CN103590242B - A kind of finish produced for polypropylene fibre - Google Patents
A kind of finish produced for polypropylene fibre Download PDFInfo
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- CN103590242B CN103590242B CN201310612426.8A CN201310612426A CN103590242B CN 103590242 B CN103590242 B CN 103590242B CN 201310612426 A CN201310612426 A CN 201310612426A CN 103590242 B CN103590242 B CN 103590242B
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- parts
- finish
- polypropylene fibre
- oil
- produced
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- -1 polypropylene Polymers 0.000 title claims abstract description 56
- 239000000835 fiber Substances 0.000 title claims abstract description 42
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 28
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 28
- 239000000839 emulsion Substances 0.000 claims abstract description 29
- 239000003921 oil Substances 0.000 claims abstract description 19
- 239000010775 animal oil Substances 0.000 claims abstract description 18
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 16
- 239000010452 phosphate Substances 0.000 claims abstract description 16
- 239000004698 Polyethylene Substances 0.000 claims abstract description 15
- 229920000573 polyethylene Polymers 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 14
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 13
- HVUMOYIDDBPOLL-UHFFFAOYSA-N 2-(3,4-Dihydroxyoxolan-2-yl)-2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)C1OCC(O)C1O HVUMOYIDDBPOLL-UHFFFAOYSA-N 0.000 claims abstract description 13
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 13
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 13
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000005642 Oleic acid Substances 0.000 claims abstract description 13
- 229920001214 Polysorbate 60 Polymers 0.000 claims abstract description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 13
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 13
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 13
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims abstract description 13
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims abstract description 13
- 229940113124 polysorbate 60 Drugs 0.000 claims abstract description 13
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 13
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 13
- 239000010703 silicon Substances 0.000 claims abstract description 13
- 235000014121 butter Nutrition 0.000 claims description 3
- 238000009987 spinning Methods 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 239000000654 additive Substances 0.000 abstract description 5
- 230000000996 additive effect Effects 0.000 abstract description 5
- 239000004744 fabric Substances 0.000 abstract description 3
- 239000004753 textile Substances 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000008041 oiling agent Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of finish produced for polypropylene fibre, belong to spinning oil technical field in field of textiles.Does finish of the present invention comprise the following raw material according to weight parts: animal oil 5-20 part, white oil 3-10 part, oleic acid 5-15 part, sorbester p18? 1-10 part, polysorbate60? 4-12 part, film 2-9 part, polyethylene emulsion 3-10 part, fatty alcohol ether phosphate kalium salt 5-30 part, organic silicon emulsion 3-10 part, potassium persulfate 0.1-2 part.The finish produced for polypropylene fibre of the present invention with animal oil and white oil for main component, for the object improving fabric hand, be aided with specific softener, i.e. film and polyethylene emulsion, antistatic additive, smooth agent, non-ionic surface active agent etc., while reducing finish cost, make this finish can give fiber better soft feel.
Description
Technical field
The present invention relates to a kind of spinning oil, more particularly, the present invention relates to a kind of finish produced for polypropylene fibre, belong to spinning oil technical field in field of textiles.
Background technology
Fiber will be subject to (comprising the inorfils such as organic polymer and glass yarn such as chemical fibre, natural fabric or synthetic fiber) effect of various parts when textile process, due to fiber and mechanical and that fiber is mutual friction, a lot of electric charge will inevitably be assembled, this generates electrostatic.So in the process of producd fibers, finish can be used, i.e. finishing agent, for meeting the requirement of processing technology and giving fiber with softness, lubrication, boundling, obvolvent, the performance such as antistatic.It is the Unctuous compositions of principal component that this finishing agent has with mineral oil, also has the emulsion of the aqueous solution based on polyethers or water-based.
Polypropylene fibre, also known as polypropylene fibre, take polypropylene as the synthetic fiber that raw material spinning obtains, it is kind the lightest in chemical fibre, intensity is 35 ~ 62cN/dtex, and ABRASION RESISTANCE is only second to polyamide fiber, and corrosion resistance is good, especially fine, not mouldy to inorganic acid, alkaline stability, without putrefaction, be not afraid of and damage by worms.But it is more difficult to dye, and polypropylene fibre also has the shortcomings such as light resistance is poor, electrostatic is large, flame resistance is poor, and the method adding various additive can be adopted to be improved.
It is the patent of invention of CN101886334A that State Intellectual Property Office discloses a publication number in 2010.11.17, this patent relates to a kind of oiling agent for polypropylene spinning, it is made up of smooth agent 30-50%, emulsifying agent 10-25%, collecting agent 10-20%, antistatic additive 1-10%, water 10-20% and defoamer 0.1-2% by weight percentage, and smooth agent is a kind of in fatty acid polyethylene glycol ester, polyethers or their mixture; Collecting agent is saturated fatty alcohol polyoxyethylene ether; Emulsifying agent is castor oil polyoxyethylene ether; Antistatic additive is fatty alcohol phosphate sylvite, fatty alcohol phosphate polyoxyethylene ether sylvite, a kind of in aliphatic alcohol polyoxyvinethene phosphate sylvite or be greater than a kind of mixture; Defoamer is organosiloxane, can reduce machine and interfibrous wearing and tearing; Improve interfibrous cohesive force; Improve the antistatic behaviour of fiber; In being applicable to, thick denier polypropylene staple fiber spinning process, is specially adapted to the polypropene staple spinning technique of 3-17 DENIER.
Although the oiling agent for polypropylene spinning in above-mentioned patent can reduce wear and improve antistatic behaviour, this finish cost is higher, and cannot give fiber good soft feel.
Summary of the invention
The finish cost that the present invention is intended to solve in above-mentioned patent is higher, and cannot give the problem of the good soft feel of fiber, and provide a kind of finish produced for polypropylene fibre, cost is lower, and can give fiber good soft feel.
In order to realize foregoing invention object, its concrete technical scheme is as follows:
For the finish that polypropylene fibre is produced, it is characterized in that: comprise the following raw material according to weight parts:
Animal oil 5-20 part
White oil 3-10 part
Oleic acid 5-15 part
Sorbester p18 1-10 part
Polysorbate60 4-12 part
Film 2-9 part
Polyethylene emulsion 3-10 part
Fatty alcohol ether phosphate kalium salt 5-30 part
Organic silicon emulsion 3-10 part
Potassium persulfate 0.1-2 part.
Animal oil of the present invention is butter or suet.
A kind of finish produced for polypropylene fibre of the present invention, is characterized in that: comprise the following raw material according to weight parts:
Animal oil 8-18 part
White oil 5-9 part
Oleic acid 6-12 part
Sorbester p18 3-9 part
Polysorbate60 5-10 part
Film 3-8 part
Polyethylene emulsion 5-9 part
Fatty alcohol ether phosphate kalium salt 7-25 part
Organic silicon emulsion 5-8 part
Potassium persulfate 0.2-1.5 part.
A kind of finish produced for polypropylene fibre of the present invention, is characterized in that: comprise the following raw material according to weight parts:
16 parts, animal oil
White oil 6 parts
Oleic acid 10 parts
Sorbester p18 8 parts
Polysorbate60 7.5 parts
Film 7.5 parts
Polyethylene emulsion 6 parts
Fatty alcohol ether phosphate kalium salt 21 parts
Organic silicon emulsion 6 parts
Potassium persulfate 0.4 part.
The Advantageous Effects that the present invention brings:
It is higher that finish for polypropylene fibre production of the present invention solves finish cost of the prior art, and the problem of the good soft feel of fiber cannot be given, with animal oil and white oil for main component, for the object improving fabric hand, be aided with specific softener, i.e. film and polyethylene emulsion, antistatic additive, smooth agent, non-ionic surface active agent etc., while reducing finish cost, make this finish can give fiber better soft feel, this finish oils effective, the flatness that fiber is good can be given, full conjunction property, it is soft, the coefficient of friction of fiber and spinning equipment is suitable, good spinnability, the product quality of fiber can be significantly improved.On the basis of basic technical scheme of the present invention each composition weight number scope, further its addition is optimized again, obtain two preferred technical schemes, further increase the properties of finish, especially further enhance the soft feel of fiber after oiling.
Detailed description of the invention
embodiment 1
For the finish that polypropylene fibre is produced, comprise the following raw material according to weight parts:
5 parts, animal oil
White oil 3 parts
Oleic acid 5 parts
Sorbester p18 1 part
Polysorbate60 4 parts
Film 2 parts
Polyethylene emulsion 3 parts
Fatty alcohol ether phosphate kalium salt 5 parts
Organic silicon emulsion 3 parts
Potassium persulfate 0.1 part.
embodiment 2
For the finish that polypropylene fibre is produced, comprise the following raw material according to weight parts:
20 parts, animal oil
White oil 10 parts
Oleic acid 15 parts
Sorbester p18 10 parts
Polysorbate60 12 parts
Film 9 parts
Polyethylene emulsion 10 parts
Fatty alcohol ether phosphate kalium salt 30 parts
Organic silicon emulsion 10 parts
Potassium persulfate 2 parts.
embodiment 3
For the finish that polypropylene fibre is produced, comprise the following raw material according to weight parts:
12.5 parts, animal oil
White oil 6.5 parts
Oleic acid 10 parts
Sorbester p18 5.5 parts
Polysorbate60 8 parts
Film 5.5 parts
Polyethylene emulsion 6.5 parts
Fatty alcohol ether phosphate kalium salt 17.5 parts
Organic silicon emulsion 6.5 parts
Potassium persulfate 0.6 part.
embodiment 4
For the finish that polypropylene fibre is produced, comprise the following raw material according to weight parts:
8 parts, animal oil
White oil 5 parts
Oleic acid 6 parts
Sorbester p18 3 parts
Polysorbate60 5 parts
Film 3 parts
Polyethylene emulsion 59 parts
Fatty alcohol ether phosphate kalium salt 7 parts
Organic silicon emulsion 5 parts
Potassium persulfate 0.2 part.
embodiment 5
For the finish that polypropylene fibre is produced, comprise the following raw material according to weight parts:
18 parts, animal oil
White oil 9 parts
Oleic acid 12 parts
Sorbester p18 9 parts
Polysorbate60 10 parts
Film 8 parts
Polyethylene emulsion 9 parts
Fatty alcohol ether phosphate kalium salt 25 parts
Organic silicon emulsion 8 parts
Potassium persulfate 1.5 parts.
embodiment 6
For the finish that polypropylene fibre is produced, comprise the following raw material according to weight parts:
13 parts, animal oil
White oil 7 parts
Oleic acid 9 parts
Sorbester p18 6 parts
Polysorbate60 7.5 parts
Film 5.5 parts
Polyethylene emulsion 7 parts
Fatty alcohol ether phosphate kalium salt 16 parts
Organic silicon emulsion 6.5 parts
Potassium persulfate 0.85 part.
embodiment 7
For the finish that polypropylene fibre is produced, comprise the following raw material according to weight parts:
16 parts, animal oil
White oil 6 parts
Oleic acid 10 parts
Sorbester p18 8 parts
Polysorbate60 7.5 parts
Film 7.5 parts
Polyethylene emulsion 6 parts
Fatty alcohol ether phosphate kalium salt 21 parts
Organic silicon emulsion 6 parts
Potassium persulfate 0.4 part.
embodiment 8
On the basis of embodiment 1-7, preferred:
Described animal oil is butter or suet.
Claims (3)
1., for the finish that polypropylene fibre is produced, it is characterized in that: comprise the following raw material according to weight parts:
Animal oil 8-18 part
White oil 5-9 part
Oleic acid 6-12 part
Sorbester p18 3-9 part
Polysorbate60 5-10 part
Film 3-8 part
Polyethylene emulsion 5-9 part
Fatty alcohol ether phosphate kalium salt 7-25 part
Organic silicon emulsion 5-8 part
Potassium persulfate 0.2-1.5 part.
2. a kind of finish produced for polypropylene fibre according to claim 1, is characterized in that: described animal oil is butter or suet.
3. a kind of finish produced for polypropylene fibre according to claim 1 and 2, is characterized in that: comprise the following raw material according to weight parts:
16 parts, animal oil
White oil 6 parts
Oleic acid 10 parts
Sorbester p18 8 parts
Polysorbate60 7.5 parts
Film 7.5 parts
Polyethylene emulsion 6 parts
Fatty alcohol ether phosphate kalium salt 21 parts
Organic silicon emulsion 6 parts
Potassium persulfate 0.4 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310612426.8A CN103590242B (en) | 2013-11-28 | 2013-11-28 | A kind of finish produced for polypropylene fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310612426.8A CN103590242B (en) | 2013-11-28 | 2013-11-28 | A kind of finish produced for polypropylene fibre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103590242A CN103590242A (en) | 2014-02-19 |
| CN103590242B true CN103590242B (en) | 2015-12-09 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310612426.8A Active CN103590242B (en) | 2013-11-28 | 2013-11-28 | A kind of finish produced for polypropylene fibre |
Country Status (1)
| Country | Link |
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| CN (1) | CN103590242B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105133311B (en) * | 2015-08-18 | 2017-10-24 | 苏州晟德竹科技发展有限公司 | A kind of polypropylene filament yarn oil agent and its application method |
| CN105178024A (en) * | 2015-11-03 | 2015-12-23 | 杭州电子科技大学 | Novel antistatic spinning oil |
| CN106381696A (en) * | 2016-08-29 | 2017-02-08 | 海安县锦荣化纤有限公司 | Oil agent for spinning |
| CN106480736A (en) * | 2016-09-27 | 2017-03-08 | 浙江四通化纤股份有限公司 | The super soft carpet yarn spinning oil agent of polypropylene and preparation method |
| CN106868858A (en) * | 2017-03-29 | 2017-06-20 | 王义辉 | A kind of fabric size and preparation method thereof |
| CN115852683B (en) * | 2022-11-30 | 2024-06-14 | 上海丰泽源科技有限公司 | Degradable PLA spinning oil and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0784707B2 (en) * | 1989-07-04 | 1995-09-13 | 東レ株式会社 | Oil agent composition for untwisted non-paste woven fabric warp and high-speed yarn making method using the oil agent composition |
| CN101629383A (en) * | 2009-08-27 | 2010-01-20 | 上虞市皇马化学有限公司 | Terylene FDY spinning oil and preparation method thereof |
| CN102978934A (en) * | 2012-11-28 | 2013-03-20 | 浙江天圣控股集团有限公司 | Low-smoke FDY (Fully Drawn Yarn) oiling agent and preparation method thereof |
-
2013
- 2013-11-28 CN CN201310612426.8A patent/CN103590242B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0784707B2 (en) * | 1989-07-04 | 1995-09-13 | 東レ株式会社 | Oil agent composition for untwisted non-paste woven fabric warp and high-speed yarn making method using the oil agent composition |
| CN101629383A (en) * | 2009-08-27 | 2010-01-20 | 上虞市皇马化学有限公司 | Terylene FDY spinning oil and preparation method thereof |
| CN102978934A (en) * | 2012-11-28 | 2013-03-20 | 浙江天圣控股集团有限公司 | Low-smoke FDY (Fully Drawn Yarn) oiling agent and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 纺织品柔软剂的应用现状及趋势;田丽;《轻纺工业与技术》;20110225;第40卷(第1期);第69-73页 * |
| 表面活性剂在化纤油剂中的应用;洪有纪;《纺织科学研究》;19991225;第29-33页 * |
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| CN103590242A (en) | 2014-02-19 |
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Effective date of registration: 20170329 Address after: 645350 Yibin City Pingshan County of Sichuan province stone plate Industrial Park Patentee after: Yibin Pingshan Pfizer Oil Co. Ltd. Address before: Yangtze River Avenue East 644002 Yibin province Sichuan City Cuiping District No. 2 Building 4, 1 floor, No. 3 Patentee before: Sun Yihua |
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Address after: 645350 Yibin City Pingshan County of Sichuan province stone plate Industrial Park Patentee after: Yibin Pingshan Pfizer Technology Co., Ltd Address before: 645350 Yibin City Pingshan County of Sichuan province stone plate Industrial Park Patentee before: YIBIN PINGSHAN HUIRUI GREASE Co.,Ltd. |
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