6.50%, N:0.08-0.10% is below P:0.030%, below S:0.015%.
The present invention is according to quality percentage composition meter, also contains to be selected from the following or Ti:0.008% of Cu:0.5-1.0%, Co:1.0% with lower at least a.
Below, unless otherwise specified, the % of chemical composition all represents the meaning of quality percentage composition.
Beneficial effect of the present invention: hot-rolled stainless steel plate hardness of the present invention is low, handling ease, and ductility is good and have high tenacity and plasticity.
Embodiment
The invention will be further described below in conjunction with specific embodiment.
At first, the reason of the composition restriction of system stainless steel hot-rolled steel sheet of the present invention is described.
Below C:0.030%
C easily forms the Cr carbide, if surpass 0.030%, forms the Cr carbide at heat affected zone when welding, and becomes the reason of grain boundary corrosion.Therefore, C is made as below 0.030%, is preferably below 0.015%.When further requiring high corrosion resistance, more preferably be made as below 0.010%.
Below Si:1.00%
If Si surpasses 1.00% make toughness drop, therefore, Si is made as below 1.00%.Be preferably below 0.50%.Should illustrate, because Si is as the useful element of reductor, so preferably be made as more than 0.05%.
Below Mn:2.00%
In steelmaking process, manganese is good reductor and sweetening agent, improves intensity, can replace the interpolation of Ni, but concerning the process of refining, adds too much Mn meeting Eroded furnace wall.
Cr:18.00-23.00%
For the main interpolation element of stainless steel, generally more than 12%, because generating Cr2O3 passive state protective membrane, be the reason of stainless steel tool solidity to corrosion maximum, the increase of Cr content, the stability of protective membrane also promotes relatively.Can high temperature oxidation resisting.
Ni:4.50-10.50%
Improve the intensity of steel, and keep good plasticity and toughness.Nickel has higher corrosion resistance to soda acid, at high temperature has antirust and temperature capacity.But because nickel is more rare resource, therefore should adopt other alloying elements to substitute steel nickel chrome as far as possible.
Below N:0.20%
Nitrogen can improve the intensity of steel, and low-temperature flexibility and weldability increase aging sensitivity.
Mo:0-3.50%
Increase Mo and can strengthen the passive state film, be conducive to anti-pitting, improve the resistivity to chlorion; Mo more than 2% can effectively improve the benefit that anti-sulfuric acid corrodes; Also increase on the other hand sclerosis energy 4, ferrite phase SF Stability Factor.
Below P:0.035%
In the ordinary course of things, phosphorus is harmful element in steel, increases the cold shortness of steel, and welding property is degenerated, and reduces plasticity, and cold-bending property is degenerated.Therefore require usually that in steel, phosphorus content is less than 0.045%, the high-quality steel requires some more low.
Below S:0.020%
Sulphur is also harmful element under normal conditions.Make steel produce red brittleness, reduce ductility and the toughness of steel, become crackle when rolling forging.Sulphur is also unfavorable to welding property, reduces erosion resistance.So usually require sulphur content less than 0.055%, the high-quality steel requires less than 0.040%.The sulphur that adds 0.08-0.20% in steel can improve machinability, usually claims free-cutting steel.
Stainless steel hot rolled steel plate of the present invention must obtain the purpose characteristic by element because of above-mentioned, but can also contain following element according to desirable characteristic.
Cu:0.5-1.0%
Cu is for the element that improves erosion resistance, particularly effective element aspect the reduction crevice corrosion.In order to bring into play this effect, be necessary for more than 0.3%.The Cu too high levels, hot workability reduces.Therefore, Cu is made as 0.5-1.0%.
Below Co:1.0%
Co is the element that helps to improve toughness.In order to obtain this effect, Co is preferably more than 0.05%.But, if surpass 1.0%, ductility is reduced.Therefore, Co is made as below 1.0%.
Ti:0.008%
Ti forms thick nitride, reduces toughness, therefore, Ti is made as below 0.015%, is preferably below 0.010%, further requires in the situation of high tenacity.More preferably be made as below 0.008%.
Embodiment 1
The stainless steel hot-rolling steel plate thickness of the present embodiment is 4mm, wide 1800mm, its chemical composition mass percent is: C:0.022%, Si:0.40%, Mn:0.30%, Cr:18.5%, Ni:4.60%, N:0.092%, Mo:2.65%, P:0.026%, S:0.006%, all the other are Fe and inevitable impurity.
Embodiment 2
The stainless steel hot-rolling steel plate thickness of the present embodiment is 10mm, wide 1600mm, its chemical composition mass percent is: C:0.012%, Si:0.270%, Mn:0.10%, Cr:21.60%, Ni:6.20%, N:0.18%, Mo:3.15%, P:0.012%, S:0.002%, all the other are Fe and inevitable impurity.
Embodiment 3
The stainless steel hot-rolling steel plate thickness of the present embodiment is 6mm, wide 1800mm, its chemical composition mass percent is: C:0.023%, Si:0.49%, Mn:1.15 %, Cr:19.6%, Ni:10.3%, N:0.03%, Mo:2.06%, P:0.030%, S:0.002%, all the other are Fe and inevitable impurity.
Embodiment 4
The stainless steel hot-rolling steel plate thickness of the present embodiment is 4mm, wide 1500mm, its chemical composition mass percent is: C:0.015%, Si:0.62%, Mn:0.53%, Cr:18.0%, Ni:8.00%, N:0.14%, Mo:0.02%, P:0.02%, S:0.001%, all the other are Fe and inevitable impurity.
Embodiment 5
The stainless steel hot-rolling steel plate thickness of the present embodiment is 8mm, wide 2000mm, its chemical composition mass percent is: C:0.02%, Si:0.54%, Mn:1.06%, Cr:21.1%, Ni:9.01%, N:0.08%, Mo:0.08%, P:0.033%, S:0.010%, all the other are Fe and inevitable impurity.
Embodiment 6
The stainless steel hot-rolling steel plate thickness of the present embodiment is 22mm, wide 2000mm, its chemical composition mass percent is: C:0.019%, Si:0.60%, Mn:0.90%, Cr:22.2%, Ni:9.14%, N:0.10%, Mo:0.00%, P:0.02%, S:0.001%, all the other are Fe and inevitable impurity.
Embodiment 7
The stainless steel hot-rolling steel plate thickness of the present embodiment is 4mm, wide 1500mm, its chemical composition mass percent is: C:0.005%, Si:0.80%, Mn:1.54%, Cr:22.6%, Ni:10.0%, N:0.03%, Mo:2.03%, P:0.031%, S:0.008%, all the other are Fe and inevitable impurity.
The embodiment of stainless steel hot rolled steel plate of the present invention and 304 stainless steel mechanical performance compares see Table 1.
Figure BDA0000295923701
Relatively see Table 2 with 304 stainless pitting corrosion resistances.
Material Average weightless g/m 2·h
Embodiment one 12.7
Embodiment two 12.8
Embodiment three 14.4
Embodiment four 12.8
Embodiment five 12.5
Embodiment six 12.9
Embodiment seven 13.1
304 11.6

Claims (3)

1. a stainless steel hot rolled steel plate, is characterized in that, according to quality percentage composition meter, contain below C:0.030 %, below Si:1.00%, below Mn:2.00%, Cr:18.00-23.00%, Ni:4.50-10.50%, below N:0.20%, Mo:0-3.50% is below P:0.035%, below S:0.020%, all the other are Fe and inevitable impurity.
2. stainless steel hot rolled steel plate according to claim 1, is characterized in that, according to quality percentage composition meter, C:0.005-0.019%, below Si:0.75%, Cr:21.00-23.00%, Ni:4.50-6.50%, N:0.08-0.10% is below P:0.030%, below S:0.015%.
3. stainless steel hot rolled steel plate according to claim 1 and 2, is characterized in that, according to quality percentage composition meter, also contains and be selected from the following or Ti:0.008% of Cu:0.5-1.0%, Co:1.0% with lower at least a.
CN2013100969788A 2013-03-25 2013-03-25 Stainless steel hot-rolled steel plate Pending CN103173696A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103526133A (en) * 2013-09-27 2014-01-22 泰州永兴合金材料科技有限公司 High nickel-chromium and free-cutting stainless steel and preparation method thereof
CN104197105A (en) * 2014-08-28 2014-12-10 安徽中臣机电装备科技有限公司 Stainless steel pipe
CN104451430A (en) * 2014-11-13 2015-03-25 湖北宏盛不锈钢制品有限公司 Stainless steel wire with high toughness
CN105970116A (en) * 2016-05-30 2016-09-28 苏州双金实业有限公司 Steel being good in plastic property
CN109355596A (en) * 2018-12-22 2019-02-19 中南大学 A kind of cupric hafnium cobalt high corrosion-resisting austenite stainless steel and its process and heat treatment method
CN115725897A (en) * 2021-08-26 2023-03-03 生生国际(香港)有限公司 Cold-rolled stainless steel material and container made of same
CN115820992A (en) * 2022-12-01 2023-03-21 江苏长新电工机械集团有限公司 High-strength wear-resistant steel for flange and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63309307A (en) * 1987-06-12 1988-12-16 Nippon Steel Corp Method for hot rolling to control crystal grains of austenitic stainless steel
CN101748342A (en) * 2008-11-28 2010-06-23 宝山钢铁股份有限公司 High-strength 18Cr-8Ni stainless steel hot rolled plate and manufacturing method thereof
CN102199734A (en) * 2010-03-26 2011-09-28 宝山钢铁股份有限公司 High-strength 301L stainless steel used for bus, and manufacture method thereof
CN102605284A (en) * 2011-01-25 2012-07-25 宝山钢铁股份有限公司 Duplex stainless steel and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63309307A (en) * 1987-06-12 1988-12-16 Nippon Steel Corp Method for hot rolling to control crystal grains of austenitic stainless steel
CN101748342A (en) * 2008-11-28 2010-06-23 宝山钢铁股份有限公司 High-strength 18Cr-8Ni stainless steel hot rolled plate and manufacturing method thereof
CN102199734A (en) * 2010-03-26 2011-09-28 宝山钢铁股份有限公司 High-strength 301L stainless steel used for bus, and manufacture method thereof
CN102605284A (en) * 2011-01-25 2012-07-25 宝山钢铁股份有限公司 Duplex stainless steel and manufacturing method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103526133A (en) * 2013-09-27 2014-01-22 泰州永兴合金材料科技有限公司 High nickel-chromium and free-cutting stainless steel and preparation method thereof
CN104197105A (en) * 2014-08-28 2014-12-10 安徽中臣机电装备科技有限公司 Stainless steel pipe
CN104451430A (en) * 2014-11-13 2015-03-25 湖北宏盛不锈钢制品有限公司 Stainless steel wire with high toughness
CN105970116A (en) * 2016-05-30 2016-09-28 苏州双金实业有限公司 Steel being good in plastic property
CN109355596A (en) * 2018-12-22 2019-02-19 中南大学 A kind of cupric hafnium cobalt high corrosion-resisting austenite stainless steel and its process and heat treatment method
CN109355596B (en) * 2018-12-22 2022-03-18 佛山培根细胞新材料有限公司 Copper-hafnium-cobalt-containing high-corrosion-resistance austenitic stainless steel and processing and heat treatment method thereof
CN115725897A (en) * 2021-08-26 2023-03-03 生生国际(香港)有限公司 Cold-rolled stainless steel material and container made of same
CN115820992A (en) * 2022-12-01 2023-03-21 江苏长新电工机械集团有限公司 High-strength wear-resistant steel for flange and preparation method thereof
CN115820992B (en) * 2022-12-01 2023-11-28 江苏长新电工机械集团有限公司 High-strength wear-resistant steel for flange and preparation method thereof

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Application publication date: 20130626