CN103046328A - Oiling agent used for wood pulp cellulose - Google Patents

Oiling agent used for wood pulp cellulose Download PDF

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Publication number
CN103046328A
CN103046328A CN2013100302929A CN201310030292A CN103046328A CN 103046328 A CN103046328 A CN 103046328A CN 2013100302929 A CN2013100302929 A CN 2013100302929A CN 201310030292 A CN201310030292 A CN 201310030292A CN 103046328 A CN103046328 A CN 103046328A
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CN
China
Prior art keywords
wood pulp
fatty acid
pulp cellulose
oiling agent
finish
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Granted
Application number
CN2013100302929A
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Chinese (zh)
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CN103046328B (en
Inventor
黄美蓉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU HAILUN DYEING AND FINISHING CO., LTD.
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Shanghai Qiucheng New Material Technology Co Ltd
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Priority to CN201310030292.9A priority Critical patent/CN103046328B/en
Publication of CN103046328A publication Critical patent/CN103046328A/en
Application granted granted Critical
Publication of CN103046328B publication Critical patent/CN103046328B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention discloses an oiling agent used for wood pulp cellulose. The oiling agent comprises the following components in parts by weight: 50-70 parts of (Z)-9-octadecenoic acid-dodecyl ester, 10-30 parts of disodium 4-(2-(2-(2-(dodecyloxy)ethoxy)ethoxy)ethyl)2-sulphonatosuccinate and 10-30 parts of a reaction product of coconut fatty acid, polyethylenimine, soya fatty acid ethoxylate and quaternization chloromethane. The oiling agent used for the wood pulp cellulose disclosed by the invention has an effect of improving smoothness and flexibility of the wood pulp cellulose and can improve antistatic property of the wood pulp cellulose.

Description

The finish that is used for wood pulp fibre
Technical field
The present invention relates to a kind of textile fabric finish, relate in particular to a kind of finish for wood pulp fibre.
Background technology
In procedure of fibre production and processing, finish is a kind of auxiliary agent, and it plays a part mediator, has very important effect in spinning, stretching, spinning, the operation such as woven.
Finish is the reagent of processing behind the fiber, basically take surfactant as main body.It can increase interfibrous armful and power and flatness, reduces the coefficient of friction between fiber and machinery, reduces generation of static electricity.If allocate suitable brute force and the anti-wear performance that also can increase yarn, reduce the strength loss of twist, improve the adhesive force of viscose glue cord fabric thread and rubber.
The main component of finish comprises smooth agent, emulsifying agent, antistatic additive, also can add other compositions according to the different purposes of fiber, promoter, organic solvent and the water etc. that adhere to such as antioxidant, mould inhibitor, rust inhibitor, defoamer, with rubber.
Summary of the invention
Technical problem to be solved by this invention provides a kind of finish for wood pulp fibre, after wood pulp fibre is oiled, has the effect that improves the fiber smooth, soft, and can improve the antistatic behaviour of fiber.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of finish for wood pulp fibre is comprised of following raw materials in parts by weight:
(Z)-9-octadecenic acid-dodecyl ester 50-70 part;
Ethoxylated dodecyl alcohol sulfosuccinate disodium 10-30 part;
Product 10-30 part of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane.
Described (Z)-9-octadecenic acid-dodecyl ester, English name: 9-Octadecenoic acid (Z)-, dodecyl ester, CAS accession number: 36078-10-1.
Described ethoxylated dodecyl alcohol sulfosuccinate disodium, English name: Disodium laureth sulfosuccinate, CAS accession number: 36409-57-1, chemical structural formula is as follows:
The product of described coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane, English name: Fatty acids, coco, reaction products with diethylenetriamine and soya fatty acids, ethoxylated.CAS accession number 68604-75-1.
With (Z)-9-octadecenic acid-dodecyl ester; Ethoxylated dodecyl alcohol sulfosuccinate disodium; The product of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane takes by weighing in proportion, mixes, and can make the finish for wood pulp fibre of the present invention.
Wood pulp fibre is a kind of of string.But it is different from the string of saying, and it is a kind of secondary stock (that is, the product of separating from former string), because it mainly extracts from wood pulp, so name with wood pulp fibre, is similar to the paper pulp of papermaking.The classification of wood pulp fibre (1) softwood pulp fiber (such as masson pine, larch, Korean pine, dragon spruce etc.) (2) hardwood pulp fiber (such as birch, poplar, linden, Eucalyptus, maple etc.).
Finish for wood pulp fibre of the present invention has the effect that improves the wood pulp fibre smooth, soft, and can improve the antistatic behaviour of wood pulp fibre.
The specific embodiment
Embodiment 1
Take by weighing: (Z)-6 kilograms of 9-octadecenic acid-dodecyl esters; 2 kilograms of ethoxylated dodecyl alcohol sulfosuccinate disodiums; 2 kilograms of the product of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane mix, and can make the finish for wood pulp fibre of the present invention.
The above-mentioned finish for wood pulp fibre of the present invention that makes is added an amount of deionized water, mix, make the emulsion of active ingredient mass concentration 20%.
Adopt again conventional spray process that above-mentioned emulsion is directly sprayed on the pinus massoniana pulp fibres.The oil effective concentration of circulating slot finish of fiber is controlled at 1.0%, and the Sprayer Circulation flow-control that oils is at 1.5m 3/ h, 55 ℃ of temperature.
Detect finished fiber oil-containing 0.20% according to GB/T6504-2008.
Adopt the general method of the industry, measure the coefficient of kinetic friction μ of rear wood pulp fibre to metal that oil d(F/M) be 0.224cm.min -1, wood pulp fibre volume resistivity 3.8 * 10 7Ω cm.
Embodiment 2
Take by weighing: (Z)-7 kilograms of 9-octadecenic acid-dodecyl esters; 1 kilogram of ethoxylated dodecyl alcohol sulfosuccinate disodium; 3 kilograms of the product of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane mix, and can make the finish for wood pulp fibre of the present invention.
Adopt such as embodiment 1 identical method and process the pinus massoniana pulp fibres.
Adopt the general method of the industry, measure the coefficient of kinetic friction μ of rear wood pulp fibre to metal that oil d(F/M) be 0.234cm.min -1, wood pulp fibre volume resistivity 4.0 * 10 7Ω cm.
Embodiment 3
Take by weighing: (Z)-5 kilograms of 9-octadecenic acid-dodecyl esters; 3 kilograms of ethoxylated dodecyl alcohol sulfosuccinate disodiums; 1 kilogram of the product of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane mixes, and can make the finish for wood pulp fibre of the present invention.
Adopt such as embodiment 1 identical method and process the pinus massoniana pulp fibres.
Adopt the general method of the industry, measure the coefficient of kinetic friction μ of rear wood pulp fibre to metal that oil d(F/M) be 0.24cm.min -1, wood pulp fibre volume resistivity 4.2 * 10 7Ω cm.
Finish for wood pulp fibre of the present invention compares with general oil solution, to the coefficient of kinetic friction μ of metal d(F/M) less, and have good antistatic property.

Claims (2)

1. a finish that is used for wood pulp fibre is characterized in that, is comprised of following raw material: (Z)-and 9-octadecenic acid-dodecyl ester; Ethoxylated dodecyl alcohol sulfosuccinate disodium; The product of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane.
2. a finish that is used for wood pulp fibre is characterized in that, is comprised of following raw materials in parts by weight:
(Z)-9-octadecenic acid-dodecyl ester 50-70 part;
Ethoxylated dodecyl alcohol sulfosuccinate disodium 10-30 part;
Product 10-30 part of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane.
CN201310030292.9A 2013-01-25 2013-01-25 Oiling agent used for wood pulp cellulose Expired - Fee Related CN103046328B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310030292.9A CN103046328B (en) 2013-01-25 2013-01-25 Oiling agent used for wood pulp cellulose

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310030292.9A CN103046328B (en) 2013-01-25 2013-01-25 Oiling agent used for wood pulp cellulose

Publications (2)

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CN103046328A true CN103046328A (en) 2013-04-17
CN103046328B CN103046328B (en) 2014-08-06

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104452429A (en) * 2014-10-23 2015-03-25 广东比伦生活用纸有限公司 Super-soft super-tough household paper and production method thereof
CN104452430A (en) * 2014-10-23 2015-03-25 广东比伦生活用纸有限公司 Super-soft aromatized household paper and production method thereof
CN106283267A (en) * 2016-08-17 2017-01-04 江苏鸿顺合纤科技有限公司 A kind of preparation method of the composite fibre for tearing woven fabric conveniently

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101858036A (en) * 2010-06-04 2010-10-13 上海里奥纤维企业发展有限公司 Solvent method fiber treatment oil solution
CN102400355A (en) * 2010-09-14 2012-04-04 殷兰芳 Vinylon spinning oil
CN102400314A (en) * 2010-09-13 2012-04-04 王琳 Chinlon filament winding oil
CN102400352A (en) * 2010-09-13 2012-04-04 曹德如 Chinlon oiling agent for braided silk

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101858036A (en) * 2010-06-04 2010-10-13 上海里奥纤维企业发展有限公司 Solvent method fiber treatment oil solution
CN102400314A (en) * 2010-09-13 2012-04-04 王琳 Chinlon filament winding oil
CN102400352A (en) * 2010-09-13 2012-04-04 曹德如 Chinlon oiling agent for braided silk
CN102400355A (en) * 2010-09-14 2012-04-04 殷兰芳 Vinylon spinning oil

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104452429A (en) * 2014-10-23 2015-03-25 广东比伦生活用纸有限公司 Super-soft super-tough household paper and production method thereof
CN104452430A (en) * 2014-10-23 2015-03-25 广东比伦生活用纸有限公司 Super-soft aromatized household paper and production method thereof
CN106283267A (en) * 2016-08-17 2017-01-04 江苏鸿顺合纤科技有限公司 A kind of preparation method of the composite fibre for tearing woven fabric conveniently

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Inventor after: Zhang Xingyu

Inventor after: Xue Haiwei

Inventor before: Huang Meirong

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Free format text: CORRECT: ADDRESS; FROM: 201111 MINHANG, SHANGHAI TO: 226500 NANTONG, JIANGSU PROVINCE

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Address after: 226500, Binhe Road, Changjiang town (Rugao port area), Nantong, Jiangsu, Rugao 36, China

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Applicant after: JIANGSU HAILUN DYEING AND FINISHING CO., LTD.

Address before: Room 271, building 280, Shuguang Road, Shanghai, Minhang District, 201111, China

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