CN103160943B - Insulation and heat insulation fiber and textile prepared by fiber thereof - Google Patents
Insulation and heat insulation fiber and textile prepared by fiber thereof Download PDFInfo
- Publication number
- CN103160943B CN103160943B CN201310069899.8A CN201310069899A CN103160943B CN 103160943 B CN103160943 B CN 103160943B CN 201310069899 A CN201310069899 A CN 201310069899A CN 103160943 B CN103160943 B CN 103160943B
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- Prior art keywords
- fiber
- insulation
- weight
- weight cell
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
- D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
Abstract
The invention relates to an insulation and heat insulation fiber and a textile prepared by the fiber, the insulation and heat insulation fiber is characterized in that a nano unit which accounts for 0.1-3wt% of routine textile fabric total weight is added for increasing the insulation rate of fiber, the nano unit comprises the corpuscules with 300-8000 nano, the corpuscules comprise a mixture of two at random or a plurality of elements of Al, Zn, Sb, Na, Fe and Si. Because that the nano unit with a certain proportion of 300-8000 nano corpuscules is added in the routine textile fabric, compared with the textiles with same weight and weaving method, the fiber of the present invention can greatly enhance the heat insulating ability and clo value of the textile, compared with current insulation fiber, the insulation and heat insulation fiber has the advantages of low manufacture cost, simple manufacturing process and easy industrial production.
Description
Technical field
The present invention relates to a kind of textile fabric and textiles, the textiles particularly relating to a kind of insulation fiber and be made up of this fiber.
Background technology
In prior art, the insulation of most conventional textile fabric and textiles is that consumption by increasing fiber and the thickness improving fiber textile and weight improve its heat-insulating property; Such as, the main flow cold-proof underwear that existing market is sold all has the problem that weight is comparatively large, thickness is thicker, in the comfortableness of dress, has the defect being difficult to make up.
In addition, part prior art is also had to have employed heat-storing material to improve the heat insulating ability of fiber textile.So-called heat-storing material be exactly a kind of can the new chemical material of heat energy storage.There is thing phase change in it, and along with absorption or releasing heat, can be used to the temperature controlling surrounding environment within specified temperatures, or in order to heat energy storage.Its principle and technical scheme and insulation have significant otherness; Such as, hygroscopic heating fibers is wherein a kind of.Hygroscopic heating fibers has good hygroscopicity, and the kinetic transformation of hydrone human body can discharged is heat energy, thus improves sendible temperature, and the rising due to temperature makes again the steam of discharging more easily evaporate.
But hygroscopic heating fibers is also more limited to the raising of textiles heat insulating ability, meanwhile, the cost of this kind of fiber is also comparatively high.
Summary of the invention
The object of the invention is to propose that a kind of heat insulating ability is better, cost is cheaper and the insulation fiber conveniently manufacturing, be easy to industrialized implementation and the textiles be made up of this fiber.
For achieving the above object, the invention provides a kind of insulation fiber, the insulation rate that the nano unit accounting for conventional textile fibers gross weight 0.1 ~ 3% weight portion improves fiber is added in conventional textile fibers, described nano unit comprises the particulate of 300 ~ 8000 nanometers, and described particulate to comprise in Al, Zn, Sb, Na, Fe, Si two or more mixture arbitrarily.
Preferably, described conventional textile fibers comprises chemical fibre, and described chemical fibre comprises artificial fibre and/or synthetic fiber.
More preferably, the particulate of 300 ~ 4000 nanometers accounting for gross weight 1.5 ~ 3% weight portion is comprised.
Further, in described nano unit, described particulate comprises the Al of 300 ~ 500 weight cell and the Na of 30 ~ 100 weight cell, or the Fe of the Sb of 30 ~ 500 weight cell and 10 ~ 500 weight cell, or the mixture of at least one group in the Si of the Zn of 100 ~ 1000 weight cell and 50 ~ 3000 weight cell.
Preferably, described insulation fiber comprises the particulate of 4000 ~ 8000 nanometers accounting for gross weight 0.1 ~ 1.5% weight portion.
More preferably, in described nano unit, described particulate comprises the Al of 300 ~ 500 weight cell and the Fe of 10 ~ 500 weight cell, or the Na of the Zn of 100 ~ 1000 weight cell and 30 ~ 100 weight cell, or the mixture of at least one group in the Si of the Sb of 30 ~ 500 weight cell and 50 ~ 3000 weight cell.
Further, in described nano unit, described particulate also comprises the S of the K of 50 ~ 100 weight cell, the Sn of 100 ~ 500 weight cell and 50 ~ 100 weight cell.
Another object of the present invention is to the textiles providing a kind of insulation, this textiles at least comprises the above-mentioned insulation fiber of part.
Another object of the present invention is to provide a kind of fiber containing nano unit preparing the application in Thermal textile product, and the described fiber containing nano unit is above-mentioned arbitrary insulation fiber.
Based on technique scheme, advantage of the present invention is:
Because the present invention adds a certain proportion of 300 ~ 8000 nano-corpuscule nano units in conventional textile fibers, make fiber of the present invention when contrasting the textiles of identical grammes per square metre and weave, significantly can improve heat insulating ability and the clo value of textiles, and the present invention is for existing insulation fibre, has that manufacturing cost is lower, manufacturing technique is simple, be easy to suitability for industrialized production etc. advantage.
Accompanying drawing explanation
Accompanying drawing described herein is used to provide a further understanding of the present invention, and form a application's part, schematic description and description of the present invention, for explaining the present invention, does not form inappropriate limitation of the present invention.In the accompanying drawings:
Fig. 1 is the insulation rate contrast figure of testing result in the embodiment of the present invention 1.
Detailed description of the invention
Below by drawings and Examples, technical scheme of the present invention is described in further detail.
Embodiment 1:
See table 1 and Fig. 1, the detection embodiment of a kind of insulation fiber thermal insulation of the present invention shown in it effect.
(1) title is detected: heat insulating ability is tested
(2) experiment purpose: test heat insulating ability fibre and fabric, in order to improve the heat insulating ability of goods and fabric, by injecting the air do not readily not conducted heat between fiber, suppresses it to dispel the heat.
(3) experimental technique: the experiment carried out based on " dried rhizome of rehmannia experimental technique of JIS L1096 fabric and volume thing ".Use heat insulating ability experimental machine, setting uniform temperature (36 ± 0.5 DEG C) hot plate and experiment slice are one group; After 2 hours, obtain the heat a that experiment slice diffuses.In addition, then obtain experiment slice not with under the state of hot plate combo, the heat b diffused out after 2 hours, calculates insulation rate (%) by following formula:
Insulation rate (%)=(1-a/b) × 100
(4) unit is detected: Japanese legal testing agency---east cause institute of general juridical person BOKEN Fang Jian quality evaluation mechanism
(5) sample is detected:
5.1-fiber sample of the present invention:
The textile fabric accounting for conventional textile fibers gross weight 2.9% weight portion nano unit is added, particle size about 300 nanometer of this nano unit in conventional textile fibers; Described particulate comprises the aluminium (Al) of 500 weight cell and the sodium (Na) of 30 weight cell, and conventionally needs other trace elements of interpolation.
Nano unit of the present invention can adopt in existing textile fabric manufacturing technology any one add.Preparation method of the present invention comprises the steps: A, the polymer substance of natural polymer substance or inorganic matter (as: viscose) or synthesis or inorganic matter (as: polyamide fibre or acrylic fibers) is made spinning melt or solution; B, in described spinning melt or solution, add above-mentioned nano unit Al and Na; C, to extrude through thread spraying structure, form fiber.Other processing steps are identical with the fiber producing processes of prior art, do not repeat them here.
It should be noted that, the weight cell ratio of above-mentioned nano unit Al and Na also can be other arbitrary ratios, the present inventor has carried out a large amount of repeating test, the nano unit of various ratio all makes fibre have good heat insulating ability, and the present embodiment one group of experimental data that only have selected in numerous experiment is explained (lower same).
In addition, particulate of the present invention can be oxide under normal temperature state or nitride, also can for other can the form of stable existence, such as compound or monomer.
It should be noted that: " weight cell " of the present invention is preferably the weight ratio of " micro-g/kg ", can certainly measure according to the actual requirements and carry out weighing (lower same) according to other unit of weight.
5.2-contrast experiment:
The sample of contrast experiment 1: the moisture absorption heating underwear that strong sales is forever sold, detection method is identical with above-mentioned " experimental technique ";
The sample of contrast experiment 2: the moisture absorption heating underwear that excellent clothing storehouse is sold, detection method is identical with above-mentioned " experimental technique ";
The sample of contrast experiment 3: the happy moisture absorption heating underwear sold of decorations dream, detection method is identical with above-mentioned " experimental technique ";
The sample of contrast experiment 4: the full flannels that Ito-Yokado sells, detection method is identical with above-mentioned " experimental technique ";
The sample of contrast experiment 5: 100% cashmere sweater that excellent clothing storehouse is sold, detection method is identical with above-mentioned " experimental technique ".
(6) testing result:
Table 1: textiles heat insulating ability measured data
The insulation rate contrast figure of above-mentioned testing result is see shown in accompanying drawing 1, wherein, as can be seen from the present invention and contrast test 1,2,3 relatively in: under identical grammes per square metre, the insulation rate of the textiles that fiber of the present invention obtains is more than 2 times of other market sale moisture absorption heating underwear insulation rates; It should be noted that: " grammes per square metre " is that weaving silk product evaluates conventional unit, and be the weight of every square meter, unit is " gram/m "; Grammes per square metre is the important technical indicator of of knit fabric.
Further, in contrast test 1,2,3, the insulation rate of textiles exceeds much than the insulation rate of underwear most on market.
According to the regulation of China's " FZ/T73022-2004 knitting thermal underwear ", the finished product external packing of cold-proof underwear must indicate the indexs such as insulation rate, content, and wherein " insulation rate " must not lower than 30%; In fact, most so-called cold-proof underwear is all improve its insulation rate by increasing grammes per square metre number (namely by increasing thickness and the weight of underwear).
And by the obtained textiles of insulation fiber of the present invention, obtain beyond thought technique effect and be: the present invention adopts the grammes per square metre number of common underwear, but reaches far away higher than the insulation rate of cold-proof underwear.
Even see in table 1 and Fig. 1, as can be seen from the comparing of the present invention and contrast test 4,5: under the grammes per square metre much smaller than wool product and cashmere product, the insulation rate of the textiles that fiber of the present invention obtains, more taller than the warming rate of wool product and cashmere product go out many.In other words, the underwear that insulation fiber of the present invention is obtained, can have the purposes of alternative woollen sweater and cashmere sweater.
It should be noted that the difference between " heat storing and heat preserving " in " insulation " of the present invention and prior art: accumulation of heat only provides energy by external heat source (or material of generate heat inside) to accumulating product, and carry out the process of store heat by accumulating product; And the operation principle of insulation fiber of the present invention is reflected via nano unit as much as possible by the heat of human body, and keep isolating with external environment.In addition, above-mentioned experiment of the present invention is all test for the heat insulating ability of underwear textiles, there is no energy supplement or the supply of external heat source (light source such as such as sunlight), therefore, the application in Thermal textile product prepared by the fiber that the present invention also belongs to containing nano unit.
Embodiment 2:
The difference of the present embodiment and above-described embodiment is, detecting sample is in conventional textile fibers, add the textile fabric accounting for conventional textile fibers gross weight 0.2% weight portion nano unit, particle size about 8000 nanometer of this nano unit; Described particulate comprises the aluminium (Al) of 300 weight cell and the sodium (Na) of 100 weight cell, and the potassium of 100 weight cell (K), the tin (Sn) of 100 weight cell and the sulphur (S) of 100 weight cell.Nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacture.
The testing result of the present embodiment is: grammes per square metre is 150(g/m
2) containing the textiles of insulation fiber of the present invention, its insulation rate is 43.2%; Other contrast experiments are identical with embodiment 1, do not repeat them here.
The insulation rate contrast figure of the present embodiment testing result: slightly.
Embodiment 3:
The difference of the present embodiment and above-described embodiment is, detecting sample is in conventional textile fibers, add the textile fabric accounting for gross weight 1.5% weight portion nano unit, particle size about 4000 nanometer of this nano unit; Described particulate comprises the antimony (Sb) of 500 weight cell, and the iron of 10 weight cell (Fe), and nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacture.
The testing result of the present embodiment is: grammes per square metre is 150(g/m
2) containing the textiles of insulation fiber of the present invention, its insulation rate is 43.5%; Other contrast experiments are identical with embodiment 1, do not repeat them here.
The insulation rate contrast figure of the present embodiment testing result: slightly.
Embodiment 4:
The difference of the present embodiment and above-described embodiment is, detecting sample is in conventional textile fibers, add the textile fabric accounting for gross weight 1.6% weight portion nano unit, particle size about 5000 nanometer of this nano unit; Described particulate comprises the antimony (Sb) of 30 weight cell and the iron (Fe) of 500 weight cell, and 80 potassium (K) of weight cell, the tin (Sn) of 300 weight cell and the sulphur (S) of 70 weight cell, nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacture.
The testing result of the present embodiment is: grammes per square metre is 150(g/m
2) containing the textiles of insulation fiber of the present invention, its insulation rate is 43.1%; Other contrast experiments are identical with embodiment 1, do not repeat them here.
The insulation rate contrast figure of the present embodiment testing result: slightly.
In addition, the present embodiment additionally uses the preparation method of another kind of insulation fiber, comprises the preparation process of textile fabric chemical fibre master batch, in the preparation process of chemical fibre master batch, adds above-mentioned nano unit, then produces fiber.Other processing steps of the present embodiment fiber producing processes are identical with the fiber producing processes of prior art, do not repeat them here.
Embodiment 5:
The difference of the present embodiment and above-described embodiment is, detecting sample is in conventional textile fibers, add the textile fabric accounting for gross weight 1.8% weight portion nano unit, particle size about 3000 nanometer of this nano unit; Described particulate comprises the antimony (Sb) of the zinc (Zn) of 1000 weight cell, the silicon (Si) of 50 weight cell, the aluminium (Al) of 400 weight cell, the sodium (Na) of 50 weight cell and 300 weight cell; And 50 potassium (K) of weight cell, the tin (Sn) of 500 weight cell and the sulphur (S) of 50 weight cell, nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacture.
The testing result of the present embodiment is: grammes per square metre is 150(g/m
2) containing the textiles of insulation fiber of the present invention, its insulation rate is 43.7%; Other contrast experiments are identical with embodiment 1, do not repeat them here.
The insulation rate contrast figure of the present embodiment testing result: slightly.
Other embodiments:
The present inventor, according to the experimental technique of above-described embodiment, has tested successively:
Nano unit combination between the Al of 300 ~ 500 weight cell and the Fe of 10 ~ 500 weight cell;
Nano unit combination between the Zn of 100 ~ 1000 weight cell and the Na of 30 ~ 100 weight cell;
Nano unit combination between the Sb of 30 ~ 500 weight cell and the Si of 50 ~ 3000 weight cell;
In addition, inventor is also to the nano unit combination of above-mentioned nano unit more than more than three kinds, carry out same experiment to detect, its result is: grammes per square metre is 150(g/m2) containing the textiles of the corresponding insulation fiber of the present invention, its insulation rate is not 40.2 ~ 43.7% not etc., because experimental data amount is comparatively large, no longer particularize again; Other contrast experiments are identical with embodiment 1, do not repeat them here.
In addition, another object of the present invention is to provide a kind of textiles of insulation, such as knitting or tatting product, in this textiles, at least comprises the fiber that part is above-mentioned, certainly, also can all use insulation fiber of the present invention to make.
Obviously, those of ordinary skill in the art, with a kind of insulation fiber of the present invention and the textiles be made up of this fiber, can form various types of textile fabric, textiles and corresponding preparation method.
Finally should be noted that: above embodiment is only in order to illustrate that technical scheme of the present invention is not intended to limit; Although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the field are to be understood that: still can modify to the specific embodiment of the present invention or carry out equivalent replacement to portion of techniques feature; And not departing from the spirit of technical solution of the present invention, it all should be encompassed in the middle of the technical scheme scope of request of the present invention protection.
Claims (9)
1. a particulate is preparing the application in insulation fiber, it is characterized in that: in conventional textile fibers, add the insulation rate that the nano unit accounting for conventional textile fibers gross weight 0.1 ~ 3% weight portion improves fiber, described nano unit comprises the particulate of 300 ~ 8000 nanometers, and described particulate to comprise in Al, Zn, Sb, Na, Fe, Si two or more mixture arbitrarily.
2. application according to claim 1, is characterized in that: described conventional textile fibers comprises chemical fibre, and described chemical fibre comprises artificial fibre and/or synthetic fiber.
3. application according to claim 2, is characterized in that: the particulate comprising 300 ~ 4000 nanometers accounting for gross weight 1.5 ~ 3% weight portion.
4. application according to claim 3, it is characterized in that: in described nano unit, described particulate comprises the Al of 300 ~ 500 weight cell and the Na of 30 ~ 100 weight cell, or the Fe of the Sb of 30 ~ 500 weight cell and 10 ~ 500 weight cell, or the mixture of at least one group in the Si of the Zn of 100 ~ 1000 weight cell and 50 ~ 3000 weight cell.
5. application according to claim 2, is characterized in that: the particulate comprising 4000 ~ 8000 nanometers accounting for gross weight 0.1 ~ 1.5% weight portion.
6. application according to claim 5, it is characterized in that: in described nano unit, described particulate comprises the Al of 300 ~ 500 weight cell and the Fe of 10 ~ 500 weight cell, or the Na of the Zn of 100 ~ 1000 weight cell and 30 ~ 100 weight cell, or the mixture of at least one group in the Si of the Sb of 30 ~ 500 weight cell and 50 ~ 3000 weight cell.
7. the application according to claim 4 or 6, is characterized in that: in described nano unit, and described particulate also comprises the S of the K of 50 ~ 100 weight cell, the Sn of 100 ~ 500 weight cell and 50 ~ 100 weight cell.
8. a textiles for insulation, is characterized in that: this textiles at least comprises the insulation fiber described in the above-mentioned any one claim of part.
9. the fiber containing nano unit, preparing the application in Thermal textile product, is characterized in that, the described fiber containing nano unit is the insulation fiber described in above-mentioned any one claim.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310069899.8A CN103160943B (en) | 2013-03-05 | 2013-03-05 | Insulation and heat insulation fiber and textile prepared by fiber thereof |
| JP2015503746A JP5985041B2 (en) | 2013-03-05 | 2013-04-11 | Thermal insulation fiber and its fabric |
| PCT/CN2013/074112 WO2014134856A1 (en) | 2013-03-05 | 2013-04-11 | Thermal insulation fibre and textile made therefrom |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310069899.8A CN103160943B (en) | 2013-03-05 | 2013-03-05 | Insulation and heat insulation fiber and textile prepared by fiber thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103160943A CN103160943A (en) | 2013-06-19 |
| CN103160943B true CN103160943B (en) | 2015-05-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310069899.8A Expired - Fee Related CN103160943B (en) | 2013-03-05 | 2013-03-05 | Insulation and heat insulation fiber and textile prepared by fiber thereof |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5985041B2 (en) |
| CN (1) | CN103160943B (en) |
| WO (1) | WO2014134856A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103147143B (en) * | 2013-03-05 | 2014-12-17 | 毛盈军 | Heat-insulation fiber and textile produced by same |
| CN104664634A (en) * | 2015-03-03 | 2015-06-03 | 北京厚文知识产权顾问有限公司 | Health-care underwear with local heating and warming functions |
| CN104664635A (en) * | 2015-03-03 | 2015-06-03 | 北京厚文知识产权顾问有限公司 | Health-care underwear with local heating and warming functions |
| CN105648560B (en) * | 2016-01-06 | 2017-12-08 | 江苏智光创业投资有限公司 | fabric |
| CN105463667B (en) * | 2016-01-06 | 2017-10-10 | 绍兴柯桥东进纺织有限公司 | A kind of weaving face fabric |
| CN106319662A (en) * | 2016-11-15 | 2017-01-11 | 李光武 | Heat insulation and preservation fiber, and preparation method and application thereof |
| JP6464245B1 (en) * | 2017-09-20 | 2019-02-06 | ▲緑▼能奈米科技有限公司 | Underwear to enhance the masculine function of far-infrared fibers |
| TWI698563B (en) * | 2018-12-25 | 2020-07-11 | 南亞塑膠工業股份有限公司 | Heat-insulating dark-cooling fiber and textiles made therefrom |
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| CN102747440A (en) * | 2012-05-14 | 2012-10-24 | 毛盈军 | Fibers with characteristics of temperature increasing and heat storage, preparation method and textile thereof |
| CN102747448A (en) * | 2012-05-14 | 2012-10-24 | 毛盈军 | Naturally warming and heating fiber under humid condition, preparation method thereof, and textile product thereof |
| CN102747445A (en) * | 2012-05-14 | 2012-10-24 | 毛盈军 | Cooling and chilling fiber, preparation method thereof, and textile product thereof |
| CN102747449A (en) * | 2012-05-14 | 2012-10-24 | 毛盈军 | Warming and heat-storing fiber, preparation method thereof, and textile product thereof |
| CN102747443A (en) * | 2012-05-14 | 2012-10-24 | 毛盈军 | Fibers with characteristics of temperature increasing and heat storage, preparation method and textile thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103160943A (en) | 2013-06-19 |
| WO2014134856A1 (en) | 2014-09-12 |
| JP2015518527A (en) | 2015-07-02 |
| JP5985041B2 (en) | 2016-09-06 |
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