CN103108890B - 用于烯烃聚合的催化剂组分 - Google Patents

用于烯烃聚合的催化剂组分 Download PDF

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Publication number
CN103108890B
CN103108890B CN201180013227.4A CN201180013227A CN103108890B CN 103108890 B CN103108890 B CN 103108890B CN 201180013227 A CN201180013227 A CN 201180013227A CN 103108890 B CN103108890 B CN 103108890B
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China
Prior art keywords
catalyst component
alkyl
hydrogen
catalyst
polymerization
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Expired - Fee Related
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CN201180013227.4A
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English (en)
Chinese (zh)
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CN103108890A (zh
Inventor
D.布里塔
G.科利纳
D.埃文格利斯蒂
B.加迪
M.卡博纳拉
P.文岑齐
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Basell Poliolefine Italia SRL
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Basell Poliolefine Italia SRL
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201180013227.4A 2010-03-08 2011-03-01 用于烯烃聚合的催化剂组分 Expired - Fee Related CN103108890B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10155773 2010-03-08
EP10155773.4 2010-03-08
PCT/EP2011/052985 WO2011110444A1 (en) 2010-03-08 2011-03-01 Catalyst components for the polymerization of olefins

Publications (2)

Publication Number Publication Date
CN103108890A CN103108890A (zh) 2013-05-15
CN103108890B true CN103108890B (zh) 2015-11-25

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Family Applications (1)

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CN201180013227.4A Expired - Fee Related CN103108890B (zh) 2010-03-08 2011-03-01 用于烯烃聚合的催化剂组分

Country Status (8)

Country Link
US (1) US20120329963A1 (https=)
EP (1) EP2545082A1 (https=)
JP (1) JP2013521388A (https=)
KR (1) KR20130004906A (https=)
CN (1) CN103108890B (https=)
BR (1) BR112012022489A2 (https=)
RU (1) RU2012142664A (https=)
WO (1) WO2011110444A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101872196B1 (ko) * 2010-12-24 2018-06-28 바셀 폴리올레핀 이탈리아 에스.알.엘 마그네슘 디클로라이드-에탄올 부가물 및 그로부터 수득한 촉매 성분
KR20140107368A (ko) * 2011-12-12 2014-09-04 사우디 베이식 인더스트리즈 코포레이션 촉매 시스템 및 이 촉매 시스템의 존재하에 초고분자량의 폴리에틸렌을 생산하는 방법
JP6710993B2 (ja) * 2016-02-08 2020-06-17 東ソー株式会社 超高分子量ポリエチレン粒子およびその製造方法
US11447580B2 (en) * 2017-12-27 2022-09-20 Borealis Ag Ziegler-Natta catalyst and preparation thereof
KR20200095577A (ko) 2017-12-28 2020-08-10 보레알리스 아게 촉매 및 이의 제조

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87103866A (zh) * 1986-04-17 1987-12-16 恩尼化学碱公司 一种制备低或中密度的直链聚乙烯的方法以及适合于该目的催化剂
WO2009027269A1 (en) * 2007-08-29 2009-03-05 Basell Poliolefine Italia S.R.L. Catalyst for the polymerization of olefins
CN101389663A (zh) * 2006-02-21 2009-03-18 巴塞尔聚烯烃意大利有限责任公司 烯烃聚合用的催化剂组分

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1136627B (it) * 1981-05-21 1986-09-03 Euteco Impianti Spa Catalizzatore supportato per la polimerizzazione di etilene
US5571877A (en) * 1986-04-17 1996-11-05 Enichem Base S.P.A. Method of preparing low or medium-density straight-chain polyethylene, and catalysts suitable for this purpose
IT1236509B (it) * 1989-10-06 1993-03-11 Francesco Masi Procedimento per la preparazione di copolimeri etilene-butene-1 con densita' ultra-bassa.
IT1262935B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
JPH06220117A (ja) * 1992-12-11 1994-08-09 Spherilene Srl 広範な分子量分布を有するエチレンの（コ）ポリマーの製造方法
DE60134175D1 (de) 2000-12-15 2008-07-03 Basell Poliolefine Srl Kontinuierliches verfahren zur herstellung von festen katalysatorbestandteilen für die polymerisation von olefinen
KR100845167B1 (ko) 2000-12-22 2008-07-09 바셀 폴리올레핀 이탈리아 에스.알.엘 마그네슘 이할라이드를 함유하는 구형 지지체의 제조방법
EP1518866A1 (en) * 2003-09-29 2005-03-30 Basell Poliolefine Italia S.P.A. Process for the preparation of porous ethylene polymers
US7942572B2 (en) 2003-10-16 2011-05-17 Basell Poliolefine Italia S.R.L. Process for the continuous production of emulsions
DE602005000009T2 (de) 2004-02-13 2006-11-23 Total Petrochemicals Research Feluy, Seneffe Katalysatorkorngrösse
JP5594969B2 (ja) * 2006-02-21 2014-09-24 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィンの重合用の触媒成分
WO2008074674A1 (en) * 2006-12-20 2008-06-26 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins and catalysts therefrom obtained
JP5583973B2 (ja) * 2006-12-22 2014-09-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィン重合用の触媒成分及びそれから得られる触媒

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87103866A (zh) * 1986-04-17 1987-12-16 恩尼化学碱公司 一种制备低或中密度的直链聚乙烯的方法以及适合于该目的催化剂
CN101389663A (zh) * 2006-02-21 2009-03-18 巴塞尔聚烯烃意大利有限责任公司 烯烃聚合用的催化剂组分
WO2009027269A1 (en) * 2007-08-29 2009-03-05 Basell Poliolefine Italia S.R.L. Catalyst for the polymerization of olefins

Also Published As

Publication number Publication date
CN103108890A (zh) 2013-05-15
JP2013521388A (ja) 2013-06-10
WO2011110444A1 (en) 2011-09-15
BR112012022489A2 (pt) 2016-10-25
EP2545082A1 (en) 2013-01-16
KR20130004906A (ko) 2013-01-14
US20120329963A1 (en) 2012-12-27
RU2012142664A (ru) 2014-04-20

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Granted publication date: 20151125

Termination date: 20170301