CN103086803A - Lumbrukinase compound fertilizer and preparation method thereof - Google Patents
Lumbrukinase compound fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN103086803A CN103086803A CN2013100623262A CN201310062326A CN103086803A CN 103086803 A CN103086803 A CN 103086803A CN 2013100623262 A CN2013100623262 A CN 2013100623262A CN 201310062326 A CN201310062326 A CN 201310062326A CN 103086803 A CN103086803 A CN 103086803A
- Authority
- CN
- China
- Prior art keywords
- lumbrukinase
- agent
- fertilizer
- composite fertilizer
- synergistic agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 78
- 150000001875 compounds Chemical class 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 58
- 238000002156 mixing Methods 0.000 claims abstract description 54
- 239000002994 raw material Substances 0.000 claims abstract description 37
- 238000001035 drying Methods 0.000 claims abstract description 32
- 238000012216 screening Methods 0.000 claims abstract description 20
- 239000000126 substance Substances 0.000 claims abstract description 14
- 238000001816 cooling Methods 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 8
- 239000012747 synergistic agent Substances 0.000 claims description 49
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 40
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 32
- 239000011248 coating agent Substances 0.000 claims description 30
- 238000000576 coating method Methods 0.000 claims description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
- 239000002131 composite material Substances 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 26
- 229910021529 ammonia Inorganic materials 0.000 claims description 20
- 238000005469 granulation Methods 0.000 claims description 19
- 230000003179 granulation Effects 0.000 claims description 19
- 238000012856 packing Methods 0.000 claims description 19
- 239000007921 spray Substances 0.000 claims description 19
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 16
- 239000008187 granular material Substances 0.000 claims description 16
- 229920002401 polyacrylamide Polymers 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- 239000004202 carbamide Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 238000010298 pulverizing process Methods 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 235000019270 ammonium chloride Nutrition 0.000 claims description 8
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 8
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 8
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 8
- 239000006012 monoammonium phosphate Substances 0.000 claims description 8
- -1 Lumbrukinase Substances 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 4
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 102000004190 Enzymes Human genes 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 3
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 3
- 235000011151 potassium sulphates Nutrition 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 235000013877 carbamide Nutrition 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 108091000080 Phosphotransferase Proteins 0.000 claims 3
- 102000020233 phosphotransferase Human genes 0.000 claims 3
- 238000012512 characterization method Methods 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 24
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 244000005700 microbiome Species 0.000 abstract description 3
- 230000004720 fertilization Effects 0.000 abstract description 2
- 208000035240 Disease Resistance Diseases 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 230000008595 infiltration Effects 0.000 abstract 1
- 238000001764 infiltration Methods 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 37
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 11
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 9
- 229910001950 potassium oxide Inorganic materials 0.000 description 9
- 210000003608 fece Anatomy 0.000 description 8
- 239000010871 livestock manure Substances 0.000 description 8
- 238000005056 compaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000618 nitrogen fertilizer Substances 0.000 description 3
- 241000361919 Metaphire sieboldi Species 0.000 description 2
- 230000035558 fertility Effects 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 230000002786 root growth Effects 0.000 description 2
- 238000004162 soil erosion Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
- 101000925662 Enterobacteria phage PRD1 Endolysin Proteins 0.000 description 1
- 108010033040 Histones Proteins 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 102000013566 Plasminogen Human genes 0.000 description 1
- 108010051456 Plasminogen Proteins 0.000 description 1
- 241001655322 Streptomycetales Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- QBKUQMGHFFGGCD-UHFFFAOYSA-N [N].[NH4+].[Cl-] Chemical compound [N].[NH4+].[Cl-] QBKUQMGHFFGGCD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000003851 biochemical process Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- AWADHHRPTLLUKK-UHFFFAOYSA-N diazanium sulfuric acid sulfate Chemical compound [NH4+].[NH4+].OS(O)(=O)=O.[O-]S([O-])(=O)=O AWADHHRPTLLUKK-UHFFFAOYSA-N 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003527 fibrinolytic agent Substances 0.000 description 1
- 230000003480 fibrinolytic effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 238000003895 groundwater pollution Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002688 soil aggregate Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- QJVXKWHHAMZTBY-GCPOEHJPSA-N syringin Chemical compound COC1=CC(\C=C\CO)=CC(OC)=C1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 QJVXKWHHAMZTBY-GCPOEHJPSA-N 0.000 description 1
- QJVXKWHHAMZTBY-KSXIZUIISA-N syringin Natural products COc1cc(C=CCO)cc(OC)c1O[C@H]2O[C@@H](CO)[C@H](O)[C@@H](O)[C@@H]2O QJVXKWHHAMZTBY-KSXIZUIISA-N 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a lumbrukinase compound fertilizer. The lumbrukinase compound fertilizer comprises the following components in percentage by weight: a basic chemical fertilizer, 11.7-49.0% of an anti-freezing agent, 1.6-12.0% of lumbrukinase and 1.7-15.0% of a synergist. A method for preparing the lumbrukinase compound fertilizer comprises the following steps of: A, crushing raw materials, metering and uniformly mixing; B, granulating; C, screening, drying, cooling and re-screening; D, enveloping; and E, metering and packaging. The obtained lumbrukinase compound fertilizer is environment-friendly, and after the lumbrukinase compound fertilizer is applied for a long time, the granular structure of soil can be effectively improved, soil hardening is eliminated, and the infiltration capacity of the soil is improved; the buffer performance of the soil is improved, so that the harm of soil secondary salinization caused by excess fertilization to crops can be relieved; the growth and development of beneficial microorganisms in the soil are promoted, so that the utilization rate of the fertilizer is improved; and the growth of crop roots is promoted, so that the crop roots are developed, the disease resistance of crops is improved, and the crop yield is obviously increased.
Description
Technical field
The present invention relates to agriculture compound manure technical field, especially a kind of composite fertilizer of containing Lumbrukinase, can keeping soil from packing together.
Background technology
At present, use chemical fertilizer on agricultural, have following problem: 1, life-time service chemical fertilizer, cause soil compaction; 2, straw-returning, the organic matter in soil can not decompose very soon; 3, nutrient loss is serious, groundwater pollution.
In addition, in China's agriculture production, this season utilization ratio of chemical fertilizer is very low.At present, China's utilization rate of nitrogen fertilizer is about 30%-35%, and external utilization rate of nitrogen fertilizer is 50-55%, and utilization rate of fertilizer low is the huge waste that causes economically, investigation report for years shows, in the loss of nitrogenous fertilizer of state-owned nearly 1/4th ultimate productions outside the farmland; The 2nd, serious environment pollution, the loss nitrogen is with greenhouse gases N
2The forms such as O spill in atmosphere, cause Greenhouse effect.The nitrogen of loss also can enter underground water and surface water, directly causes body eutrophication, and water quality deterioration and hydrobiont are dead.Cause simultaneously underground water and tap water nitrate content to exceed standard, directly the serious threat human health.
Lumbrukinase is to extract a histone lytic enzyme of preparation in the middle of the earthworm, has the hydrolysis fibrinolytic protein, activates profibr(in)olysin and become the plasminogen function, medically is being widely used.In recent years, Lumbrukinase also comes into one's own in the middle of plant-growth and agriculture production gradually.There are some researches show, Lumbrukinase contains two kinds of antagonistic microbes (styreptomyces globispotus strain and syringin streptomycete) and can also kill virus, the harmful bacteria in soil and plant-growth is had inhibiting material.Find according to test-results for many years, Lumbrukinase can promote stalk to decompose, improve soil and improve the rhizospheric microorganism environment, and the containment soil-borne disease strengthens crop resistance, not only significantly improve crop yield and quality, and reduce applying quantity of chemical fertilizer and improve fertilizer utilization efficiency.Yet current Lumbrukinase is used very limited in agriculture production, on the one hand, due to technical reason, the peasant is difficult to grasp to Lumbrukinase application process and consumption, and the input cost that has increased material and personnel's work is used in the field on the other hand, makes overall economic benefit not obvious.Utilize modern industrial technology, with composite fertilizer and Lumbrukinase common granulation by a certain percentage, in the farmland, disposable applying can effectively address the above problem, and also there is no at present the report about compound Lumbrukinase fertilizer.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of Lumbrukinase composite fertilizer and preparation method thereof, the products obtained therefrom environmental protection, and long-term application may be improved soil aggregate effectively, eliminates soil compaction, strengthens soil penetrability; Improve the shock-absorbing capacity of soil, can alleviate the soil secondary salinization that causes because of excessive fertilization to the harm of crop; Promote that in soil, beneficial microorganism grows, improve utilization rate of fertilizer; Promote crop root growth, well developed root system, strengthen resistance against diseases, obviously volume increase.
For solving the problems of the technologies described above, the technical solution used in the present invention is as follows.
A kind of Lumbrukinase composite fertilizer, it comprises following composition: basic chemical fertilizer, antifreezing agent, Lumbrukinase, synergistic agent; Wherein, the content that calculates described antifreezing agent according to the weight permillage is 1.17 ‰-4.90 ‰, and the content of Lumbrukinase is 0.16 ‰-1.20 ‰, and the content of synergistic agent is 0.17 ‰-1.50 ‰.
As a preferred technical solution of the present invention, described basic chemical fertilizer is one or more mixtures in ammonium chloride, ammonium sulfate, urea, powdery monoammonium phosphate, powdery Repone K, powdered potassium sulfate.
As a preferred technical solution of the present invention, described anti-hard caking agent is one or both mixtures in paste anti-hard caking agent, powdered anti-caking agent.
As a preferred technical solution of the present invention, the enzyme activity of described Lumbrukinase is not less than 10000u/mg.
As a preferred technical solution of the present invention, described synergistic agent is one or both mixtures in a-Nafusaku, linear polyacrylamide.
As a preferred technical solution of the present invention, also include binding agent, sulfuric acid, liquefied ammonia in its composition; Described binding agent is one or both mixtures in attapulgite, wilkinite.
The preparation method of above-mentioned Lumbrukinase composite fertilizer, its step comprises:
A, raw material pulverizing, metering, mixing: take basic chemical fertilizer and binding agent, pulverize respectively, be transported to stirring and evenly mixing in mixer;
B, granulation: the raw material of mixing is transported in the spray drum tablets press, sulfuric acid, liquefied ammonia are joined in the spray drum tablets press through the TAV tubular reactor; Under atmospheric pressure state, utilize the chemical reaction heat of sulfuric acid, liquefied ammonia will be the raw material of homogenizing carry out granulation;
C, screening, drying, cooling, regrading: the product that tablets press is produced meets the requirements of particle through screening, send in drying cylinder, drying cylinder opening for feed temperature is controlled at 120 ℃-210 ℃, carry out drying, 50 ℃-70 ℃ of dry rear temperature of charge enter in refrigerating unit, normal temperature is taken out cold wind and is carried out countercurrent ventilating, be cooled to below 35 ℃, through regrading, qualified granular fertilizer is done anti-caking through the cylinder coating machine and is processed;
D coating: add Lumbrukinase and synergistic agent to anti-hard caking agent in the process of coating in, thereby take anti-hard caking agent as carrier, evenly add to Lumbrukinase and synergistic agent in composite fertilizer; Wherein the consumption of anti-hard caking agent, Lumbrukinase and synergistic agent guarantees that the content of antifreezing agent in Lumbrukinase composite fertilizer finished product is 1.17 ‰-4.90 ‰, and the content of Lumbrukinase is 0.16 ‰-1.20 ‰, and the content of synergistic agent is 0.17 ‰-1.50 ‰; Permillage is calculated by weight;
E, metering packing: the fertiliser granulates after cylinder coating machine anti-caking is processed is finished product through metering packing.
Wherein, in step C, drying cylinder opening for feed temperature is controlled in accordance with following standard: be controlled at 120 ℃-130 ℃ during high nitrogen formula, during the high phosphorus formula, be controlled at 190 ℃-210 ℃.
Wherein, in step D, when adopting the paste anti-hard caking agent, the addition means of Lumbrukinase and synergistic agent is as follows:
D-1, the paste anti-hard caking agent is added in dissolving tank, heating for dissolving is added Lumbrukinase and synergistic agent, stirring and evenly mixing; Count by ratio of weight and the number of copies, paste anti-hard caking agent, Lumbrukinase, synergistic agent adding proportion are (5-6): (1-1.5): (1-1.5);
D-2,, the paste liquor that contains Lumbrukinase and synergistic agent that will stir after the volume pump pressurization, be sprayed at the composite fertilizer surface; Every 1000kg finished product, the ratio of adding above-mentioned paste mixture is 2kg-3.5kg.
Wherein, in step D, when adopting Powdered anti-hard caking agent, the addition means of Lumbrukinase and synergistic agent is as follows:
D-1, Lumbrukinase and synergistic agent are added in powdered anti-caking agent to stirring and evenly mixing; Count by ratio of weight and the number of copies, Powdered anti-hard caking agent, Lumbrukinase, synergistic agent adding proportion are (7-9): (1-1.5): 2;
The pulverulent mixture of D-2, mixing is added in parcel cylinder with the speed governing screw feeder, and by the rotation of parcel cylinder, the anti-hard caking agent that is mixed with Lumbrukinase and synergistic agent will be adsorbed onto the compound fertilizer granules surface; Every 1000kg finished product, the ratio of adding above-mentioned pulverulent mixture is 4kg-6kg.
If when adopting simultaneously paste anti-hard caking agent and Powdered anti-hard caking agent, can be first carry out according to the method for mixing material of top, then get final product according to following method of mixing material.
Adopt beneficial effect that technique scheme produces be following some.
1, has effective control soil compaction
The Lumbrukinase that adds in this product and the linear polyacrylamide in synergistic agent, it is all polymer substance, can improve the structure of soil surface, improve the stability of coacervate, effectively suppress the formation of soil crust, thereby effectively prevent and treat soil compaction and soil erosion, drought-relief promotes root growth, strengthens disease-resistant resistance, improve the nutrient utilization ratio, thereby reach the purpose of crop yield.
2, prevent the top layer soil erosion
The composite fertilizer that the present invention produces, because adding Lumbrukinase and synergistic agent, its surface adsorption effect strengthens, and sharply strengthens the absorption between soil particle, moisture content and fertilizer, thereby reaches the purpose of preserve moisture and fertility.
3, have the preserve moisture and fertility ability, improve utilization rate of fertilizer
This product can be by regulating Soil structure, by creating and stable water-stable granular structure, improve the chemical physics environment of fertilizer in soil, improve the content of soil water Heshui, suppress fertilizer element with rainwater or the irrigation advance direct evaporation of becoming estranged, thereby improve utilization rate of fertilizer.
Embodiment
Following examples describe the present invention in detail.Various raw material used in the present invention and items of equipment are conventional commercially available prod, all can buy directly by market to obtain.Wherein: the ammonium chloride nitrogen content is 25%, and specification is 25-0-0; The ammonium sulfate nitrogen content is 20.5%, and specification is 20.5-0-0; In urea, nitrogen content is 46%, and specification is 46-0-0; In powdery monoammonium phosphate, nitrogen content is 11%, and phosphorus pentoxide content is 47%, and specification is 11-47-0; Powdery Repone K contains potassium oxide 60%, and specification is 0-0-60; Powdered potassium sulfate contains potassium oxide 50%, and specification is 0-0-50; The liquefied ammonia nitrogen content is 82%; Sulfuric acid is 98% the vitriol oil; The content that relates in above raw material is mass percent.Lumbrukinase of the present invention is the extract of pure natural earthworm after special biochemical process is processed, and enzyme activity 10000u/mg is purchased from Hubei emerging milky way chemical industry company limited.
Embodiment 1
Preparation Lumbrukinase compound manure (26-0-0), nitrogen, Vanadium Pentoxide in FLAKES, potassium oxide content are respectively 26%, 0%, 0%, are mass percent.
1, raw material pulverizing, metering, mixing
According to every production 1000kg finished product meter, metering urea 170kg, ammonium chloride 700kg, wilkinite 90kg, the raw material that pulverizing is measured is transported to respectively stirring and evenly mixing in mixer.
2, granulation
The raw material of step 1 mixing is transported in the spray drum tablets press, 30kg sulfuric acid, 10kg liquefied ammonia are joined in the spray drum tablets press through the TAV tubular reactor; Under atmospheric pressure state, utilize the chemical reaction heat of sulfuric acid, liquefied ammonia will be the raw material of homogenizing carry out granulation.
3, screening, dry, cooling, regrading
The product that tablets press is produced reaches the particle of (1.00mm-4.75mm) through screening; send in drying cylinder; drying cylinder opening for feed temperature is controlled at 120 ℃-130 ℃; carry out drying; after dry, temperature of charge is 50 ℃-70 ℃, enters in refrigerating unit, takes out cold wind (normal temperature) and carries out countercurrent ventilating and be cooled to below 35 ℃; through regrading, qualified granular fertilizer is done anti-caking through the cylinder coating machine and is processed.
4, coating
A, the paste anti-hard caking agent is added in dissolving tank, heating for dissolving is added Lumbrukinase and synergistic agent, stirring and evenly mixing.Anti-hard caking agent, Lumbrukinase and synergistic agent adding proportion are=5:1:1 that synergistic agent is the mixture of a-Nafusaku, linear polyacrylamide 1:1.
B, the mixing solutions that contains Lumbrukinase, a-Nafusaku and linear polyacrylamide that will stir are sprayed at the composite fertilizer surface after the volume pump pressurization.
C, every 1000kg finished product, the amount that sprays above-mentioned paste mixing solutions is 3kg.
5, metering packing
Fertiliser granulates after cylinder coating machine anti-caking is processed is finished product through metering packing.
Embodiment 2
Preparation Lumbrukinase compound manure (28-6-6), nitrogen, Vanadium Pentoxide in FLAKES, potassium oxide content are respectively 28%, 6%, 6%, are mass percent.
1, raw material pulverizing, metering, mixing
According to every production 1000kg finished product meter, metering urea 380kg, ammonium chloride 290kg, powdery monoammonium phosphate 135kg, powdery Repone K 110kg, attapulgite 35kg.The raw material that measures is transported to respectively stirring and evenly mixing in mixer.
2, granulation
The raw material of step 1 mixing is transported in the spray drum tablets press, 30kg sulfuric acid, 20kg liquefied ammonia are joined in the spray drum tablets press through the TAV tubular reactor; Under atmospheric pressure state, utilize the chemical reaction heat of sulfuric acid, liquefied ammonia will be the raw material of homogenizing carry out granulation.
3, screening, dry, cooling, regrading
The product that tablets press is produced meets the requirements of particle through screening; send in drying cylinder; drying cylinder opening for feed temperature is controlled at 120 ℃-130 ℃; carry out drying; after dry, temperature of charge is 50 ℃-70 ℃, enters in refrigerating unit, takes out cold wind (normal temperature) and carries out countercurrent ventilating and be cooled to below 35 ℃; through regrading, qualified granular fertilizer is done anti-caking through the cylinder coating machine and is processed.
4, coating
A, Lumbrukinase and synergistic agent are added in powdered anti-caking agent to stirring and evenly mixing.By percentage to the quality, Powdered anti-hard caking agent, Lumbrukinase and linear polyacrylamide addition are 7:1:2.
B, the pulverulent mixture of mixing is added in the parcel cylinder with the speed governing screw feeder, by the rotation of parcel cylinder, the anti-hard caking agent that is mixed with Lumbrukinase and synergistic agent will be adsorbed onto the compound fertilizer granules surface.
C, every 1000kg finished product, the amount of adding above-mentioned pulverulent mixture is 4kg.
5, metering packing
Fertiliser granulates after cylinder coating machine anti-caking is processed is finished product through metering packing.
Embodiment 3
Preparation Lumbrukinase compound manure (20-10-10), nitrogen, Vanadium Pentoxide in FLAKES, potassium oxide content are respectively 20%, 10%, 10%, are mass percent.
1, raw material pulverizing, metering, mixing
According to every production 1000kg finished product meter, metering ammonium chloride 435kg, powdery monoammonium phosphate 230kg, urea 130kg, Repone K 155kg is transported to respectively stirring and evenly mixing in mixer with the raw material that measures.
2, granulation
The raw material of mixing is transported in the spray drum tablets press, sulfuric acid 30kg, liquefied ammonia 20kg are also joined in the spray drum tablets press through the TAV tubular reactor; Under atmospheric pressure state, utilize the chemical reaction heat of sulfuric acid, liquefied ammonia will be the raw material of homogenizing carry out granulation.
3, screening, dry, cooling, regrading
The product that tablets press is produced meets the requirements of particle through screening; send in drying cylinder; drying cylinder opening for feed temperature is controlled at 130 ℃-150 ℃; carry out drying; after dry, temperature of charge is 50 ℃-70 ℃, enters in refrigerating unit, takes out cold wind (normal temperature) and carries out countercurrent ventilating and be cooled to below 35 ℃; through regrading, qualified granular fertilizer is done anti-caking through the cylinder coating machine and is processed.
4, coating
In the process of coating, first adopt paste anti-hard caking agent parcel once, then wrap up with Powdered anti-hard caking agent.
(1) the paste anti-hard caking agent is added in dissolving tank, heating for dissolving is added Lumbrukinase and linear polyacrylamide, stirring and evenly mixing.By percentage to the quality, paste anti-hard caking agent, Lumbrukinase and linear polyacrylamide adding proportion are 6:1:1.
(2) with the mixing solutions of step (1) gained that stirs after the volume pump pressurization, be sprayed at the composite fertilizer surface.Every 1000kg finished product, the amount of the mixing solutions of spraying step (1) gained is 2kg.
(3) Lumbrukinase and synergistic agent are added in powdered anti-caking agent to stirring and evenly mixing.By percentage to the quality, Powdered anti-hard caking agent, Lumbrukinase and a-Nafusaku addition are 9:1.5:2.
(4) pulverulent mixture of mixing is added in the parcel cylinder with the speed governing screw feeder, by the rotation of parcel cylinder, the anti-hard caking agent that is mixed with Lumbrukinase and synergistic agent will be adsorbed onto the compound fertilizer granules surface.Every 1000kg finished product, the amount of adding step (3) gained pulverulent mixture is 4kg.
5, metering packing
Fertiliser granulates after cylinder coating machine anti-caking is processed is finished product through metering packing.
Embodiment 4
Preparation Lumbrukinase compound manure (17-23-5), nitrogen, Vanadium Pentoxide in FLAKES, potassium oxide content are respectively 17%, 23%, 5%, are mass percent.
1, raw material pulverizing, metering, mixing
According to every production 1000kg finished product meter, metering urea 60kg, powdery monoammonium phosphate 520kg, ammonium chloride 322kg, Repone K 85kg.The raw material that measures is transported to respectively stirring and evenly mixing in mixer.
2, granulation
The raw material of step 1 mixing is transported in the spray drum tablets press, 13kg liquefied ammonia is joined in the spray drum tablets press through the TAV tubular reactor; Under atmospheric pressure state, utilize the chemical reaction heat of sulfuric acid, liquefied ammonia will be the raw material of homogenizing carry out granulation.
3, screening, dry, cooling, regrading
The product that tablets press is produced reaches the particle of (1.00mm-4.75mm) through screening; send in drying cylinder; drying cylinder opening for feed temperature is controlled at 180 ℃-200 ℃; carry out drying; after dry, temperature of charge is 50 ℃-70 ℃, enters in refrigerating unit, takes out cold wind (normal temperature) and carries out countercurrent ventilating and be cooled to below 35 ℃; through regrading, qualified granular fertilizer is done anti-caking through the cylinder coating machine and is processed.
4, coating
A, the paste anti-hard caking agent is added in dissolving tank, heating for dissolving is added Lumbrukinase and linear polyacrylamide, stirring and evenly mixing.Anti-hard caking agent, Lumbrukinase and linear polyacrylamide adding proportion are=6:1:1.
B, the mixing solutions that contains Lumbrukinase and linear polyacrylamide that will stir are sprayed at the composite fertilizer surface after the volume pump pressurization.
C, every 1000kg finished product, the amount of adding above-mentioned paste mixture is 3.5kg.
5, metering packing
Fertiliser granulates after cylinder coating machine anti-caking is processed is finished product through metering packing.
Embodiment 5
Preparation Lumbrukinase compound manure (30-0-0), nitrogen, Vanadium Pentoxide in FLAKES, potassium oxide content are respectively 30%, 0%, 0%, are mass percent.
1, raw material pulverizing, metering, mixing
According to every production 1000kg finished product meter, metering urea 355kg, ammonium sulfate 65kg, ammonium chloride 440kg, wilkinite 100kg is transported to respectively stirring and evenly mixing in mixer with the raw material that measures.
2, granulation
The raw material of step 1 mixing is transported in the spray drum tablets press, 30kg sulfuric acid, 10kg liquefied ammonia are joined in the spray drum tablets press through the TAV tubular reactor; Under atmospheric pressure state, utilize the chemical reaction heat of sulfuric acid, liquefied ammonia will be the raw material of homogenizing carry out granulation.
3, screening, dry, cooling, regrading
The product that tablets press is produced reaches the particle of (1.00mm-4.75mm) through screening; send in drying cylinder; drying cylinder opening for feed temperature is controlled at 120 ℃-130 ℃; carry out drying; after dry, temperature of charge is 50 ℃-70 ℃, enters in refrigerating unit, takes out cold wind (normal temperature) and carries out countercurrent ventilating and be cooled to below 35 ℃; through regrading, qualified granular fertilizer is done anti-caking through the cylinder coating machine and is processed.
4, coating
A, Lumbrukinase and synergistic agent are added in powdered anti-caking agent to stirring and evenly mixing.By percentage to the quality, Powdered anti-hard caking agent, Lumbrukinase and synergistic agent addition are 7:1.5:2.Synergistic agent is the mixture of a-Nafusaku, linear polyacrylamide 1:2.
B, the pulverulent mixture of mixing is added in the parcel cylinder with the speed governing screw feeder, by the rotation of parcel cylinder, the anti-hard caking agent that is mixed with Lumbrukinase and synergistic agent will be adsorbed onto the compound fertilizer granules surface.
C, every 1000kg finished product, the amount of adding above-mentioned pulverulent mixture is 5kg.
5, metering packing
Fertiliser granulates after cylinder coating machine anti-caking is processed is finished product through metering packing.
Embodiment 6
Preparation Lumbrukinase compound manure (13-17-15), nitrogen, Vanadium Pentoxide in FLAKES, potassium oxide content are respectively 13%, 17%, 15%, are mass percent.
1, raw material pulverizing, metering, mixing
According to every production 1000kg finished product meter, metering urea 75kg, powdery monoammonium phosphate 395kg, vitriolate of tartar 305kg, ammonium sulfate 215kg is transported to respectively stirring and evenly mixing in mixer with the raw material that measures.
2, granulation
The raw material of step 1 mixing is transported in the spray drum tablets press, 10kg liquefied ammonia is joined in the spray drum tablets press through the TAV tubular reactor; Under atmospheric pressure state, utilize the chemical reaction heat of sulfuric acid, liquefied ammonia will be the raw material of homogenizing carry out granulation.
3, screening, dry, cooling, regrading
The product that tablets press is produced reaches the particle of (1.00mm-4.75mm) through screening; send in drying cylinder; drying cylinder opening for feed temperature is controlled at 160 ℃-180 ℃; carry out drying; after dry, temperature of charge is 50 ℃-70 ℃, enters in refrigerating unit, takes out cold wind (normal temperature) and carries out countercurrent ventilating and be cooled to below 35 ℃; through regrading, qualified granular fertilizer is done anti-caking through the cylinder coating machine and is processed.
4, coating
A, Lumbrukinase and synergistic agent are added in powdered anti-caking agent to stirring and evenly mixing.By percentage to the quality, Powdered anti-hard caking agent, Lumbrukinase and linear polyacrylamide addition are 9:1:2.
B, the pulverulent mixture of mixing is added in the parcel cylinder with the speed governing screw feeder, by the rotation of parcel cylinder, the anti-hard caking agent that is mixed with Lumbrukinase and synergistic agent will be adsorbed onto the compound fertilizer granules surface.
C, every 1000kg finished product, the amount of adding above-mentioned pulverulent mixture is 6kg.
5, metering packing
Fertiliser granulates after cylinder coating machine anti-caking is processed is finished product through metering packing.
Embodiment 7
Preparation Lumbrukinase compound manure (20-20-0), nitrogen, Vanadium Pentoxide in FLAKES, potassium oxide content are respectively 20%, 20%, 0%, are mass percent.
1, raw material pulverizing, metering, mixing
According to every production 1000kg finished product meter, metering urea 70kg, ammonium chloride 470kg, monoammonium phosphate 450kg is transported to respectively stirring and evenly mixing in mixer with the raw material that measures.
2, granulation
The raw material of step 1 mixing is transported in the spray drum tablets press, 10kg liquefied ammonia is joined in the spray drum tablets press through the TAV tubular reactor; Under atmospheric pressure state, utilize the chemical reaction heat of sulfuric acid, liquefied ammonia will be the raw material of homogenizing carry out granulation.
3, screening, dry, cooling, regrading
The product that tablets press is produced reaches the particle of (1.00mm-4.75mm) through screening; send in drying cylinder; drying cylinder opening for feed temperature is controlled at 140 ℃-160 ℃; carry out drying; after dry, temperature of charge is 50 ℃-70 ℃, enters in refrigerating unit, takes out cold wind (normal temperature) and carries out countercurrent ventilating and be cooled to below 35 ℃; through regrading, qualified granular fertilizer is done anti-caking through the cylinder coating machine and is processed.
4, coating
A, Lumbrukinase and synergistic agent are added in powdered anti-caking agent to stirring and evenly mixing.By percentage to the quality, Powdered anti-hard caking agent, Lumbrukinase and synergistic agent addition are 8:1.5:2.Synergistic agent is the mixture of a-Nafusaku, linear polyacrylamide 2:3.
B, the pulverulent mixture of mixing is added in the parcel cylinder with the speed governing screw feeder, by the rotation of parcel cylinder, the anti-hard caking agent that is mixed with Lumbrukinase and synergistic agent will be adsorbed onto the compound fertilizer granules surface.
C, every 1000kg finished product, the amount of adding above-mentioned pulverulent mixture is 5kg.
5, metering packing
Fertiliser granulates after cylinder coating machine anti-caking is processed is finished product through metering packing.
Foregoing description only proposes as the enforceable technical scheme of the present invention, not as the Single restriction condition to its technical scheme itself.
Claims (10)
1. a Lumbrukinase composite fertilizer, is characterized in that comprising following composition: basic chemical fertilizer, antifreezing agent, Lumbrukinase, synergistic agent; Wherein, the content that calculates described antifreezing agent according to the weight permillage is 1.17 ‰-4.90 ‰, and the content of Lumbrukinase is 0.16 ‰-1.20 ‰, and the content of synergistic agent is 0.17 ‰-1.50 ‰.
2. Lumbrukinase according to claim 1 composite fertilizer, it is characterized in that: described basic chemical fertilizer is one or more mixtures in ammonium chloride, ammonium sulfate, urea, powdery monoammonium phosphate, powdery Repone K, powdered potassium sulfate.
3. Lumbrukinase according to claim 1 composite fertilizer, it is characterized in that: described anti-hard caking agent is one or both mixtures in paste anti-hard caking agent, powdered anti-caking agent.
4. Lumbrukinase according to claim 1 composite fertilizer, it is characterized in that: the enzyme activity of described Lumbrukinase is not less than 10000u/mg.
5. Lumbrukinase according to claim 1 composite fertilizer, it is characterized in that: described synergistic agent is one or both mixtures in a-Nafusaku, linear polyacrylamide.
6. Lumbrukinase according to claim 1 composite fertilizer, is characterized in that: also include binding agent, sulfuric acid, liquefied ammonia in its composition; Described binding agent is one or both mixtures in attapulgite, wilkinite.
7. the preparation method of above-mentioned Lumbrukinase composite fertilizer, its characterization step comprises:
A, raw material pulverizing, metering, mixing: take basic chemical fertilizer and binding agent, pulverize respectively, be transported to stirring and evenly mixing in mixer;
B, granulation: the raw material of mixing is transported in the spray drum tablets press, sulfuric acid, liquefied ammonia are joined in the spray drum tablets press through the TAV tubular reactor; Under atmospheric pressure state, utilize the chemical reaction heat of sulfuric acid, liquefied ammonia will be the raw material of homogenizing carry out granulation;
C, screening, drying, cooling, regrading: the product that tablets press is produced meets the requirements of particle through screening, send in drying cylinder, drying cylinder opening for feed temperature is controlled at 120 ℃-210 ℃, carry out drying, 50 ℃-70 ℃ of dry rear temperature of charge enter in refrigerating unit, normal temperature is taken out cold wind and is carried out countercurrent ventilating, be cooled to below 35 ℃, through regrading, qualified granular fertilizer is done anti-caking through the cylinder coating machine and is processed;
D, coating: in the process of coating, Lumbrukinase and synergistic agent are added in anti-hard caking agent, thereby take anti-hard caking agent as carrier, evenly add to Lumbrukinase and synergistic agent in composite fertilizer; Wherein the consumption of anti-hard caking agent, Lumbrukinase and synergistic agent guarantees that the content of antifreezing agent in Lumbrukinase composite fertilizer finished product is 1.17 ‰-4.90 ‰, and the content of Lumbrukinase is 0.16 ‰-1.20 ‰, and the content of synergistic agent is 0.17 ‰-1.50 ‰; Permillage is calculated by weight;
E, metering packing: the fertiliser granulates after cylinder coating machine anti-caking is processed is finished product through metering packing.
8. the preparation method of kinases according to claim 7 composite fertilizer, it is characterized in that: in step C, drying cylinder opening for feed temperature is controlled in accordance with following standard: be controlled at 120 ℃-130 ℃ during high nitrogen formula, during the high phosphorus formula, be controlled at 190 ℃-210 ℃.
9. the preparation method of kinases according to claim 7 composite fertilizer, it is characterized in that: in step D, when adopting the paste anti-hard caking agent, the addition means of Lumbrukinase and synergistic agent is as follows:
D-1, the paste anti-hard caking agent is added in dissolving tank, heating for dissolving is added Lumbrukinase and synergistic agent, stirring and evenly mixing; Count by ratio of weight and the number of copies, paste anti-hard caking agent, Lumbrukinase, synergistic agent adding proportion are (5-6): (1-1.5): (1-1.5);
D-2,, the paste liquor that contains Lumbrukinase and synergistic agent that will stir after the volume pump pressurization, be sprayed at the composite fertilizer surface; Every 1000kg finished product, the ratio of adding above-mentioned paste mixture is 2kg-3.5kg.
10. the preparation method of kinases according to claim 7 composite fertilizer, it is characterized in that: in step D, when adopting Powdered anti-hard caking agent, the addition means of Lumbrukinase and synergistic agent is as follows:
D-1, Lumbrukinase and synergistic agent are added in powdered anti-caking agent to stirring and evenly mixing; Count by ratio of weight and the number of copies, Powdered anti-hard caking agent, Lumbrukinase, synergistic agent adding proportion are (7-9): (1-1.5): 2;
The pulverulent mixture of D-2, mixing is added in parcel cylinder with the speed governing screw feeder, and by the rotation of parcel cylinder, the anti-hard caking agent that is mixed with Lumbrukinase and synergistic agent will be adsorbed onto the compound fertilizer granules surface; Every 1000kg finished product, the ratio of adding above-mentioned pulverulent mixture is 4kg-6kg.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2013100623262A CN103086803A (en) | 2013-02-28 | 2013-02-28 | Lumbrukinase compound fertilizer and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2013100623262A CN103086803A (en) | 2013-02-28 | 2013-02-28 | Lumbrukinase compound fertilizer and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN103086803A true CN103086803A (en) | 2013-05-08 |
Family
ID=48199996
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2013100623262A Pending CN103086803A (en) | 2013-02-28 | 2013-02-28 | Lumbrukinase compound fertilizer and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103086803A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103933894A (en) * | 2014-03-12 | 2014-07-23 | 华南理工大学 | Method and composite surfactant for regulating and controlling aquatic water environment |
CN106719850A (en) * | 2016-11-23 | 2017-05-31 | 江苏步龙生物科技有限公司 | A kind of growth regulator and its application method for improving red sage root selenium-rich level |
CN108947743A (en) * | 2018-10-12 | 2018-12-07 | 天津大学前沿技术研究院有限公司 | A kind of preparation method based on Lumbrokinase-concave convex rod soil remediation fertilizer |
CN112028697A (en) * | 2020-08-03 | 2020-12-04 | 安徽省旌一农业旅游发展有限公司 | Process for preventing and controlling caking of compound fertilizer |
CN112410041A (en) * | 2019-08-21 | 2021-02-26 | 薛保珠 | Live earthworm bio-enzyme preparation and soil restoration ferment bacteria balancing agent for worm eggs |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101229984A (en) * | 2008-02-01 | 2008-07-30 | 中国科学院地球化学研究所 | Biological potassic fertilizer produced by using low-grade potassium-bearing rocks and production method thereof |
CN101591207A (en) * | 2008-05-29 | 2009-12-02 | 乔山峰 | Polynutrient anti-blocking synergy urea and preparation method thereof |
CN102173937A (en) * | 2011-01-27 | 2011-09-07 | 中盐安徽红四方股份有限公司 | Composite nitrogen fertilizer and production method thereof |
CN102452861A (en) * | 2010-11-03 | 2012-05-16 | 黄卫忠 | Fertilizer synergistic additive and preparation method thereof |
CN102746068A (en) * | 2012-07-31 | 2012-10-24 | 四川泸天化股份有限公司 | Externally added anticaking agent for urea |
CN102757284A (en) * | 2012-06-19 | 2012-10-31 | 阜阳富瑞雪化工科技有限公司 | Compound fertilizer anti-agglomeration agent as well as preparation method and applications thereof |
CN102924139A (en) * | 2012-10-11 | 2013-02-13 | 安徽三星化工有限责任公司 | Slow release bulk blend fertilizer and preparation method thereof |
-
2013
- 2013-02-28 CN CN2013100623262A patent/CN103086803A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101229984A (en) * | 2008-02-01 | 2008-07-30 | 中国科学院地球化学研究所 | Biological potassic fertilizer produced by using low-grade potassium-bearing rocks and production method thereof |
CN101591207A (en) * | 2008-05-29 | 2009-12-02 | 乔山峰 | Polynutrient anti-blocking synergy urea and preparation method thereof |
CN102452861A (en) * | 2010-11-03 | 2012-05-16 | 黄卫忠 | Fertilizer synergistic additive and preparation method thereof |
CN102173937A (en) * | 2011-01-27 | 2011-09-07 | 中盐安徽红四方股份有限公司 | Composite nitrogen fertilizer and production method thereof |
CN102757284A (en) * | 2012-06-19 | 2012-10-31 | 阜阳富瑞雪化工科技有限公司 | Compound fertilizer anti-agglomeration agent as well as preparation method and applications thereof |
CN102746068A (en) * | 2012-07-31 | 2012-10-24 | 四川泸天化股份有限公司 | Externally added anticaking agent for urea |
CN102924139A (en) * | 2012-10-11 | 2013-02-13 | 安徽三星化工有限责任公司 | Slow release bulk blend fertilizer and preparation method thereof |
Non-Patent Citations (3)
Title |
---|
HTTP://DW9.BLOG.163.COM/正蚓螯核 液体(缓控型)肥料: "http://dw9.blog.163.com/正蚓螯核 液体(缓控型)肥料", 《网易博客》 * |
李东光: "《150种农用复合肥配方与制作》", 31 July 2010 * |
陈三斌: "《农用化工产品手册》", 31 December 2008 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103933894A (en) * | 2014-03-12 | 2014-07-23 | 华南理工大学 | Method and composite surfactant for regulating and controlling aquatic water environment |
CN103933894B (en) * | 2014-03-12 | 2015-12-02 | 华南理工大学 | A kind of regulate and control the method for breeding water body environment and complexed surfactant |
CN106719850A (en) * | 2016-11-23 | 2017-05-31 | 江苏步龙生物科技有限公司 | A kind of growth regulator and its application method for improving red sage root selenium-rich level |
CN108947743A (en) * | 2018-10-12 | 2018-12-07 | 天津大学前沿技术研究院有限公司 | A kind of preparation method based on Lumbrokinase-concave convex rod soil remediation fertilizer |
CN112410041A (en) * | 2019-08-21 | 2021-02-26 | 薛保珠 | Live earthworm bio-enzyme preparation and soil restoration ferment bacteria balancing agent for worm eggs |
CN112028697A (en) * | 2020-08-03 | 2020-12-04 | 安徽省旌一农业旅游发展有限公司 | Process for preventing and controlling caking of compound fertilizer |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104829340B (en) | A kind of micro-capsule graphene composite material controlled release fertilizer granules and preparation method thereof | |
CN102816018B (en) | Special fertilizer for early rice as well as preparation method thereof | |
CN100586903C (en) | Slow release long-acting organic inorganic complex blending fertilizer | |
CN104387210B (en) | granular soil conditioner containing microbial bacteria and preparation method thereof | |
CN105152781A (en) | Biological semi-organic fertilizer containing amino acid and making method thereof | |
CN103382140B (en) | Environment-friendly nitrogen potassium dressing fertilizer containing various nitrogen elements and preparation method thereof | |
CN103086803A (en) | Lumbrukinase compound fertilizer and preparation method thereof | |
CN103664369B (en) | A kind of synergy loss controlling fertilizer and preparation method thereof | |
CN102503628A (en) | Preparation method of humic acid/urea long-acting nitrogen fertilizer | |
CN103896686B (en) | A kind of stability urea | |
CN105418323A (en) | Production method of humic acid synergistic active compound fertilizer | |
CN105384550B (en) | A kind of organic-inorganic complex fertilizer and preparation method thereof of long-acting slow-release P | |
CN108484300A (en) | Ureaformaldehyde Synergistic composite fertilizer production technology | |
CN105481555A (en) | Biological organic-inorganic loss-controlled fertilizer with core-shell structure | |
CN104692951A (en) | Water-soluble compound nitrogen fertilizer and preparation method | |
CN103694038A (en) | Value-added humic acid urea and preparation method thereof | |
CN104355788A (en) | Organic fertilizer capable of promoting strong seedling formation and preparation method of organic fertilizer | |
CN105237295A (en) | Special humic acid chelated slow-release fertilizer for wheat and preparation method thereof | |
CN105152791A (en) | Special humic acid chelated slow-release fertilizer for cotton and preparation method thereof | |
CN102515911A (en) | High-nitrogen composite fertilizer and preparation method thereof | |
CN104058874B (en) | A kind of complex microorganism granulated fertilizer containing middle trace element and production technology thereof | |
WO2014101269A1 (en) | Method for preparing special slow-release long-acting compound fertilizer for paddy rice | |
CN105110999A (en) | Biological compound fertilizer for soybeans and preparation method of biological compound fertilizer | |
CN105418322A (en) | Soil restoration element | |
CN103086804A (en) | Stable lumbrukinase granulated fertilizer and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130508 |