CN103113997A - Food-grade detergent and preparation method thereof - Google Patents
Food-grade detergent and preparation method thereof Download PDFInfo
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- CN103113997A CN103113997A CN2013100761811A CN201310076181A CN103113997A CN 103113997 A CN103113997 A CN 103113997A CN 2013100761811 A CN2013100761811 A CN 2013100761811A CN 201310076181 A CN201310076181 A CN 201310076181A CN 103113997 A CN103113997 A CN 103113997A
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- China
- Prior art keywords
- liquid detergent
- fatty acid
- acyl group
- food grade
- hydroxypropionate
- Prior art date
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- 239000003599 detergent Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 235000013305 food Nutrition 0.000 claims abstract description 29
- 229920000223 polyglycerol Polymers 0.000 claims abstract description 12
- -1 acyl sodium lactate Chemical compound 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims description 38
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 20
- 239000000194 fatty acid Substances 0.000 claims description 20
- 229930195729 fatty acid Natural products 0.000 claims description 20
- 125000002252 acyl group Chemical group 0.000 claims description 18
- NGSFWBMYFKHRBD-UHFFFAOYSA-N sodium;2-hydroxypropanoic acid Chemical compound [Na+].CC(O)C(O)=O NGSFWBMYFKHRBD-UHFFFAOYSA-N 0.000 claims description 18
- 239000003921 oil Substances 0.000 claims description 13
- 235000019198 oils Nutrition 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 235000013311 vegetables Nutrition 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
- 239000005639 Lauric acid Substances 0.000 claims description 4
- 235000019482 Palm oil Nutrition 0.000 claims description 4
- 239000003240 coconut oil Substances 0.000 claims description 4
- 235000019864 coconut oil Nutrition 0.000 claims description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 claims description 4
- 239000003346 palm kernel oil Substances 0.000 claims description 4
- 235000019865 palm kernel oil Nutrition 0.000 claims description 4
- 239000002540 palm oil Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 241000282693 Cercopithecidae Species 0.000 claims description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 3
- 229920002774 Maltodextrin Polymers 0.000 claims description 3
- 239000005913 Maltodextrin Substances 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 239000008103 glucose Substances 0.000 claims description 3
- 229940070765 laurate Drugs 0.000 claims description 3
- 229940035034 maltodextrin Drugs 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000010773 plant oil Substances 0.000 abstract description 7
- 239000013543 active substance Substances 0.000 abstract description 6
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 abstract description 3
- 150000002148 esters Chemical class 0.000 abstract description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 abstract description 3
- 239000002689 soil Substances 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 239000003209 petroleum derivative Substances 0.000 abstract 1
- 239000002574 poison Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 229940005581 sodium lactate Drugs 0.000 abstract 1
- 235000011088 sodium lactate Nutrition 0.000 abstract 1
- 239000001540 sodium lactate Substances 0.000 abstract 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000004310 lactic acid Substances 0.000 description 5
- 235000014655 lactic acid Nutrition 0.000 description 5
- 150000002632 lipids Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000004851 dishwashing Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 208000007502 anemia Diseases 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229960000935 dehydrated alcohol Drugs 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000012262 fermentative production Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000005452 food preservative Substances 0.000 description 1
- 235000019249 food preservative Nutrition 0.000 description 1
- 235000003086 food stabiliser Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000008085 renal dysfunction Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
Landscapes
- Edible Oils And Fats (AREA)
Abstract
The invention discloses a food-grade detergent and a preparation method thereof, and belongs to the field of the detergent. Purely natural plant materials, namely food grade plant oil acyl sodium lactate and polyglycerol ester are adopted as active agent ingredients of the detergent to replace petroleum derivative sodium dodecyl benzene sulfonate which is harmful to a human body, so as to achieve the food grade requirement. Compared with the existing detergent, the food-grade detergent is strong in soil removability, small in residue and free of poison, and ensures human health.
Description
Technical field
The present invention relates to a kind of clean-out system, particularly tableware, food apparatus, fruits and vegetables etc. are had liquid detergent of food grade requirement and preparation method thereof, belong to detergent applications.
Background technology
Its main component of liquid detergent that present cleaning tableware uses is Sodium dodecylbenzene sulfonate (LAS), and this composition is petroleum chemical ingredient, when this material reaches certain level at people's cylinder accumulation, can endanger healthy.According to Chinese Central Television's quality weekly, after washing tableware with 9 kinds of liquid detergents, rinse 12 times with tap water, can also detect average 0.03% residual, accumulate over a long period, take care of the pence, be deposited on the vital organs of the human body of human body, health to us causes serious threat, easily causes human liver renal dysfunction, anaemia, even brings out cancer.
In order to ensure food safety, ensure the healthy of the people, replace the petroleum-type tensio-active agent with the natural phant surfacant, be applied to the food grade liquid detergent and satisfy safe, nontoxic, the healthy requirement of people, have important practical significance.For this reason, exploitation Natural Food grade liquid detergent makes it satisfy foodstuff additive and uses hygienic standard (GB2760-2011) requirement, and is extremely urgent.Have not yet to see related products and preparation method's bibliographical information.
Summary of the invention
The object of the invention is to provide a kind of food grade liquid detergent that replaces the petroleum-type tensio-active agent with the natural phant surfacant; Another purpose is to provide its preparation method.
For realizing the object of the invention; the present invention adopts the plant oil based tensio-active agent of food grade-vegetables oil acyl group Sodium.alpha.-hydroxypropionate and polyglycerol ester as main active ingredient; be prepared into the food grade liquid detergent by adding the batchings such as deionized water, polyvalent alcohol, edible salt, food preservatives, food stabiliser, satisfy the GB2760-2011 requirement.
The actives of described food grade liquid detergent is vegetables oil acyl group Sodium.alpha.-hydroxypropionate and polyglycerol fatty acid ester; Described vegetables oil acyl group Sodium.alpha.-hydroxypropionate has following structure:
R-CO-[O-CHCH
3-CO]
nONa
Wherein R-CO is coco-nut oil fatty acid acyl group, palm-kernel oil fatty acid acyl, palm oil fatty acid acyl group, lauric acid acyl group; N=1-3;
The preferred Polyglycerine C of wherein said polyglycerol fatty acid ester
8-C
12Fatty acid ester.More preferably Polyglycerine mono-laurate, Polyglycerine list octanoate or Polyglycerine monkey cell.
Described food grade liquid detergent can be prepared into liquid or powder.
Food-class liquid liquid detergent formula is:
Vegetables oil acyl group Sodium.alpha.-hydroxypropionate 15-40%
Polyglycerol fatty acid ester 1-5%
Polyvalent alcohol 3-5%
Essence 0.1-0.2%
Water surplus
To be prepared into liquid detergent after above-mentioned composition mixing and stirring.
Food grade powder liquid detergent formula is:
Vegetables oil acyl group Sodium.alpha.-hydroxypropionate 15-40%
Polyglycerol fatty acid ester 1-5%
Composite phosphate 3-8%
Essence 0.1-0.2%
Glucose starch or maltodextrin 50-70%
Xylo-Mucine CMC 0-0.5%
Water 0-5%
Above-mentioned composition is mixed by spraying drying or extruder grain be prepared into the powder liquid detergent.
The present invention is compared with prior art: replace the petroleum-type tensio-active agent by selecting the plant oil based tensio-active agent of food grade-vegetables oil acyl group Sodium.alpha.-hydroxypropionate and polyglycerol ester, be mixed with the food grade liquid detergent take natural surface active agent as activeconstituents.Compare with existing liquid detergent, soil removability is strong, and is residual little, nontoxic, is conducive to HUMAN HEALTH.It is applied to improve food safety, ensure people's health.Its preparation method convenient operation, no coupling product is conducive to suitability for industrialized production.
Embodiment
For the present invention is illustrated better, as follows for embodiment:
Embodiment 1 food-class liquid liquid detergent
Coco-nut oil fatty acid acyl group Sodium.alpha.-hydroxypropionate (n=1) 20%
Polyglycerine mono-laurate 5%
Polyvalent alcohol 3%
Essence 0.2%
Water 71.8%
In container, the above-mentioned water that measures is heated to 40-60 ℃, then other compositions are slowly added, 30 minutes packings of stir about get final product.
Embodiment 2 food-class liquid liquid detergents
Palm-kernel oil fatty acid acyl Sodium.alpha.-hydroxypropionate (n=2) 35%
Polyglycerine list octanoate 2%
Polyvalent alcohol 5%
Essence 0.1%
Water 57.9
Embodiment 3 food grade solid liquid detergents
Lauric acid acyl group Sodium.alpha.-hydroxypropionate (n=3) 17%
Polyglycerine list octanoate 3%
Solid glucose starch 68%
Tripoly phosphate sodium STPP 6%
Sodium hexametaphosphate 99 1%
Xylo-Mucine CMC 0.5%
Essence 0.1%
Water 4.4%
In container, the above-mentioned water that measures is heated to 40-60 ℃, then other compositions are slowly added, stir and to make approximately 50% milk sap, by carrying out spraying drying after homogeneous or extruder grain is prepared into the solid liquid detergent.
Embodiment 4 food grade solid liquid detergents
Palm oil fatty acid acyl group Sodium.alpha.-hydroxypropionate (n=2) 25%
Polyglycerine monkey cell 4.7%
Composite phosphate 5%
Essence 0.1%
Maltodextrin 60%
Xylo-Mucine CMC 0.2%
Water 5%
The food grade liquid detergent that above-described embodiment makes and commercially available several liquid detergent and standard dish washing detergent carry out the detersive power contrast, and soil removability is strong, and washing effect is good.
The configuration of standard dish washing detergent:
Sodium dodecylbenzene sulfonate 14%
Alkyl polyoxyethylene ether sodium sulfate 1%
Dehydrated alcohol 5%
Urea 5%
Water 75%
Regulating pH value with hydrochloric acid or aqueous sodium hydroxide solution is 7-8.
The evaluation method of detersive power is carried out by the rate method step of deoiling in GB9985-2000, and the rate of deoiling result is as follows:
Standard dish washing detergent 91.0%
Commercially available liquid detergent A 95.3%
Commercially available liquid detergent B 93.8%
The inventive example 1 96.6%
The inventive example 2 98.8%
The inventive example 3 96.1%
The inventive example 4 98.3%
Described vegetables oil acyl group Sodium.alpha.-hydroxypropionate prepares by the following technical programs:
Food grade lactic acid is put in reactor, carried out under 90-130 ℃ of vacuum polyreaction 1-2 hour, after surveying acid number to 230-500, drop into plant oil based lipid acid, add simultaneously catalyzer sodium hydroxide, be heated to 160-190 ℃ of reaction 4-6 hour under vacuum, measure acid number to 140-160, temperature is reduced to 70-90 ℃, more slowly adds the edible soda ash aqueous solution to neutralize.
Also can realize by following steps: food grade lactic acid is put in reactor; control temperature at 40-60 ℃; slowly add the edible soda ash aqueous solution to neutralize; then drop into plant oil based lipid acid, add simultaneously catalyzer sodium hydroxide, vacuumize; carried out polyreaction 1-2 hour at 90-130 ℃; continue to be warmed up to 160-190 ℃ of reaction 4-6 hour under vacuum, measure acid number to less than after 80s, obtain vegetables oil acyl group Sodium.alpha.-hydroxypropionate.
Described plant oil based lipid acid is: coco-nut oil fatty acid, palm-kernel oil lipid acid, palm oil fatty acid, lauric acid.
The lactic acid of the fermentative production such as lactic acid preferred food product level corn used, rice, potato class, molasses juice.
The mol ratio of lactic acid and plant oil based lipid acid is 1-3:1.
Claims (6)
1. a food grade liquid detergent, is characterized in that, the actives of this liquid detergent is vegetables oil acyl group Sodium.alpha.-hydroxypropionate and polyglycerol fatty acid ester; Described vegetables oil acyl group Sodium.alpha.-hydroxypropionate has following structure:
R-CO-[O-CHCH
3-CO]
nONa
Wherein R-CO is coco-nut oil fatty acid acyl group, palm-kernel oil fatty acid acyl, palm oil fatty acid acyl group or lauric acid acyl group; N=1-3.
2. food grade liquid detergent as claimed in claim 1, is characterized in that, the liquid detergent formula is:
Vegetables oil acyl group Sodium.alpha.-hydroxypropionate 15-40%
Polyglycerol fatty acid ester 1-5%
Polyvalent alcohol 3-5%
Essence 0.1-0.2%
Water surplus.
3. food grade liquid detergent as claimed in claim 1, is characterized in that, powder liquid detergent formula is:
Vegetables oil acyl group Sodium.alpha.-hydroxypropionate 15-40%
Polyglycerol fatty acid ester 1-5%
Composite phosphate 3-8%
Xylo-Mucine CMC 0-0.5%
Essence 0.1-0.2%
Glucose starch or maltodextrin 50-70%
Water 0-5%.
4. as one of them described food grade liquid detergent of claim 1-3, it is characterized in that the preferred Oleum Cocois acyl group of vegetables oil acyl group Sodium.alpha.-hydroxypropionate Sodium.alpha.-hydroxypropionate.
5. as claim 1-3 food grade liquid detergent as described in one of them, it is characterized in that the preferred Polyglycerine C of described polyglycerol fatty acid ester
8-C
12Fatty acid ester.
6. food grade liquid detergent as claimed in claim 5, is characterized in that the preferred Polyglycerine mono-laurate of described polyglycerol fatty acid ester, Polyglycerine list octanoate or Polyglycerine monkey cell.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310076181.1A CN103113997B (en) | 2013-03-11 | 2013-03-11 | Food-grade detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310076181.1A CN103113997B (en) | 2013-03-11 | 2013-03-11 | Food-grade detergent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103113997A true CN103113997A (en) | 2013-05-22 |
| CN103113997B CN103113997B (en) | 2014-10-29 |
Family
ID=48412416
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|---|---|---|---|
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104611159A (en) * | 2014-12-31 | 2015-05-13 | 鲁东大学 | Cleaning agent for cleaning fruits and vegetables |
| CN105400600A (en) * | 2014-09-15 | 2016-03-16 | 福建省梦娇兰日用化学品有限公司 | Edible fruit and vegetable cleaning agent |
| CN106773137A (en) * | 2017-02-28 | 2017-05-31 | 陈邦宋 | The preparation method of Anti-fog glasses and the bloom inhibitor for the glasses |
| CN107164982A (en) * | 2017-07-04 | 2017-09-15 | 济宁锦祥科技发展有限公司 | A kind of textile printing and dyeing pollution-free food level detergent |
| CN109453060A (en) * | 2018-11-05 | 2019-03-12 | 宁波御坊堂生物科技有限公司 | Long-acting edibility detergent of microemulsion-type and preparation method thereof |
| CN111286411A (en) * | 2018-12-10 | 2020-06-16 | 上海家化联合股份有限公司 | Cleaning composition for hard surface cleaning |
| CN113841896A (en) * | 2021-10-25 | 2021-12-28 | 玉山县大成仓食品有限公司 | Edible oil with health care function and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104611159A (en) * | 2014-12-31 | 2015-05-13 | 鲁东大学 | Cleaning agent for cleaning fruits and vegetables |
| CN104611159B (en) * | 2014-12-31 | 2018-06-22 | 鲁东大学 | A kind of cleaning agent for being used to clean fruits and vegetables |
| CN106773137A (en) * | 2017-02-28 | 2017-05-31 | 陈邦宋 | The preparation method of Anti-fog glasses and the bloom inhibitor for the glasses |
| CN107164982A (en) * | 2017-07-04 | 2017-09-15 | 济宁锦祥科技发展有限公司 | A kind of textile printing and dyeing pollution-free food level detergent |
| CN109453060A (en) * | 2018-11-05 | 2019-03-12 | 宁波御坊堂生物科技有限公司 | Long-acting edibility detergent of microemulsion-type and preparation method thereof |
| CN109453060B (en) * | 2018-11-05 | 2021-09-14 | 宁波御坊堂生物科技有限公司 | Microemulsion long-acting edible detergent and preparation method thereof |
| CN111286411A (en) * | 2018-12-10 | 2020-06-16 | 上海家化联合股份有限公司 | Cleaning composition for hard surface cleaning |
| CN113841896A (en) * | 2021-10-25 | 2021-12-28 | 玉山县大成仓食品有限公司 | Edible oil with health care function and preparation method thereof |
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