CN103046322B - Oil solution for poly-p-phenylene terephthamide fibers - Google Patents
Oil solution for poly-p-phenylene terephthamide fibers Download PDFInfo
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- CN103046322B CN103046322B CN201310028387.7A CN201310028387A CN103046322B CN 103046322 B CN103046322 B CN 103046322B CN 201310028387 A CN201310028387 A CN 201310028387A CN 103046322 B CN103046322 B CN 103046322B
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Abstract
The invention discloses an oil solution for poly-p-phenylene terephthamide fibers. The oil solution consists of the following raw materials in parts by weight: 50 to 70 parts of 9-octadecenoic acid (Z)-dodecyl ester, 10 to 30 parts of 1,2-di(2-amino-phenoxy)-ethane-N,N,N',N'-tetraacethyl tetrasodium salt, 10 to 30 parts of 1-tridecanol dihydrogen phosphate, 20 to 40 parts of potassium chloride, and 10 to 30 parts of fatty acids, coco, reaction products with diethylenetriamine and soya fatty acids, ethoxylated. The oil solution for the poly-p-phenylene terephthamide fibers has a function of improving smoothness and softness of the poly-p-phenylene terephthamide fibers, and can improve the antistatic property of the poly-p-phenylene terephthamide fibers.
Description
Technical field
The present invention relates to a kind of textile fabric finish, relate in particular to a kind of Fanglun 1414's finish.
Background technology
In procedure of fibre production and processing, finish is a kind of auxiliary agent, and it plays a part mediator, has very important effect in spinning, stretching, spinning, the operation such as woven.
Finish is the reagent of processing after fiber, substantially taking surfactant as main body.It can increase interfibrous armful and power and flatness, reduces the coefficient of friction between fiber and machinery, reduces generation of static electricity.If allocate suitable brute force and the anti-wear performance that also can increase yarn, reduce the strength loss of twist, improve the adhesive force of viscose glue cord fabric thread and rubber.
The main component of finish comprises smooth agent, emulsifying agent, antistatic additive, also can add other compositions according to the different purposes of fiber, promoter, organic solvent and the water etc. that adhere to as antioxidant, mould inhibitor, rust inhibitor, defoamer, with rubber.
Fanglun 1414, English name: poly-p-phenylene terephthamide, another name: p-aramid fiber, Fanglun l414.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of Fanglun 1414's finish, after Fanglun 1414 is oiled, has the effect that improves fiber smooth, soft, and can improve the antistatic behaviour of fiber.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of Fanglun 1414's finish, is made up of following raw materials in parts by weight:
(Z)-9-octadecenic acid-dodecyl ester 50-70 part;
Two (the 2-amino-benzene oxygen)-ethane-N of 1,2-, N, N`, N`-tetraacethyl tetrasodium salt 10-30 part;
Dihydrogen phosphoric acid tridecyl ester 10-30 part;
Potassium chloride 20-40 part;
Product 10-30 part of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane.
Described (Z)-9-octadecenic acid-dodecyl ester, English name: 9-Octadecenoic acid (Z)-, dodecyl ester, CAS accession number: 36078-10-1.
Described 1, two (the 2-amino-benzene oxygen)-ethane-N of 2-, N, N`, N`-tetraacethyl tetrasodium salt, No. CAS: 126824-24-6.
Described dihydrogen phosphoric acid tridecyl ester, No. CAS: 5116-94-9.1-Tridecanol,dihydrogen?phosphate。
The product of described coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane, English name: Fatty acids, coco, reaction products with diethylenetriamine and soya fatty acids, ethoxylated.CAS accession number 68604-75-1.
By (Z)-9-octadecenic acid-dodecyl ester; Two (the 2-amino-benzene oxygen)-ethane-N of 1,2-, N, N`, N`-tetraacethyl tetrasodium salt; Dihydrogen phosphoric acid tridecyl ester; Potassium chloride; The product of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane takes in proportion, is uniformly mixed, and can make Fanglun 1414's finish of the present invention.
Fanglun 1414's finish of the present invention, has the effect that improves Fanglun 1414's smooth, soft, and can improve Fanglun 1414's antistatic behaviour.
Detailed description of the invention
Embodiment 1
Take: (Z)-6 kilograms of 9-octadecenic acid-dodecyl esters; Two (the 2-amino-benzene oxygen)-ethane-N of 1,2-, N, N`, 2 kilograms of N`-tetraacethyl tetrasodium salts; 2 kilograms of dihydrogen phosphoric acid tridecyl esters; 3 kilograms, potassium chloride; 2 kilograms of the product of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane, are uniformly mixed, and can make Fanglun 1414's finish of the present invention.
The above-mentioned Fanglun 1414 of the present invention who makes is added in appropriate deionized water with finish, be uniformly mixed, make the emulsion of active ingredient mass concentration 10%.
After emulsion prepares, can oil by spray thrower, oiling roller or immersion trough.
Test:
The above-mentioned Fanglun 1414 of the present invention who makes is added in appropriate deionized water with finish, be uniformly mixed, make the finish water liquid of active ingredient mass concentration 1%, in the water-bath of 40 DEG C of left and right, stir.To put into this finish water liquid without oily Kevlar29 fiber and soak 4 minutes, and dry, in baking oven, 100 DEG C are dried 6 hours, make test fiber sample.Test data sees the following form.
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Kevlar29 fiber volume fraction resistance, Ω cm | 6.3×10 7 | 7.1×10 7 | 6.8×10 7 |
| Oil applying rate, % | 0.7 | 0.7 | 0.7 |
Embodiment 2
Take: (Z)-7 kilograms of 9-octadecenic acid-dodecyl esters; Two (the 2-amino-benzene oxygen)-ethane-N of 1,2-, N, N`, 1 kilogram of N`-tetraacethyl tetrasodium salt; 1 kilogram of dihydrogen phosphoric acid tridecyl ester; 2 kilograms, potassium chloride; 3 kilograms of the product of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane, are uniformly mixed, and can make Fanglun 1414's finish of the present invention.
Embodiment 3
Take: (Z)-5 kilograms of 9-octadecenic acid-dodecyl esters; Two (the 2-amino-benzene oxygen)-ethane-N of 1,2-, N, N`, 3 kilograms of N`-tetraacethyl tetrasodium salts; 3 kilograms of dihydrogen phosphoric acid tridecyl esters; 4 kilograms, potassium chloride; 1 kilogram of the product of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane, is uniformly mixed, and can make Fanglun 1414's finish of the present invention.
Claims (1)
1. Fanglun 1414's finish, is characterized in that, is made up of following raw materials in parts by weight:
(Z)-9-octadecenic acid-dodecyl ester 50-70 part;
Two (the 2-amino-benzene oxygen)-ethane-N of 1,2-, N, N`, N`-tetraacethyl tetrasodium salt 10-30 part;
Dihydrogen phosphoric acid tridecyl ester 10-30 part;
Potassium chloride 20-40 part;
Product 10-30 part of coconut fatty acid and two polyethyene diamines, soya bean fatty acid ethoxylate, quaternized chloromethane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310028387.7A CN103046322B (en) | 2013-01-25 | 2013-01-25 | Oil solution for poly-p-phenylene terephthamide fibers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310028387.7A CN103046322B (en) | 2013-01-25 | 2013-01-25 | Oil solution for poly-p-phenylene terephthamide fibers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103046322A CN103046322A (en) | 2013-04-17 |
| CN103046322B true CN103046322B (en) | 2014-08-27 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310028387.7A Active CN103046322B (en) | 2013-01-25 | 2013-01-25 | Oil solution for poly-p-phenylene terephthamide fibers |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104947424A (en) * | 2015-07-20 | 2015-09-30 | 中蓝晨光化工研究设计院有限公司 | Aramid fiber oiling agent |
| CN105401417A (en) * | 2015-12-30 | 2016-03-16 | 王璐 | Heatproof oil for textile fibers |
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| CN1361326A (en) * | 2000-12-26 | 2002-07-31 | 上海石油化工股份有限公司 | Short-stable Dacron oil solution suitable for high-speed spinning |
| CN102321975A (en) * | 2011-07-26 | 2012-01-18 | 苏州晟德竹科技发展有限公司 | Oil agent for chopped polyester fiber |
| CN102373619A (en) * | 2011-07-26 | 2012-03-14 | 苏州晟德竹科技发展有限公司 | Terylene short fiber oil agent |
| CN102400355A (en) * | 2010-09-14 | 2012-04-04 | 殷兰芳 | Vinylon spinning oil |
| CN102400352A (en) * | 2010-09-13 | 2012-04-04 | 曹德如 | Chinlon oiling agent for braided silk |
| CN102400314A (en) * | 2010-09-13 | 2012-04-04 | 王琳 | Chinlon filament winding oil |
| CN102535158A (en) * | 2010-12-20 | 2012-07-04 | 中国石油化工股份有限公司 | Filament oil agent for poly-p-phenylene telephthalamide |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01246471A (en) * | 1988-03-23 | 1989-10-02 | Kao Corp | Lubricant for treatment of thermoplastic synthetic fiber |
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2013
- 2013-01-25 CN CN201310028387.7A patent/CN103046322B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1361325A (en) * | 2000-12-26 | 2002-07-31 | 上海石油化工股份有限公司 | Short-staple Dacron oil solution for great-capacity high-speed spinning |
| CN1361323A (en) * | 2000-12-26 | 2002-07-31 | 上海石油化工股份有限公司 | Short-staple Dacron oil solution suitable for great-capacity high-speed spinning |
| CN1361326A (en) * | 2000-12-26 | 2002-07-31 | 上海石油化工股份有限公司 | Short-stable Dacron oil solution suitable for high-speed spinning |
| CN102400352A (en) * | 2010-09-13 | 2012-04-04 | 曹德如 | Chinlon oiling agent for braided silk |
| CN102400314A (en) * | 2010-09-13 | 2012-04-04 | 王琳 | Chinlon filament winding oil |
| CN102400355A (en) * | 2010-09-14 | 2012-04-04 | 殷兰芳 | Vinylon spinning oil |
| CN102535158A (en) * | 2010-12-20 | 2012-07-04 | 中国石油化工股份有限公司 | Filament oil agent for poly-p-phenylene telephthalamide |
| CN102321975A (en) * | 2011-07-26 | 2012-01-18 | 苏州晟德竹科技发展有限公司 | Oil agent for chopped polyester fiber |
| CN102373619A (en) * | 2011-07-26 | 2012-03-14 | 苏州晟德竹科技发展有限公司 | Terylene short fiber oil agent |
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Effective date of registration: 20181018 Address after: 215228 217, 23 building, 1188 west two ring road, Shengze Town, Wujiang District, Suzhou, Jiangsu. Patentee after: Suzhou Hua longitudinal textile Mstar Technology Ltd Address before: 201111 room 271, thirtieth building, 280 Shuguang Road, Minhang District, Shanghai. Patentee before: Shanghai Qiucheng New Material Technology Co., Ltd. |
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Effective date of registration: 20181113 Address after: 215228 No. 1188 west two ring road, Shengze Town, Wujiang District, Suzhou, Jiangsu. Patentee after: Suzhou Shengze science and Technology Pioneer Park Development Co., Ltd. Address before: 215228 217, 23 building, 1188 west two ring road, Shengze Town, Wujiang District, Suzhou, Jiangsu. Patentee before: Suzhou Hua longitudinal textile Mstar Technology Ltd |