CN103125504A - Sterilizing composition containing Tiadinil - Google Patents
Sterilizing composition containing Tiadinil Download PDFInfo
- Publication number
- CN103125504A CN103125504A CN2011104171617A CN201110417161A CN103125504A CN 103125504 A CN103125504 A CN 103125504A CN 2011104171617 A CN2011104171617 A CN 2011104171617A CN 201110417161 A CN201110417161 A CN 201110417161A CN 103125504 A CN103125504 A CN 103125504A
- Authority
- CN
- China
- Prior art keywords
- tiadinil
- tricyclazole
- days
- medicine
- valid density
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a sterilizing composition containing Tiadinil. Effective ingredients of the sterilizing composition containing Tiadinil are Tiadinil and tricyclazole. Quality proportion of the Tiadinil and the tricyclazole is 50:1 to 1:50. The sterilizing composition containing the Tiadinil has evident synergism function, and can be used for preventing and treating rice blast.
Description
Technical field
The present invention relates to a kind of bactericidal composition, especially a kind of bactericidal composition that contains tiadinil.
Background technology
Tiadinil (tiadinil) is the Japanese agricultural chemicals company novel bactericide of induction of resistance type newly developed, and it is mainly to stop sick mattress mycelia to invade contiguous healthy cell that its effect machine buries, and can induce the generation disease-resistant gene.Be mainly used in preventing and treating rice blast, the lasting period is long.In addition, tiadinil also has certain effect to powdery mildew, rust, late blight or epidemic disease, downy mildew etc.But the independent use cost of tiadinil is higher and have the risk that develops immunity to drugs.
Tricyclazole (tricyclazole) is mainly used in the control of rice blast.Its mechanism of action is mainly to synthesize to stop by check melanin to adhere to the spore intrusion.Can be rapidly by each position absorption of paddy rice, the lasting period is long, efficacy stability and anti-rain drop erosion.But tricyclazole does not almost have killing action to the rice blast pathogene of invading in cellular tissure.
Summary of the invention
The object of the invention is to: the efficient bactericidal composition that uses on a kind of suitable agricultural is provided.
For solving the problems of the technologies described above, the inventor is by a large amount of biologicall test screening tests, and unexpected discovery tiadinil and tricyclazole are composite with certain proportion, and rice blast is had significant synergies.
On the basis of above-mentioned discovery, through composition is carried out symphyogenetic quantitative analysis, formed technical scheme of the present invention, it is a kind of bactericidal composition, it is characterized in that take tiadinil and tricyclazole as active ingredient, the mass ratio of tiadinil and tricyclazole is 50: 1-1: 50, and ratio is 20 preferably: 1-1: 20, better ratio is 5: 1-1: 5.
The present composition can be prepared into known method the formulation that is fit to agricultural use, and in preparation, the total content of active ingredient is 2.5%-80%.
Comprise also except active ingredient in composition of the present invention that the auxiliary element such as dispersant, wetting agent, antifreezing agent and other are of value to the known substance of active ingredient stable and drug effect performance in storing and using, all various compositions commonly used in pesticidal preparations or that permission is used, be not particularly limited, concrete composition and consumption require to determine by simple experiment according to formula.
Composition described in the invention can the finished product preparation form provide, and namely in composition, each material mixes, and the composition of composition also can provide with the single dose form, directly directly mixes in bucket or tank before use, then is diluted to required concentration.
Bactericidal composition of the present invention is applicable to prevent and treat rice blast.
Compared with prior art, the beneficial effect of the present invention's generation is: (1) is compared with single dose, and this bactericidal composition has obvious synergy to rice blast, has improved control efficiency; (2) can reduce the field dosage, effectively environmental contamination reduction and residue of pesticide.(3) in bactericidal composition, the mechanism of action of active ingredient is different, is conducive to avoid and delays the drug-fast generation of germ.(4) compare with single medicament, can reduce and produce and use cost.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is limited to absolutely not these examples.
The present composition take tiadinil as a kind of active ingredient, tricyclazole is another kind of active ingredient, combination between them is applicable to prevent and treat rice blast, have obvious synergistic function, and be not only the simple addition of two kinds of pharmacy effects, see biologicall test embodiment 1 for details.
Biologicall test embodiment 1: the composite Toxicity Determination to rice blast of tiadinil and tricyclazole
Subjects: Pyricularia oryzae (pick up from the field, and through separation and purification)
Test method: with reference to " the agricultural industry criteria NY/T1154.7-2006 of the People's Republic of China (PRC) ", pot-culture method.Choose the consistent rice seedlings in tri-leaf period of growth potential, each processing selects 5 basins for the examination rice seedling.Pyricularia oryzae is cultivated on tomato oat agar medium, washed spore with sterile water after the product spore, make 1*10
5The suspension of individual spore/mL, spray inoculation in for trying on rice seedling, puts black plastic sack moisturizing and cultivates 24h after inoculation equably.After inoculation 24h, carry out chemicals treatment, each medicament arranges 5 concentration gradients, sprays under 50PSI pressure with spray tower.After the spray medicine, rice seedling is placed under the condition of 25 ℃ of left and right, relative moisture 〉=90% and cultivates, after medicine, 7d according to the morbidity grade scale investigation incidence of rice blast, and is calculated as follows control efficiency:
Control efficiency is converted into probability value (y), liquor strength (μ g/ml) converts logarithm value (x) to, calculate concentration EC50 in virulence equation and inhibition with method of least squares, calculate toxicity index and the co-toxicity coefficient (CTC) of medicament according to the abundant method of Sun Yun.Toxicity test the results are shown in Table 1.
Actual measurement toxicity index (ATI)=(standard medicament EC50/ reagent agent EC50) * 100
The percentage composition of B in the percentage composition of A+B medicament toxicity index * mixture in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/theoretical toxicity index (TTI) of mixture] * 100
When CTC≤80, the composition performance is for antagonism, and when 80＜CTC＜120, the composition performance is for summation action, and when CTC 〉=120, the composition performance is synergistic effect.
The composite Toxicity Determination result to rice blast of table 1 tiadinil and tricyclazole
| Process | EC 50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
| Tiadinil | 0.2169 | 100.0 | / | / |
| Tricyclazole | 1.8478 | 11.7 | / | / |
| Tiadinil 50: tricyclazole 1 | 0.1811 | 119.8 | 98.3 | 121.9 |
| Tiadinil 20: tricyclazole 1 | 0.1501 | 144.5 | 95.8 | 150.8 |
| Tiadinil 10: tricyclazole 1 | 0.1424 | 152.3 | 92.0 | 165.6 |
| Tiadinil 5: tricyclazole 1 | 0.1286 | 168.7 | 85.3 | 197.8 |
| Tiadinil 1: tricyclazole 1 | 0.1843 | 117.7 | 55.9 | 210.7 |
| Tiadinil 1: tricyclazole 5 | 0.3035 | 71.5 | 26.4 | 270.2 |
| Tiadinil 1: tricyclazole 10 | 0.5953 | 36.4 | 19.8 | 184.4 |
| Tiadinil 1: tricyclazole 20 | 0.8074 | 26.9 | 15.9 | 168.5 |
| Tiadinil 1: tricyclazole 50 | 1.1425 | 19.0 | 13.5 | 141.0 |
The result of table 1 shows, tiadinil and tricyclazole are at proportioning 50: 1-1: 50 o'clock, rice blast all there is synergistic effect, and especially 20: 1-1: in the time of between 20, listed proportioning co-toxicity coefficient is all higher than 150.8, and synergistic effect is more obvious.
Bactericidal composition of the present invention can be prepared into known method wetting powder, suspending agent, suspension emulsion, the water dispersible granules that is fit to agricultural use.Below describe with specific embodiment, in present specification, active component or active ingredient refer to tiadinil and tricyclazole, in formula, percentage is mass percent, below repeats no more.
Embodiment 1:2.4% tiadinil tricyclazole suspending agent
The ratio of each components such as the former medicine of active component, dispersant, wetting agent and water in formula mixed, obtain 2.4% tiadinil tricyclazole suspending agent after grinding and/or high speed shear.
This embodiment is applied to prevent and treat rice blast.With 1500 times of 2.4% tiadinil tricyclazole suspending agent thin ups (tiadinil valid density is 2.67 μ g/ml, and tricyclazole valid density is 13.3 μ g/ml) sprayings, after medicine, the control efficiency of 7 days and 15 days is respectively 97.8%, 96.7%.6% tiadinil granule by 2500 times (valid density is 24 μ g/ml) and 20% tricyclazole wettable powder by 500 times (valid density is 400 μ g/ml), use with same method, after medicine, the preventive effect of 7 days is respectively 93.4% and 90.7%, and after medicine, 15 days is 90.2% and 86.4%.The composite rear synergistic effect of tiadinil and tricyclazole is obvious, and significantly better than single dose, not only control efficiency improves to the preventive effect of rice blast, and the amount ratio of active ingredient obviously reduces when using separately, has also alleviated the pollution to environment simultaneously.
Embodiment 2:31.5% tiadinil tricyclazole suspension emulsion
The ratio of each components such as tricyclazole, dispersant, wetting agent and water in formula mixed, obtain suspending agent after grinding and/or high speed shear, then with tiadinil, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, obtain 31.5% tiadinil tricyclazole suspension emulsion.
This embodiment is applied to prevent and treat rice blast.31.5% tiadinil tricyclazole suspension emulsion is sprayed by 8000 times of (tiadinil valid density is 37.5 μ g/ml, and tricyclazole valid density is 1.875 μ g/ml) thin ups, and after medicine, the control efficiency of 7 days and 15 days is respectively 97.4%, 95.3%.6% tiadinil granule by 1500 times (valid density is 40 μ g/ml) and 75% tricyclazole wettable powder by 1500 times (valid density is 500 μ g/ml), use with same method, after medicine, the preventive effect of 7 days is respectively 83.4% and 81.7%, and after medicine, 15 days is 82.5% and 80.7%.The composite rear synergistic effect of tiadinil and tricyclazole is obvious, and significantly better than single dose, not only control efficiency improves to the preventive effect of rice blast, and the amount ratio of active ingredient obviously reduces when using separately, has also alleviated the pollution to environment simultaneously.
Embodiment 3:10.2% tiadinil tricyclazole water dispersible granule
Active component, dispersant, wetting agent, disintegrant and the filler ratio in formula is mixed, become wetting powder through air-flow crushing, then add a certain amount of water mixing extruding to make material.Obtain 10.2% tiadinil tricyclazole water dispersible granule after the drying screening.
This embodiment is applied to prevent and treat rice blast.With 4000 times of 10.2% tiadinil tricyclazole water dispersible granules (tiadinil valid density is 25 μ g/ml, and tricyclazole valid density is 0.5 μ g/ml) thin up spraying, after medicine, the control efficiency of 7 days and 15 days is respectively 98.2%, 96.7%.6% tiadinil granule by 2000 times (valid density is 30 μ g/ml) and 75% tricyclazole water dispersible granule by 1500 times (valid density is 500 μ g/ml), use with same method, after medicine, the preventive effect of 7 days is respectively 83.4% and 81.7%, and after medicine, 15 days is 82.5% and 80.7%.The composite rear synergistic effect of tiadinil and tricyclazole is obvious, and significantly better than single dose, not only control efficiency improves to the preventive effect of rice blast, and the amount ratio of active ingredient obviously reduces when using separately, has also alleviated the pollution to environment simultaneously.
Embodiment 4:15% tiadinil tricyclazole wettable powder
Active component, various auxiliary agent and filler etc. are fully mixed in the ratio of formula, after ultra-fine pulverizer disintegrating, namely get 15% tiadinil tricyclazole wettable powder.
This embodiment is applied to rice blast.15% tiadinil tricyclazole wettable powder is sprayed by 3000 times of (tiadinil valid density is 25 μ g/ml, and tricyclazole valid density is 25 μ g/ml) thin ups, and after medicine, the control efficiency of 7 days and 15 days is respectively 96.2%, 91.7%.6% tiadinil granule by 2000 times (valid density is 30 μ g/ml) and 75% tricyclazole wettable powder by 1500 times (valid density is 500 μ g/ml), use with same method, after medicine, the preventive effect of 7 days is respectively 93.4% and 87.5%, and after medicine, 15 days is 89.1% and 83.7%.The composite rear synergistic effect of tiadinil and tricyclazole is obvious, to the preventive effect of rice blast significantly better than single dose.
Embodiment 5:55% tiadinil tricyclazole wettable powder
Active component, various auxiliary agent and filler etc. are fully mixed in the ratio of formula, after ultra-fine pulverizer disintegrating, namely get 55% tiadinil tricyclazole wettable powder.
This embodiment is applied to rice blast.55% tiadinil tricyclazole wettable powder is sprayed by 2500 times of (tiadinil valid density is 20 μ g/ml, and tricyclazole valid density is 200 μ g/ml) thin ups, and after medicine, the control efficiency of 7 days and 15 days is respectively 96.5%, 93.3%.6% tiadinil granule by 2000 times (valid density is 30 μ g/ml) and 20% tricyclazole wettable powder by 500 times (valid density is 400 μ g/ml), use with same method, after medicine, the preventive effect of 7 days is respectively 93.4% and 90.7%, and after medicine, 15 days is 89.5% and 85.0%.The composite rear synergistic effect of tiadinil and tricyclazole is obvious, and significantly better than single dose, not only control efficiency improves to the preventive effect of rice blast, and the amount ratio of active ingredient obviously reduces when using separately, has also alleviated the pollution to environment simultaneously.
Embodiment 6:3% tiadinil tricyclazole suspension emulsion
The ratio of each components such as tricyclazole, dispersant, wetting agent and water in formula mixed, obtain suspending agent after grinding and/or high speed shear, then with tiadinil, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, obtain 3% tiadinil tricyclazole suspension emulsion.
This embodiment is applied to prevent and treat rice blast.3% tiadinil tricyclazole suspending agent is sprayed by 1500 times of (tiadinil valid density is 16.67 μ g/ml, and tricyclazole valid density is 3.33 μ g/ml) thin ups, and after medicine, the control efficiency of 7 days and 15 days is respectively 97.7%, 96.4%.6% tiadinil granule by 2500 times (valid density is 24 μ g/ml) and 20% tricyclazole wettable powder by 500 times (valid density is 400 μ g/ml), use with same method, after medicine, the preventive effect of 7 days is respectively 95.4% and 86.7%, and after medicine, 15 days is 85.3% and 80.2%.The composite rear synergistic effect of tiadinil and tricyclazole is obvious, to the preventive effect of rice blast significantly better than single dose.Simultaneously, the consumption of active ingredient reduces, thereby has reduced cost and the pollution that has alleviated environment.
Embodiment 7:31.5% tiadinil tricyclazole suspending agent
The ratio of each components such as the former medicine of active component, dispersant, wetting agent and water in formula mixed, obtain 31.5% tiadinil tricyclazole suspending agent after grinding and/or high speed shear.
This embodiment is applied to prevent and treat rice blast.With 2000 times of 31.5% tiadinil tricyclazole suspending agent thin ups (tiadinil valid density is 7.5 μ g/ml, and tricyclazole valid density is 150 μ g/ml) sprayings, after medicine, the control efficiency of 7 days and 15 days is respectively 97.1%, 90.2%.6% tiadinil granule by 2500 times (valid density is 24 μ g/ml) and 75% tricyclazole wettable powder by 1500 times (valid density is 500 μ g/ml), use with same method, after medicine, the preventive effect of 7 days is respectively 86.6% and 82.3%, and after medicine, 15 days is 83.0% and 80.1%.The composite rear synergistic effect of tiadinil and tricyclazole is obvious, and significantly better than single dose, not only control efficiency improves to the preventive effect of rice blast, and the amount ratio of active ingredient obviously reduces when using separately, has also alleviated the pollution to environment simultaneously.
Embodiment 8:25.5% tiadinil tricyclazole water dispersible granule
Active component, dispersant, wetting agent, disintegrant and the filler ratio in formula is mixed, become wetting powder through air-flow crushing, then add a certain amount of water mixing extruding to make material.Obtain 25.5% tiadinil tricyclazole water dispersible granule after the drying screening.
This embodiment is applied to prevent and treat rice blast.(tiadinil valid density is 3.33 μ g/ml with 1500 times of 25.5% tiadinil tricyclazole water dispersible granules, tricyclazole valid density is 166.67 μ g/ml) thin up spraying, after medicine, the control efficiency of 7 days and 15 days is respectively 97.5%, 95.1%.6% tiadinil granule by 2500 times (valid density is 24 μ g/ml) and 75% tricyclazole water dispersible granule by 1500 times (valid density is 500 μ g/ml), use with same method, after medicine, the preventive effect of 7 days is respectively 89.4% and 87.7%, and after medicine, 15 days is 83.5% and 80.7%.The composite rear synergistic effect of tiadinil and tricyclazole is obvious, and significantly better than single dose, not only control efficiency improves to the preventive effect of rice blast, and the amount ratio of active ingredient obviously reduces when using separately, has also alleviated the pollution to environment simultaneously.
Embodiment 9:5.5% tiadinil tricyclazole suspending agent
The ratio of each components such as the former medicine of active component, dispersant, wetting agent and water in formula mixed, obtain 5.5% tiadinil tricyclazole suspending agent after grinding and/or high speed shear.
This embodiment is applied to prevent and treat rice blast.With 2500 times of 5.5% tiadinil tricyclazole suspending agent thin ups (tiadinil valid density is 20 μ g/ml, and tricyclazole valid density is 2 μ g/ml) sprayings, after medicine, the control efficiency of 7 days and 15 days is respectively 96.8%, 92.7%.6% tiadinil granule by 2500 times (valid density is 24 μ g/ml) and 20% tricyclazole wettable powder by 500 times (valid density is 400 μ g/ml), use with same method, after medicine, the preventive effect of 7 days is respectively 94.0% and 91.6%, and after medicine, 15 days is 88.2% and 83.4%.The composite rear synergistic effect of tiadinil and tricyclazole is obvious, and significantly better than single dose, not only control efficiency improves to the preventive effect of rice blast, and the amount ratio of active ingredient obviously reduces when using separately, has also alleviated the pollution to environment simultaneously.
Claims (4)
1. bactericidal composition, it is characterized in that: in described bactericidal composition, active ingredient is tiadinil and tricyclazole, the mass ratio of tiadinil and tricyclazole is 50: 1-1: 50.
2. a kind of bactericidal composition according to claim 1, it is characterized in that: the mass ratio of active ingredient tiadinil and tricyclazole is 20: 1-1: 20.
3. a kind of bactericidal composition according to claim 2, it is characterized in that: the mass ratio of active ingredient tiadinil and tricyclazole is 5: 1-1: 5.
4. the application of the described bactericidal composition of any one in claims 1 to 3 is characterized in that: bactericidal composition is used for control rice blast.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110417161.7A CN103125504B (en) | 2011-11-28 | 2011-11-28 | Sterilizing composition containing Tiadinil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110417161.7A CN103125504B (en) | 2011-11-28 | 2011-11-28 | Sterilizing composition containing Tiadinil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103125504A true CN103125504A (en) | 2013-06-05 |
| CN103125504B CN103125504B (en) | 2014-02-26 |
Family
ID=48486452
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110417161.7A Active CN103125504B (en) | 2011-11-28 | 2011-11-28 | Sterilizing composition containing Tiadinil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103125504B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103416425A (en) * | 2012-05-22 | 2013-12-04 | 陕西韦尔奇作物保护有限公司 | Fungicidal composition containing tiadinil and triazole fungicide |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101091490A (en) * | 2007-01-12 | 2007-12-26 | 南开大学 | New type heterocycle bactericide and composition |
| EP2014167A1 (en) * | 2007-07-13 | 2009-01-14 | Bayer CropScience AG | Active compound combinations |
| CN101798316A (en) * | 2008-08-28 | 2010-08-11 | 南开大学 | Triazolothiadiazole compounds and preparation method and application thereof |
| WO2011076726A2 (en) * | 2009-12-23 | 2011-06-30 | Bayer Cropscience Ag | Pesticidal compound mixtures |
-
2011
- 2011-11-28 CN CN201110417161.7A patent/CN103125504B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101091490A (en) * | 2007-01-12 | 2007-12-26 | 南开大学 | New type heterocycle bactericide and composition |
| EP2014167A1 (en) * | 2007-07-13 | 2009-01-14 | Bayer CropScience AG | Active compound combinations |
| CN101798316A (en) * | 2008-08-28 | 2010-08-11 | 南开大学 | Triazolothiadiazole compounds and preparation method and application thereof |
| WO2011076726A2 (en) * | 2009-12-23 | 2011-06-30 | Bayer Cropscience Ag | Pesticidal compound mixtures |
Non-Patent Citations (3)
| Title |
|---|
| 张杨，等: "稻瘟病菌对三环唑抗药性风险研究", 《沈阳农业大学学报》 * |
| 赵卫光，等: "新型稻田杀菌剂噻酰菌胺", 《农药》 * |
| 黄星，等: "三环唑防治稻瘟病的应用技术剂防效影响因素研究", 《农药学学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103416425A (en) * | 2012-05-22 | 2013-12-04 | 陕西韦尔奇作物保护有限公司 | Fungicidal composition containing tiadinil and triazole fungicide |
| CN103416425B (en) * | 2012-05-22 | 2016-02-17 | 陕西韦尔奇作物保护有限公司 | A kind of bactericidal composition containing tiadinil and triazole type |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103125504B (en) | 2014-02-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102172240B (en) | A kind of bactericidal composition containing benziothiazolinone and methoxy acrylic bactericide | |
| CN102715187B (en) | Sterilization composition containing Dufulin and strobilurins | |
| CN101690483A (en) | Bactericidal composition containing triazole class compounds | |
| CN101690480A (en) | Pesticide composition containing methoxy acrylic bactericide and application thereof | |
| CN101642104A (en) | Sterilization composition containing fenoxanil | |
| CN102578108A (en) | Bactericidal composition containing probenazole | |
| CN103918668B (en) | Bactericidal composition | |
| CN103918658A (en) | Compound bactericide composition containing cyazofamid | |
| CN104351254B (en) | A kind of containing Nikemycin with the bactericidal composition of Fluoxastrobin | |
| CN103636668B (en) | Sterilization composition containing Dufulin and orysastrobin | |
| CN102972410B (en) | Pesticide composition containing prothioconazole and methoxyl acrylic ester bactericides | |
| CN103125504B (en) | Sterilizing composition containing Tiadinil | |
| CN101642109B (en) | Bactericidal composition containing famoxadone | |
| CN103636670B (en) | Sterilization composition containing Dufulin and enestroburin | |
| CN106234367A (en) | A kind of containing fluopicolide and the bactericidal composition of methoxy acrylic | |
| CN103081925A (en) | Fenamidone-containing bactericidal composition | |
| CN101849546A (en) | Pesticide composition | |
| CN103081920A (en) | Sterilizing composition containing penconazole | |
| CN103636669B (en) | Sterilization composition containing Dufulin and trifloxystrobin | |
| CN103478152B (en) | Fenamidone-containing sterilization composition | |
| CN105831132A (en) | Sterilization composition containing benzothiostrobin and fluoride ether bacteria amide | |
| CN101647466B (en) | Sterilization combination | |
| CN106135232A (en) | Bactericidal composition | |
| CN105794859A (en) | Insecticidal compound containing conidioblous thromboides and biological sources | |
| CN103975923B (en) | A kind of agricultural bactericidal composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |