CN103141500A - Insect killing and sterilizing composition containing tiadinil - Google Patents
Insect killing and sterilizing composition containing tiadinil Download PDFInfo
- Publication number
- CN103141500A CN103141500A CN2013100912614A CN201310091261A CN103141500A CN 103141500 A CN103141500 A CN 103141500A CN 2013100912614 A CN2013100912614 A CN 2013100912614A CN 201310091261 A CN201310091261 A CN 201310091261A CN 103141500 A CN103141500 A CN 103141500A
- Authority
- CN
- China
- Prior art keywords
- composition
- component
- tiadinil
- rice
- insect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 103
- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 241000238631 Hexapoda Species 0.000 title claims abstract description 27
- 230000001954 sterilising effect Effects 0.000 title abstract 2
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 28
- 150000001408 amides Chemical class 0.000 claims abstract description 7
- DSOOGBGKEWZRIH-UHFFFAOYSA-N nereistoxin Chemical compound CN(C)C1CSSC1 DSOOGBGKEWZRIH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003120 macrolide antibiotic agent Substances 0.000 claims abstract description 5
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 3
- 239000002728 pyrethroid Substances 0.000 claims abstract description 3
- 239000000375 suspending agent Substances 0.000 claims abstract description 3
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 3
- 235000007164 Oryza sativa Nutrition 0.000 claims description 41
- 235000009566 rice Nutrition 0.000 claims description 41
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 31
- 201000010099 disease Diseases 0.000 claims description 30
- 239000000470 constituent Substances 0.000 claims description 19
- 241000607479 Yersinia pestis Species 0.000 claims description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- 239000005906 Imidacloprid Substances 0.000 claims description 11
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims description 11
- 229940056881 imidacloprid Drugs 0.000 claims description 11
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims description 10
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 claims description 10
- CFRPSFYHXJZSBI-DHZHZOJOSA-N (E)-nitenpyram Chemical compound [O-][N+](=O)/C=C(\NC)N(CC)CC1=CC=C(Cl)N=C1 CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 claims description 10
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 claims description 10
- HOKKPVIRMVDYPB-UVTDQMKNSA-N (Z)-thiacloprid Chemical compound C1=NC(Cl)=CC=C1CN1C(=N/C#N)/SCC1 HOKKPVIRMVDYPB-UVTDQMKNSA-N 0.000 claims description 10
- 239000005875 Acetamiprid Substances 0.000 claims description 10
- 239000005888 Clothianidin Substances 0.000 claims description 10
- 240000008067 Cucumis sativus Species 0.000 claims description 10
- 239000005940 Thiacloprid Substances 0.000 claims description 10
- 229940079888 nitenpyram Drugs 0.000 claims description 10
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 10
- 241000008892 Cnaphalocrocis patnalis Species 0.000 claims description 9
- 230000000844 anti-bacterial effect Effects 0.000 claims description 9
- 230000006378 damage Effects 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims description 8
- 239000005925 Pymetrozine Substances 0.000 claims description 8
- 241000176086 Sogatella furcifera Species 0.000 claims description 8
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 claims description 8
- 235000007516 Chrysanthemum Nutrition 0.000 claims description 7
- 241000233679 Peronosporaceae Species 0.000 claims description 7
- 241000018137 Trialeurodes vaporariorum Species 0.000 claims description 7
- 239000005660 Abamectin Substances 0.000 claims description 6
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- -1 MTI-446 Chemical compound 0.000 claims description 5
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 claims description 5
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 230000002265 prevention Effects 0.000 claims description 4
- AZSNMRSAGSSBNP-UHFFFAOYSA-N 22,23-dihydroavermectin B1a Natural products C1CC(C)C(C(C)CC)OC21OC(CC=C(C)C(OC1OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C1)C(C)C=CC=C1C3(C(C(=O)O4)C=C(C)C(O)C3OC1)O)CC4C2 AZSNMRSAGSSBNP-UHFFFAOYSA-N 0.000 claims description 3
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims description 3
- 230000008030 elimination Effects 0.000 claims description 3
- 238000003379 elimination reaction Methods 0.000 claims description 3
- 229960002418 ivermectin Drugs 0.000 claims description 3
- 229940041033 macrolides Drugs 0.000 claims description 3
- 235000021317 phosphate Nutrition 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims description 2
- XUNYDVLIZWUPAW-UHFFFAOYSA-N (4-chlorophenyl) n-(4-methylphenyl)sulfonylcarbamate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(=O)OC1=CC=C(Cl)C=C1 XUNYDVLIZWUPAW-UHFFFAOYSA-N 0.000 claims description 2
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 claims description 2
- 239000005653 Bifenazate Substances 0.000 claims description 2
- 239000005946 Cypermethrin Substances 0.000 claims description 2
- 239000005893 Diflubenzuron Substances 0.000 claims description 2
- 239000005900 Flonicamid Substances 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 2
- 239000005959 Fosthiazate Substances 0.000 claims description 2
- 239000005903 Gamma-cyhalothrin Substances 0.000 claims description 2
- 239000005907 Indoxacarb Substances 0.000 claims description 2
- XRHGWAGWAHHFLF-UHFFFAOYSA-N Isazofos Chemical compound CCOP(=S)(OCC)OC=1N=C(Cl)N(C(C)C)N=1 XRHGWAGWAHHFLF-UHFFFAOYSA-N 0.000 claims description 2
- 239000005912 Lufenuron Substances 0.000 claims description 2
- 241000220225 Malus Species 0.000 claims description 2
- 235000011430 Malus pumila Nutrition 0.000 claims description 2
- 235000015103 Malus silvestris Nutrition 0.000 claims description 2
- FJUJRXCRSJWOSA-UHFFFAOYSA-N NC(=O)N.N1=CC=CC=C1.[F] Chemical compound NC(=O)N.N1=CC=CC=C1.[F] FJUJRXCRSJWOSA-UHFFFAOYSA-N 0.000 claims description 2
- 244000061456 Solanum tuberosum Species 0.000 claims description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 2
- 239000005938 Teflubenzuron Substances 0.000 claims description 2
- 239000005939 Tefluthrin Substances 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims description 2
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 2
- 230000000895 acaricidal effect Effects 0.000 claims description 2
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 2
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 claims description 2
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 claims description 2
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims description 2
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 claims description 2
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 2
- 229960005424 cypermethrin Drugs 0.000 claims description 2
- 229940019503 diflubenzuron Drugs 0.000 claims description 2
- 125000004494 ethyl ester group Chemical group 0.000 claims description 2
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 claims description 2
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- DUFVKSUJRWYZQP-UHFFFAOYSA-N fosthiazate Chemical compound CCC(C)SP(=O)(OCC)N1CCSC1=O DUFVKSUJRWYZQP-UHFFFAOYSA-N 0.000 claims description 2
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 claims description 2
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 claims description 2
- VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 claims description 2
- PWPJGUXAGUPAHP-UHFFFAOYSA-N lufenuron Chemical compound C1=C(Cl)C(OC(F)(F)C(C(F)(F)F)F)=CC(Cl)=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F PWPJGUXAGUPAHP-UHFFFAOYSA-N 0.000 claims description 2
- 229960000521 lufenuron Drugs 0.000 claims description 2
- 230000000361 pesticidal effect Effects 0.000 claims description 2
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 claims description 2
- 229950001664 phoxim Drugs 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 claims description 2
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 claims description 2
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 3
- 244000189548 Chrysanthemum x morifolium Species 0.000 claims 2
- 239000000575 pesticide Substances 0.000 abstract description 7
- 238000005507 spraying Methods 0.000 abstract description 6
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 229960002715 nicotine Drugs 0.000 abstract description 3
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000011161 development Methods 0.000 abstract description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 abstract 2
- 230000002035 prolonged effect Effects 0.000 abstract 2
- HRYILSDLIGTCOP-UHFFFAOYSA-N N-benzoylurea Chemical compound NC(=O)NC(=O)C1=CC=CC=C1 HRYILSDLIGTCOP-UHFFFAOYSA-N 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 241000209094 Oryza Species 0.000 description 38
- 230000000694 effects Effects 0.000 description 26
- 230000003449 preventive effect Effects 0.000 description 22
- 239000003814 drug Substances 0.000 description 12
- 239000004480 active ingredient Substances 0.000 description 6
- 238000011835 investigation Methods 0.000 description 6
- 241000723353 Chrysanthemum Species 0.000 description 5
- 206010039509 Scab Diseases 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 239000002917 insecticide Substances 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 4
- 241000221785 Erysiphales Species 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- OMFXVFTZEKFJBZ-HJTSIMOOSA-N corticosterone Chemical compound O=C1CC[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@H](CC4)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 OMFXVFTZEKFJBZ-HJTSIMOOSA-N 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 241001465828 Cecidomyiidae Species 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 239000005786 Flutolanil Substances 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 239000005800 Kresoxim-methyl Substances 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 241000985245 Spodoptera litura Species 0.000 description 1
- 239000005941 Thiamethoxam Substances 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002164 acetylcholinergic effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 1
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- 238000003912 environmental pollution Methods 0.000 description 1
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 1
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
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- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides an insect killing and sterilizing composition containing tiadinil. The composition comprises two active components A and B in effective quantity, wherein the component A is tiadinil, and the component B is selected from one of nicotine insecticidal component, macrolide insecticidal component, amide insecticidal component, organophosphorus insecticidal component, pyrethroid insecticidal component, nereistoxin insecticidal component and benzoyl urea insecticidal component. When the composition is used, the composition is processed to missible oil, water aqua, microemulsions, suspending agents, wettable powder or water dispersible granules which are used for stirring seeds, spraying, dripping and irrigating roots. The pesticide composition provided by the invention has the synergetic effect; and the application target is expanded, the resistance development of nicotine pesticides can be prolonged, and the service life of the composition is prolonged.
Description
Technical field
The present invention relates to contain the insecticidal and bactericidal composition of tiadinil, belong to the plant protection field, composition is used for the damage by disease and insect of control crops.
Background technology
Rice blast, downy mildew, powdery mildew, rust, epidemic disease etc. are the diseases that paddy rice, vegetables, fruit tree etc. generally occur, simultaneously, the insects such as rice fulgorid, trialeurodes vaporariorum, aphid, scale insect, thrips, rice gall midge are the important pests on the crops such as paddy rice, vegetables, fruit tree, these insect breeding amounts are large, and generation overlap is obvious.In agricultural production, the damage by disease and insect of same crop often occurs simultaneously, and the peasant often attends to one thing and lose sight of another when pest control or disease separately, not only delay work and miss control opportunity, from and strengthen dosage etc.In recent years, due to single and Scientific Usage of Drugs not, cause the destruction of the raising of peasant's cost, environmental pollution and ecotope etc.
Tiadinil is the new type bactericide of amide containing structure, is a kind of New-type long-acting rice field bactericide, can effectively stop the invasion of pathogen, and have obvious induction of resistance.The nicotinic insecticide Main Function is in the acetylcholinergic receptor of insect, owing to having unique mechanism of action, with conventional pesticide without cross resistance, not only have absorption in efficient, wide spectrum and good root, tag and stomach poison function, and environmentally safe, be one of medicament that substitutes organic phosphates, carbamates and organochlorine class etc. with high poison, high residue.
In insecticidal constituent, Imidacloprid (imidacloprid) is the nicotinic insecticide of using early, for a long time, is widely used in control plant hopper, aphid, aleyrodid etc.Yet over 2005, various pests has produced higher pesticide resistance to Imidacloprid.And the medicaments such as Acetamiprid (acetamiprid), Diacloden (thiamethoxam), thiacloprid (thiacloprid), Nitenpyram (nitenpyram), MTI-446 (dinotefuran) and clothianidin (clothianidin) are the nicotinic insecticides outstanding to the insect preventive effect.And for example, the insecticide of macrolide constituents, as Avermectin, pleocidin, emamectin-benzoate (calling first dimension salt in the following text), ivermectin etc. have to the pest efficients such as the rice leaf roller in Lepidoptera, beet armyworm, prodenia litura, environmentally safe, to the mammal low toxicity, yet insect has also produced certain resistance to these medicaments.
Patent application CN101473829 discloses the bactericidal composition of tiadinil and flutolanil, but openly whether the composition of tiadinil and other bactericide can synergy.
For the Reasonable Protection medicament and delay germ to the drug-fast formation of tiadinil and insect to the drug-fast generation of above-mentioned insecticidal constituent, be necessary to carry out rational composition research.The inventor has carried out a large amount of tiadinils and the tests of pesticide effectiveness such as nicotine compound, tiadinil and macrolides compounds, find beyond thought effect, can reach synergy, the double texts of controlling, reduced spraying times, be beneficial to and reduce agriculture originally, improve the agricultural product economic benefit.
Summary of the invention
The objective of the invention is to delay the generation of medicament pesticide resistance, expanding prevention target and improve the damage by disease and insect drug effect, a kind of insecticidal and bactericidal composition and application that contains tiadinil is provided.
The invention provides a kind of insecticidal and bactericidal composition that contains tiadinil, it is characterized in that said composition comprises A component and two kinds of active components of B component of effective dose, the A component is tiadinil, and the B component is selected from a kind of in following pesticide activity component:
A kind of in nicotinoids insecticidal constituent Nitenpyram, Diacloden, Imidacloprid, Acetamiprid, thiacloprid, MTI-446 and clothianidin;
Or the macrolides insecticidal constituent is a kind of in Avermectin, pleocidin, first dimension salt, ivermectin;
Or a kind of in amide-type insecticidal constituent cyanogen insect amide, Tolfenpyrad, flonicamid and Rynaxypyr;
Or a kind of in organic phosphates insecticidal constituent chlopyrifos, fosthiazate, isazofos, phoxim and Profenofos;
Or a kind of in pyrethroid insecticidal constituent ether chrysanthemum ester, Biphenthrin, gamma cyhalothrin, beta-cypermethrin, cypermethrin and tefluthrin;
Or a kind of in nereistoxin constituents desinsection list, dimehypo, cartap;
Or a kind of in carbamates insecticidal constituent Mobucin, thiodicarb;
Or a kind of in benzoyl area kind insecticidal constituent HEXAFLUMURON, flufenoxuron, fluorine pyridine urea, lufenuron, fluorine uride, go out young urea, diflubenzuron and Teflubenzuron;
Or desinsection or kill a kind of of acaricidal composition in pymetrozine, spiral shell mite ester, Bifenazate, spiral shell worm ethyl ester, chlorfenapyr, indoxacarb.
In above-mentioned composition provided by the invention, preferred, the ratio of quality and the number of copies of A component and B component is 20:1-1:40.Especially preferred, the ratio of quality and the number of copies of A component and B component is 5:1-1:10, and is particularly preferred, and the ratio of quality and the number of copies of A component and B component is 1:1-10.
In above-mentioned composition of the present invention, preferably, B component is selected from a kind of in Nitenpyram, Diacloden, Imidacloprid, Acetamiprid, thiacloprid, MTI-446, clothianidin, Avermectin, first dimension salt, cyanogen insect amide, Tolfenpyrad, chlopyrifos, dimehypo, ether chrysanthemum ester, pymetrozine.
Above-mentioned composition of the present invention can be processed and be mixed with missible oil, aqua, microemulsion, suspending agent, wetting powder or water dispersible granules, and processing method is the formulation preparation method of this area routine.
The present invention also provides the method for using the above-mentioned composition prevention and elimination of disease and pests, it is characterized in that root is dressed seed, sprays, sheds or filled with to composition is applicable to crop.
The present invention also provides above-mentioned composition to be used for the purposes of prevention and elimination of disease and pests, and the application concentration that it is characterized in that active component is 100-3000mg/Kg, and preferred, application concentration is 500-1500mg/Kg.
In said method or purposes, preferred, damage by disease and insect is the diseases such as paddy rice, cucumber, potato, grape, apple, insect pest or mite evil.Especially preferred, damage by disease and insect is downy mildew and the trialeurodes vaporariorum of rice blast, rice fulgorid, rice leaf roller and the cucumber of paddy rice.
Composition pesticide of the present invention compared with prior art produces following beneficial effect:
(1) composition has synergistic effect;
(2) composition has enlarged the application target, and a dispenser can prevent and treat disease and insect pest simultaneously;
(3) mechanism of action due to the composition active component is different, and according to the pest resistance to insecticide theory and practice, the application of composition can delay the resistance development of nicotinoids medicament, extends its service life.
Embodiment
The following stated only is used for explaining the present invention, for not departing from modification, replacement or the improvement that the present invention is spiritual and principle is made, all belongs to the scope of protection of present invention.
The preventive effect of embodiment 1 composition to rice blast and rice fulgorid
At the rice field ridging, keep furrow face and parapsidal furrow water surface hold the line.The preparation of preparation tiadinil, Imidacloprid, Acetamiprid, Diacloden, thiacloprid, Nitenpyram, MTI-446, clothianidin, kresoxim-methyl, pymetrozine, tiadinil and imidacloprid composition, tiadinil and Acetamiprid composition, tiadinil and Diacloden composition, tiadinil and thiacloprid composition, tiadinil and composition containing nitenpyram, tiadinil and MTI-446 composition, tiadinil and clothianidin composition, tiadinil and ether chrysanthemum ester composition, tiadinil and pymetrozine composition is mixed with missible oil.Paddy rice 30 ℃ of constant incubator vernalization, by setting each preparation of the accurate weighing of concentration, is diluted quantitative pharmacy respectively and quantitative and even seed dressing 30min before showing money or valuables one carries unintentionally with suitable quantity of water.After being seeded in rice field furrow face, gently spreading one deck nutrition thin soil and cover, every processing 5m
2, establish blank.After seed sprouting, about 20 days, rice transplanting is transplanted.In booting stage, corresponding different paddy rice is processed spraying again and once, sprays and investigated in rear 10 days, the percentage of the blade face rice blast disease of every processing random searching 50 strain paddy rice and investigation 20 strain rice hoppers quantity.Use the Abbot formula, convert percentage to preventive effect.
In theoretical effect, x is the effect of the compd A of concentration when being a, and y is the effect of the compd B of concentration when being b, and relatively theoretical effect and actual effect are estimated the synergy of composition.Be synergistic effect when collaborative toxicity index more than or equal to 20 the time, being less than or equal at negative 20 o'clock is antagonism, is summation action between negative 20 and positive 20.The results are shown in Table 1.
Table 1 contains the composition rice blast of tiadinil and the effect of rice fulgorid
The composition that contains tiadinil is shown in Table 1 the effect of rice pest, can find out, with respect to single dose, composition is 1:1-10 in the active ingredient proportioning, when the active ingredient dosage is 500-2000mg/Kg, composition to the actual preventive effect of rice blast all higher than the theoretical preventive effect of composition to disease; Equally, composition for the actual preventive effect of rice fulgorid all higher than the theoretical preventive effect of composition to insect.obviously, the composition of tiadinil and Imidacloprid shows as summation action to rice blast and rice fulgorid, and the composition of tiadinil and Acetamiprid, the composition of tiadinil and Diacloden, the composition of tiadinil and thiacloprid, the composition of tiadinil and Nitenpyram, the composition of tiadinil and MTI-446, the composition of tiadinil and clothianidin, the composition of tiadinil and ether chrysanthemum ester, the composition of tiadinil and pymetrozine shows as synergy to the preventive effect of rice blast and rice fulgorid, all reach the dispenser effect of preventing disease and pest of holding concurrently, in addition, range estimation is found, the rice sheath blight disease disease incidence of compositions-treated is lighter than the rice disease that single dose is processed, color is dark green, growing way is better than the paddy rice that single dose is processed.
The preventive effect of embodiment 2 compositions to Cucumber Pests And Diseases
Single compound or composition are prepared into the mother liquor of 1000mg/L with organic solvent dissolution.According to the biological activity determination trial test, a certain amount of above-mentioned mother liquor is diluted with 0.1% Tween 80, be mixed with the concentration that needs.During test, cucumber plant is substantially in 4 leaf phases, investigation downy mildew incidence before the 1st medicine, with and establish corresponding single dose and blank, adopt the conventional conventional spray of manual sprayer, every medicament sprays 10 strains.Spraying, 7-10d sprays 1 time again after 1 time.10-14d investigation after the 2nd dispenser, every strain whole blade diseases of investigation and trialeurodes vaporariorum situation.Record investigation total number of sheets, the sick number of sheets and trialeurodes vaporariorum number calculate disease index and preventive effect according to following stage division.
The blade staging:
0 grade: anosis
1 grade: the connected area of scab accounts for below 1% of whole leaf area;
3 grades: the connected area of scab accounts for the 1%-10% of whole leaf area;
5 grades: the connected area of scab accounts for the 11%-20% of whole leaf area;
7 grades: the connected area of scab accounts for the 21%-50% of whole leaf area;
9 grades: the connected area of scab accounts for more than 51% of whole leaf area;
In theoretical effect, x is the effect of the compd A of concentration when being a, and y is the effect of the compd B of concentration when being b, and relatively theoretical effect and actual effect are estimated the synergy of composition.Be synergistic effect when collaborative toxicity index more than or equal to 20 the time, being less than or equal at negative 20 o'clock is antagonism, is summation action between negative 20 and positive 20.The results are shown in Table 2.
Table 2 contains the composition of tiadinil to the preventive effect of Cucumber Pests And Diseases
The effect that contains the composition Cucumber Pests And Diseases of tiadinil is shown in Table 2, can find out, with respect to single dose, composition is 1:1-10 in the active ingredient proportioning, when the active ingredient dosage is 500-2000mg/Kg, composition to the actual preventive effect of cucumber downy mildew all higher than the theoretical preventive effect of composition; Equally, composition for the actual preventive effect of trialeurodes vaporariorum all also all higher than the theoretical preventive effect of composition to insect.calculate collaborative toxicity index as can be known, the composition of tiadinil and Acetamiprid, the composition of tiadinil and Diacloden, the composition of tiadinil and thiacloprid, the composition of tiadinil and Nitenpyram, the composition of tiadinil and MTI-446, the composition of tiadinil and clothianidin, the composition of tiadinil and ether chrysanthemum ester, the preventive effect synergy of the composition of tiadinil and pymetrozine to downy mildew and trialeurodes vaporariorum, the composition of tiadinil and Imidacloprid is to downy mildew, the powdery mildew preventive effect is summation action, but reach the dispenser effect of preventing disease and pest of holding concurrently, in addition, range estimation is found, the cucumber plant color of compositions-treated is dark green, effect to powdery mildew also is better than the plant that single dose is processed.
The effect of embodiment 3 compositions to paddy rice rice leaf roller and rice blast
Be in tillering stage to booting stage in paddy rice, in the rice field, the experimental plot be set, residential quarter 50m is established in every processing
2, every residential quarter is adopted at 5 and is listed, and 5 clumps every, accurately prepare respectively medicament and accurately dilute according to concentration, conventional even spraying when selecting field to have adult or ovum to occur, and establish space management.7d after medicine, corresponding different paddy rice is processed spraying again and once, investigates the percentage of investigation rice leaf roller quantity and the blade face rice blast disease of the paddy rice of listing after 10 days.Use the Abbot formula, convert percentage to preventive effect.
In theoretical effect, x is the effect of the compd A of concentration when being a, and y is the effect of the compd B of concentration when being b, and relatively theoretical effect and actual effect are estimated the synergy of composition.Be synergistic effect when collaborative toxicity index more than or equal to 20 the time, being less than or equal at negative 20 o'clock is antagonism, is summation action between negative 20 and positive 20.The results are shown in Table 3.
The effect of table 3 composition to paddy rice rice leaf roller and rice blast
Composition is shown in Table 3 the effect of paddy rice rice leaf roller and rice blast, can find out, with respect to single dose, composition is 1:1-10 in the active ingredient proportioning, when the active ingredient dosage is 500-2500mg/Kg, composition to the actual preventive effect of rice leaf roller all higher than the theoretical preventive effect of composition; Equally, composition for the actual preventive effect of rice blast all also all higher than the theoretical preventive effect of composition to insect.Calculate collaborative toxicity index as can be known, the composition of composition, tiadinil and the chlopyrifos of composition, tiadinil and the Tolfenpyrad of composition, tiadinil and the cyanogen insect amide of the composition of tiadinil and Avermectin, tiadinil and first dimension salt and the composition of tiadinil and dimehypo are synergy to the synergy of rice leaf roller, above composition is synergy or addition to the synergy of rice blast, and reaches the dispenser effect of preventing disease and pest of holding concurrently.Improve drug effect, reduce the medication number of times, be beneficial to and increase economic efficiency and environmental ecology.
Claims (7)
1. an insecticidal and bactericidal composition that contains tiadinil, is characterized in that said composition comprises A component and two kinds of active components of B component of effective dose, and the A component is tiadinil, and the B component is selected from a kind of in following pesticide activity component:
A kind of in nicotinoids insecticidal constituent Nitenpyram, Diacloden, Imidacloprid, Acetamiprid, thiacloprid, MTI-446 and clothianidin;
Or the macrolides insecticidal constituent is a kind of in Avermectin, pleocidin, first dimension salt, ivermectin;
Or a kind of in amide-type insecticidal constituent cyanogen insect amide, Tolfenpyrad, flonicamid and Rynaxypyr;
Or a kind of in organic phosphates insecticidal constituent chlopyrifos, fosthiazate, isazofos, phoxim and Profenofos;
Or a kind of in pyrethroid insecticidal constituent ether chrysanthemum ester, Biphenthrin, gamma cyhalothrin, beta-cypermethrin, cypermethrin and tefluthrin;
Or a kind of in nereistoxin constituents desinsection list, dimehypo, cartap;
Or a kind of in carbamates insecticidal constituent Mobucin, thiodicarb;
Or a kind of in benzoyl area kind insecticidal constituent HEXAFLUMURON, flufenoxuron, fluorine pyridine urea, lufenuron, fluorine uride, go out young urea, diflubenzuron and Teflubenzuron;
Or desinsection or kill a kind of of acaricidal composition in pymetrozine, spiral shell mite ester, Bifenazate, spiral shell worm ethyl ester, chlorfenapyr, indoxacarb.
2. composition according to claim 1, wherein the ratio of quality and the number of copies of A component and B component is 20:1-1:40; Especially preferred, the ratio of quality and the number of copies of A component and B component is 5:1-1:10; Particularly preferred, the ratio of quality and the number of copies of A component and B component is 1:1-10.
3. composition according to claim 1 and 2, wherein B component is selected from a kind of in Nitenpyram, Diacloden, Imidacloprid, Acetamiprid, thiacloprid, MTI-446, clothianidin, Avermectin, first dimension salt, cyanogen insect amide, Tolfenpyrad, chlopyrifos, dimehypo, ether chrysanthemum ester, pymetrozine.
4. the described composition of claim 1-3 any one is characterized in that described composition can be processed to be mixed with missible oil, aqua, microemulsion, suspending agent, wetting powder or water dispersible granules.
5. the method for the described composition for preventing and controlling damage by disease and insect of claim 1-4 any one, is characterized in that root is dressed seed, sprays, sheds or filled with to composition is applicable to crop.
6. the described composition of claim 1-4 any one is used for the purposes of prevention and elimination of disease and pests, and the application concentration that it is characterized in that active component is 100-3000mg/Kg, and preferred, application concentration is 500-1500mg/Kg.
7. method claimed in claim 5 or purposes claimed in claim 6, wherein damage by disease and insect is the diseases such as paddy rice, cucumber, potato, grape, apple, insect pest or mite evil; Especially preferred, damage by disease and insect is downy mildew and the trialeurodes vaporariorum of rice blast, rice fulgorid, rice leaf roller and the cucumber of paddy rice.
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| CN104522005A (en) * | 2014-12-15 | 2015-04-22 | 广西颐生园生态农业有限公司 | Pesticide composition containing thiobenzamide |
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| CN103843811A (en) * | 2014-02-21 | 2014-06-11 | 罗晓丹 | Granules for controlling sugarcane stem borer |
| CN103843811B (en) * | 2014-02-21 | 2015-10-14 | 顾祥茂 | A kind of granule preventing and treating sugarcane moth borer |
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| CN104396974A (en) * | 2014-11-18 | 2015-03-11 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Pesticide composition containing thifluzamide and chlorantraniliprole as well as application of pesticide composition |
| CN104522005A (en) * | 2014-12-15 | 2015-04-22 | 广西颐生园生态农业有限公司 | Pesticide composition containing thiobenzamide |
| CN104621157A (en) * | 2015-02-04 | 2015-05-20 | 河南科技学院 | Cyprodinil and iprovalicarb containing sterilizing composition and application thereof |
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Address after: 571924 the development of Hainan County of Chengmai province old town village distribution Applicant after: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Address before: Four, building 25, glorious cinema tower, 570206 Nansha Road, Longhua District, Hainan, Haikou Applicant before: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. |
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Denomination of invention: Insect killing and sterilizing composition containing tiadinil Effective date of registration: 20160822 Granted publication date: 20150610 Pledgee: Bank of Hainan Limited by Share Ltd. Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: 2016460000002 |
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Denomination of invention: Insect killing and sterilizing composition containing tiadinil Effective date of registration: 20190617 Granted publication date: 20150610 Pledgee: Bank of Hainan Limited by Share Ltd. Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: 2019460000007 |
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Address after: Fuchang Village, Laocheng Development Zone, Chengmai County, Hainan Province, 571923 Patentee after: Hainan Zhengye Biotechnology Co.,Ltd. Address before: 571924 Fuchang village, Laocheng Development Zone, Chengmai County, Hainan Province Patentee before: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. |