CN103099741A - Photochromic nail polish - Google Patents
Photochromic nail polish Download PDFInfo
- Publication number
- CN103099741A CN103099741A CN2011103584877A CN201110358487A CN103099741A CN 103099741 A CN103099741 A CN 103099741A CN 2011103584877 A CN2011103584877 A CN 2011103584877A CN 201110358487 A CN201110358487 A CN 201110358487A CN 103099741 A CN103099741 A CN 103099741A
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- CN
- China
- Prior art keywords
- photochromic
- parts
- nail polish
- essence
- nial polish
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
The invention provides a photochromic nail polish which comprises the following components in parts by weight: 5-10 parts of ethyl acetate, 15-20 parts of butyl acetate, 10-15 parts of nitrocellulose, 3-5 parts of resins, 0-5 parts of pigment, 0.1-1.5 parts of essence, 3-5.5 parts of anti-settling agent, and 0.5-10 parts of microencapsulated photochromic powder. The photochromic nail polish provided by the invention has the advantages and beneficial effects that because a photochromic compound is added, the photochromic nail polish can be changed into different colors in the sun so as to generate a novel and peculiar effect; and a photochromic material is processed by using a microencapsulated processing method, so that the photochromic nail polish is better in dispersity, the obtained color is more uniform, and the photochromic nail polish is firmer after being coated on nails; and the essence in the photochromic nail polish provided by the invention is selected from plant essence, and the other materials are all benzene-free, methanol-free and formaldehyde-free materials, therefore, the photochromic nail polish is non-toxic, environment-friendly and healthful.
Description
Technical field
The present invention relates to a kind of nial polish, especially can realize photochromic nial polish.
Background technology
Nial polish is as a kind of makeups articles for use, deeply be subjected to youthfully to like, but existing nial polish generally all contains a lot of organic solvents, abnormal smells from the patient is pungent, be unfavorable for healthy, although and color various, but a kind of nial polish generally only presents a kind of color, and is comparatively dull.
Application number is that 99116071.1 patent discloses a kind of color changeable nail enamel, the fluorescent material that adds proper proportion in the nial polish formula, can use in public places of entertainment such as nightclub, dance halls, produce novel gorgeous effect, but the deficiency of this patent is: contain toluene in formula, Odor stimulation is larger to the harm of human body; Realize variable color by fluorescent material, color change interval is narrower, and fluorescent material directly adds in nial polish formula, disperse and lasting effect undesirable.
Summary of the invention
The technical scheme that the present invention will solve be to provide a kind of can be photochromic, color change interval is more wide in range, the nial polish that off-color material is uniformly dispersed and bonding effect is strong.
Concrete technical scheme is as follows:
A kind of photochromic nial polish is characterized in that: the component that comprises following weight portion:
Further, a kind of photochromic nial polish is characterized in that: the component that comprises following weight portion:
Described essence is plant essence.
The preparation method of described micro encapsulation light-induced variable toner is:
1) core preparation: the ratio according to percentage by weight 0.5-3% in the organic solvent adds photochromic material, is heated to 60-90 ℃, and stirring and dissolving is cooled to room temperature, gets core solution;
2) add appropriate emulsifier solution in core solution, emulsify at a high speed obtains the emulsifying core solution of oil droplet size 1-10 μ m;
3) add suitable quantity of water in the emulsifying core solution that obtains in the step 2, stir, slowly splashing into the wall material under rapid stirring is the melamine resin prepolymer, dropwise, rapid stirring, oil bath is warming up to 50-70 ℃, reaction 1-2h, continue to be warmed up to 70-90 ℃, rapid stirring reacts 2-3h, obtains encapsulating the melamine resin microcapsule slurry of photochromic material;
4) serosity that step 3 is obtained is cooled to room temperature, uses 5%NaOH aqueous solution regulation system pH value to 8.0-9.0;
5) the serosity spray drying that step 4 is obtained, obtaining solid product is micro encapsulation light-induced variable toner.
Further, the organic solvent addition is: 30-65g, the emulsifying agent addition is: 90-130g, wall material: 30-65g, water: 200-1000mL.
In the preparation method of described micro encapsulation light-induced variable toner, organic solvent in step 1 is selected any in dioctyl phthalate, normal hexane, cyclohexane extraction, tetrachloroethylene, carbon tetrachloride, and described emulsifying agent is selected any in SDS (sodium lauryl sulphate), dodecylbenzene sodium sulfonate, styrene-maleic anhydride copolymer.
Ethyl acetate and butyl acetate in the formula of described nial polish use as active solvent, are used for dissolving other materials; Nitrocellulose can form a skim at nail surface as a kind of film former after coating, its mobility has guaranteed that nial polish presents flowable state in container simultaneously; Adding of resin can be so that nitrocellulose filter has more pliability; The main component of anti-heavy agent is the high-performance bentonite through overactivation, can guarantee the nial polish stability of system, improves the brightness of nial polish; Make the adding of highly active vegetable essence nial polish fragrance and be of value to health.
Described colorant is common pigments, can match colors according to the color needs.The all right pearl essence of colorant, with different colors, allotment is advanced in nial polish, and some effect is not arranged.
The preparation method of described nial polish is: stir after first ethyl acetate and butyl acetate being mixed according to formula proportion; Add while stirring nitrocellulose, and continue with 1200rpm (rev/min) rotating speed stirs 5min; Then add resin, anti-heavy agent, essence, and continue to stir 5min with the 1200rpm rotating speed; Add colorant and micro encapsulation light-induced variable toner, 1200rpm stirs 15min, to color even, crosses 200 mesh sieves, can obtain nial polish of the present invention.
Photochromic material main body of the present invention is photochromic compound, mainly selects following large class:
(1) naphtho-spirooxazine
R
1=H, CH
3, OCH
3, halogen
R
2=C
1-C
6Alkyl, C
1-C
6Alkyl heterocycle
R
3=azacyclo-, C
1-C
6Alkyl diamine
R
4=C
1-C
6Alkoxyl
At Chinese patent: ZL97120274.5 photochromic spiro-compound and preparation method thereof; ZL200410072348.8 6 '-heterocycle substituted spirooxazine photochromic compound and preparation method thereof; 201110058243.7 record in detail in the preparation method of substituted spirooxazine photochromic compound.
(2) quino spirooxazine
R
1=H, CH
3, OCH
3, halogen
R
2=C
1-C
6Alkyl, C
1-C
6Alkyl heterocycle
R
3=azacyclo-, C
1-C
6Alkyl diamine
Be documented in 201110058251.1 quino spirooxazine photochromic compounds and preparation method thereof
(3) benzo spirooxazine
R
1=H, CH
3, OCH
3, halogen
R
2=C
1-C
6Alkyl, C
1-C
6Alkyl heterocycle
R
3=azacyclo-, C
1-C
6Alkyl diamine
(4) two aromatic heterocyclic ethylene compounds
X＝Y＝S X＝S Y＝N
R
1＝R
2＝R
3＝CH
3 R
1＝R
2＝R
3＝CH
3
R
1＝R
3＝CH
3 R
1＝R
2＝CH
3
R
1＝H R
2＝H
R
2＝R
1＝CH
3，R
3＝H R
2＝R
1＝CH
3，R
3＝H
X＝Y＝S X＝S Y＝N
R
1＝R
2＝R
3＝CH
3 R
1＝R
2＝R
3＝CH
3
R
1＝R
3＝CH
3 R
1＝R
3＝CH
3
R
1＝H R
2＝H
X＝Y＝S X＝S Y＝N
R＝CH
3 R＝CH
3
X＝Y＝S X＝S Y＝N
R＝CH
3 R＝CH
3
X＝Y＝S X＝N Y＝S
R
1＝R
2＝R
3＝CH
3 R
1＝R
2＝R
3＝CH
3
R
4＝H R
4＝OCH
3
R
1＝R
2＝CH
3 R
1＝R
2＝CH
3
R
3＝CN，CHO R
3＝CN，CHO
R
4＝H R
4＝OCH
3
R
1＝CH
3， R
2＝H，R
3＝CN，CHO，R
4＝OCH
3
X＝Y＝S X＝N Y＝S
R
1＝R
2＝R
3＝CH
3 R
1＝R
2＝R
3＝CH
3
R
4＝H R
4＝OCH
3
R
3＝R
1＝CH
3 R
2＝R
4＝H
R
1＝CH
3，R
2＝R
4＝H R
1＝R
2＝CH
3 R
3＝CN，CHO
R
3＝CN，CHO R
4＝OCH
3
R
1＝CH
3，R
2＝H
R
3＝CN，CHO R
4＝OCH
3
(5) aryl replaces the aphthopyrans class
R
1=2-C
1-C
8Alkoxyl R
2=4-C
1-C
8Alkoxyl
R
1=2-halogen R
2=4-C
1-C
8Alkoxyl or C
1-C
8Alkyl
R
1＝H R
2＝SCH
3
R
1=2-C
1-C
8Alkoxyl R
2=4-C
1-C
8Alkyl
R
1=2-aryl oxide R
2=4-aryl oxide
R
1=H R
2=4-C
1-C
8Alkoxyl
R
1=H R
2=4-halogen
R
1＝H R
2＝4-CF
3
R
1＝R
2＝H
At 200510013276.4 photochromic compound of naphtho-pyrans and goods thereof; 200410072350.5 be documented in 2,2-diaryl naphthopyran compounds and preparation method thereof.
(6) spiro-pyrans compounds
R
1=H, halogen, C
1-C
6Alkyl, C
1-C
6Alkoxyl
R
2=C
1-C
8Alkyl, C
1-C
8The alkoxy aromatic heterocycle
Patents: ZL97120274.5 photochromic spiro-compound and preparation method thereof
R
1=H, halogen, C
1-C
6Alkyl, C
1-C
6Alkoxyl
R
2=C
1-C
8Alkyl, C
1-C
8The alkoxy aromatic heterocycle
Advantage and beneficial effect that the present invention has are: a kind of photochromic nial polish of the present invention, it has added photochromic compound, can be changed to different colors under the irradiation of sunlight, produce the effect of Unique, and photochromic compound has adopted the processing method of micro encapsulation, make its dispersibility better, the tone that obtains is more even, is applied on fingernail also more firm; Increase anti-heavy agent, made more stable uniform of nial polish system of the present invention; Essence of the present invention has been selected plant essence, and the selection of other materials also is without benzene, without methanol, formaldehydeless material, and asepsis environment-protecting is good for health.
The specific embodiment
Embodiment 1
The photochromic compound of selecting is the benzo spirooxazine compounds, the concrete benzo Luo oxazine two aromatic heterocyclic ethylene of selecting.
Embodiment 2
The photochromic compound of selecting is the benzo spirooxazine compounds.
Embodiment 3
The photochromic compound of selecting is that aryl replaces the aphthopyrans class
Embodiment 4
The photochromic compound of selecting is Photo-chromic Compounds of Spriopyrans.
In above-mentioned four embodiment, the preparation method of micro encapsulation light-induced variable toner is:
1) core preparation: add the 0.6g photochromic material in dioctyl phthalate 30g, be heated to 70 ℃, stirring and dissolving is cooled to room temperature, gets core solution;
2) add 5% emulsifier solution 90g in core solution, what the present embodiment was selected is styrene-maleic anhydride copolymer, and emulsify at a high speed obtains the emulsifying core solution of oil droplet size 1-10 μ m;
3) add entry 500ml in the emulsifying core solution that obtains in the step 2, stir, slowly splashing into the wall material under rapid stirring is melamine resin prepolymer 30g, dropwise, rapid stirring, oil bath is warming up to 70 ℃, reaction 1h, continue to be warmed up to 90 ℃, rapid stirring reacts 2h, obtains encapsulating the melamine resin microcapsule slurry of photochromic material;
4) serosity that step 3 is obtained is cooled to room temperature, with 5%NaOH aqueous solution regulation system pH value to 8.0;
5) the serosity spray drying that step 4 is obtained, obtaining solid product is micro encapsulation light-induced variable toner.The preparation method of the nial polish described in above-mentioned four embodiment is:
1) after being mixed according to formula proportion, ethyl acetate and butyl acetate stir;
2) add while stirring nitrocellulose, and continue with 1200rpm (rev/min) rotating speed stirs 5min;
3) add resin, anti-heavy agent, essence, and continue to stir 5min with the 1200rpm rotating speed;
4) add colorant and micro encapsulation light-induced variable toner, 1200rpm stirs 15min, to color even;
5) cross 200 mesh sieves, namely obtain nial polish of the present invention.
Claims (5)
1. photochromic nial polish is characterized in that: the component that comprises following weight portion:
2. a kind of photochromic nial polish according to claim 1, it is characterized in that: the preparation method of described micro encapsulation light-induced variable toner is:
1) core preparation: the ratio according to percentage by weight 0.5-3% in the organic solvent adds photochromic material, is heated to 60-90 ℃, and stirring and dissolving is cooled to room temperature, gets core solution;
2) add appropriate emulsifier solution in core solution, emulsify at a high speed obtains the emulsifying core solution of oil droplet size 1-10 μ m;
3) add suitable quantity of water in the emulsifying core solution that obtains in the step 2, stir, slowly splashing into the wall material under rapid stirring is the melamine resin prepolymer, dropwise, rapid stirring, oil bath is warming up to 50-70 ℃, reaction 1-2h, continue to be warmed up to 70-90 ℃, rapid stirring reacts 2-3h, obtains encapsulating the melamine resin microcapsule slurry of photochromic material;
4) serosity that step 3 is obtained is cooled to room temperature, uses 5%NaOH aqueous solution regulation system pH value to 8.0-9.0;
5) the serosity spray drying that step 4 is obtained, obtaining solid product is micro encapsulation light-induced variable toner.
3. a kind of photochromic nial polish according to claim 2, it is characterized in that: in the preparation method of described micro encapsulation light-induced variable toner, organic solvent in step 1 is selected any in dioctyl phthalate, normal hexane, cyclohexane extraction, tetrachloroethylene, carbon tetrachloride, and described emulsifying agent is selected any in SDS, dodecylbenzene sodium sulfonate, styrene-maleic anhydride copolymer.
4. a kind of photochromic nial polish according to claim 1 is characterized in that: the component that comprises following weight portion:
5. according to claim 1 or 4 described a kind of photochromic nial polishs, it is characterized in that: described resin is selected at least a of acrylic resin or mylar, described anti-heavy agent main component is bentonite, and described colorant is pigment or pearl essence, and described essence is plant essence.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103584877A CN103099741A (en) | 2011-11-14 | 2011-11-14 | Photochromic nail polish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103584877A CN103099741A (en) | 2011-11-14 | 2011-11-14 | Photochromic nail polish |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103099741A true CN103099741A (en) | 2013-05-15 |
Family
ID=48308155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103584877A Pending CN103099741A (en) | 2011-11-14 | 2011-11-14 | Photochromic nail polish |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103099741A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105980429A (en) * | 2013-12-19 | 2016-09-28 | 雅芳产品公司 | Styrene Maleic Anhydride Polymers in Cosmetics and Personal Care Products |
| CN106580725A (en) * | 2016-12-02 | 2017-04-26 | 清华大学 | Photochromic nail polish and preparation method thereof |
| CN106726694A (en) * | 2017-02-06 | 2017-05-31 | 金华市名仕科技股份有限公司 | A kind of temperature becomes nail pad pasting and preparation method thereof |
| CN106924076A (en) * | 2017-03-23 | 2017-07-07 | 杭州莱凡网络科技有限公司 | A kind of color changeable nail enamel |
| CN109876743A (en) * | 2019-03-05 | 2019-06-14 | 上海甘田光学材料有限公司 | A kind of light-sensitive microcapsule and the preparation method and application thereof containing photosensitive colour-changing material |
| CN110527382A (en) * | 2019-09-09 | 2019-12-03 | 天津孚信阳光科技有限公司 | A kind of photochromic fragrance slow-release water paint and preparation method thereof |
| CN110693755A (en) * | 2019-11-25 | 2020-01-17 | 金华市科维思日化有限公司 | Novel safe and environment-friendly optically variable nail polish |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1231169A (en) * | 1999-02-26 | 1999-10-13 | 广州智拓贸易发展有限公司 | Color changeable nail enamel |
| CN1767806A (en) * | 2003-03-28 | 2006-05-03 | 纳幕尔杜邦公司 | Nail enamel composition and preparation method thereof |
-
2011
- 2011-11-14 CN CN2011103584877A patent/CN103099741A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1231169A (en) * | 1999-02-26 | 1999-10-13 | 广州智拓贸易发展有限公司 | Color changeable nail enamel |
| CN1767806A (en) * | 2003-03-28 | 2006-05-03 | 纳幕尔杜邦公司 | Nail enamel composition and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 未知: "美国禁止生产含甲苯指甲油", 《标准化信息》, no. 19943, 31 December 1994 (1994-12-31), pages 29 * |
| 金玲: "光致变色微胶囊的制备及其应用研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》, no. 20096, 15 June 2009 (2009-06-15), pages 020 - 63 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105980429A (en) * | 2013-12-19 | 2016-09-28 | 雅芳产品公司 | Styrene Maleic Anhydride Polymers in Cosmetics and Personal Care Products |
| CN105980429B (en) * | 2013-12-19 | 2018-08-28 | 雅芳产品公司 | Maleic anhydride of styrene polymer in cosmetics and personal care product |
| CN109125128A (en) * | 2013-12-19 | 2019-01-04 | 雅芳产品公司 | Maleic anhydride of styrene polymer in cosmetics and personal care product |
| CN106580725A (en) * | 2016-12-02 | 2017-04-26 | 清华大学 | Photochromic nail polish and preparation method thereof |
| CN106580725B (en) * | 2016-12-02 | 2019-05-21 | 清华大学 | A kind of Photochromic nail polish and preparation method thereof |
| CN106726694A (en) * | 2017-02-06 | 2017-05-31 | 金华市名仕科技股份有限公司 | A kind of temperature becomes nail pad pasting and preparation method thereof |
| CN106726694B (en) * | 2017-02-06 | 2020-02-07 | 金华市科维思日化有限公司 | Temperature-variable nail film and preparation method thereof |
| CN106924076A (en) * | 2017-03-23 | 2017-07-07 | 杭州莱凡网络科技有限公司 | A kind of color changeable nail enamel |
| CN109876743A (en) * | 2019-03-05 | 2019-06-14 | 上海甘田光学材料有限公司 | A kind of light-sensitive microcapsule and the preparation method and application thereof containing photosensitive colour-changing material |
| CN110527382A (en) * | 2019-09-09 | 2019-12-03 | 天津孚信阳光科技有限公司 | A kind of photochromic fragrance slow-release water paint and preparation method thereof |
| CN110693755A (en) * | 2019-11-25 | 2020-01-17 | 金华市科维思日化有限公司 | Novel safe and environment-friendly optically variable nail polish |
| WO2021103632A1 (en) * | 2019-11-25 | 2021-06-03 | 金华市科维思日化有限公司 | Safe and environmentally friendly iridescent nail polish |
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Application publication date: 20130515 |