CN103160943A - Insulation and heat insulation fiber and textile prepared by fiber thereof - Google Patents
Insulation and heat insulation fiber and textile prepared by fiber thereof Download PDFInfo
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- CN103160943A CN103160943A CN2013100698998A CN201310069899A CN103160943A CN 103160943 A CN103160943 A CN 103160943A CN 2013100698998 A CN2013100698998 A CN 2013100698998A CN 201310069899 A CN201310069899 A CN 201310069899A CN 103160943 A CN103160943 A CN 103160943A
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- fiber
- insulation
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- weight cell
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Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
- D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
Abstract
The invention relates to an insulation and heat insulation fiber and a textile prepared by the fiber, the insulation and heat insulation fiber is characterized in that a nano unit which accounts for 0.1-3wt% of routine textile fabric total weight is added for increasing the insulation rate of fiber, the nano unit comprises the corpuscules with 300-8000 nano, the corpuscules comprise a mixture of two at random or a plurality of elements of Al, Zn, Sb, Na, Fe and Si. Because that the nano unit with a certain proportion of 300-8000 nano corpuscules is added in the routine textile fabric, compared with the textiles with same weight and weaving method, the fiber of the present invention can greatly enhance the heat insulating ability and clo value of the textile, compared with current insulation fiber, the insulation and heat insulation fiber has the advantages of low manufacture cost, simple manufacturing process and easy industrial production.
Description
Technical field
The present invention relates to a kind of textile fabric and textiles, the textiles that particularly relates to a kind of insulation fiber and made by this fiber.
Background technology
In prior art, the insulation of most traditional textile fibers and textiles is to improve its heat-insulating property by the consumption that increases fiber and the thickness and the weight that improve fiber textile; For example, the main flow cold-proof underwear that existing market is sold all has the problem that weight is large, thickness is thicker, aspect the comfortableness of dress, has the defective that is difficult to make up.
In addition, also there is the part prior art to adopt heat-storing material to improve the heat insulating ability of fiber textile.So-called heat-storing material is exactly a kind of new chemical material that can heat energy storage.It issues the biofacies variation in specific temperature, and is accompanied by absorption or emits heat, can be used to control the temperature of surrounding environment, or in order to heat energy storage.Its principle and technical scheme and insulation have significant otherness; For example, hygroscopic heating fibers is wherein a kind of.Hygroscopic heating fibers has good hygroscopicity, and the kinetic transformation of the hydrone that human body can be discharged is heat energy, thereby improves sendible temperature, because the rising of temperature makes again the steam of discharge more easily evaporate.
But hygroscopic heating fibers is also more limited to the raising of textiles heat insulating ability, and simultaneously, the cost of this kind fiber is also comparatively high.
Summary of the invention
The objective of the invention is to propose that a kind of heat insulating ability is better, cost is cheaper and conveniently make, be easy to the insulation fiber of industrialized implementation and the textiles of being made by this fiber.
For achieving the above object, the invention provides a kind of insulation fiber, add the insulation rate of the nano unit raising fiber that accounts for conventional textile fabric gross weight 0.1～3% weight portion in conventional textile fabric, described nano unit comprises the particulate of 300～8000 nanometers, and described particulate comprises in Al, Zn, Sb, Na, Fe, Si two or more mixture arbitrarily.
Preferably, described conventional textile fabric comprises chemical fibre, and described chemical fibre comprises artificial fibre and/or synthetic fiber.
More preferably, the particulate that comprises 300～4000 nanometers that account for gross weight 1.5～3% weight portions.
Further, in described nano unit, described particulate comprises the Al of 300～500 weight cell and the Na of 30～100 weight cell, the perhaps Fe of the Sb of 30～500 weight cell and 10～500 weight cell, the perhaps mixture of at least one group in the Si of the Zn of 100～1000 weight cell and 50～3000 weight cell.
Preferably, described insulation fiber comprises the particulate of 4000～8000 nanometers that account for gross weight 0.1～1.5% weight portion.
More preferably, in described nano unit, described particulate comprises the Al of 300～500 weight cell and the Fe of 10～500 weight cell, the perhaps Na of the Zn of 100～1000 weight cell and 30～100 weight cell, the perhaps mixture of at least one group in the Si of the Sb of 30～500 weight cell and 50～3000 weight cell.
Further, in described nano unit, described particulate also comprises the K of 50～100 weight cell, the Sn of 100～500 weight cell and the S of 50～100 weight cell.
Another object of the present invention is to provide a kind of textiles of insulation, this textiles comprises the insulation fiber that part is above-mentioned at least.
Another purpose of the present invention is to provide a kind of application of fiber in preparation Thermal textile product that contains nano unit, and the described fiber that contains nano unit is the above-mentioned fiber of insulation arbitrarily.
Based on technique scheme, advantage of the present invention is:
A certain proportion of 300～8000 nano-corpuscule nano units have been added in conventional textile fabric due to the present invention, make fiber of the present invention when the textiles of the identical grammes per square metre of contrast and weave, can significantly improve heat insulating ability and the clo value of textiles, and the present invention is for existing insulation fibre, has that manufacturing cost is lower, manufacturing technique simple, be easy to suitability for industrialized production etc. advantage.
Description of drawings
Accompanying drawing described herein is used to provide a further understanding of the present invention, consists of the application's a part, and illustrative examples of the present invention and explanation thereof are used for explaining the present invention, do not consist of improper restriction of the present invention.In the accompanying drawings:
Fig. 1 is the insulation rate contrast figure of testing result in the embodiment of the present invention 1.
The specific embodiment
Below by drawings and Examples, technical scheme of the present invention is described in further detail.
Embodiment 1:
Referring to table 1 and Fig. 1, the detection embodiment of a kind of insulation fiber thermal insulation of the present invention shown in it effect.
(1) detect title: the heat insulating ability experiment
(2) experiment purpose: fibre and fabric are tested heat insulating ability, in order to improve the heat insulating ability of goods and fabric, will to injecting the air that does not readily conduct heat between fiber, be suppressed its heat radiation.
(3) experimental technique: take " dried rhizome of rehmannia experimental technique of JIS L1096 fabric and volume thing " as the basic experiment of carrying out.Use the heat insulating ability experimental machine, setting uniform temperature (36 ± 0.5 ℃) hot plate and experiment slice is one group; After 2 hours, obtain the heat a that experiment slice diffuses.In addition, then obtain experiment slice not with the state of hot plate combo under, the heat b through diffusing out after 2 hours, calculate insulation rate (%) by following formula:
Insulation rate (%)=(1-a/b) * 100
(4) detecting unit: Japanese legal testing agency---general juridical person BOKEN spins and examines east cause institute of quality evaluation mechanism
(5) test sample:
5.1-fiber sample of the present invention:
Added the textile fabric that accounts for conventional textile fabric gross weight 2.9% weight portion nano unit in conventional textile fabric, the particle size of this nano unit is 300 nanometers approximately; Described particulate comprises the aluminium (Al) of 500 weight cell and the sodium (Na) of 30 weight cell, and other trace elements that need to add according to prior art.
Nano unit of the present invention can adopt any one in existing textile fabric manufacturing technology to add.Preparation method of the present invention comprises the steps: A, natural polymer substance or inorganic matter (as: viscose) or synthetic polymer substance or inorganic matter (as: polyamide fibre or acrylic fibers) is made spinning melt or solution; B, add above-mentioned nano unit Al and Na in described spinning melt or solution; C, extrude through thread spraying structure, form fiber.Other processing steps are identical with the fiber preparation method of prior art, do not repeat them here.
Need to prove, the weight cell ratio of above-mentioned nano unit Al and Na also can be other arbitrary ratios, the present inventor has carried out a large amount of repeated tests, the nano unit of various ratios all makes fibre have heat insulating ability preferably, and the present embodiment has only selected one group of experimental data in numerous experiments to explain (down together).
In addition, particulate of the present invention can be the oxide under the normal temperature state or nitride, also can for other can stable existence form, for example compound or monomer.
Need to prove: " weight cell " of the present invention is preferably the weight ratio of " microgram/kilogram ", can certainly measure according to the actual requirements according to other unit of weight and carry out weighing (lower same).
5.2-contrast experiment:
Contrast experiment 1 sample: the moisture absorption heating underwear that strong sales is forever sold, detection method is identical with above-mentioned " experimental technique ";
Contrast experiment 2 sample: the moisture absorption heating underwear of excellent clothing storehouse sale, detection method is identical with above-mentioned " experimental technique ";
Contrast experiment 3 sample: the happy moisture absorption heating underwear of selling of decorations dream, detection method is identical with above-mentioned " experimental technique ";
Contrast experiment 4 sample: the full flannels that Ito-Yokado sells, detection method is identical with above-mentioned " experimental technique ";
Contrast experiment 5 sample: 100% cashmere sweater of excellent clothing storehouse sale, detection method is identical with above-mentioned " experimental technique ".
(6) testing result:
Table 1: textiles heat insulating ability measured data
The insulation rate contrast figure of above-mentioned testing result is referring to shown in accompanying drawing 1, wherein, from the present invention and contrast test 1,2,3 relatively can find out: under identical grammes per square metre, the insulation rate of the textiles that fiber of the present invention makes is more than 2 times of other market sale moisture absorption heating underwear insulation rates; Need to prove: " grammes per square metre " is that the weaving silk product is estimated conventional unit, is the weight of every square metre of fabric, unit be " g/m "; Grammes per square metre is an important technical indicator of knit fabric.
Further, in contrast test 1,2,3, the insulation rate of textiles exceeds much than the insulation rate of most underwears on market.
According to the regulation of China's " FZ/T73022-2004 knitting thermal underwear ", must indicate the indexs such as insulation rate, content in the finished product external packing of cold-proof underwear, wherein " insulation rate " must not be lower than 30%; In fact, most so-called cold-proof underwears are all to improve its insulation rate by increasing grammes per square metre number (namely by increasing thickness and the weight of underwear).
And the textiles that made by insulation fiber of the present invention, the beyond thought technique effect that obtains is: the present invention adopts the grammes per square metre number of common underwear, has but reached far away the insulation rate higher than cold-proof underwear.
Even referring in table 1 and Fig. 1, from the present invention and contrast test 4,5 relatively can find out: under the grammes per square metre of wool product and cashmere product, the insulation rate of the textiles that fiber of the present invention makes, than the warming rate of wool product and cashmere product taller go out many.In other words, the underwear that insulation fiber of the present invention makes can have the purposes of alternative woollen sweater and cashmere sweater.
Need to prove the difference between " heat storing and heat preserving " in " insulation " of the present invention and prior art: accumulation of heat is only to provide energy by external heat source (or inner material that produces heat) to the accumulation of heat product, and is carried out the process of store heat by the accumulation of heat product; And the operation principle of insulation fiber of the present invention to be heat with human body reflect via nano unit as much as possible, and keep isolation with external environment.In addition, above-mentioned experiment of the present invention is all the heat insulating ability experiments for the underwear textiles, there is no energy supplement or the supply of extraneous thermal source (such as light sources such as sunlight), therefore, the present invention also belongs to the application of fiber in preparation Thermal textile product that contains nano unit.
Embodiment 2:
The difference of the present embodiment and above-described embodiment is, test sample is to have added the textile fabric that accounts for conventional textile fabric gross weight 0.2% weight portion nano unit in conventional textile fabric, and the particle size of this nano unit is 8000 nanometers approximately; Described particulate comprises the aluminium (Al) of 300 weight cell and the sodium (Na) of 100 weight cell, and the potassium of 100 weight cell (K), the tin (Sn) of 100 weight cell and the sulphur (S) of 100 weight cell.Nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacturing.
The testing result of the present embodiment is: grammes per square metre is 150(g/m
2) the textiles that contains insulation fiber of the present invention, its insulation rate is 43.2%; Other contrast experiments are identical with embodiment 1, do not repeat them here.
The insulation rate contrast figure of the present embodiment testing result: slightly.
Embodiment 3:
The difference of the present embodiment and above-described embodiment is, test sample is to have added the textile fabric that accounts for gross weight 1.5% weight portion nano unit in conventional textile fabric, and the particle size of this nano unit is 4000 nanometers approximately; Described particulate comprises the antimony (Sb) of 500 weight cell, and the iron of 10 weight cell (Fe), and nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacturing.
The testing result of the present embodiment is: grammes per square metre is 150(g/m
2) the textiles that contains insulation fiber of the present invention, its insulation rate is 43.5%; Other contrast experiments are identical with embodiment 1, do not repeat them here.
The insulation rate contrast figure of the present embodiment testing result: slightly.
Embodiment 4:
The difference of the present embodiment and above-described embodiment is, test sample is to have added the textile fabric that accounts for gross weight 1.6% weight portion nano unit in conventional textile fabric, and the particle size of this nano unit is 5000 nanometers approximately; Described particulate comprises the antimony (Sb) of 30 weight cell and the iron (Fe) of 500 weight cell, and the potassium of 80 weight cell (K), the tin (Sn) of 300 weight cell and the sulphur (S) of 70 weight cell, nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacturing.
The testing result of the present embodiment is: grammes per square metre is 150(g/m
2) the textiles that contains insulation fiber of the present invention, its insulation rate is 43.1%; Other contrast experiments are identical with embodiment 1, do not repeat them here.
The insulation rate contrast figure of the present embodiment testing result: slightly.
In addition, the present embodiment has also adopted the preparation method of another kind of insulation fiber, comprises the preparation process of textile fabric chemical fibre master batch, in the preparation process of chemical fibre master batch, adds above-mentioned nano unit, then produces fiber.Other processing steps of the present embodiment fiber preparation method are identical with the fiber preparation method of prior art, do not repeat them here.
Embodiment 5:
The difference of the present embodiment and above-described embodiment is, test sample is to have added the textile fabric that accounts for gross weight 1.8% weight portion nano unit in conventional textile fabric, and the particle size of this nano unit is 3000 nanometers approximately; Described particulate comprises the zinc (Zn) of 1000 weight cell, the silicon (Si) of 50 weight cell, the aluminium (Al) of 400 weight cell, the sodium (Na) of 50 weight cell and the antimony (Sb) of 300 weight cell; And the potassium of 50 weight cell (K), the tin (Sn) of 500 weight cell and the sulphur (S) of 50 weight cell, nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacturing.
The testing result of the present embodiment is: grammes per square metre is 150(g/m
2) the textiles that contains insulation fiber of the present invention, its insulation rate is 43.7%; Other contrast experiments are identical with embodiment 1, do not repeat them here.
The insulation rate contrast figure of the present embodiment testing result: slightly.
Other embodiment:
The present inventor has tested successively according to the experimental technique of above-described embodiment:
Nano unit combination between the Fe of the Al of 300～500 weight cell and 10～500 weight cell;
Nano unit combination between the Na of the Zn of 100～1000 weight cell and 30～100 weight cell;
Nano unit combination between the Si of the Sb of 30～500 weight cell and 50～3000 weight cell;
In addition, the inventor also makes up more than the nano unit more than three kinds above-mentioned nano unit, having carried out same experiment detects, its result is: grammes per square metre is 150(g/m2) the textiles that contains the corresponding insulation fiber of the present invention, its insulation rate is 40.2～43.7% not wait, because the experimental data amount is larger, particularize no longer again; Other contrast experiments are identical with embodiment 1, do not repeat them here.
In addition, another object of the present invention is to provide a kind of textiles of insulation, and for example knitting or tatting product, in this textiles, comprise the fiber that part is above-mentioned at least, certainly, also can all use insulation fiber of the present invention to make.
Obviously, those of ordinary skill in the art can with a kind of insulation fiber of the present invention and by the textiles that this fiber is made, consist of various types of textile fabrics, textiles and corresponding preparation method.
Should be noted that at last: above embodiment is only in order to illustrate that technical scheme of the present invention is not intended to limit; Although with reference to preferred embodiment, the present invention is had been described in detail, those of ordinary skill in the field are to be understood that: still can modify or the part technical characterictic is equal to replacement the specific embodiment of the present invention; And not breaking away from the spirit of technical solution of the present invention, it all should be encompassed in the middle of the technical scheme scope that the present invention asks for protection.
Claims (9)
1. insulation fiber, it is characterized in that: add the insulation rate that the nano unit that accounts for conventional textile fabric gross weight 0.1～3% weight portion improves fiber in conventional textile fabric, described nano unit comprises the particulate of 300～8000 nanometers, and described particulate comprises in Al, Zn, Sb, Na, Fe, Si two or more mixture arbitrarily.
2. insulation fiber according to claim 1, it is characterized in that: described conventional textile fabric comprises chemical fibre, and described chemical fibre comprises artificial fibre and/or synthetic fiber.
3. insulation fiber according to claim 2, is characterized in that: the particulate that comprises 300～4000 nanometers that account for gross weight 1.5～3% weight portions.
4. insulation fiber according to claim 3, it is characterized in that: in described nano unit, described particulate comprises the Al of 300～500 weight cell and the Na of 30～100 weight cell, the perhaps Fe of the Sb of 30～500 weight cell and 10～500 weight cell, the perhaps mixture of at least one group in the Si of the Zn of 100～1000 weight cell and 50～3000 weight cell.
5. insulation fiber according to claim 2, is characterized in that: the particulate that comprises 4000～8000 nanometers that account for gross weight 0.1～1.5% weight portion.
6. insulation fiber according to claim 5, it is characterized in that: in described nano unit, described particulate comprises the Al of 300～500 weight cell and the Fe of 10～500 weight cell, the perhaps Na of the Zn of 100～1000 weight cell and 30～100 weight cell, the perhaps mixture of at least one group in the Si of the Sb of 30～500 weight cell and 50～3000 weight cell.
7. according to claim 4 or 6 described insulation fibers, it is characterized in that: in described nano unit, described particulate also comprises the K of 50～100 weight cell, the Sn of 100～500 weight cell and the S of 50～100 weight cell.
8. the textiles of an insulation, it is characterized in that: this textiles comprises the described fiber of the above-mentioned any one claim of part at least.
9. the application of fiber in preparation Thermal textile product that contains nano unit, is characterized in that, the described fiber that contains nano unit is the described insulation fiber of above-mentioned any one claim.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310069899.8A CN103160943B (en) | 2013-03-05 | 2013-03-05 | Insulation and heat insulation fiber and textile prepared by fiber thereof |
| JP2015503746A JP5985041B2 (en) | 2013-03-05 | 2013-04-11 | Thermal insulation fiber and its fabric |
| PCT/CN2013/074112 WO2014134856A1 (en) | 2013-03-05 | 2013-04-11 | Thermal insulation fibre and textile made therefrom |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310069899.8A CN103160943B (en) | 2013-03-05 | 2013-03-05 | Insulation and heat insulation fiber and textile prepared by fiber thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103160943A true CN103160943A (en) | 2013-06-19 |
| CN103160943B CN103160943B (en) | 2015-05-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310069899.8A Expired - Fee Related CN103160943B (en) | 2013-03-05 | 2013-03-05 | Insulation and heat insulation fiber and textile prepared by fiber thereof |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5985041B2 (en) |
| CN (1) | CN103160943B (en) |
| WO (1) | WO2014134856A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104664634A (en) * | 2015-03-03 | 2015-06-03 | 北京厚文知识产权顾问有限公司 | Health-care underwear with local heating and warming functions |
| CN104664635A (en) * | 2015-03-03 | 2015-06-03 | 北京厚文知识产权顾问有限公司 | Health-care underwear with local heating and warming functions |
| CN105463667A (en) * | 2016-01-06 | 2016-04-06 | 长兴翎耀纺织有限公司 | Textile fabric |
| CN105648560A (en) * | 2016-01-06 | 2016-06-08 | 长兴翎耀纺织有限公司 | Novel fabric |
| EP2966198A4 (en) * | 2013-03-05 | 2016-09-28 | Yingjun Mao | Thermal insulation fibre and textile made therefrom |
| CN106319662A (en) * | 2016-11-15 | 2017-01-11 | 李光武 | Heat insulation and preservation fiber, and preparation method and application thereof |
| CN111364111A (en) * | 2018-12-25 | 2020-07-03 | 南亚塑胶工业股份有限公司 | Heat-insulating dark color cool textile and dark color cool fiber thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP6464245B1 (en) * | 2017-09-20 | 2019-02-06 | ▲緑▼能奈米科技有限公司 | Underwear to enhance the masculine function of far-infrared fibers |
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| CN111364111A (en) * | 2018-12-25 | 2020-07-03 | 南亚塑胶工业股份有限公司 | Heat-insulating dark color cool textile and dark color cool fiber thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2015518527A (en) | 2015-07-02 |
| JP5985041B2 (en) | 2016-09-06 |
| WO2014134856A1 (en) | 2014-09-12 |
| CN103160943B (en) | 2015-05-20 |
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