CN103113163B - Soil-loosening root growth promoting agent and preparation method thereof - Google Patents
Soil-loosening root growth promoting agent and preparation method thereof Download PDFInfo
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- CN103113163B CN103113163B CN201310067402.9A CN201310067402A CN103113163B CN 103113163 B CN103113163 B CN 103113163B CN 201310067402 A CN201310067402 A CN 201310067402A CN 103113163 B CN103113163 B CN 103113163B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 230000002786 root growth Effects 0.000 title abstract description 7
- 230000001737 promoting effect Effects 0.000 title abstract description 5
- 239000002689 soil Substances 0.000 claims abstract description 78
- 229920001214 Polysorbate 60 Polymers 0.000 claims abstract description 7
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims abstract description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 7
- 229950011392 sorbitan stearate Drugs 0.000 claims abstract description 7
- 150000001413 amino acids Chemical class 0.000 claims abstract description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 5
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 5
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 5
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims abstract description 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 5
- -1 0.06-0.2 part Chemical compound 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- 238000005984 hydrogenation reaction Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 238000006386 neutralization reaction Methods 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000006277 sulfonation reaction Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 230000036541 health Effects 0.000 abstract description 6
- 239000003337 fertilizer Substances 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 239000007789 gas Substances 0.000 abstract description 4
- 230000004931 aggregating effect Effects 0.000 abstract 2
- 239000008187 granular material Substances 0.000 abstract 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 abstract 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 abstract 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 229940099596 manganese sulfate Drugs 0.000 abstract 1
- 235000007079 manganese sulphate Nutrition 0.000 abstract 1
- 239000011702 manganese sulphate Substances 0.000 abstract 1
- 239000000084 colloidal system Substances 0.000 description 16
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- 239000002734 clay mineral Substances 0.000 description 6
- 235000015097 nutrients Nutrition 0.000 description 6
- 239000002681 soil colloid Substances 0.000 description 5
- 238000005056 compaction Methods 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000036449 good health Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 238000003971 tillage Methods 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910018626 Al(OH) Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 231100000652 hormesis Toxicity 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000003248 secreting effect Effects 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002688 soil aggregate Substances 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 235000019157 thiamine Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Abstract
The invention relates to a soil-loosening root growth promoting agent for creating a good and health environment for the root growth of a plant, enhancing the granule aggregating structure of soil and improving the yield of the plant and a preparation method thereof. The soil-loosening root growth promoting agent comprises the following raw materials in parts by weight: 0.007 to 0.09 part of ammonium sulfate, 0.003 to 0.03 part of amino acid powder, 0.05 to 0.20 part of zinc sulfate, 0.06 to 0.2 part of ferrous sulfate, 0.003 to 0.15 part of dehydrated polyoxyethylene sorbitan stearate, 0.01 to 0.20 part of sodium lauryl ether sulfate, 0.01 to 0.20 part of dodecylbenzene sulfonic acid, 0.06 to 0.20 part of methyl sodiosul foaliphatate, 0.03 to 0.15 part of manganese sulfate and 0.02 to 0.3 part of ammonium hydrogen phosphate. Through application of the soil-loosening root growth promoting agent, a root layer is activated, the soil of the root layer is loosened, the soil hardening of the root layer is broken, the soil living environment of the root layer is improved, the proportion of water, fertilizer, gas and heat in the soil of the root layer is automatically harmonized, the granule aggregating structure of the soil is enhanced,and substances which can pollute the soil and are harmful to soil health are cleaned and removed, so that a good and health environment for the root growth is created. As a result, the yield of the plant is improved.
Description
Technical field
The present invention relates to a kind of is a good health environment of plant root growth creation, strengthens the crumb structure of soil and improves the promoter and preparation method thereof that loosens the soil of crop yield.
Background technology
Since entering the new millennium, the cultivation of crop, breeding, fertilizer practice and Development of Farming System have reached to a certain degree, crop yield will further improve very limited, hovered in recent years always or fluctuateed, improving constantly along with Agricultural Mechanization Degree particularly, peasant generally uses Rotary tillage rake to plow, because of the Rotary tillage rake speed of plowing fast, prepartion of land, clod is few, popularized rapidly, but the consequence causing is Rotary tillage rake, the topsoil that plows is shallow, generally between 8 ~ 12cm, routine is plowed between general 25 ~ 30cm, in the course of time, use continuously, cause soil compaction, soil permeability is obstructed, water, fertile, gas, heat is inharmonious, the soil growing environment that crop root has not had.Under crop root, prick difficulty, crop yield fluctuates always, has seriously restricted the raising of crop yield.Meanwhile, residual in a large number along with the not scientific and agricultural chemicals of using of part fertilizer, also causes part soil compaction and soil pollution, causes the not high and quality of the to a certain degree output of crop to decline.
At present, on market, also do not activate root layer, loose root layer soil, break root layer soil compaction, improve root layer soil living environment, the ratio of the water of automatic synchronization soil root layer, fertilizer, gas, heat, increase the crumb structure of soil, the material to the pollution substance of soil and unfavorable soil health is fallen in clean, drip washing.For the growth of root system, create the environment of a good health, significantly promoting a kind of material that root system increases or the plant husbandry of technology ，Zhe Dui China further to improve crop yield in producing, to improve crop quality particularly important.
Summary of the invention
In order to overcome above-mentioned defect of the prior art, the invention provides a kind of can chessom, add deep plough level, improve the grow promoter and preparation method thereof that loosens the soil in bad border of crop root.
For achieving the above object, technical scheme provided by the invention is as follows:
A promoter, is characterized in that: this promoter that loosens the soil comprises that following raw material makes by weight: 0.007-0.09 part, ammonium sulfate, 0.003-0.03 part of amino acid powder, 0.05-0.20 part, zinc sulfate, 0.06-0.2 part, ferrous sulfate, 0.003-0.15 part of polyoxyethylene sorbitan stearate, 0.0 1-0.20 part, alkylpolyoxyethylene sodium sulfate, 0.06-0.20 part of methyl sodiosul foaliphatate, 0.03-0.15 part of manganous sulfate, 0.02-0.3 part of ammonium hydrogen phosphate.
Described in the loosen the soil preparation method of promoter, it is characterized in that: carry out in accordance with the following steps in process of production:
Step 1), methyl sodiosul foaliphatate are to be made through sulfonation neutralization by the saturated C12 ~ C18 fatty acid methyl ester of hydrogenation;
Step 2), polyoxyethylene sorbitan stearate is that and reacting ethylene oxide make;
Step 3), by polyoxyethylene sorbitan stearate, alkylpolyoxyethylene sodium sulfate, methyl sodiosul foaliphatate liquid, inject reactor, fully mix after 12 hours, again liquid is injected in advance ammonium sulfate, amino acid powder, zinc sulfate, manganous sulfate, ammonium hydrogen phosphate, the solid of ferrous sulfate is proportionally prepared in the stirrer after mixing, under 25 ° of C room temperatures, stir 45 minutes, after fully mixing, put in the container of sealing 56 hours, after reaction thoroughly, open container, aeration-cooling, make it consistent with outside temperature, then, granulation sub-sieve, detect chemical examination, metering, filling, sealing, packing, warehouse-in.
The present invention can activate root layer, loose root layer soil, break root layer soil compaction, improve root layer soil living environment, the ratio of the water of automatic synchronization soil root layer, fertilizer, gas, heat, the crumb structure of increase soil, the material to the pollution substance of soil and unfavorable soil health is fallen in clean, drip washing.For the growth of root system, create the environment of a good health, strengthen soil crumb structure, loose root layer soil, promote that root system of plant increases, lower bundle and improve crop yield.
The promoter mechanism of loosening the soil of the present invention:
Soil is much comprised of soil colloid, and soil colloid generally can be divided into mineral colloid, organic colloid, organic-inorganic composite gel;
1, mineral colloid: mineral colloid quantitatively wants many more than organic colloid, is mainly soil clay particle, and it comprises hydrous oxide class clay mineral and the laminar silicic acid salt clay minerals such as Fe, Al, Si.
The hydrous oxides such as Fe, Al, Si: oxidizing aqueous silicon: write as SiO more<sub TranNum="77">2</sub>h<sub TranNum="78">2</sub>o, also can be write as metasilicic acid H2SiO<sub TranNum="79">3</sub>, SiO<sub TranNum="80">2</sub>h<sub TranNum="81">2</sub>o can dissociate H+ while there is ionization and make colloid electronegative.Oxidizing aqueous Fe, Al: write as Fe more<sub TranNum="82">2</sub>o<sub TranNum="83">3</sub>nH<sub TranNum="84">2</sub>o, Al<sub TranNum="85">2</sub>o<sub TranNum="86">3</sub>nH<sub TranNum="87">2</sub>o, also available Fe(OH)<sub TranNum="88">3</sub>, Al(OH)<sub TranNum="89">3</sub>form represent, it is the product of the thorough weathering of silicate minerals, on the high soil of rate of decay, these class mineral are more.These class mineral belong to amphotytoid, and its charged situation depends primarily on the acid-base reaction of soil, and acidic conditions (pH < 5) is positively charged, electronegative under alkaline condition.General soils of north China: degree of base saturation is large, and soil pH is higher, soils in south china: degree of base saturation is low, and soil pH is low.
2, organic colloid:
Organic colloid mainly refers to the soil ulmin in soil.
A. soil ulmin particle is very tiny, has huge specific surface area.
The total surface area of every 1 kilogram of soil ulmin can reach 1000 ㎡, and specific surface area is extremely huge.
B. with a large amount of negative charges
Soil ulmin has a lot of functional groups in forming, such as these functional groups such as R-COOH, R-CH2-OH can be with a large amount of negative charges after dissociating, the electronegative quantity of soil ulmin is more much bigger than clay mineral, so it is also much bigger than clay mineral to preserve cationic ability.
R-NH in soil ulmin functional group in addition
2protonated, can also make soil ulmin positively charged.
C. soil ulmin is hydrophilic colloid, has the wetting ability of height
3, organic-inorganic composite gel:
The general Individual existence seldom of organic colloid in soil, the overwhelming majority is closely linked and forms organic-inorganic compounding colloid with mineral colloid, the mode of connection of organic colloid and mineral colloid is diversified, but is mainly by polyvalent cation (Ca such as divalence, trivalents
2+, Mg
2+, Fe
3+, Al
3+deng) as bridge, soil ulmin and clay mineral are connected together, or the functional group by soil ulmin surface such as-COOH ,-OH connect together with mode and the clay mineral of hydrogen bond.
Soil colloid, much with very strong negative charge, attracts positively charged hydrogen ion in soil and water.In loosing soil agent, contain very polyanionic tensio-active agent, it is a kind of multivalent anions active substance, utilize the soil water to activate its effective constituent, by soil pore, in soil, react and play a role, utilize the physical chemistry absorptive character principle of soil, carry out the ion exchange of soil, make the hydrogen ion of adsorption by soil free out, increase Cation Exchange Capacity in Soils, make soil form more hole, improve soil aggregate, strengthen ventilation property and the rich water penetrating power of soil, thereby reach the object of chessom.
In addition the multiple nutrients in promoter when having an effect by adsorption by soil on colloid, by reversible reaction, that is to say that the positively charged ion of absorption on soil colloid is when the composition of the soil solution and concentration change, completely can be replaced and enter the soil solution by other positively charged ion, this point plays a very important role in root system of plant dietetic alimentation, plant is mainly the nutrient that absorbs the soil solution to the absorption of nutrient, the nutrient overwhelming majority of soil colloids need to be transferred in the soil solution and just can be absorbed, because cation exchange reaction is reversible reaction, make by the positively charged ion of absorption, can be got off by other cationic exchange completely, entering the soil solution absorbs for plant, so, improved the nutrient environment of root of the crop layer, just make easily lower bundle of crop root, nutritional sufficiency, amino acid thiamines has again certain hormesis to the secretory product of root system, can promote that the bundle of root system is dark, bundle is many, plant growth is healthy and strong.In addition a part of tensio-active agent that the multiple nutrients in promoter is loosened the soil on colloid by adsorption by soil in promoter when having an effect is in effect soil; after reacting, the acid agrichemical residual with a part dissolve; with water will leaching loss, clean, to a certain degree protected the health of edatope.
Claims (2)
1. the promoter that loosens the soil, is characterized in that: this promoter that loosens the soil is made by following raw material by weight: 0.007-0.09 part, ammonium sulfate, 0.003-0.03 part of amino acid powder, 0.05-0.20 part, zinc sulfate, 0.06-0.2 part, ferrous sulfate, 0.003-0.15 part of polyoxyethylene sorbitan stearate, 0.0 1-0.20 part, alkylpolyoxyethylene sodium sulfate, 0.06-0.20 part of methyl sodiosul foaliphatate, 0.03-0.15 part of manganous sulfate, 0.02-0.3 part of ammonium hydrogen phosphate.
2. a preparation method for the promoter that loosens the soil as claimed in claim 1, is characterized in that: carry out in accordance with the following steps in process of production:
Step 1), methyl sodiosul foaliphatate are to be made through sulfonation neutralization by the saturated C12 ~ C18 fatty acid methyl ester of hydrogenation;
Step 2), polyoxyethylene sorbitan stearate is that and reacting ethylene oxide make;
Step 3), by polyoxyethylene sorbitan stearate, alkylpolyoxyethylene sodium sulfate, , methyl sodiosul foaliphatate liquid, inject reactor, fully mix after 12 hours, again liquid is injected in advance ammonium sulfate, amino acid powder, zinc sulfate, manganous sulfate, ammonium hydrogen phosphate, the solid of ferrous sulfate is proportionally prepared in the stirrer after mixing, under 25 ° of C room temperatures, stir 45 minutes, after fully mixing, put in the container of sealing 56 hours, after reaction thoroughly, open container, aeration-cooling, make it consistent with outside temperature, then, granulation sub-sieve, detect chemical examination, metering, filling, sealing, packing, warehouse-in.
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| CN103113163B true CN103113163B (en) | 2014-01-15 |
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| CN107162728A (en) * | 2017-05-25 | 2017-09-15 | 四川雷鸣环保装备有限公司 | Charcoal base high-effective organic and inorganic composite fertilizer preparation method |
| CN107324941A (en) * | 2017-06-12 | 2017-11-07 | 四川雷鸣环保装备有限公司 | Municipal sludge charcoal base composite fertilizer and biological fuel gas joint production process |
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| CN101670206A (en) * | 2008-09-09 | 2010-03-17 | 黄小雷 | Filter membrane replacing apparatus for pollution index value monitoring instrument |
| CN101913952B (en) * | 2010-09-03 | 2013-04-17 | 中港泰富(北京)高科技有限公司 | Polyelement composite fertilizer and preparation method and application thereof |
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Application publication date: 20130522 Assignee: Shangqiu Woli fertilizer Co.,Ltd. Assignor: Henan Railway Locomotive Agricultural Technology Co.,Ltd. Contract record no.: X2022980011657 Denomination of invention: Soil loosening root promoting agent and preparation method thereof Granted publication date: 20140115 License type: Common License Record date: 20220804 |
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