CN103668951A - Fabric flame-retardant finishing agent and preparation method thereof - Google Patents
Fabric flame-retardant finishing agent and preparation method thereof Download PDFInfo
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- CN103668951A CN103668951A CN201310624202.9A CN201310624202A CN103668951A CN 103668951 A CN103668951 A CN 103668951A CN 201310624202 A CN201310624202 A CN 201310624202A CN 103668951 A CN103668951 A CN 103668951A
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- retardant finishing
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 37
- 239000003063 flame retardant Substances 0.000 title claims abstract description 32
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000004744 fabric Substances 0.000 title abstract description 11
- 239000004753 textile Substances 0.000 claims abstract description 29
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 18
- -1 Sucrose fatty acid ester Chemical class 0.000 claims abstract description 12
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004327 boric acid Substances 0.000 claims abstract description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 9
- 239000000194 fatty acid Substances 0.000 claims abstract description 9
- 229930195729 fatty acid Natural products 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 7
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 claims abstract description 6
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229930006000 Sucrose Natural products 0.000 claims abstract description 4
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 9
- MPNORNXGQNTTLT-UHFFFAOYSA-N 2-[diethoxy(3-methylpentan-3-yloxy)silyl]ethylphosphonic acid Chemical class OP(=O)(O)CC[Si](OCC)(OCC)OC(C)(CC)CC MPNORNXGQNTTLT-UHFFFAOYSA-N 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 8
- 229920002907 Guar gum Polymers 0.000 claims description 6
- 239000000665 guar gum Substances 0.000 claims description 6
- 229960002154 guar gum Drugs 0.000 claims description 6
- 235000010417 guar gum Nutrition 0.000 claims description 6
- 150000002171 ethylene diamines Chemical class 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- 239000001211 (E)-4-phenylbut-3-en-2-one Substances 0.000 claims description 4
- 229930008407 benzylideneacetone Natural products 0.000 claims description 4
- BWHOZHOGCMHOBV-BQYQJAHWSA-N trans-benzylideneacetone Chemical group CC(=O)\C=C\C1=CC=CC=C1 BWHOZHOGCMHOBV-BQYQJAHWSA-N 0.000 claims description 4
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 3
- 239000001593 sorbitan monooleate Substances 0.000 claims description 3
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 3
- 229960004793 sucrose Drugs 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 2
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical group [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 abstract description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 abstract 1
- VZGGORYUNHMESL-UHFFFAOYSA-N 1-diethylphosphorylethoxy-diethoxy-ethylsilane Chemical compound C(C)P(=O)(CC)C(C)O[Si](OCC)(OCC)CC VZGGORYUNHMESL-UHFFFAOYSA-N 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000005720 sucrose Substances 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- BWHOZHOGCMHOBV-UHFFFAOYSA-N benzylideneacetone Chemical class CC(=O)C=CC1=CC=CC=C1 BWHOZHOGCMHOBV-UHFFFAOYSA-N 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
Abstract
The invention relates to a fabric flame-retardant finishing agent and a preparation method thereof, belonging to the technical field of a textile assistant. The finishing agent contains the following ingredients in part by weight: 6-10 parts of boric acid 3 (2, 3-2 bromide) propyl ester, 5-8 parts of N, N'2 (2-thio-5, 5-dimethyl-1,3,2-phospho cyclohexyl) ethylenediamine, 3-6 parts of Diethyl phosphoryl ethyl triethoxy silane, 12-15 parts of sorbitan mo-nooleate, 7-9 parts of Sucrose fatty acid ester, 1-3 parts of a fixing agent, 0.5-1 part of a thickener and 100-130 parts of deionized water. The adopted flame retardant is a halogen-free flame retardant which is safe and environment-friendly. A fabric finished by the fabric flame-retardant finishing agent has a good flame-retardant effect and can prevent molten drops. The preparation method is simple and is easy for popularization and application.
Description
Technical field
The invention belongs to textile auxiliary technical field, be specifically related to a kind of textile flame-retardant finishing agent and preparation method thereof.
Background technology
Along with social progress, the development of urban construction, all kinds of civilian and consumption figures technical textile increase difficulty rapidly, and in especially various indoor, cabins, paving is adornd fabric, as the demand of curtain, carpet, bedding etc. grows with each passing day.But meanwhile, the fire being caused by textiles also constantly increases, and has caused huge loss.
Current existing textile flame-retardant finishing agent major part is Halogen antiflaming finishing agent, although their good flame retardation effect, addition is few, performance impact to material is less, but the amount of being fuming is large, the hydrogen halide discharging has corrosivity, and can produce poisonous many bromos of carcinogen benzo evil English and PBDF, affects human homergy.Therefore how overcoming the deficiencies in the prior art is problems that current textile auxiliary technical field is needed solution badly.
Summary of the invention
The object of the invention is, in order to solve the deficiencies in the prior art, provides a kind of textile flame-retardant finishing agent and preparation method thereof, and the fabrics flame resistance of using this finishing agent to arrange is effective, and preparation technology is simple.
The technical solution used in the present invention is as follows:
A kind of textile flame-retardant finishing agent, comprise the following component according to parts by weight meter: boric acid three (2,3-dibromo) 6 ~ 10 parts of propyl ester, N, N'-bis-(2-sulfo--5,5-dimethyl-1,3,2-dioxy phosphorus heterocycle cyclohexyl) 5 ~ 8 parts of ethylenediamines, 3 ~ 6 parts of diethyl phosphonoethyl triethoxysilanes, 12 ~ 15 parts of sorbitan monooleates, 7 ~ 9 parts of fatty acid cane sugar esters, 1 ~ 3 part of sticking agent, 0.5 ~ 1 part of thickener, 100 ~ 130 parts of deionized waters.
Further preferably described sticking agent is benzylideneacetone.
Further preferably described thickener is guar gum.
The preparation method of above-mentioned textile flame-retardant finishing agent joins sorbitan monooleate and fatty acid cane sugar ester in deionized water, stirring at low speed is to after mixing, add wherein again boric acid three (2,3-dibromo) propyl ester, N, N'-bis-(2-sulfo--5,5-dimethyl-1,3,2-dioxy phosphorus heterocycle cyclohexyl) ethylenediamine and diethyl phosphonoethyl triethoxysilane, stirring at low speed is to mixing, finally add sticking agent and thickener, high-speed stirred, to after mixing, obtains textile flame-retardant finishing agent of the present invention.
Further preferably the mixing speed of described high-speed stirred is 1200 ~ 1600r/min.
Further preferably the mixing speed of described stirring at low speed is 40 ~ 60r/min.
compared with prior art, its beneficial effect is in the present invention:(1) fire retardant adopting in product of the present invention is halogen-free flame retardants, and safety is environmentally friendly; (2) adopt the fabrics flame resistance of Product organization of the present invention effective, and can prevent molten drop; (3) product preparation method of the present invention is simple, is easy to apply.
Specific embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
A kind of textile flame-retardant finishing agent, comprise the following component according to parts by weight meter: boric acid three (2,3-dibromo) 6 parts of propyl ester, N, N'-bis-(2-sulfo--5,5-dimethyl-1,3,2-dioxy phosphorus heterocycle cyclohexyl) 5 parts of ethylenediamines, 3 parts of diethyl phosphonoethyl triethoxysilanes, 12 parts of sorbitan monooleates, 7 parts of fatty acid cane sugar esters, 1 part of benzylideneacetone, 0.5 part of guar gum, 100 parts of deionized waters.
The preparation method of the textile flame-retardant finishing agent of the present embodiment joins sorbitan monooleate and fatty acid cane sugar ester in deionized water, stirring at low speed is to after mixing, add wherein again boric acid three (2,3-dibromo) propyl ester, N, N'-bis-(2-sulfo--5,5-dimethyl-1,3,2-dioxy phosphorus heterocycle cyclohexyl) ethylenediamine and diethyl phosphonoethyl triethoxysilane, stirring at low speed is to mixing, finally add benzylideneacetone and guar gum, high-speed stirred, to after mixing, obtains the textile flame-retardant finishing agent of the present embodiment.Wherein, the mixing speed of high-speed stirred is 1200 ~ 1600r/min, and the mixing speed of stirring at low speed is 40 ~ 60r/min.
Embodiment 2
A kind of textile flame-retardant finishing agent, comprise the following component according to parts by weight meter: boric acid three (2,3-dibromo) 10 parts of propyl ester, N, N'-bis-(2-sulfo--5,5-dimethyl-1,3,2-dioxy phosphorus heterocycle cyclohexyl) 8 parts of ethylenediamines, 6 parts of diethyl phosphonoethyl triethoxysilanes, 15 parts of sorbitan monooleates, 9 parts of fatty acid cane sugar esters, 3 parts of benzylideneacetones, 1 part of guar gum, 130 parts of deionized waters.
The preparation method of the present embodiment textile flame-retardant finishing agent is identical with the preparation method of embodiment 1 textile flame-retardant finishing agent.
Embodiment 3
A kind of textile flame-retardant finishing agent, comprise the following component according to parts by weight meter: boric acid three (2,3-dibromo) 8 parts of propyl ester, N, N'-bis-(2-sulfo--5,5-dimethyl-1,3,2-dioxy phosphorus heterocycle cyclohexyl) 7 parts of ethylenediamines, 4 parts of diethyl phosphonoethyl triethoxysilanes, 13 parts of sorbitan monooleates, 8 parts of fatty acid cane sugar esters, 2 parts of benzylideneacetones, 0.7 part of guar gum, 120 parts of deionized waters.
The preparation method of the present embodiment textile flame-retardant finishing agent is identical with the preparation method of embodiment 1 textile flame-retardant finishing agent.
The resulting textile flame-retardant finishing agent of the embodiment of the present invention 1 ~ 3 is mixed with to the dressing liquid that concentration is 40 grams per liters, adopt the NaOH solution that mass concentration is 30% that dressing liquid pH is adjusted to 7-8, then by Quality Pure Cotton Yarn Production card (128 * 60,20s * 16s) be placed in after dressing liquid infiltration, two soak two rolls, fried remaining rate is 80%, finally takes out fabric and at 120 ℃, dries, shapes, and obtains having the fabric of fire resistance.
The resulting fabric with fire resistance is tested, and test result is as shown in table 1.
Table 1 test result
| ? | After flame time/s | Time/s glows | Char length/cm | Cloth cover formaldehyde content/(mg/kg) | CIE whiteness |
| Embodiment 1 | 0 | 0 | 12 | 0 | 74.2 |
| Embodiment 2 | 0 | 0 | 15 | 0 | 74 |
| Embodiment 3 | 0 | 0 | 10 | 0 | 75.5 |
| Do not arrange | After-flame | After-flame | After-flame | 0 | 76 |
Claims (6)
1. a textile flame-retardant finishing agent, it is characterized in that comprising the following component according to parts by weight meter: boric acid three (2,3-dibromo) 6 ~ 10 parts of propyl ester, N, N'-bis-(2-sulfo--5,5-dimethyl-1,3,2-dioxy phosphorus heterocycle cyclohexyl) 5 ~ 8 parts of ethylenediamines, 3 ~ 6 parts of diethyl phosphonoethyl triethoxysilanes, 12 ~ 15 parts of sorbitan monooleates, 7 ~ 9 parts of fatty acid cane sugar esters, 1 ~ 3 part of sticking agent, 0.5 ~ 1 part of thickener, 100 ~ 130 parts of deionized waters.
2. textile flame-retardant finishing agent according to claim 1, is characterized in that described sticking agent is benzylideneacetone.
3. textile flame-retardant finishing agent according to claim 1, is characterized in that described thickener is guar gum.
4. the preparation method of textile flame-retardant finishing agent as claimed in claim 1, it is characterized in that sorbitan monooleate and fatty acid cane sugar ester to join in deionized water, stirring at low speed is to after mixing, add wherein again boric acid three (2,3-dibromo) propyl ester, N, N'-bis-(2-sulfo--5,5-dimethyl-1,3,2-dioxy phosphorus heterocycle cyclohexyl) ethylenediamine and diethyl phosphonoethyl triethoxysilane, stirring at low speed, to mixing, finally adds sticking agent and thickener, high-speed stirred, to after mixing, obtains textile flame-retardant finishing agent of the present invention.
5. the preparation method of textile flame-retardant finishing agent according to claim 4, is characterized in that the mixing speed of described high-speed stirred is 1200 ~ 1600r/min.
6. the preparation method of textile flame-retardant finishing agent according to claim 4, is characterized in that the mixing speed of described stirring at low speed is 40 ~ 60r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310624202.9A CN103668951B (en) | 2013-11-29 | 2013-11-29 | Fabric flame-retardant finishing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310624202.9A CN103668951B (en) | 2013-11-29 | 2013-11-29 | Fabric flame-retardant finishing agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103668951A true CN103668951A (en) | 2014-03-26 |
| CN103668951B CN103668951B (en) | 2015-07-08 |
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| CN201310624202.9A Expired - Fee Related CN103668951B (en) | 2013-11-29 | 2013-11-29 | Fabric flame-retardant finishing agent and preparation method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104294601A (en) * | 2014-10-20 | 2015-01-21 | 苏州富美纺织科技有限公司 | Flame-retardant finishing agent for washable fabrics |
| CN104313885A (en) * | 2014-10-20 | 2015-01-28 | 苏州富美纺织科技有限公司 | Flame-retardant finishing agent for fabric |
| CN104862956A (en) * | 2015-06-15 | 2015-08-26 | 湖州厉华妤婕联合纺织有限公司 | Novel flame retardant finishing agent for fabric |
| CN105274838A (en) * | 2015-12-07 | 2016-01-27 | 常熟市华谊织造有限公司 | After finishing technology for coral fleece fabric |
| CN105350318A (en) * | 2015-12-14 | 2016-02-24 | 苏州伊甸园苹果服饰有限公司 | Finishing technology of cotton cloth fabric |
| CN105369595A (en) * | 2015-11-27 | 2016-03-02 | 常熟市通惠织造有限公司 | Production process of velcro cloth |
| CN105484040A (en) * | 2015-12-18 | 2016-04-13 | 成路凯尔服装（苏州）有限公司 | Preparation method for fabric flame-retardant finishing liquor |
| CN105544216A (en) * | 2015-12-14 | 2016-05-04 | 苏州伊甸园苹果服饰有限公司 | Finishing process of silk-like fabric |
| CN105906779A (en) * | 2016-04-19 | 2016-08-31 | 滁州环球聚氨酯科技有限公司 | High-strength flame-retardant modified polyurethane composite material |
| CN106337278A (en) * | 2016-08-25 | 2017-01-18 | 代长华 | Flame-retardant stiff finishing agent and preparation method thereof |
| CN106592202A (en) * | 2016-12-15 | 2017-04-26 | 吴江市北厍盛源纺织品助剂厂 | Antifouling flame-retardant finishing agent special for textile and preparation method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104294601A (en) * | 2014-10-20 | 2015-01-21 | 苏州富美纺织科技有限公司 | Flame-retardant finishing agent for washable fabrics |
| CN104313885A (en) * | 2014-10-20 | 2015-01-28 | 苏州富美纺织科技有限公司 | Flame-retardant finishing agent for fabric |
| CN104862956A (en) * | 2015-06-15 | 2015-08-26 | 湖州厉华妤婕联合纺织有限公司 | Novel flame retardant finishing agent for fabric |
| CN105369595A (en) * | 2015-11-27 | 2016-03-02 | 常熟市通惠织造有限公司 | Production process of velcro cloth |
| CN105274838A (en) * | 2015-12-07 | 2016-01-27 | 常熟市华谊织造有限公司 | After finishing technology for coral fleece fabric |
| CN105350318A (en) * | 2015-12-14 | 2016-02-24 | 苏州伊甸园苹果服饰有限公司 | Finishing technology of cotton cloth fabric |
| CN105544216A (en) * | 2015-12-14 | 2016-05-04 | 苏州伊甸园苹果服饰有限公司 | Finishing process of silk-like fabric |
| CN105484040A (en) * | 2015-12-18 | 2016-04-13 | 成路凯尔服装（苏州）有限公司 | Preparation method for fabric flame-retardant finishing liquor |
| CN105906779A (en) * | 2016-04-19 | 2016-08-31 | 滁州环球聚氨酯科技有限公司 | High-strength flame-retardant modified polyurethane composite material |
| CN106337278A (en) * | 2016-08-25 | 2017-01-18 | 代长华 | Flame-retardant stiff finishing agent and preparation method thereof |
| CN106592202A (en) * | 2016-12-15 | 2017-04-26 | 吴江市北厍盛源纺织品助剂厂 | Antifouling flame-retardant finishing agent special for textile and preparation method thereof |
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| CN103668951B (en) | 2015-07-08 |
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Effective date of registration: 20150610 Address after: 325600, 39-40, Hung Tung Road, Hongqiao Town, Yueqing City, Zhejiang, Wenzhou Applicant after: Wan Xiaoyi Address before: 226300 Industrial Park, Xianfeng Town, Nantong, Jiangsu, Tongzhou District Applicant before: Jiangsu ZhongXin Resources Group Co., Ltd. |
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Effective date of registration: 20160524 Address after: 226199 Jiangsu city of Nantong Province Haimen Haimen Town Road No. 503 in 3. Patentee after: Jiangsu holiday Textile Technology Co Ltd Address before: 325600, 39-40, Hung Tung Road, Hongqiao Town, Yueqing City, Zhejiang, Wenzhou Patentee before: Wan Xiaoyi |
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