CN103059405B - 抗菌聚丙烯塑料 - Google Patents
抗菌聚丙烯塑料 Download PDFInfo
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- CN103059405B CN103059405B CN201310003576.9A CN201310003576A CN103059405B CN 103059405 B CN103059405 B CN 103059405B CN 201310003576 A CN201310003576 A CN 201310003576A CN 103059405 B CN103059405 B CN 103059405B
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- polypropylene
- antibiotic
- plastic
- polypropylene plastic
- complex antimicrobials
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- -1 polypropylene Polymers 0.000 title claims abstract description 49
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 35
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 35
- 239000004033 plastic Substances 0.000 title claims abstract description 33
- 229920003023 plastic Polymers 0.000 title claims abstract description 33
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 26
- 239000004599 antimicrobial Substances 0.000 claims abstract description 16
- 229920001661 Chitosan Polymers 0.000 claims abstract description 11
- 241000218645 Cedrus Species 0.000 claims abstract description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000010457 zeolite Substances 0.000 claims abstract description 9
- 239000002023 wood Substances 0.000 claims abstract description 8
- 239000004698 Polyethylene Substances 0.000 claims description 7
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- 238000011160 research Methods 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 150000008064 anhydrides Chemical class 0.000 claims description 3
- LKAVYBZHOYOUSX-UHFFFAOYSA-N buta-1,3-diene;2-methylprop-2-enoic acid;styrene Chemical compound C=CC=C.CC(=C)C(O)=O.C=CC1=CC=CC=C1 LKAVYBZHOYOUSX-UHFFFAOYSA-N 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 17
- 241000894006 Bacteria Species 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 2
- 230000003389 potentiating effect Effects 0.000 abstract description 2
- 239000000565 sealant Substances 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 12
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000003921 oil Substances 0.000 description 7
- 230000001954 sterilising effect Effects 0.000 description 7
- 201000010099 disease Diseases 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 230000000845 anti-microbial effect Effects 0.000 description 4
- 208000015181 infectious disease Diseases 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 244000052616 bacterial pathogen Species 0.000 description 3
- 230000000721 bacterilogical effect Effects 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 229960004274 stearic acid Drugs 0.000 description 3
- 206010011409 Cross infection Diseases 0.000 description 2
- 206010029803 Nosocomial infection Diseases 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 206010064097 avian influenza Diseases 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000000968 intestinal effect Effects 0.000 description 2
- 230000003211 malignant effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 241000193738 Bacillus anthracis Species 0.000 description 1
- 206010008631 Cholera Diseases 0.000 description 1
- 241000218691 Cupressaceae Species 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 208000007212 Foot-and-Mouth Disease Diseases 0.000 description 1
- 241000710198 Foot-and-mouth disease virus Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 206010035664 Pneumonia Diseases 0.000 description 1
- 206010057190 Respiratory tract infections Diseases 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 239000010627 cedar oil Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940023064 escherichia coli Drugs 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000023597 hemostasis Effects 0.000 description 1
- 208000006454 hepatitis Diseases 0.000 description 1
- 231100000283 hepatitis Toxicity 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010057 rubber processing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 201000008827 tuberculosis Diseases 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实施例2 | 实施例3 | 实施例4 | 对比例3 | 对比例4 | |
聚丙烯 | 100 | 100 | 100 | 100 | 100 |
实施例1的复合抗菌剂 | 0.4 | 0.4 | 0.4 | ||
对比例1的复合抗菌剂 | 0.4 | ||||
对比例2的复合抗菌剂 | 0.4 | ||||
乙撑双硬脂酰胺 | 0.3 | 0.3 | |||
聚丙烯接枝马来酸酐 | 3 |
实施例2 | 实施例3 | 实施例4 | 对比例3 | 对比例4 | |
大肠杆菌杀菌率,% | 98.2 | 99.0 | 99.9 | 92.4 | 94.0 |
金黄色葡萄球菌杀菌率,% | 98.4 | 98.8 | 99.8 | 93.0 | 93.6 |
Claims (3)
Priority Applications (1)
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CN201310003576.9A CN103059405B (zh) | 2013-01-06 | 2013-01-06 | 抗菌聚丙烯塑料 |
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CN103059405A CN103059405A (zh) | 2013-04-24 |
CN103059405B true CN103059405B (zh) | 2016-01-20 |
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Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103483691A (zh) * | 2013-09-22 | 2014-01-01 | 苏州市湘园特种精细化工有限公司 | 一种抗菌、高强度滑石粉改性聚丙烯塑料 |
CN103724797B (zh) * | 2013-12-06 | 2016-04-27 | 宁波康德新材料有限公司 | 一种高强度的聚丙烯抗菌塑料 |
CN103642127A (zh) * | 2013-12-09 | 2014-03-19 | 宁波康氏塑料科技有限公司 | 一种高强度聚丙烯抗菌塑料的制备方法 |
CN104893045A (zh) * | 2015-06-08 | 2015-09-09 | 苏州市湘园特种精细化工有限公司 | 一种抗菌橡胶薄膜 |
CN105061771A (zh) * | 2015-07-30 | 2015-11-18 | 山东惠民力洁生物科技有限公司 | 一种消毒材料甲基胍盐酸化壳聚糖的制备方法 |
CN105400066A (zh) * | 2015-11-25 | 2016-03-16 | 全椒祥瑞塑胶有限公司 | 一种食品包装袋用塑料 |
CN105400067A (zh) * | 2015-11-25 | 2016-03-16 | 全椒祥瑞塑胶有限公司 | 一种具有抑菌作用的聚丙烯 |
CN105400041A (zh) * | 2015-11-25 | 2016-03-16 | 全椒祥瑞塑胶有限公司 | 一种具有抑菌作用的聚乙烯 |
CN105694229B (zh) * | 2016-04-24 | 2017-12-12 | 广州美泰塑料包装有限公司 | 一种pp抗菌塑料及其制备方法 |
CN106397965A (zh) * | 2016-08-26 | 2017-02-15 | 常州瑞杰新材料科技股份有限公司 | 一种抗菌型聚丙烯材料及制备方法 |
CN106977814B (zh) * | 2017-04-21 | 2020-03-06 | 石家庄学院 | 一种具有稳定抗菌性能的复合材料及其用途 |
CN108129703A (zh) * | 2017-11-13 | 2018-06-08 | 孝感市锐思新材科技有限公司 | 一种塑料抗菌材料的制备方法 |
CN108641178A (zh) * | 2018-04-04 | 2018-10-12 | 高猛 | 一种高抗菌阻燃塑料及其制备方法 |
CN109535763A (zh) * | 2018-11-26 | 2019-03-29 | 庄雪芸 | 一种抗菌塑料配方 |
CN110835439A (zh) * | 2019-11-19 | 2020-02-25 | 杭州科技职业技术学院 | 一种医用抗菌塑料材料及其制备方法 |
WO2021148938A1 (en) * | 2020-01-20 | 2021-07-29 | Association For The Advancement Of Tissue Engineering And Cell Based Technologies & Therapies (A4Tec) - Associação | Ceramic-based composites materials methods and uses thereof |
CN113527856A (zh) * | 2021-06-24 | 2021-10-22 | 浙江白鹿源科技有限公司 | 一种自清洁抗菌工程塑料基体及其制备的强制送风口罩面罩 |
CN114031848B (zh) * | 2021-11-16 | 2023-06-30 | 惠州市晋裕塑料科技有限公司 | 一种口罩用聚丙烯复合材料 |
CN114163734B (zh) * | 2022-02-10 | 2022-05-10 | 广东烽业科技有限公司 | 一种高抗菌聚丙烯材料及其制备方法和应用 |
Citations (3)
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CN101724284A (zh) * | 2008-10-31 | 2010-06-09 | 中国石油化工股份有限公司 | 一种抗菌热塑性塑料组合物及其制备方法 |
CN102241883A (zh) * | 2010-09-25 | 2011-11-16 | 深圳市科聚新材料有限公司 | 一种抗菌聚酰胺材料及其制备方法 |
CN102838809A (zh) * | 2012-09-26 | 2012-12-26 | 上海瀚氏模具成型有限公司 | 抗菌聚丙烯塑料及其制备方法 |
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2013
- 2013-01-06 CN CN201310003576.9A patent/CN103059405B/zh active Active
Patent Citations (3)
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CN101724284A (zh) * | 2008-10-31 | 2010-06-09 | 中国石油化工股份有限公司 | 一种抗菌热塑性塑料组合物及其制备方法 |
CN102241883A (zh) * | 2010-09-25 | 2011-11-16 | 深圳市科聚新材料有限公司 | 一种抗菌聚酰胺材料及其制备方法 |
CN102838809A (zh) * | 2012-09-26 | 2012-12-26 | 上海瀚氏模具成型有限公司 | 抗菌聚丙烯塑料及其制备方法 |
Non-Patent Citations (1)
Title |
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《芳香型植物精油抑菌致果的测定和比较》;王红星等;《中国饲料》;19960323(第6期);第32-34页 * |
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Inventor after: Yan Peiqi Inventor before: Huang Meirong |
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Effective date of registration: 20160224 Address after: 321017 Zhejiang province Jinhua Bailong Dong Xi industrial zone Patentee after: Zhejiang Beiqier Medical Products Co., Ltd. Address before: Room 271, building 280, Shuguang Road, Shanghai, Minhang District, 201111, China Patentee before: Shanghai Qiucheng New Material Technology Co., Ltd. |
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Address after: 321017 Zhejiang province Jinhua Bailong Dong Xi industrial zone Patentee after: Zhejiang home doctor health industry Limited by Share Ltd Address before: 321017 Zhejiang province Jinhua Bailong Dong Xi industrial zone Patentee before: Zhejiang Beiqier Medical Products Co., Ltd. |
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Denomination of invention: Antibacterial polypropylene plastic Effective date of registration: 20171205 Granted publication date: 20160120 Pledgee: Agricultural Bank of China Limited by Share Ltd Jinhua Economic Development Zone Branch Pledgor: Zhejiang home doctor health industry Limited by Share Ltd Registration number: 2017990001119 |
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Date of cancellation: 20190618 Granted publication date: 20160120 Pledgee: Agricultural Bank of China Limited by Share Ltd Jinhua Economic Development Zone Branch Pledgor: Zhejiang home doctor health industry Limited by Share Ltd Registration number: 2017990001119 |