CN103109836B - Pesticidal combination containing metaflumizone and dimehypo or cartap - Google Patents
Pesticidal combination containing metaflumizone and dimehypo or cartap Download PDFInfo
- Publication number
- CN103109836B CN103109836B CN201310091188.0A CN201310091188A CN103109836B CN 103109836 B CN103109836 B CN 103109836B CN 201310091188 A CN201310091188 A CN 201310091188A CN 103109836 B CN103109836 B CN 103109836B
- Authority
- CN
- China
- Prior art keywords
- metaflumizone
- pesticidal combination
- dimehypo
- cartap
- kinds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000005914 Metaflumizone Substances 0.000 title claims abstract description 86
- MIFOMMKAVSCNKQ-HWIUFGAZSA-N Metaflumizone Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)N\N=C(C=1C=C(C=CC=1)C(F)(F)F)\CC1=CC=C(C#N)C=C1 MIFOMMKAVSCNKQ-HWIUFGAZSA-N 0.000 title claims abstract description 86
- 230000000361 pesticidal effect Effects 0.000 title claims abstract description 22
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 title claims abstract description 14
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 title claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 35
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 14
- 241000500437 Plutella xylostella Species 0.000 claims abstract description 13
- 241000255777 Lepidoptera Species 0.000 claims abstract description 10
- 241000008892 Cnaphalocrocis patnalis Species 0.000 claims abstract description 7
- 229920000742 Cotton Polymers 0.000 claims abstract description 7
- 241000209094 Oryza Species 0.000 claims abstract description 7
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 7
- 235000009566 rice Nutrition 0.000 claims abstract description 7
- 235000013311 vegetables Nutrition 0.000 claims abstract description 7
- 241000255967 Helicoverpa zea Species 0.000 claims abstract description 6
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 6
- 241000665051 Chilo sacchariphagus indicus Species 0.000 claims abstract description 5
- 241000426497 Chilo suppressalis Species 0.000 claims abstract description 5
- 241000256247 Spodoptera exigua Species 0.000 claims abstract description 5
- 241000255901 Tortricidae Species 0.000 claims abstract description 5
- 238000009825 accumulation Methods 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 14
- 238000009736 wetting Methods 0.000 claims description 14
- 239000000375 suspending agent Substances 0.000 claims description 12
- 239000004562 water dispersible granule Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 241000238631 Hexapoda Species 0.000 abstract description 11
- 239000003814 drug Substances 0.000 abstract description 10
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 239000004615 ingredient Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 239000000470 constituent Substances 0.000 abstract description 3
- 238000009472 formulation Methods 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000001035 drying Methods 0.000 description 9
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 8
- 239000005875 Acetamiprid Substances 0.000 description 8
- 239000005663 Pyridaben Substances 0.000 description 8
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 8
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 description 8
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 6
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 description 6
- 229960001952 metrifonate Drugs 0.000 description 6
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 description 6
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 6
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 5
- 239000002917 insecticide Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000010534 mechanism of action Effects 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000000227 grinding Methods 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 108010052164 Sodium Channels Proteins 0.000 description 2
- 102000018674 Sodium Channels Human genes 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 241000256844 Apis mellifera Species 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241000738498 Epitrix pubescens Species 0.000 description 1
- 241001486250 Etiella zinckenella Species 0.000 description 1
- 241000256602 Isoptera Species 0.000 description 1
- -1 Mobucin Chemical compound 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 241000985245 Spodoptera litura Species 0.000 description 1
- 239000005937 Tebufenozide Substances 0.000 description 1
- ZXQYGBMAQZUVMI-XDHOZWIPSA-N [cyano-(3-phenoxyphenyl)methyl] 3-[(e)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(\C=C(\Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-XDHOZWIPSA-N 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 210000003050 axon Anatomy 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000007905 drug manufacturing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 150000007659 semicarbazones Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Abstract
The invention discloses a kind of Pesticidal combination containing metaflumizone, wherein, be made up of two kinds of active components A and B, A composition is metaflumizone, and B component is the one of dimehypo, cartap, and it is 1:50 ~ 10:1 that described two kinds of active components A and B form mass ratio.The lepidoptera pest of the crops such as the control of this Pesticidal combination vegetables, paddy rice, fruit tree, cotton, as diamond-back moth, beet armyworm, rice leaf roller, striped rice borer, paddy stem borer, leaf roller, cotton bollworm etc.The present invention utilizes two kinds of active constituent mixtures, according to the co-toxicity coefficient CTC value calculating mixture by the abundant method of Sun Yun, shows to have obvious synergistic effect, can reduce effective ingredient dosage, delay insect to the drug-fast generation of new medicament metaflumizone.<!-- 2 -->
Description
The application is the divisional application of " Pesticidal combination containing metaflumizone " application for a patent for invention, original application day: on January 5th, 2010, application number: 201010003850.9
Technical field
The present invention relates to a kind of composition pesticide, particularly relate to the Pesticidal combination containing metaflumizone.
Background technology
The lepidoptera pests such as rice leaf roller, striped rice borer, paddy stem borer, diamond-back moth, cotton bollworm are the important pests on the crops such as paddy rice, vegetables, cotton.In recent years, owing to using containing a kind of insecticide of active constituent continuously, these insects have produced pesticide resistance in various degree, and times for spraying increases, and cause that peasant burden increases the weight of, the destruction etc. of environmental pollution and ecotope.
Metaflumizone (metaflumizone) is recent years abroad company a kind of noval chemical compound newly developed, belong to semicarbazones insecticides, mechanism of action is unique, effectively can prevent and treat the larva of the multiple lepidoptera pest such as diamond-back moth, rice leaf roller and some coleoptera, adult, also can be used for control sanitary insect pest as insects such as ant, termite, fly class, cockroaches.Metaflumizone is a kind of insecticide of brand-new mechanism of action, by being attached on the acceptor of sodium-ion channel, hinders sodium ion to pass through.Enter polypide after this medicine of insect's food-taking, block the sodium-ion channel on insect neuron axon film by the mechanism of action of uniqueness, make sodium ion not by axolemma, and then suppressing nerve impulse to make excessive the loosening of polypide, paralysis, after several hours, namely insect stops taking food, dead in 1 ~ 3 day.Metaflumizone, to birds, honeybee low toxicity, can promptly be hydrolyzed and photodissociation in water.
In Chinese patent, also there is no the report of metaflumizone Pesticidal combination.
Advantage of the present invention and good effect are undertaken composite by the insecticide of two kinds of different structures, the different mechanism of action, be control resistant insect, expand the effective way of insecticidal spectrum and raising drug effect, the more important thing is and avoid or delay the generation of insect to new composition metaflumizone resistance.
Summary of the invention
The object of the invention is to: for preventing the drug-fast generation of metaflumizone, providing a kind of Pesticidal combination containing metaflumizone of efficient, wide spectrum, low toxicity, to prevent and treat the multiple lepidoptera pest on paddy rice of causing harm, vegetables, fruit tree, cotton etc.
To achieve these goals, technical scheme of the present invention is: provide a kind of Pesticidal combination containing metaflumizone, wherein, be made up of two kinds of active components A and B, A composition is metaflumizone, B component is the one of beta-cypermethrin, Cyhalothrin, Profenofos, chlorophos, diafenthiuron, pleocidin, worm hydrazides, HEXAFLUMURON, chlorfenapyr, pyridaben, Acetamiprid, Mobucin, dimehypo, cartap, and it is 1:50 ~ 10:1 that described two kinds of active components A and B form mass ratio.
Preferably, described two kinds of active components A and B mass accumulation percentage account for 1% ~ 60% of gross mass.
Preferably, this Pesticidal combination contains the auxiliary ingredients such as normally used solvent, auxiliary agent, carrier in pesticidal preparations, is convenient to make the formulation being suitable for using, as wetting powder, water dispersible granules, suspending agent.
Preferably, the lepidoptera pest of the crops such as the control of this Pesticidal combination vegetables, paddy rice, fruit tree, cotton, as diamond-back moth, beet armyworm, rice leaf roller, striped rice borer, paddy stem borer, leaf roller, cotton bollworm etc.
The invention has the advantages that: the present invention utilizes two kinds of active constituent mixtures, according to the co-toxicity coefficient CTC value calculating mixture by the abundant method of Sun Yun, show that there is obvious synergistic effect, effective ingredient dosage can be reduced, delay insect to the drug-fast generation of new medicament chlorine worm benzoyl.
Embodiment
Below in conjunction with preferred embodiment, the invention will be further described, but the present invention is never limited to following embodiment.In following examples, each component percentages all by quality ratio.
Example of formulations 1
4% metaflumizone beta-cypermethrin, namely both mass ratioes are the wettable mealiness pulvis of 1:3
After above-mentioned each component fully being mixed, carry out drying, cooling, fine grinding, both must be mixed with 4% metaflumizone beta-cypermethrin wetting powder.
Described metaflumizone and beta-cypermethrin mass accumulation percentage account for 4% of gross mass.
Example of formulations 2
5% metaflumizone Cyhalothrin, namely both mass ratioes are the wettable mealiness pulvis of 1:1
After above-mentioned each component is fully mixed, carry out drying, cooling, levigate, both must be mixed with 5% metaflumizone Cyhalothrin wetting powder.
Described metaflumizone and Cyhalothrin mass accumulation percentage account for 5% of gross mass.
Example of formulations 3
11% metaflumizone Profenofos, namely both mass ratioes are the water dispersible granules of 1:10
After above-mentioned each component is fully mixed, carry out granulation after ultra-fine grinding, drying, screening, both made 11% metaflumizone Profenofos water dispersible granules.
Described metaflumizone and Profenofos mass accumulation percentage account for 11% of gross mass.
Example of formulations 4
17.5% metaflumizone chlorophos, namely both mass ratioes are the wetting powder of 1:6
After above-mentioned each component is fully mixed, carry out drying, cooling, levigate, both must be mixed with 17.5% metaflumizone chlorophos wetting powder.
Described metaflumizone and chlorophos mass accumulation percentage account for 17.5% of gross mass.
Example of formulations 5
30% metaflumizone diafenthiuron, namely both mass ratioes are the suspending agent of 1:5
Above-mentioned each component fully mixed, the 25g that adds water fully grinds, and water complements to 100g, is mixed with 30% metaflumizone diafenthiuron suspension agent.
Described metaflumizone and diafenthiuron mass accumulation percentage account for 30% of gross mass.
Example of formulations 6
4.5% metaflumizone pleocidin, namely both mass ratioes are the suspending agent of 2:1
Above-mentioned each component fully mixed, the 25g that adds water fully grinds, and water complements to 100g, is mixed with 4.5% metaflumizone pleocidin suspension.
Described metaflumizone and pleocidin mass accumulation percentage account for 4.5% of gross mass.
Example of formulations 7
10% metaflumizone worm hydrazides, namely both mass ratioes are the suspending agent of 1:1
Above-mentioned each component fully mixed, the 25g that adds water fully grinds, and water complements to 100g, is mixed with 10% metaflumizone Tebufenozide suspending agent.
Described metaflumizone and worm hydrazides mass accumulation percentage account for 10% of gross mass.
Example of formulations 8
10% metaflumizone HEXAFLUMURON, namely both mass ratioes are the wetting powder of 1:1
After above-mentioned each component is fully mixed, carry out drying, cooling, levigate, be both mixed with 10% metaflumizone HEXAFLUMURON wetting powder.
Described metaflumizone and HEXAFLUMURON mass accumulation percentage account for 10% of gross mass.
Example of formulations 9
15% metaflumizone chlorfenapyr, namely both mass ratioes are the suspending agent of 1:2
After above-mentioned each component fully being mixed, the 25g that adds water fully grinds, and water complements to 100g, is mixed with 15% metaflumizone chlorfenapyr suspending agent.
Described metaflumizone and chlorfenapyr mass accumulation percentage account for 15% of gross mass.
Example of formulations 10
20% metaflumizone pyridaben, namely both mass ratioes are the water dispersible granules of 1:3
After above-mentioned each component is fully mixed, mixture is carried out granulation after ultra-fine grinding, drying, screening, both made 20% metaflumizone pyridaben water dispersible granule.
Described metaflumizone and pyridaben mass accumulation percentage account for 20% of gross mass.
Example of formulations 11
20% metaflumizone Acetamiprid, namely both mass ratioes are the wetting powder of 1:1
After above-mentioned each component is fully mixed, carry out drying, cooling, levigate, both must be mixed with 20% metaflumizone acetamiprid wettable powder.
Described metaflumizone and Acetamiprid mass accumulation percentage account for 20% of gross mass.
Example of formulations 12
20% metaflumizone Mobucin, namely both mass ratioes are the wetting powder of 1:3
After above-mentioned each component is fully mixed, carry out drying, cooling, levigate, both must be mixed with 20% metaflumizone Mobucin wetting powder.
Described metaflumizone and Mobucin mass accumulation percentage account for 20% of gross mass.
Example of formulations 13
2% metaflumizone dimehypo, namely both mass ratioes are the suspending agent of 1:1
After above-mentioned each component fully being mixed, the 25g that adds water fully grinds, and water complements to 100g, is mixed with 2% metaflumizone dimehypo suspending agent.
Described metaflumizone and dimehypo mass accumulation percentage account for 2% of gross mass.
Example of formulations 14
41% metaflumizone cartap, namely both mass ratioes are the wetting powder of 1:40
After above-mentioned each component is fully mixed, carry out drying, cooling, levigate, both must be mixed with 41% metaflumizone cartap wetting powder.
Described metaflumizone and cartap mass accumulation percentage account for 41% of gross mass.
This Pesticidal combination contains the auxiliary ingredients such as normally used solvent, auxiliary agent, carrier in pesticidal preparations, is convenient to make the formulation being suitable for using, as wetting powder, water dispersible granules, suspending agent.The lepidoptera pest of the crops such as the control of this Pesticidal combination vegetables, paddy rice, fruit tree, cotton, as diamond-back moth, beet armyworm, rice leaf roller, striped rice borer, paddy stem borer, leaf roller, cotton bollworm etc.
By a large amount of screening tests, find that the composition containing metaflumizone has obvious synergistic function to diamond-back moth, be specifically illustrated with following biological examples.
Biological Examples one:
Examination worm adopts the indoor diamond-back moth connected for raising, and concrete grammar is:
Medicament is prepared: test former medicine and provide former medicine for producer, be made up the preparation of needs of I Products development centre Drug Manufacturing Room.Before test, be mixed with different concentration gradients according to different ratio scheme, every proportioning 6 concentration.
Connect worm: put into 3, cabbage leaves dish of the same size in 9cm culture dish, select 3 consistent instar larvaes of straight uniform in culture dish, every ware connects worm 30.
Spraying: spray under 50PSI pressure with POTT spray tower, each spray medicine 2 milliliters.Leaf dish positive and negative is all sprayed.Spraying is from low concentration, and blank sprays equivalent clear water.Each proportioning arranges 6 concentration gradients, and every concentration sprays three wares.Put into after having sprayed in insectary (25 ± 1 DEG C, 12H/12H).
Investigation statistics: process and check dead borer population after 48 hours, with Abbott formulae discovery corrected mortality.Appliance computer program is obtained each for examination single dose lethal concentration of 50 LC50, calculates the co-toxicity coefficient (CTC value) of mixed medicament according to the abundant method of Sun Yun, CTC value be greater than 120 be synergistic effect.Circular is as follows:
Set a kind of single dose (A) for standard single dose, specify its toxicity index (TI) to be 100, then:
The percentage of TI × single dose in mixture of theoretical toxicity index (the TTI)=each single dose of Σ of mixture
Result of the test is in table 1, table 2.
The each reagent agent of table 1 is to the virulence of diamond-back moth
| Medicament | LC50(ppm) |
| Metaflumizone | 13.56 |
| Beta-cypermethrin | 223.02 |
| Cyhalothrin | 218.24 |
| Profenofos | 272.46 |
| Chlorophos | 284.43 |
| Diafenthiuron | 59.50 |
| Pleocidin | 15.65 |
| Worm hydrazides | 78.90 |
| HEXAFLUMURON | 10.26 |
| Chlorfenapyr | 8.22 |
| Pyridaben | 340.25 |
| Acetamiprid | 380.76 |
| Mobucin | 270.11 |
| Dimehypo | 340.37 |
| Cartap | 355.41 |
Table 2 contains the composition of metaflumizone to the composite effect of diamond-back moth
| Composition | Ratio | LC50(ppm) | CTC |
| Metaflumizone+beta-cypermethrin | 1:3 | 35.77 | 128.23 |
| Metaflumizone+Cyhalothrin | 1:1 | 18.81 | 135.77 |
| Metaflumizone+Profenofos | 1:10 | 67.43 | 147.65 |
| Metaflumizone+chlorophos | 1:6 | 55.77 | 132.35 |
| Metaflumizone+diafenthiuron | 1:5 | 30.06 | 126.48 |
| Metaflumizone+pleocidin | 2:1 | 11.05 | 128.42 |
| Metaflumizone+worm hydrazides | 1:1 | 15.95 | 145.13 |
| Metaflumizone+HEXAFLUMURON | 1:1 | 8.45 | 138.28 |
| Metaflumizone+chlorfenapyr | 1:2 | 6.99 | 135.43 |
| Metaflumizone+pyridaben | 1:3 | 39.70 | 122.04 |
| Metaflumizone+Acetamiprid | 1:1 | 18.96 | 138.15 |
| Metaflumizone+Mobucin | 1:3 | 36.66 | 128.62 |
| Metaflumizone+dimehypo | 1:1 | 20.06 | 130.05 |
| Metaflumizone+cartap | 1:40 | 172.02 | 127.76 |
As can be seen from Table 1 and Table 2, each composition co-toxicity coefficient (CTC) to diamond-back moth composite with metaflumizone is all greater than 120, and show, each composite effect all has synergistic effect to diamond-back moth.Each complex composition is processed into suitable formulation, can the multiple lepidoptera pest such as effectively preventing diamond-back moth, rice leaf roller, cotton bollworm, beet armyworm, prodenia litura, lima bean pod borer, leaf roller.Excellent activity is had to flea beetle, aleyrodid, plant hopper etc. because diafenthiuron, chlorfenapyr and pyridaben have acaricidal activity, Acetamiprid and Mobucin, so the built agent of the built agent of the built agent of metaflumizone and diafenthiuron or chlorfenapyr or pyridaben, metaflumizone and Acetamiprid, metaflumizone and Mobucin is except effectively preventing and treating except lepidoptera pest, also certain effect is had to other insect, expand insecticidal spectrum, decrease the times for spraying of agricultural chemicals.For new medicament metaflumizone, delay the generation of pest resistance to insecticide, can be used for the various pests of preventing and treating the generations such as vegetables, paddy rice, cotton, fruit tree.
Claims (5)
1. contain the Pesticidal combination of metaflumizone and dimehypo or cartap, it is characterized in that: be made up of two kinds of active components A and B, A composition is metaflumizone, and B component is the one of dimehypo, cartap, and described two kinds of active components A and B mass ratio are 1:40 ~ 1:1.
2. the Pesticidal combination containing metaflumizone and dimehypo or cartap as claimed in claim 1, is characterized in that: described two kinds of active components A and B mass accumulation account for 1% ~ 60% of composition gross mass.
3. the Pesticidal combination containing metaflumizone and dimehypo or cartap as claimed in claim 1, it is characterized in that: this Pesticidal combination contains normally used solvent, auxiliary agent, carrier in pesticidal preparations, be convenient to make the wetting powder, water dispersible granules, the suspending agent that are suitable for using.
4. the purposes containing the Pesticidal combination of metaflumizone and dimehypo or cartap as claimed in claim 1, is characterized in that: the lepidoptera pest of this Pesticidal combination control vegetables, paddy rice, fruit tree, cotton.
5. purposes as claimed in claim 4, is characterized in that: lepidoptera pest is diamond-back moth, beet armyworm, rice leaf roller, striped rice borer, paddy stem borer, leaf roller, cotton bollworm.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010003850 CN102113510B (en) | 2010-01-05 | 2010-01-05 | Insecticidal composition containing metaflumizone |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010003850 Division CN102113510B (en) | 2010-01-05 | 2010-01-05 | Insecticidal composition containing metaflumizone |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103109836A CN103109836A (en) | 2013-05-22 |
| CN103109836B true CN103109836B (en) | 2016-04-13 |
Family
ID=44212532
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310091188.0A Active CN103109836B (en) | 2010-01-05 | 2010-01-05 | Pesticidal combination containing metaflumizone and dimehypo or cartap |
| CN 201010003850 Active CN102113510B (en) | 2010-01-05 | 2010-01-05 | Insecticidal composition containing metaflumizone |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010003850 Active CN102113510B (en) | 2010-01-05 | 2010-01-05 | Insecticidal composition containing metaflumizone |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN103109836B (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101773132B (en) * | 2010-03-18 | 2012-08-29 | 陕西上格之路生物科学有限公司 | Insecticide composition containing metaflumizone |
| CN103283745A (en) * | 2012-03-01 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Insecticide composition containing metaflumizone |
| CN103283772A (en) * | 2012-03-03 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Pesticide composition containing metaflumizone and pyrethroids |
| CN105994270A (en) * | 2012-03-12 | 2016-10-12 | 陕西韦尔奇作物保护有限公司 | Chromafenozide-containing insecticidal composition |
| CN102630694A (en) * | 2012-03-31 | 2012-08-15 | 广西田园生化股份有限公司 | Ultralow-volume liquid containing metaflumizone and nicotine insecticide |
| CN102630688A (en) * | 2012-03-31 | 2012-08-15 | 广西田园生化股份有限公司 | Ultra low volume concentrate containing metaflumizone and carbamate insecticides |
| CN102657213B (en) * | 2012-04-16 | 2014-07-23 | 广西田园生化股份有限公司 | Ultra-low volume liquor containing metaflumizone and esbiothrin pesticides |
| CN102657204A (en) * | 2012-05-11 | 2012-09-12 | 湖南农业大学 | Synergetic insecticide composition |
| CN102894007A (en) * | 2012-11-19 | 2013-01-30 | 江苏钟山化工有限公司 | Synergistic insecticidal composition containing metaflumizone and beta-cypermethrin and application thereof |
| CN103053599A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Pesticide composition of metaflumizone and beta-cyfluthrin |
| CN103503912A (en) * | 2013-09-29 | 2014-01-15 | 江志鑫 | Acaricidal composite composition |
| CN103651458B (en) * | 2013-12-10 | 2016-08-17 | 南通纺都置业有限公司 | A kind of multiple killing teichomycin and the suspension emulsion of Mobucin and application |
| CN104082325B (en) * | 2014-06-19 | 2016-09-14 | 广东中迅农科股份有限公司 | A kind of containing chlorine chlorfenapyr with the Pesticidal combination of metaflumizone |
| CN105660673A (en) * | 2014-11-18 | 2016-06-15 | 陕西美邦农药有限公司 | Agricultural chemical insecticidal composition containing penflumizone |
| CN105613545A (en) * | 2014-11-26 | 2016-06-01 | 陕西美邦农药有限公司 | Insecticidal composition containing pentaflumizone and nereistoxin |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1471822A (en) * | 2003-07-15 | 2004-02-04 | 江苏省农药研究所有限公司 | Composition with insect killing activity |
| WO2009035908A1 (en) * | 2007-09-11 | 2009-03-19 | Wyeth | Compositions and their use for the treatment of protozoal infections comprising metaflumi zone |
| CN101524087A (en) * | 2009-04-28 | 2009-09-09 | 北京燕化永乐农药有限公司 | Pesticide composition containing metaflumizone and acephate |
| CN101564038A (en) * | 2009-04-23 | 2009-10-28 | 惠州市中迅化工有限公司 | Insecticidal composition containing metaflumizone |
| CN101584343A (en) * | 2009-07-06 | 2009-11-25 | 浙江省农业科学院 | Metaflumizone and chlorpyrifos mixture insecticide |
-
2010
- 2010-01-05 CN CN201310091188.0A patent/CN103109836B/en active Active
- 2010-01-05 CN CN 201010003850 patent/CN102113510B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1471822A (en) * | 2003-07-15 | 2004-02-04 | 江苏省农药研究所有限公司 | Composition with insect killing activity |
| WO2009035908A1 (en) * | 2007-09-11 | 2009-03-19 | Wyeth | Compositions and their use for the treatment of protozoal infections comprising metaflumi zone |
| CN101564038A (en) * | 2009-04-23 | 2009-10-28 | 惠州市中迅化工有限公司 | Insecticidal composition containing metaflumizone |
| CN101524087A (en) * | 2009-04-28 | 2009-09-09 | 北京燕化永乐农药有限公司 | Pesticide composition containing metaflumizone and acephate |
| CN101584343A (en) * | 2009-07-06 | 2009-11-25 | 浙江省农业科学院 | Metaflumizone and chlorpyrifos mixture insecticide |
Non-Patent Citations (1)
| Title |
|---|
| 新型杀虫剂氰氟虫腙;李鑫;《农药》;20071115;第46卷(第11期);第774页正文部分第1段 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103109836A (en) | 2013-05-22 |
| CN102113510A (en) | 2011-07-06 |
| CN102113510B (en) | 2013-03-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103109836B (en) | Pesticidal combination containing metaflumizone and dimehypo or cartap | |
| CN102113516B (en) | Insect killing compound containing chlorantraniliprole | |
| CN101669478A (en) | Pesticide combination | |
| CN101692819A (en) | Pesticide composition with synergy effect and application thereof | |
| CN103039526B (en) | Disinsection composition containing larvatrol | |
| CN102484994B (en) | Synergy composition of matrine and chlorantraniliprole | |
| CN104186554A (en) | Compounded biological insecticide of pyrethrin and acillus thuringiensis and application of compounded biological insecticide | |
| CN105532680B (en) | A kind of highly efficiency compositional composition pesticide of pyrimidine containing trifluoro-benzene and cycloxaprid | |
| CN108552234A (en) | The extracting method of the insecticide active substance containing castor-oil plant and its combination application with insecticide | |
| CN103109835B (en) | Insecticide composition containing metaflumizone and tebufenozide | |
| CN103109834B (en) | Insecticide composition containing metaflumizone and hexaflumuron | |
| CN104488915A (en) | insecticidal composition containing IPP | |
| CN105519551B (en) | A kind of highly efficiency compositional composition pesticide of the pyrimidine containing trifluoro-benzene | |
| CN106135238B (en) | A kind of composition pesticide containing propylene glycol alginate and cycloxaprid | |
| CN110313481A (en) | A kind of Pesticidal combination | |
| CN104285951A (en) | Compound insecticide | |
| CN102771511A (en) | Insecticidal composition containing fosthiazate | |
| CN103155938B (en) | Clothianidin/Diafenthiuron compound insecticidal composition | |
| CN109984145A (en) | Synergistic composition containing Nylar and decis | |
| CN107494582A (en) | Pesticidal combination containing cycolxylidin and indoxacarb | |
| CN101480185A (en) | Pesticide composition with synergistic insecticidal action and use thereof | |
| CN108157371B (en) | Pesticide composition for seed coating agent | |
| CN104488880B (en) | Composition pesticide | |
| CN107318857A (en) | A kind of Pesticidal combination | |
| CN105707096B (en) | Agricultural insecticidal composite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 571924 the development of Hainan County of Chengmai province old town village distribution Applicant after: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Address before: Four, building 25, glorious cinema tower, 570206 Nansha Road, Longhua District, Hainan, Haikou Applicant before: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180213 Address after: Hainan city of Haikou province is 570216 square Longhua District No. seven gold Lianlu on Ge layer fourth Patentee after: Hainan is the Green Pesticide Research Institute Co.,Ltd. Address before: 571924 the development of Hainan County of Chengmai province old town village distribution Patentee before: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200407 Address after: 571924 the development of Hainan County of Chengmai province old town village distribution Patentee after: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Address before: Hainan city of Haikou province is 570216 square Longhua District No. seven gold Lianlu on Ge layer fourth Patentee before: Hainan is the Green Pesticide Research Institute Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Insecticidal composition containing cyflufenozone, chlordimer or fenitrogen Effective date of registration: 20220304 Granted publication date: 20160413 Pledgee: Bank of Hainan Limited by Share Ltd. Pledgor: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. Registration number: 2019460000007 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CP03 | Change of name, title or address |
Address after: Fuchang Village, Laocheng Development Zone, Chengmai County, Hainan Province, 571923 Patentee after: Hainan Zhengye Biotechnology Co.,Ltd. Address before: 571924 Fuchang village, Laocheng Development Zone, Chengmai County, Hainan Province Patentee before: HAINAN ZHENGYE ZHONGNONG HIGH TECHNOLOGY Co.,Ltd. |
|
| CP03 | Change of name, title or address |