CN102677203B - Heating thermal storage fiber and preparation method as well as textile thereof - Google Patents
Heating thermal storage fiber and preparation method as well as textile thereof Download PDFInfo
- Publication number
- CN102677203B CN102677203B CN201210148038.4A CN201210148038A CN102677203B CN 102677203 B CN102677203 B CN 102677203B CN 201210148038 A CN201210148038 A CN 201210148038A CN 102677203 B CN102677203 B CN 102677203B
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- Prior art keywords
- fiber
- preparation
- weight
- particulate
- heat
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
Abstract
The invention relates to a heating thermal storage fiber and a preparation method as well as a textile thereof. The heating thermal storage fiber comprises a conventional textile fiber and a nanometer unit which occupies 0.1-3% by weight of the total weight. The nanometer unit comprises 300-8000 nanometer micro-particles; and the micro-particles contain titanium, sulphur and a mixture of the titanium and the sulphur. As a certain proportion of nanometer unit comprising the 300-8000 nanometer micro-particles is added to the conventional textile fiber, the fiber provided by the invention has the unexpected fast heating effect under light under the same illumination time and illumination intensity; simultaneously, the fiber provided by the invention has better thermal storage property in comparison with the conventional chemical fiber after illumination is ended; and compared with the traditional heating fiber, the fiber provided by the invention has the advantages of lower manufacturing cost, simple manufacturing process, easy industrial production and the like and is a novel better heating fiber material under a lower temperature environment.
Description
Technical field
The present invention relates to a kind of textile fabric and preparation method thereof, particularly relate to fiber of a kind of accumulation of heat that heats up and preparation method thereof and textiles.
Background technology
The insulation of traditional fibre and textiles is the thermal runaway stoping health to send is master.Along with the reach of science, people also develop the fiber except partly having heating function, such as:
1. fibre electroheating
A kind of warmth-retaining clothing material of Japan's trial-production is the composite fibre utilizing thermo electric material to participate in composition, and its principle, as electric blanket, utilizes conductive fiber to be energized and fiber generated heat, to reach the effect of heating.With the clothes that this fiber is made, the unlined garment that outer likeness in form one is very thin, be an electrically-heated suit in fact, the energy is from the rechargeable battery carried with, and in the winter of cold, it is heat endlessly, is enough to resist severe cold.
The defect of this kind of fibre electroheating is, manufacturing cost is high, needs to carry rechargeable battery and powers, and uses rather inconvenience in daily life.
2. sun velvet
Sun velvet is the representative material of a new generation of making according to space wadding principle.It is by traditional abundant suede of 100% wool fibre, is fluffyly placed between two-layer soft lens face, it is made to form the controlled thermal convection current barrier layer (air bag) of thin and thick, its thermal conductivity factor is extremely low, has reflex to the heat ray of human body simultaneously, achieves effect of double warm.Because in air bag, gas content accounts for 90%, thus sun velvet not only light softness but also warming.Fibre weight fewer than cotton 2/3 in its unit volume, fewer than eider down 4/5, the clothes made are attractive in appearance and not too fat to move.Its Crow (clo) value is 3.062 after testing.Two-layer minute surface has micropore to be opened/closed, and as the pore of skin, expansible heat radiation during heat, can close insulation again time cold, temperature is adjustable and have gas permeability, is the desirable dress material of autumn and winter.
This kind of sun velvet material also has manufacturing technique complexity, with high costs, is difficult to the defects such as industrialization.
3. chemistry insulation, temperature-regulating fiber
Someone utilizes chemical method to produce insulation, temperature-regulating fiber.Such as have a kind of with the fluid-tight film of one deck, the textiles of in-built sodium sulphate, can liquefy storage heat after sodium sulphate is heated, and its heat-retaining is stronger than water 60 times, thus sendible temperature is declined; And sodium sulphate can solidify when meeting cold, the heat of absorption is come out simultaneously.
This kind of material is after making textiles, and easily in daily life due to various scratch, collision and produce leakage, therefore, its practicality needs to improve further.
Summary of the invention
The object of the invention is to propose a kind of easily manufactured, with low cost, intensification thermal storage fiber of being easy to industrialized implementation and preparation method thereof and textiles.
For achieving the above object, the invention provides a kind of fiber of the accumulation of heat that heats up, described fiber comprises conventional textile fibers and accounts for the nano unit of gross weight 0.1 ~ 3% weight portion, described nano unit comprises the particulate of 300 ~ 8000 nanometers, and described particulate comprises titanium, sulphur or their mixture.
Preferably, described conventional textile fibers comprises chemical fibre, and described chemical fibre comprises artificial fibre and/or synthetic fiber.
More preferably, the particulate of 300 ~ 4000 nanometers accounting for gross weight 1.5 ~ 3% weight portion is comprised.
Further, in described nano unit, described particulate comprises the titanium of 500 ~ 10000 weight cell and the sulphur of 50 ~ 100 weight cell.
Preferably, the particulate of 4000 ~ 8000 nanometers accounting for gross weight 0.1 ~ 1.5% weight portion is comprised.
More preferably, in described nano unit, described particulate comprises the titanium of 500 ~ 10000 weight cell and the sulphur of 50 ~ 100 weight cell.
Preferably, in described nano unit, described particulate also comprises the silicon of 50 ~ 3000 weight cell and the iron of 10 ~ 500 weight cell.
Another object of the present invention is to provide a kind of light of meeting to be rapidly heated and the preparation method of the textile fabric of accumulation of heat, described preparation method comprises the steps: A, the polymer substance of natural polymer substance or inorganic matter or synthesis or inorganic matter is made spinning melt or solution; B, in described spinning melt or solution, add above-mentioned nano unit; C, to extrude through thread spraying structure, form fiber.
Another object of the present invention is to provide a kind of light of meeting to be rapidly heated and the preparation method of the textile fabric of accumulation of heat, and described preparation method comprises the preparation process of textile fabric chemical fibre master batch, in the preparation process of chemical fibre master batch, adds above-mentioned nano unit.
Another object of the present invention is to provide a kind of light of meeting to be rapidly heated and the textiles of accumulation of heat, it is characterized in that: this textiles at least comprises the above-mentioned fiber of part.
Based on technique scheme, advantage of the present invention is:
Because the present invention adds the particulate nano unit of certain proportion 300 ~ 8000 nanometer in conventional textile fibers, make fiber of the present invention under identical light application time and intensity of illumination, there is unforeseeable chance light to be rapidly heated effect, simultaneously, fiber of the present invention is after illumination stops, than conventional chemical fibre, also there is better heat storage performance, and the present invention is for existing heat generating fiber, having that manufacturing cost is lower, manufacturing technique is simple, be easy to suitability for industrialized production etc. advantage, is type of heat fibrous material preferably at low ambient temperatures.
Accompanying drawing explanation
Accompanying drawing described herein is used to provide a further understanding of the present invention, and form a application's part, schematic description and description of the present invention, for explaining the present invention, does not form inappropriate limitation of the present invention.In the accompanying drawings:
Fig. 1 is the checkout gear of the technology of the present invention effect;
Fig. 2 is the Temperature-time change curve of measuring method in embodiment 1.
Detailed description of the invention
Below by drawings and Examples, technical scheme of the present invention is described in further detail.
Embodiment 1:
See Fig. 1, the detection embodiment of the fiber heating effect of a kind of accumulation of heat that heats up of the present invention shown in it.
Detect unit: the general nearly Ji office of juridical person BOKEN quality evaluation structure of Japan
Quality test report is numbered: 11604789-1
Test item: temperature measuring, test method is as follows:
1, sample is detected
1.: fiber of the present invention: for adding the textile fabric accounting for gross weight 2.9% weight portion nano unit in conventional textile fibers, particle size about 300 nanometer of this nano unit; Described particulate comprises the titanium of 9000 weight cell and the sulphur (also only can add one wherein) of 90 weight cell, and other trace elements, nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacture.
2.: control group fiber: not containing the conventional textile fibers of nano unit.
It should be noted that: " weight cell " of the present invention is preferably the weight ratio of " micro-g/kg ", also can weigh according to other weight cell according to actual needs.
2, detection method:
As shown in Figure 1, fabric S to be measured for the fiber of two pieces of stratiforms is placed on foamed plastics table top C, at fabric S(15cm × 15cm to be measured) inner side of middle body arranges thermocouple thermometer B, and measured once fabric S to be measured variations in temperature under light illumination according to following condition every 20 minutes:
Use light source: the PRF-500WB reflectoscope A that PANASONIC is produced;
Irradiation distance: L=30cm;
Condition determination: first irradiate 10 minutes with reflectoscope A, close reflectoscope at once, and continue to measure for 10 minutes under the state of not irradiating;
Measure environment: 20 DEG C, 65%RH;
Assay method: first measured together by two pieces of fabrics to be measured, again measure after then exchanging the position of two pieces of fabrics to be measured, the mean value finally calculating twice mensuration draws result of the test.
3, the laboratory test results of above-mentioned sample is:
The Temperature-time relation curve of above-mentioned testing result is see shown in accompanying drawing 2, wherein, fiber of the present invention is comprised in the fabric to be measured that the Curves that upper position is higher is corresponding, and for not comprising the common textile fabric of fiber of the present invention in fabric to be measured corresponding to the lower Curves of lower position.
Can be drawn by the above-mentioned detection architecture of general juridical person BOKEN quality evaluation structure nearly Ji office of this Japan, the present invention heats up the fiber of accumulation of heat under identical intensity of illumination and light application time, than conventional chemical fibre, there is more significant, the unforeseeable effect that is rapidly heated, simultaneously, after illumination stops, than conventional chemical fibre, also there is better heat storage performance, as shown in Figure 2.
Embodiment 2:
The difference of the present embodiment and above-described embodiment is, detecting sample is in conventional textile fibers, add the textile fabric accounting for gross weight 0.2% weight portion nano unit, particle size about 8000 nanometer of this nano unit; Described particulate comprises the titanium of 500 weight cell, and the iron of the silicon of 3000 weight cell and 12 weight cell, and nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacture.
Such as: the present embodiment have employed a kind of light of meeting and is rapidly heated and the preparation method of textile fabric of accumulation of heat, comprise the steps: A, the polymer substance of natural polymer substance or inorganic matter (as: viscose) or synthesis or inorganic matter (as: polyamide fibre or acrylic fibers) are made spinning melt or solution; B, in described spinning melt or solution, add above-mentioned nano unit; C, to extrude through thread spraying structure, form fiber.Other processing steps are identical with the fiber producing processes of prior art, do not repeat them here.
The laboratory test results of this sample is:
The Temperature-time relation curve of the present embodiment testing result: slightly.
Embodiment 3:
The difference of the present embodiment and above-described embodiment is, detecting sample is in conventional textile fibers, add the textile fabric accounting for gross weight 1.5% weight portion nano unit, particle size about 4000 nanometer of this nano unit; Described particulate comprises the sulphur of 55 weight cell, and the iron of the silicon of 50 weight cell and 500 weight cell, and nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacture.
Such as: the present embodiment have employed a kind of light of meeting and is rapidly heated and the preparation method of the textile fabric of accumulation of heat, comprises the preparation process of textile fabric chemical fibre master batch, in the preparation process of chemical fibre master batch, adds above-mentioned nano unit, then produce fiber.Other processing steps of the present embodiment fiber producing processes are identical with the fiber producing processes of prior art, do not repeat them here.
The laboratory test results of this sample is:
The Temperature-time relation curve of the present embodiment testing result: slightly.
Because existing textile technology limit, the present invention adopts the nano unit adding 300 ~ 8000 nanometers of 0.1 ~ 3% weight portion in conventional chemical fiber, has unexpected chance light be rapidly heated and the beneficial effect of accumulation of heat to make new chemical fibre.But under it will be understood by those skilled in the art that the prerequisite allowed in textile technology, can add the nano unit of more weight part and/or less nano particle, its chemical fibre formed also will have good heating, accumulation of heat effect.
In addition, another object of the present invention is to provide a kind of light of meeting and is rapidly heated and the textiles of accumulation of heat, and such as knitting or tatting product, in this textiles, at least comprises the fiber that part is above-mentioned, certainly, also can all use the heat up fiber of accumulation of heat of the present invention to make.
Obviously, those of ordinary skill in the art, with fiber of a kind of accumulation of heat that heats up of the present invention and preparation method thereof and textiles, can form various types of textile fabric, textiles and preparation method thereof.
Finally should be noted that: above embodiment is only in order to illustrate that technical scheme of the present invention is not intended to limit; Although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the field are to be understood that: still can modify to the specific embodiment of the present invention or carry out equivalent replacement to portion of techniques feature; And not departing from the spirit of technical solution of the present invention, it all should be encompassed in the middle of the technical scheme scope of request of the present invention protection.
Claims (9)
1. the application of mixture in preparation intensification thermal storage fiber of particulate titanium, sulphur, described fiber also comprises conventional textile fibers and accounts for the nano unit of gross weight 0.1 ~ 3% weight portion, described nano unit comprises the particulate of 300 ~ 8000 nanometers, and described particulate comprises the mixture of titanium, sulphur.
2. application according to claim 1, is characterized in that: described conventional textile fibers comprises chemical fibre, and described chemical fibre comprises artificial fibre and/or synthetic fiber.
3. application according to claim 2, is characterized in that: the particulate comprising 300 ~ 4000 nanometers accounting for gross weight 1.5 ~ 3% weight portion.
4. application according to claim 3, is characterized in that: in described nano unit, and described particulate comprises the titanium of 500 ~ 10000 weight cell and the sulphur of 50 ~ 100 weight cell.
5. application according to claim 2, is characterized in that: the particulate comprising 4000 ~ 8000 nanometers accounting for gross weight 0.1 ~ 1.5% weight portion.
6. application according to claim 5, is characterized in that: in described nano unit, and described particulate comprises the titanium of 500 ~ 10000 weight cell and the sulphur of 50 ~ 100 weight cell.
7. meet light to be rapidly heated and a preparation method for the textile fabric of accumulation of heat, it is characterized in that: described preparation method comprises the steps:
A, the polymer substance of natural polymer substance or inorganic matter or synthesis or inorganic matter are made spinning melt or solution;
B, in described spinning melt or solution, add the nano unit described in any one claim in claim 1 ~ 6;
C, to extrude through thread spraying structure, form fiber.
8. meet light and be rapidly heated and the preparation method of textile fabric of accumulation of heat for one kind, it is characterized in that: described preparation method comprises the preparation process of textile fabric chemical fibre master batch, in the preparation process of chemical fibre master batch, add the nano unit described in any one claim in claim 1 ~ 6.
9. meet light to be rapidly heated and a textiles for accumulation of heat, it is characterized in that: this textiles chance light at least comprised in Partial rights requirement 7 or 8 described in any one claim is rapidly heated and the textile fabric of accumulation of heat.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210148038.4A CN102677203B (en) | 2012-05-14 | 2012-05-14 | Heating thermal storage fiber and preparation method as well as textile thereof |
| PCT/CN2012/080093 WO2013170543A1 (en) | 2012-05-14 | 2012-08-14 | Temperature-raising, heat-preserving fiber and preparation method therefor, and textile product |
| TW101130583A TW201346083A (en) | 2012-05-14 | 2012-08-23 | A heat storage fiber with rapid temperature-rising effect, a method for preparing the same, and a fabric containing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210148038.4A CN102677203B (en) | 2012-05-14 | 2012-05-14 | Heating thermal storage fiber and preparation method as well as textile thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102677203A CN102677203A (en) | 2012-09-19 |
| CN102677203B true CN102677203B (en) | 2015-01-21 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210148038.4A Expired - Fee Related CN102677203B (en) | 2012-05-14 | 2012-05-14 | Heating thermal storage fiber and preparation method as well as textile thereof |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN102677203B (en) |
| TW (1) | TW201346083A (en) |
| WO (1) | WO2013170543A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102747444B (en) * | 2012-05-14 | 2014-12-17 | 毛盈军 | Fibers with characteristics of temperature reducing and cooling, preparation method and textile thereof |
| CN103147143B (en) * | 2013-03-05 | 2014-12-17 | 毛盈军 | Heat-insulation fiber and textile produced by same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709511A (en) * | 2009-11-26 | 2010-05-19 | 毛盈军 | Chemical fiber quickly increasing temperature and heating when encountering light and textile containing fiber |
| CN102115920A (en) * | 2009-12-31 | 2011-07-06 | 天津市赛远保健品有限公司 | Synthetic fibre with functions of heat storage, warm keeping and health protection and preparation method thereof |
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| JPS60252712A (en) * | 1984-05-28 | 1985-12-13 | Teijin Ltd | Fiber for heat-insulation material |
| JPH03190990A (en) * | 1989-12-20 | 1991-08-20 | Toshio Komuro | Powder for radiation of infrared ray-weak energy and synthetic fiber containing same powder |
| JPH059804A (en) * | 1991-06-28 | 1993-01-19 | Kuraray Co Ltd | Synthetic fiber having excellent heat-accumulating and heat-insulation property |
| JP3205358B2 (en) * | 1991-08-01 | 2001-09-04 | 忠雄 一色 | Hot spring medical substance-containing fiber |
| JPH09217272A (en) * | 1996-02-02 | 1997-08-19 | Asahi Chem Ind Co Ltd | Fiber product |
| JP3664585B2 (en) * | 1998-03-26 | 2005-06-29 | 株式会社クラレ | Fiber with excellent heat radiation |
| CN1103385C (en) * | 2000-04-10 | 2003-03-19 | 天津工业大学 | Autoamtic temp-regulating fibre and its products |
| JP2008045240A (en) * | 2006-08-17 | 2008-02-28 | Shiontekku:Kk | Functional fiber and method for producing the same, and textile product |
| CN101070626A (en) * | 2007-06-12 | 2007-11-14 | 江苏盛虹化纤有限公司 | Micro biochemical jade fibre |
| CN101665987A (en) * | 2009-09-28 | 2010-03-10 | 海安县中山合成纤维有限公司 | Alloy germanium chinlon filament and production method thereof |
-
2012
- 2012-05-14 CN CN201210148038.4A patent/CN102677203B/en not_active Expired - Fee Related
- 2012-08-14 WO PCT/CN2012/080093 patent/WO2013170543A1/en active Application Filing
- 2012-08-23 TW TW101130583A patent/TW201346083A/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709511A (en) * | 2009-11-26 | 2010-05-19 | 毛盈军 | Chemical fiber quickly increasing temperature and heating when encountering light and textile containing fiber |
| CN102115920A (en) * | 2009-12-31 | 2011-07-06 | 天津市赛远保健品有限公司 | Synthetic fibre with functions of heat storage, warm keeping and health protection and preparation method thereof |
Non-Patent Citations (4)
| Title |
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| "蓄热调温纤维及其在非织造材料中的应用";王向钦等;《非织造布》;20060831;第14卷(第4期);第33-35页 * |
| JP特开平11-279830A 1999.10.12 * |
| 伍玉娇."11.1纯钛".《金属材料学》.北京大学出版社,2011,(第1版),第296-298页. * |
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Also Published As
| Publication number | Publication date |
|---|---|
| TW201346083A (en) | 2013-11-16 |
| WO2013170543A1 (en) | 2013-11-21 |
| CN102677203A (en) | 2012-09-19 |
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