CN103111331B - 粉煤灰基碱性材料的制备方法及其应用方法 - Google Patents
粉煤灰基碱性材料的制备方法及其应用方法 Download PDFInfo
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- CN103111331B CN103111331B CN201310012435.3A CN201310012435A CN103111331B CN 103111331 B CN103111331 B CN 103111331B CN 201310012435 A CN201310012435 A CN 201310012435A CN 103111331 B CN103111331 B CN 103111331B
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- Prior art keywords
- coal ash
- preparation
- fly ash
- acrylic acid
- formaldehyde
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- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000000463 material Substances 0.000 title abstract description 9
- 239000010883 coal ash Substances 0.000 title abstract 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 52
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 21
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 12
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims abstract description 11
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 11
- 229940079827 sodium hydrogen sulfite Drugs 0.000 claims abstract description 11
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims abstract description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 8
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010881 fly ash Substances 0.000 claims description 34
- 239000000347 magnesium hydroxide Substances 0.000 claims description 7
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 5
- 239000007789 gas Substances 0.000 abstract description 4
- 230000004913 activation Effects 0.000 abstract description 3
- 239000002910 solid waste Substances 0.000 abstract description 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- 238000002474 experimental method Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000006555 catalytic reaction Methods 0.000 description 4
- 238000003915 air pollution Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000011165 process development Methods 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Processing Of Solid Wastes (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
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CN201310012435.3A CN103111331B (zh) | 2013-01-14 | 2013-01-14 | 粉煤灰基碱性材料的制备方法及其应用方法 |
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CN201310012435.3A CN103111331B (zh) | 2013-01-14 | 2013-01-14 | 粉煤灰基碱性材料的制备方法及其应用方法 |
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CN103111331A CN103111331A (zh) | 2013-05-22 |
CN103111331B true CN103111331B (zh) | 2015-03-11 |
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CN201310012435.3A Expired - Fee Related CN103111331B (zh) | 2013-01-14 | 2013-01-14 | 粉煤灰基碱性材料的制备方法及其应用方法 |
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CN (1) | CN103111331B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106698490B (zh) * | 2017-01-24 | 2018-05-22 | 东华理工大学 | 一种从粉煤灰中制备铝前驱物及其制备纳米氧化铝的方法 |
CN108993379B (zh) * | 2018-07-18 | 2021-02-19 | 太原理工大学 | 一种粉煤灰基吸附材料的制备方法及其应用 |
CN109109109A (zh) * | 2018-08-01 | 2019-01-01 | 福州市晋安区绿奇鑫环保科技有限公司 | 一种人造板去甲醛的方法 |
CN109126723B (zh) * | 2018-09-13 | 2021-04-16 | 太原理工大学 | 一种含羟基的粉煤灰基吸附材料的制备方法及其应用于镍污染治理 |
CN111434378A (zh) * | 2019-01-15 | 2020-07-21 | 浙江明江新材料科技股份有限公司 | 一种高分子甲醛吸附剂的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1589952A (zh) * | 2003-08-26 | 2005-03-09 | 上海赛艾生物科技有限公司 | 可视型甲醛气体消除剂和甲醛检测珠及它们的制备方法 |
CN101376050A (zh) * | 2007-08-29 | 2009-03-04 | 旭玻璃纤维股份有限公司 | 醛捕捉剂及使用该醛捕捉剂的建筑材料 |
WO2011119714A1 (en) * | 2010-03-26 | 2011-09-29 | E.I. Dupont De Nemours And Company | Perhydrolase providing improved specific activity |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS59189144A (ja) * | 1983-04-12 | 1984-10-26 | Hokuriku Electric Power Co Inc:The | ゴム用充填剤 |
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2013
- 2013-01-14 CN CN201310012435.3A patent/CN103111331B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1589952A (zh) * | 2003-08-26 | 2005-03-09 | 上海赛艾生物科技有限公司 | 可视型甲醛气体消除剂和甲醛检测珠及它们的制备方法 |
CN101376050A (zh) * | 2007-08-29 | 2009-03-04 | 旭玻璃纤维股份有限公司 | 醛捕捉剂及使用该醛捕捉剂的建筑材料 |
WO2011119714A1 (en) * | 2010-03-26 | 2011-09-29 | E.I. Dupont De Nemours And Company | Perhydrolase providing improved specific activity |
Non-Patent Citations (2)
Title |
---|
蔡志红,等."改性粉煤灰对空气中甲醛的吸附研究".《中南大学学报(自然科学版)》.2011,第42卷(第7期),第2156-2161页. * |
袁立强,等."改性粉煤灰处理工业废水的最新研究进展".《粉煤灰综合利用》.2011,(第3期),第47-53页. * |
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Owner name: TAIYUAN UNIV. OF TECHNOLOGY Free format text: FORMER OWNER: DU YALI Effective date: 20150505 Owner name: SHANXI SHUOBO TECHNOLOGY CO., LTD. Effective date: 20150505 |
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Inventor after: Wu Xu Inventor after: Du Yali Inventor after: Wang Bin Inventor after: Zhao Qiang Inventor after: Song Shaofei Inventor after: Zhu Baolin Inventor after: Liu Youjun Inventor before: Du Yali Inventor before: Wang Bin Inventor before: Zhao Qiang Inventor before: Song Shaofei Inventor before: Zhu Baolin Inventor before: Liu Youjun |
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Free format text: CORRECT: INVENTOR; FROM: DU YALI WANG BIN ZHAO QIANG SONG SHAOFEI ZHU BAOLIN LIU YOUJUN TO: WU XU DU YALI WANG BIN ZHAO QIANG SONG SHAOFEI ZHU BAOLIN LIU YOUJUN |
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TR01 | Transfer of patent right |
Effective date of registration: 20150505 Address after: 030024 Yingze, Shanxi Province, Berlin District, West Street, No. 79, No. Patentee after: Taiyuan University of Technology Patentee after: Shanxi Yuan Technology Co., Ltd. Address before: 030024 room 1006, science and technology building, Taiyuan University of Technology, 79 West Avenue, Wan Berlin District, Shanxi, Taiyuan, Yingze Patentee before: Du Yali |
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